KR20200010312A - 변형 가능한 준고체 전극 재료를 갖는 알칼리 금속 전지 - Google Patents

변형 가능한 준고체 전극 재료를 갖는 알칼리 금속 전지 Download PDF

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Publication number: KR20200010312A
Authority: KR; South Korea
Prior art keywords: lithium; sodium; alkali metal; cell; active material
Prior art date: 2017-05-24

Application number

KR1020197036580A

Other languages

English (en)

Korean (ko)

Inventor

아루나 자하무

보르 제트. 장

Original Assignee

나노텍 인스트러먼츠, 인코포레이티드

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2017-05-24

Filing date

2018-03-13

Publication date

2020-01-30

2017-05-24 Priority claimed from US15/604,606 external-priority patent/US9960451B1/en

2017-05-24 Priority claimed from US15/604,607 external-priority patent/US10243217B2/en

2018-03-13 Application filed by 나노텍 인스트러먼츠, 인코포레이티드 filed Critical 나노텍 인스트러먼츠, 인코포레이티드

2020-01-30 Publication of KR20200010312A publication Critical patent/KR20200010312A/ko

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229910052783 alkali metal Inorganic materials 0.000 title claims abstract description 115
239000007772 electrode material Substances 0.000 title claims abstract description 46
150000001340 alkali metals Chemical class 0.000 title description 5
239000003792 electrolyte Substances 0.000 claims abstract description 182
238000000034 method Methods 0.000 claims abstract description 118
239000011149 active material Substances 0.000 claims abstract description 79
239000002482 conductive additive Substances 0.000 claims abstract description 42
239000007787 solid Substances 0.000 claims abstract description 32
230000000903 blocking effect Effects 0.000 claims abstract description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 319
239000011734 sodium Substances 0.000 claims description 241
229910052744 lithium Inorganic materials 0.000 claims description 190
229910021389 graphene Inorganic materials 0.000 claims description 165
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 145
239000002904 solvent Substances 0.000 claims description 126
229910052708 sodium Inorganic materials 0.000 claims description 101
239000002245 particle Substances 0.000 claims description 93
239000006182 cathode active material Substances 0.000 claims description 88
229910001416 lithium ion Inorganic materials 0.000 claims description 87
-1 or Cd Substances 0.000 claims description 86
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 85
229910001415 sodium ion Inorganic materials 0.000 claims description 81
239000006183 anode active material Substances 0.000 claims description 80
239000007788 liquid Substances 0.000 claims description 80
150000001875 compounds Chemical class 0.000 claims description 78
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 76
229910002804 graphite Inorganic materials 0.000 claims description 75
239000010439 graphite Substances 0.000 claims description 74
239000000203 mixture Substances 0.000 claims description 69
150000003839 salts Chemical class 0.000 claims description 65
229910052751 metal Inorganic materials 0.000 claims description 63
239000002184 metal Substances 0.000 claims description 63
239000010936 titanium Substances 0.000 claims description 57
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 56
HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 56
239000000463 material Substances 0.000 claims description 50
229910052723 transition metal Inorganic materials 0.000 claims description 47
229910052799 carbon Inorganic materials 0.000 claims description 46
150000003568 thioethers Chemical class 0.000 claims description 46
239000011572 manganese Substances 0.000 claims description 44
159000000000 sodium salts Chemical class 0.000 claims description 40
150000003624 transition metals Chemical class 0.000 claims description 40
239000002608 ionic liquid Substances 0.000 claims description 37
150000002500 ions Chemical class 0.000 claims description 35
IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 35
229910052759 nickel Inorganic materials 0.000 claims description 34
229910052797 bismuth Inorganic materials 0.000 claims description 33
229910010272 inorganic material Inorganic materials 0.000 claims description 33
239000011147 inorganic material Substances 0.000 claims description 33
229910003002 lithium salt Inorganic materials 0.000 claims description 33
229920000642 polymer Polymers 0.000 claims description 33
229910052719 titanium Inorganic materials 0.000 claims description 33
159000000002 lithium salts Chemical class 0.000 claims description 29
230000008569 process Effects 0.000 claims description 29
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 28
229910052718 tin Inorganic materials 0.000 claims description 28
229910052787 antimony Inorganic materials 0.000 claims description 26
238000003780 insertion Methods 0.000 claims description 26
230000037431 insertion Effects 0.000 claims description 26
229910052710 silicon Inorganic materials 0.000 claims description 26
KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims description 25
229910052782 aluminium Inorganic materials 0.000 claims description 25
239000002041 carbon nanotube Substances 0.000 claims description 24
229910052732 germanium Inorganic materials 0.000 claims description 24
229910052748 manganese Inorganic materials 0.000 claims description 24
229910021393 carbon nanotube Inorganic materials 0.000 claims description 23
238000009830 intercalation Methods 0.000 claims description 23
239000000725 suspension Substances 0.000 claims description 23
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 22
239000002134 carbon nanofiber Substances 0.000 claims description 21
239000010941 cobalt Substances 0.000 claims description 21
229910017052 cobalt Inorganic materials 0.000 claims description 21
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 21
239000000835 fiber Substances 0.000 claims description 21
229910044991 metal oxide Inorganic materials 0.000 claims description 21
150000004706 metal oxides Chemical class 0.000 claims description 21
229910052742 iron Inorganic materials 0.000 claims description 20
235000021317 phosphate Nutrition 0.000 claims description 20
229910052725 zinc Inorganic materials 0.000 claims description 20
239000011701 zinc Substances 0.000 claims description 20
239000002931 mesocarbon microbead Substances 0.000 claims description 19
229910052793 cadmium Inorganic materials 0.000 claims description 18
229910001463 metal phosphate Inorganic materials 0.000 claims description 18
150000004772 tellurides Chemical class 0.000 claims description 18
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 17
238000004519 manufacturing process Methods 0.000 claims description 17
FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 claims description 16
239000003990 capacitor Substances 0.000 claims description 16
238000000576 coating method Methods 0.000 claims description 16
229910052745 lead Inorganic materials 0.000 claims description 16
229910021382 natural graphite Inorganic materials 0.000 claims description 16
239000003960 organic solvent Substances 0.000 claims description 16
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 15
229910052757 nitrogen Inorganic materials 0.000 claims description 15
229910045601 alloy Inorganic materials 0.000 claims description 14
239000000956 alloy Substances 0.000 claims description 14
229910021385 hard carbon Inorganic materials 0.000 claims description 14
229920005989 resin Polymers 0.000 claims description 14
239000011347 resin Substances 0.000 claims description 14
239000011669 selenium Substances 0.000 claims description 14
239000000126 substance Substances 0.000 claims description 14
229920000049 Carbon (fiber) Polymers 0.000 claims description 13
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 13
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 13
239000004917 carbon fiber Substances 0.000 claims description 13
239000011248 coating agent Substances 0.000 claims description 13
229910052735 hafnium Inorganic materials 0.000 claims description 13
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 13
229910052750 molybdenum Inorganic materials 0.000 claims description 13
239000011733 molybdenum Substances 0.000 claims description 13
239000002070 nanowire Substances 0.000 claims description 13
229910052758 niobium Inorganic materials 0.000 claims description 13
239000010955 niobium Substances 0.000 claims description 13
GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 13
239000010452 phosphate Substances 0.000 claims description 13
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 13
229910052715 tantalum Inorganic materials 0.000 claims description 13
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 13
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 13
229910052721 tungsten Inorganic materials 0.000 claims description 13
239000010937 tungsten Substances 0.000 claims description 13
229910052726 zirconium Inorganic materials 0.000 claims description 13
229910018871 CoO 2 Inorganic materials 0.000 claims description 12
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 12
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 12
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 12
229910000625 lithium cobalt oxide Inorganic materials 0.000 claims description 12
GELKBWJHTRAYNV-UHFFFAOYSA-K lithium iron phosphate Chemical compound [Li+].[Fe+2].[O-]P([O-])([O-])=O GELKBWJHTRAYNV-UHFFFAOYSA-K 0.000 claims description 12
BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 claims description 12
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 12
150000001247 metal acetylides Chemical class 0.000 claims description 12
150000004767 nitrides Chemical class 0.000 claims description 12
XSOKHXFFCGXDJZ-UHFFFAOYSA-N telluride(2-) Chemical compound [Te-2] XSOKHXFFCGXDJZ-UHFFFAOYSA-N 0.000 claims description 12
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 11
RLTFLELMPUMVEH-UHFFFAOYSA-N [Li+].[O--].[O--].[O--].[V+5] Chemical compound [Li+].[O--].[O--].[O--].[V+5] RLTFLELMPUMVEH-UHFFFAOYSA-N 0.000 claims description 11
229910021383 artificial graphite Inorganic materials 0.000 claims description 11
229910052731 fluorine Inorganic materials 0.000 claims description 11
229910000686 lithium vanadium oxide Inorganic materials 0.000 claims description 11
238000002156 mixing Methods 0.000 claims description 11
239000011331 needle coke Substances 0.000 claims description 11
CLYVDMAATCIVBF-UHFFFAOYSA-N pigment red 224 Chemical compound C=12C3=CC=C(C(OC4=O)=O)C2=C4C=CC=1C1=CC=C2C(=O)OC(=O)C4=CC=C3C1=C42 CLYVDMAATCIVBF-UHFFFAOYSA-N 0.000 claims description 11
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 10
XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 claims description 10
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 10
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 10
URIIGZKXFBNRAU-UHFFFAOYSA-N lithium;oxonickel Chemical compound [Li].[Ni]=O URIIGZKXFBNRAU-UHFFFAOYSA-N 0.000 claims description 10
229910003455 mixed metal oxide Inorganic materials 0.000 claims description 10
239000002074 nanoribbon Substances 0.000 claims description 10
229910052760 oxygen Inorganic materials 0.000 claims description 10
239000010703 silicon Substances 0.000 claims description 10
229910001935 vanadium oxide Inorganic materials 0.000 claims description 10
OXQYGVSMUGQPDF-UHFFFAOYSA-N 5-amino-1,4-dihydroxyanthracene-9,10-dione Chemical compound O=C1C2=C(O)C=CC(O)=C2C(=O)C2=C1C=CC=C2N OXQYGVSMUGQPDF-UHFFFAOYSA-N 0.000 claims description 9
229910052582 BN Inorganic materials 0.000 claims description 9
PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 9
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
239000006229 carbon black Substances 0.000 claims description 9
229910002102 lithium manganese oxide Inorganic materials 0.000 claims description 9
VLXXBCXTUVRROQ-UHFFFAOYSA-N lithium;oxido-oxo-(oxomanganiooxy)manganese Chemical compound [Li+].[O-][Mn](=O)O[Mn]=O VLXXBCXTUVRROQ-UHFFFAOYSA-N 0.000 claims description 9
AZQWKYJCGOJGHM-UHFFFAOYSA-N para-benzoquinone Natural products O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims description 9
OMEPJWROJCQMMU-UHFFFAOYSA-N selanylidenebismuth;selenium Chemical compound [Se].[Bi]=[Se].[Bi]=[Se] OMEPJWROJCQMMU-UHFFFAOYSA-N 0.000 claims description 9
MDCIYXHEPARHMN-UHFFFAOYSA-N 3,5,6,7,8,30-hexazaheptacyclo[20.8.0.02,11.04,9.012,21.014,19.024,29]triaconta-1(30),2,4(9),5,7,10,12,14,16,18,20,22,24,26,28-pentadecaene Chemical group N1=NN=C2C=C3C4=CC5=CC=CC=C5C=C4C4=CC5=CC=CC=C5N=C4C3=NC2=N1 MDCIYXHEPARHMN-UHFFFAOYSA-N 0.000 claims description 8
229910004341 Na1.5VOPO4F0.5 Inorganic materials 0.000 claims description 8
229910001373 Na3V2(PO4)2F3 Inorganic materials 0.000 claims description 8
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 8
YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims description 8
239000011651 chromium Substances 0.000 claims description 8
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 8
230000002687 intercalation Effects 0.000 claims description 8
229910000765 intermetallic Inorganic materials 0.000 claims description 8
229910001465 mixed metal phosphate Inorganic materials 0.000 claims description 8
239000002055 nanoplate Substances 0.000 claims description 8
235000011649 selenium Nutrition 0.000 claims description 8
229910021384 soft carbon Inorganic materials 0.000 claims description 8
229910052717 sulfur Inorganic materials 0.000 claims description 8
239000011593 sulfur Substances 0.000 claims description 8
JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 claims description 8
NLDYACGHTUPAQU-UHFFFAOYSA-N tetracyanoethylene Chemical group N#CC(C#N)=C(C#N)C#N NLDYACGHTUPAQU-UHFFFAOYSA-N 0.000 claims description 8
YWJVFBOUPMWANA-UHFFFAOYSA-H [Li+].[V+5].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O Chemical compound [Li+].[V+5].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O YWJVFBOUPMWANA-UHFFFAOYSA-H 0.000 claims description 7
ILXAVRFGLBYNEJ-UHFFFAOYSA-K lithium;manganese(2+);phosphate Chemical compound [Li+].[Mn+2].[O-]P([O-])([O-])=O ILXAVRFGLBYNEJ-UHFFFAOYSA-K 0.000 claims description 7
239000012528 membrane Substances 0.000 claims description 7
150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 7
239000005077 polysulfide Substances 0.000 claims description 7
229920001021 polysulfide Polymers 0.000 claims description 7
150000008117 polysulfides Polymers 0.000 claims description 7
150000003464 sulfur compounds Chemical class 0.000 claims description 7
PGTILBWXJWTDMY-UHFFFAOYSA-N 1-(9,10-dioxoanthracen-1-yl)sulfanylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2SC1=C2C(=O)C3=CC=CC=C3C(=O)C2=CC=C1 PGTILBWXJWTDMY-UHFFFAOYSA-N 0.000 claims description 6
229910013275 LiMPO Inorganic materials 0.000 claims description 6
150000001447 alkali salts Chemical class 0.000 claims description 6
RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 claims description 6
239000011368 organic material Substances 0.000 claims description 6
229910052711 selenium Inorganic materials 0.000 claims description 6
125000003748 selenium group Chemical group *[Se]* 0.000 claims description 6
229910000314 transition metal oxide Inorganic materials 0.000 claims description 6
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 5
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 5
229920000997 Graphane Polymers 0.000 claims description 5
125000003118 aryl group Chemical group 0.000 claims description 5
239000010949 copper Substances 0.000 claims description 5
238000002425 crystallisation Methods 0.000 claims description 5
230000008025 crystallization Effects 0.000 claims description 5
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 5
239000002135 nanosheet Substances 0.000 claims description 5
230000037361 pathway Effects 0.000 claims description 5
DGQOCLATAPFASR-UHFFFAOYSA-N tetrahydroxy-1,4-benzoquinone Chemical class OC1=C(O)C(=O)C(O)=C(O)C1=O DGQOCLATAPFASR-UHFFFAOYSA-N 0.000 claims description 5
UDTSPKADQGPZFS-SOFGYWHQSA-N (5e)-5-benzylideneimidazolidine-2,4-dione Chemical compound N1C(=O)NC(=O)\C1=C/C1=CC=CC=C1 UDTSPKADQGPZFS-SOFGYWHQSA-N 0.000 claims description 4
RXFDPQXLULKAFY-UHFFFAOYSA-N 1,2,4,5-tetrakis(propylsulfanyl)benzene Chemical compound CCCSc1cc(SCCC)c(SCCC)cc1SCCC RXFDPQXLULKAFY-UHFFFAOYSA-N 0.000 claims description 4
DXCZBBFNFURETH-UHFFFAOYSA-N 1,4-dipropylpiperazine-2,3,5,6-tetrone Chemical compound CCCN1C(=O)C(=O)N(CCC)C(=O)C1=O DXCZBBFNFURETH-UHFFFAOYSA-N 0.000 claims description 4
UDTSPKADQGPZFS-UHFFFAOYSA-N 1/7/3775 Natural products N1C(=O)NC(=O)C1=CC1=CC=CC=C1 UDTSPKADQGPZFS-UHFFFAOYSA-N 0.000 claims description 4
TXROZCSFVVIBFI-UHFFFAOYSA-N 2,3,6,7,10,11-hexamethoxytriphenylene Chemical group C12=CC(OC)=C(OC)C=C2C2=CC(OC)=C(OC)C=C2C2=C1C=C(OC)C(OC)=C2 TXROZCSFVVIBFI-UHFFFAOYSA-N 0.000 claims description 4
KMHSUNDEGHRBNV-UHFFFAOYSA-N 2,4-dichloropyrimidine-5-carbonitrile Chemical compound ClC1=NC=C(C#N)C(Cl)=N1 KMHSUNDEGHRBNV-UHFFFAOYSA-N 0.000 claims description 4
PGBFPRKWAGYWOP-UHFFFAOYSA-N 2-[4-(1,3-dithiolan-2-yl)phenyl]-1,3-dithiolane Chemical compound S1CCSC1C1=CC=C(C2SCCS2)C=C1 PGBFPRKWAGYWOP-UHFFFAOYSA-N 0.000 claims description 4
RKBPDPLCHXWHRQ-UHFFFAOYSA-N 2-phenyl-1,3-dithiolane Chemical compound S1CCSC1C1=CC=CC=C1 RKBPDPLCHXWHRQ-UHFFFAOYSA-N 0.000 claims description 4
YFCSASDLEBELEU-UHFFFAOYSA-N 3,4,5,6,9,10-hexazatetracyclo[12.4.0.02,7.08,13]octadeca-1(18),2(7),3,5,8(13),9,11,14,16-nonaene-11,12,15,16,17,18-hexacarbonitrile Chemical compound N#CC1=C(C#N)C(C#N)=C2C3=C(C#N)C(C#N)=NN=C3C3=NN=NN=C3C2=C1C#N YFCSASDLEBELEU-UHFFFAOYSA-N 0.000 claims description 4
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims description 4
PMOWGTZPOVDCDO-UHFFFAOYSA-N NC1=C2C(C3=C(CCC(=C3C(C2=CC=C1)=O)O)O)=O Chemical compound NC1=C2C(C3=C(CCC(=C3C(C2=CC=C1)=O)O)O)=O PMOWGTZPOVDCDO-UHFFFAOYSA-N 0.000 claims description 4
229910021316 NaFe2Mn(PO4)3 Inorganic materials 0.000 claims description 4
229910015222 Ni1/3Mn1/3Co1/3O2 Inorganic materials 0.000 claims description 4
229910003266 NiCo Inorganic materials 0.000 claims description 4
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 4
229910010413 TiO 2 Inorganic materials 0.000 claims description 4
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
HGBJDVIOLUMVIS-UHFFFAOYSA-N [Co]=O.[Na] Chemical group [Co]=O.[Na] HGBJDVIOLUMVIS-UHFFFAOYSA-N 0.000 claims description 4
MSAGRFJHKIDOCC-UHFFFAOYSA-N [Li].N1C(=O)C(=O)C2=CC=CC=C12 Chemical compound [Li].N1C(=O)C(=O)C2=CC=CC=C12 MSAGRFJHKIDOCC-UHFFFAOYSA-N 0.000 claims description 4
FMLZGWFPVTXRBT-UHFFFAOYSA-N [Li].[C]=O Chemical compound [Li].[C]=O FMLZGWFPVTXRBT-UHFFFAOYSA-N 0.000 claims description 4
238000010521 absorption reaction Methods 0.000 claims description 4
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WDEQGLDWZMIMJM-UHFFFAOYSA-N benzyl 4-hydroxy-2-(hydroxymethyl)pyrrolidine-1-carboxylate Chemical compound OCC1CC(O)CN1C(=O)OCC1=CC=CC=C1 WDEQGLDWZMIMJM-UHFFFAOYSA-N 0.000 claims description 4
150000007942 carboxylates Chemical class 0.000 claims description 4
229910052804 chromium Inorganic materials 0.000 claims description 4
MPMSMUBQXQALQI-UHFFFAOYSA-N cobalt phthalocyanine Chemical compound [Co+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 MPMSMUBQXQALQI-UHFFFAOYSA-N 0.000 claims description 4
229920001940 conductive polymer Polymers 0.000 claims description 4
HQQKMOJOCZFMSV-UHFFFAOYSA-N dilithium phthalocyanine Chemical compound [Li+].[Li+].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 HQQKMOJOCZFMSV-UHFFFAOYSA-N 0.000 claims description 4
BFMYDTVEBKDAKJ-UHFFFAOYSA-L disodium;(2',7'-dibromo-3',6'-dioxido-3-oxospiro[2-benzofuran-1,9'-xanthene]-4'-yl)mercury;hydrate Chemical compound O.[Na+].[Na+].O1C(=O)C2=CC=CC=C2C21C1=CC(Br)=C([O-])C([Hg])=C1OC1=C2C=C(Br)C([O-])=C1 BFMYDTVEBKDAKJ-UHFFFAOYSA-L 0.000 claims description 4
RLIPRTIUFVAOLU-UHFFFAOYSA-N formaldehyde naphthalene-1,4,5,8-tetrol Chemical compound C=O.Oc1ccc(O)c2c(O)ccc(O)c12 RLIPRTIUFVAOLU-UHFFFAOYSA-N 0.000 claims description 4
229910001092 metal group alloy Inorganic materials 0.000 claims description 4
229910052976 metal sulfide Inorganic materials 0.000 claims description 4
GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical compound CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 claims description 4
239000002121 nanofiber Substances 0.000 claims description 4
YZOGOBWHTVNKGA-UHFFFAOYSA-N pentacene-5,7,12,14-tetrone Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3C(=O)C1=C2 YZOGOBWHTVNKGA-UHFFFAOYSA-N 0.000 claims description 4
239000002006 petroleum coke Substances 0.000 claims description 4
FQVOWPCGHLYSLB-UHFFFAOYSA-N pyrene-4,5,9,10-tetrone Chemical compound C12=C(C(C3=O)=O)C=CC=C2C(=O)C(=O)C2=C1C3=CC=C2 FQVOWPCGHLYSLB-UHFFFAOYSA-N 0.000 claims description 4
229910052709 silver Inorganic materials 0.000 claims description 4
239000004332 silver Substances 0.000 claims description 4
AWRQDLAZGAQUNZ-UHFFFAOYSA-K sodium;iron(2+);phosphate Chemical compound [Na+].[Fe+2].[O-]P([O-])([O-])=O AWRQDLAZGAQUNZ-UHFFFAOYSA-K 0.000 claims description 4
229930192474 thiophene Natural products 0.000 claims description 4
AYNNSCRYTDRFCP-UHFFFAOYSA-N triazene Chemical compound NN=N AYNNSCRYTDRFCP-UHFFFAOYSA-N 0.000 claims description 4
229910052720 vanadium Inorganic materials 0.000 claims description 4
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims description 4
229940005561 1,4-benzoquinone Drugs 0.000 claims description 3
YALAUFUASBIEEA-UHFFFAOYSA-N 1,4-diphenylpiperazine-2,3,5,6-tetrone Chemical compound O=C1C(=O)N(C=2C=CC=CC=2)C(=O)C(=O)N1C1=CC=CC=C1 YALAUFUASBIEEA-UHFFFAOYSA-N 0.000 claims description 3
229910011157 LiMBO Inorganic materials 0.000 claims description 3
229910015118 LiMO Inorganic materials 0.000 claims description 3
229910015868 MSiO Inorganic materials 0.000 claims description 3
229910019142 PO4 Inorganic materials 0.000 claims description 3
ZMVMBTZRIMAUPN-UHFFFAOYSA-H [Na+].[V+5].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O Chemical compound [Na+].[V+5].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O ZMVMBTZRIMAUPN-UHFFFAOYSA-H 0.000 claims description 3
IQQJSTNKDJGJPH-UHFFFAOYSA-N [Ni]=O.[Na] Chemical compound [Ni]=O.[Na] IQQJSTNKDJGJPH-UHFFFAOYSA-N 0.000 claims description 3
WSKOARFZINZCTI-UHFFFAOYSA-H [V+5].P(=O)([O-])([O-])[O-].[K+].P(=O)([O-])([O-])[O-] Chemical compound [V+5].P(=O)([O-])([O-])[O-].[K+].P(=O)([O-])([O-])[O-] WSKOARFZINZCTI-UHFFFAOYSA-H 0.000 claims description 3
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SMBQBQBNOXIFSF-UHFFFAOYSA-N dilithium Chemical compound [Li][Li] SMBQBQBNOXIFSF-UHFFFAOYSA-N 0.000 claims description 3
235000013490 limbo Nutrition 0.000 claims description 3
PRMHOXAMWFXGCO-UHFFFAOYSA-M molport-000-691-708 Chemical compound N1=C(C2=CC=CC=C2C2=NC=3C4=CC=CC=C4C(=N4)N=3)N2[Ga](Cl)N2C4=C(C=CC=C3)C3=C2N=C2C3=CC=CC=C3C1=N2 PRMHOXAMWFXGCO-UHFFFAOYSA-M 0.000 claims description 3
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AAGHWTGPJCVOMM-UHFFFAOYSA-K potassium manganese(2+) phosphate Chemical compound [K+].[Mn+2].[O-]P([O-])([O-])=O AAGHWTGPJCVOMM-UHFFFAOYSA-K 0.000 claims description 3
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IKULXUCKGDPJMZ-UHFFFAOYSA-N sodium manganese(2+) oxygen(2-) Chemical compound [O-2].[Mn+2].[Na+] IKULXUCKGDPJMZ-UHFFFAOYSA-N 0.000 claims description 3
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HEVWJXJIIXJVKU-UHFFFAOYSA-K sodium;manganese(2+);phosphate Chemical compound [Na+].[Mn+2].[O-]P([O-])([O-])=O HEVWJXJIIXJVKU-UHFFFAOYSA-K 0.000 claims description 3
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PCCVSPMFGIFTHU-UHFFFAOYSA-N tetracyanoquinodimethane Chemical compound N#CC(C#N)=C1C=CC(=C(C#N)C#N)C=C1 PCCVSPMFGIFTHU-UHFFFAOYSA-N 0.000 claims description 2
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KMKSVAGOBVUFRO-UHFFFAOYSA-N 1-nonylsulfanylnonane Chemical compound CCCCCCCCCSCCCCCCCCC KMKSVAGOBVUFRO-UHFFFAOYSA-N 0.000 claims 2
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VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims 2
AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims 2
LBAIJNRSTQHDMR-UHFFFAOYSA-N magnesium phthalocyanine Chemical compound [Mg].C12=CC=CC=C2C(N=C2NC(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2N1 LBAIJNRSTQHDMR-UHFFFAOYSA-N 0.000 claims 2
RVKNAJFYQBIAHS-UHFFFAOYSA-N 2-amino-1,4-dihydroxyanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=C(O)C(N)=CC(O)=C3C(=O)C2=C1 RVKNAJFYQBIAHS-UHFFFAOYSA-N 0.000 claims 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
229910000398 iron phosphate Inorganic materials 0.000 claims 1
WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 claims 1
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238000009792 diffusion process Methods 0.000 description 32
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RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 13
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NIQREIWCURIAMA-UHFFFAOYSA-P (phthalocyaninato(2-))magnesium Chemical compound [Mg+2].[N-]1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)[N-]3)=[NH+]2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=[NH+]1 NIQREIWCURIAMA-UHFFFAOYSA-P 0.000 description 2
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Images

Classifications

- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
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KR1020197036580A 2017-05-24 2018-03-13 변형 가능한 준고체 전극 재료를 갖는 알칼리 금속 전지 KR20200010312A (ko)

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US15/604,607		2017-05-24
US15/604,606 US9960451B1 (en)	2017-05-24	2017-05-24	Method of producing deformable quasi-solid electrode material for alkali metal batteries
US15/604,606		2017-05-24
US15/604,607 US10243217B2 (en)	2017-05-24	2017-05-24	Alkali metal battery having a deformable quasi-solid electrode material
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CN110692152A (zh)	2020-01-14
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JP2020522839A (ja)	2020-07-30
CN110692152B (zh)	2023-08-15

Publication	Publication Date	Title
US9960451B1 (en)	2018-05-01	Method of producing deformable quasi-solid electrode material for alkali metal batteries
CN110679009B (zh)	2022-10-21	具有导电且可变形准固体聚合物电极的形状适形的碱金属电池
US10243217B2 (en)	2019-03-26	Alkali metal battery having a deformable quasi-solid electrode material
US10170789B2 (en)	2019-01-01	Method of producing a shape-conformable alkali metal battery having a conductive and deformable quasi-solid polymer electrode
US10535892B2 (en)	2020-01-14	Shape-conformable alkali metal battery having a conductive and deformable quasi-solid polymer electrode
US10903527B2 (en)	2021-01-26	Rolled 3D alkali metal batteries and production process
KR102662816B1 (ko)	2024-05-03	초고 체적 에너지 밀도를 갖는 충전식 리튬 전지 및 요구되는 제조 방법
JP7175284B2 (ja)	2022-11-18	変形可能な準固体電極材料を備えたアルカリ金属電池
US10950897B2 (en)	2021-03-16	Method of producing shape-conformable alkali metal-sulfur battery having a deformable and conductive quasi-solid electrode
US11394058B2 (en)	2022-07-19	Method of producing shape-conformable alkali metal-sulfur battery
US11335946B2 (en)	2022-05-17	Shape-conformable alkali metal-sulfur battery
US20190067732A1 (en)	2019-02-28	Continuous Process for Producing Electrochemical Cells
US10651512B2 (en)	2020-05-12	Shape-conformable alkali metal-sulfur battery having a deformable and conductive quasi-solid electrode
CN110679008B (zh)	2022-09-20	形状适形的碱金属-硫电池
CN110800127B (zh)	2022-12-06	具有可变形且导电准固体电极的形状适形的碱金属-硫电池
US20180323474A1 (en)	2018-11-08	Rolled Alkali Metal Batteries and Production Process

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