KR102441694B1 - 코팅 적용을 위한 낮은 voc 및 높은 고체 플루오로폴리머 - Google Patents
코팅 적용을 위한 낮은 voc 및 높은 고체 플루오로폴리머 Download PDFInfo
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- KR102441694B1 KR102441694B1 KR1020177006549A KR20177006549A KR102441694B1 KR 102441694 B1 KR102441694 B1 KR 102441694B1 KR 1020177006549 A KR1020177006549 A KR 1020177006549A KR 20177006549 A KR20177006549 A KR 20177006549A KR 102441694 B1 KR102441694 B1 KR 102441694B1
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- 238000000576 coating method Methods 0.000 title claims abstract description 34
- 239000011248 coating agent Substances 0.000 title claims abstract description 31
- 239000007787 solid Substances 0.000 title claims description 22
- 239000004811 fluoropolymer Substances 0.000 title description 7
- 229920002313 fluoropolymer Polymers 0.000 title description 7
- 239000012855 volatile organic compound Substances 0.000 claims abstract description 99
- 239000000178 monomer Substances 0.000 claims abstract description 82
- 239000008199 coating composition Substances 0.000 claims abstract description 68
- 238000000034 method Methods 0.000 claims abstract description 49
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000012298 atmosphere Substances 0.000 claims abstract description 27
- 238000007334 copolymerization reaction Methods 0.000 claims abstract description 21
- 229920001567 vinyl ester resin Polymers 0.000 claims abstract description 21
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 32
- 125000000217 alkyl group Chemical group 0.000 claims description 31
- 239000001257 hydrogen Substances 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 25
- 125000004432 carbon atom Chemical group C* 0.000 claims description 24
- 239000000758 substrate Substances 0.000 claims description 23
- CDOOAUSHHFGWSA-OWOJBTEDSA-N (e)-1,3,3,3-tetrafluoroprop-1-ene Chemical group F\C=C\C(F)(F)F CDOOAUSHHFGWSA-OWOJBTEDSA-N 0.000 claims description 20
- 229920000642 polymer Polymers 0.000 claims description 17
- 239000011253 protective coating Substances 0.000 claims description 17
- -1 alkyl acetate Chemical compound 0.000 claims description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 15
- 150000002431 hydrogen Chemical class 0.000 claims description 14
- 230000002829 reductive effect Effects 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 230000008901 benefit Effects 0.000 claims description 9
- FXRLMCRCYDHQFW-UHFFFAOYSA-N 2,3,3,3-tetrafluoropropene Chemical compound FC(=C)C(F)(F)F FXRLMCRCYDHQFW-UHFFFAOYSA-N 0.000 claims description 8
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 7
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 claims description 7
- 238000001704 evaporation Methods 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 6
- 230000001681 protective effect Effects 0.000 claims description 6
- 239000004446 fluoropolymer coating Substances 0.000 claims description 5
- 230000009467 reduction Effects 0.000 claims description 3
- 230000003247 decreasing effect Effects 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 description 24
- 239000002904 solvent Substances 0.000 description 24
- 239000003973 paint Substances 0.000 description 15
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 230000014759 maintenance of location Effects 0.000 description 8
- 238000005507 spraying Methods 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 230000033228 biological regulation Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- KTIBRDNFZLYLNA-UHFFFAOYSA-N 2-(2-hydroxyethenoxy)ethenol Chemical compound OC=COC=CO KTIBRDNFZLYLNA-UHFFFAOYSA-N 0.000 description 3
- UIHCLUNTQKBZGK-UHFFFAOYSA-N 3-methyl-2-pentanone Chemical compound CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- 238000004587 chromatography analysis Methods 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- HMBNQNDUEFFFNZ-UHFFFAOYSA-N 4-ethenoxybutan-1-ol Chemical compound OCCCCOC=C HMBNQNDUEFFFNZ-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- IEZWOVIWXFLQTP-UHFFFAOYSA-N hydroperoxyethene Chemical compound OOC=C IEZWOVIWXFLQTP-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 2
- HGXJDMCMYLEZMJ-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOOC(=O)C(C)(C)C HGXJDMCMYLEZMJ-UHFFFAOYSA-N 0.000 description 1
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 description 1
- SKYXLDSRLNRAPS-UHFFFAOYSA-N 1,2,4-trifluoro-5-methoxybenzene Chemical compound COC1=CC(F)=C(F)C=C1F SKYXLDSRLNRAPS-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- OZCMOJQQLBXBKI-UHFFFAOYSA-N 1-ethenoxy-2-methylpropane Chemical compound CC(C)COC=C OZCMOJQQLBXBKI-UHFFFAOYSA-N 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- NSOAQRMLVFRWIT-UHFFFAOYSA-N 1-ethenoxydecane Chemical class CCCCCCCCCCOC=C NSOAQRMLVFRWIT-UHFFFAOYSA-N 0.000 description 1
- LAYAKLSFVAPMEL-UHFFFAOYSA-N 1-ethenoxydodecane Chemical class CCCCCCCCCCCCOC=C LAYAKLSFVAPMEL-UHFFFAOYSA-N 0.000 description 1
- YAOJJEJGPZRYJF-UHFFFAOYSA-N 1-ethenoxyhexane Chemical compound CCCCCCOC=C YAOJJEJGPZRYJF-UHFFFAOYSA-N 0.000 description 1
- XXCVIFJHBFNFBO-UHFFFAOYSA-N 1-ethenoxyoctane Chemical compound CCCCCCCCOC=C XXCVIFJHBFNFBO-UHFFFAOYSA-N 0.000 description 1
- OVGRCEFMXPHEBL-UHFFFAOYSA-N 1-ethenoxypropane Chemical compound CCCOC=C OVGRCEFMXPHEBL-UHFFFAOYSA-N 0.000 description 1
- VUIWJRYTWUGOOF-UHFFFAOYSA-N 2-ethenoxyethanol Chemical compound OCCOC=C VUIWJRYTWUGOOF-UHFFFAOYSA-N 0.000 description 1
- OJXVWULQHYTXRF-UHFFFAOYSA-N 3-ethenoxypropan-1-ol Chemical compound OCCCOC=C OJXVWULQHYTXRF-UHFFFAOYSA-N 0.000 description 1
- BCTDCDYHRUIHSF-UHFFFAOYSA-N 5-ethenoxypentan-1-ol Chemical compound OCCCCCOC=C BCTDCDYHRUIHSF-UHFFFAOYSA-N 0.000 description 1
- ASPUDHDPXIBNAP-UHFFFAOYSA-N 6-ethenoxyhexan-1-ol Chemical compound OCCCCCCOC=C ASPUDHDPXIBNAP-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000012674 dispersion polymerization Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- QLCCBKRRTJZZOE-UHFFFAOYSA-N ethenoxycyclobutane Chemical compound C=COC1CCC1 QLCCBKRRTJZZOE-UHFFFAOYSA-N 0.000 description 1
- HJVKTYVDOZVQPA-UHFFFAOYSA-N ethenoxycyclopentane Chemical compound C=COC1CCCC1 HJVKTYVDOZVQPA-UHFFFAOYSA-N 0.000 description 1
- YCUBDDIKWLELPD-UHFFFAOYSA-N ethenyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)C(=O)OC=C YCUBDDIKWLELPD-UHFFFAOYSA-N 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- JZRGFKQYQJKGAK-UHFFFAOYSA-N ethenyl cyclohexanecarboxylate Chemical compound C=COC(=O)C1CCCCC1 JZRGFKQYQJKGAK-UHFFFAOYSA-N 0.000 description 1
- GLVVKKSPKXTQRB-UHFFFAOYSA-N ethenyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC=C GLVVKKSPKXTQRB-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000008821 health effect Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229960004592 isopropanol Drugs 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000012453 solvate Substances 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 230000029305 taxis Effects 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/26—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
- C09D123/28—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/007—After-treatment
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- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06Q—INFORMATION AND COMMUNICATION TECHNOLOGY [ICT] SPECIALLY ADAPTED FOR ADMINISTRATIVE, COMMERCIAL, FINANCIAL, MANAGERIAL OR SUPERVISORY PURPOSES; SYSTEMS OR METHODS SPECIALLY ADAPTED FOR ADMINISTRATIVE, COMMERCIAL, FINANCIAL, MANAGERIAL OR SUPERVISORY PURPOSES, NOT OTHERWISE PROVIDED FOR
- G06Q40/00—Finance; Insurance; Tax strategies; Processing of corporate or income taxes
- G06Q40/12—Accounting
- G06Q40/123—Tax preparation or submission
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- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Economics (AREA)
- General Business, Economics & Management (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Marketing (AREA)
- Strategic Management (AREA)
- Technology Law (AREA)
- Physics & Mathematics (AREA)
- Theoretical Computer Science (AREA)
- General Physics & Mathematics (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
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Abstract
Description
Claims (21)
- 휘발성 유기 화합물들(VOCs)의 지구의 대기 중으로의 탈출을 허용하는 유형의 코팅 작업들 도중, VOCs를 지구의 대기 중으로 방출시키는 것을 감소시키는 방법으로서,
(a) 휘발성 유기 화합물들(VOCs)을 포함하는 캐리어를 포함하는 유형의 코팅 조성물로 코팅되는 기재를 제공하는 단계;
(b)
(i) (1) 하이드로플루오로에틸렌들, 하이드로플루오로프로펜들, 하이드로플루오로뷰텐들, 하이드로플루오로펜텐들 및 이들의 조합들로 이루어진 군으로부터 선택되는 제 1 모노머, (2) 바이닐 에스테르(들)를 포함하는 제 2 모노머, 및 (3) 바이닐 에테르 모노머의 적어도 일부가 하이드록실 기-함유 바이닐 에테르인 바이닐 에테르(들)를 포함하는 제 3 모노머의 공중합화에 의해 하나 이상의 플루오로코폴리머들을 제공하는 단계;
(ii) 상기 플루오로코폴리머들 중 하나 이상에 대해 VOC 화합물들을 포함하는 캐리어를 제공하되, 상기 캐리어는 휘발성 유기 화합물들(VOCs)을 포함하는 단계; 및
(iii) 상기 플루오로코폴리머가 코팅 조성물의 적어도 70 중량%를 차지하고, 상기 캐리어의 VOC가 코팅 조성물의 30 중량% 이하가 되도록 상기 플루오로코폴리머들 중 하나 이상을 상기 캐리어와 조합하되, 상기 플루오로코폴리머는 10,000 내지 14,000의 수 평균 분자량을 갖는 단계
를 포함하는 단계들에 의해 형성되는 코팅 조성물을 제공하는 단계;
(c) 상기 제공 단계(b)의 상기 코팅 조성물로 기재를 코팅하는 단계; 및
(d) 상기 캐리어 내의 상기 VOC를 대기 중으로 증발시킴으로써 보호 코팅이 형성되도록 허용하여서, 보호 폴리머 층을 상기 기재 위에 형성하고 상기 기재에 부착시키는 단계
를 포함하는 방법.
- 제1항에 있어서,
단계(b)에 의해 형성된 플루오로폴리머 코팅 조성물은 고체 함량 70 중량% 내지 90 중량%를 갖는 방법.
- 제1항에 있어서,
단계(b)에 의해 형성된 플루오로폴리머 코팅 조성물은 고체 함량 75 중량% 내지 85 중량%를 갖는 방법.
- 제3항에 있어서,
단계(b)에 의해 형성된 플루오로폴리머 코팅 조성물은 VOC 함량 400 g/l 미만을 갖는 방법.
- 제3항에 있어서,
단계(b)에 의해 형성된 플루오로폴리머 코팅 조성물은 VOC 함량 400 g/l 내지 200 g/l를 갖는 방법.
- 제4항에 있어서,
제 1 모노머는 1,3,3,3-테트라플루오로프로펜, 2,3,3,3-테트라플루오로프로펜 및 이들의 조합들로 이루어진 군으로부터 선택되는 방법.
- 제6항에 있어서,
단계(b)의 플루오로코폴리머는 단계(b)의 모노머 (1), (2) 및 (3)의 용액 공중합화에 의해 형성되는 방법.
- 제6항에 있어서,
단계(b)의 플루오로코폴리머는 공중합화 공정에서 사용되는 캐리어의 양이 10 중량% 내지 40 중량%인 용액 공중합화에 의해 형성되는 방법.
- 제6항에 있어서,
단계(b)의 플루오로코폴리머는 공중합화 공정에서 사용되는 캐리어의 양이 15 중량% 내지 25 중량%인 용액 공중합화에 의해 형성되는 방법.
- 제6항에 있어서,
캐리어는 C2-C5 알킬 아세테이트를 포함하는 방법.
- 제1항에 있어서,
상기 기재를 코팅하는 단계는 야외 작업장(open-air job site)에서 발생하는 방법.
- 제11항에 있어서,
상기 기재 위에 보호 폴리머 층을 형성하는 상기 단계는 상기 야외 작업장에서 발생하는 방법.
- 휘발성 유기 화합물들(VOCs)의 지구의 대기 중으로의 탈출을 허용하는 유형의 코팅 작업들 도중, VOC를 지구의 대기 중으로 방출시키는 것을 감소시키는 방법으로서,
(a) 휘발성 유기 화합물들(VOCs)을 포함하는 캐리어를 포함하는 유형의 코팅 조성물로 코팅되는 기재를 제공하는 단계;
(b)
(i)
(1) 1,3,3,3-테트라플루오로프로펜 45 몰% 내지 55 몰%,
(2A) 식 CH2=CR1-0(C=O)xR2(여기서, x는 1이고, R1은 수소이고, R2은 6 내지 8개의 탄소원자들을 갖는 비치환된 분지쇄 알킬 기이고, 상기 알킬 기는 적어도 하나의 3가 또는 하나의 4가 탄소원자를 포함함)로 표시되는 바이닐 에스테르 10 몰% 내지 20 몰%,
(2B) 식 CH2=CR3-O-R4(여기서, R3은 수소이고, R4는 1 내지 3개의 탄소원자들을 갖는 비치환된 직쇄 알킬 기임)로 표시되는 바이닐 에테르 10 몰% 내지 20 몰%, 및
(3) 식 CH2=CR3-O-R5-OH(여기서, R3은 수소이고, R5는 C3 내지 C5의 비치환된 직쇄 알킬 기임)로 표시되는 하이드록시 알킬 바이닐 에테르 3 몰% 내지 30 몰%로 필수적으로 이루어진 모노머들의 공중합화에 의해 하나 이상의 플루오로코폴리머들
을 제공하되, 상기 플루오로코폴리머(들)은 수 평균 분자량 10,000 내지 14,000를 갖는 단계;
(ii) 휘발성 유기 화합물들(VOCs)을 포함하는, 하나 이상의 상기 플루오로코폴리머를 위한 캐리어를 제공하는 단계; 및
(iii) 하나 이상의 상기 플루오로코폴리머를 상기 캐리어와 조합하여서 상기 플루오로코폴리머(들) 적어도 70 중량% 및 상기 캐리어 30 중량% 이하를 포함하는 코팅 조성물을 형성하는 단계
를 포함하는 단계들에 의해 형성되는 코팅 조성물을 제공하는 단계;
(c) 상기 제공 단계(b)의 상기 코팅 조성물로 기재를 코팅하는 단계; 및
(d) 상기 캐리어 내의 상기 VOC를 대기 중으로 증발시킴으로써 보호 폴리머 층을 상기 기재 위에 형성하고 상기 기재에 부착시키며, 이로 인해 상기 보호 코팅이 형성되는 단계
를 포함하는 방법.
- 제13항에 있어서,
상기 캐리어는 알킬 아세테이트를 포함하는 방법.
- 제13항에 있어서,
상기 캐리어는 뷰틸 아세테이트를 포함하는 방법.
- 제13항에 있어서,
상기 코팅 조성물은, 적어도 12 분당 회전(revolution per minute)(r/m), 30 r/m 및 60 r/m 중 하나에서 포드 컵(Ford Cup)에 의한 측정시, VOC 함량 400 g/l 미만 및 점도 1900 mPa-s 미만을 갖는 방법.
- 제13항에 있어서,
상기 코팅 조성물은, 적어도 각각의 12 분당 회전(r/m), 30 r/m 및 60 r/m에서 포드 컵에 의한 측정시, VOC 함량 400 g/l 미만 및 점도 1900 mPa-s 미만을 갖는 방법.
- 제13항에 있어서,
R5는 C3 내지 C5 비치환된 직쇄 알킬 기인 방법.
- 제18항에 있어서,
R4는 2개의 탄소원자들을 갖는 비치환된 직쇄 알킬 기인 방법.
- (i)
(1) 1,3,3,3-테트라플루오로프로펜 45 몰% 내지 55 몰%,
(2A) 식 CH2=CR1-0(C=O)xR2(여기서, x는 1이고, R1은 수소이고, R2은 6 내지 8개의 탄소원자들을 갖는 비치환된 분지쇄 알킬 기이고, 상기 알킬 기는 적어도 하나의 3가 또는 하나의 4가 탄소원자를 포함함)로 표시되는 바이닐 에스테르 10 몰% 내지 20 몰%,
(2B) 식 CH2=CR3-O-R4(여기서, R3은 수소이고, R4는 비치환된 1 내지 3개의 탄소원자들을 갖는 직쇄 알킬 기임)로 표시되는 바이닐 에테르 10 몰% 내지 20 몰%, 및
(3) 식 CH2=CR3-O-R5-OH(여기서, R3은 수소이고, R5는 C3 내지 C5의 비치환된 직쇄 알킬 기임)로 표시되는 하이드록시 알킬 바이닐 에테르 3 몰% 내지 30 몰%
로 필수적으로 이루어진 모노머들의 공중합화에 의해 형성되는 하나 이상의 플루오로코폴리머로서, 수 평균 분자량이 10,000 내지 14,000인 하나 이상의 플루오로코폴리머; 및
(ii) 휘발성 유기 화합물들(VOCs)을 포함하는, 하나 이상의 상기 플루오로코폴리머를 위한 캐리어
를 포함하는 코팅 조성물이며,
코팅 조성물은 (a) 상기 플루오로코폴리머(들) 적어도 70 중량%; (b) 상기 캐리어 30 중량% 이하를 포함하고; (c) VOC 함량 400 g/l 미만; 및 (d) 적어도 12 분당 회전(r/m), 30 r/m 및 60 r/m 중 하나에서 포드 컵(Ford Cup)으로 측정시 점도 1900mPa-s 미만을 갖는 코팅 조성물.
- 휘발성 유기 화합물들(VOCs)의 지구의 대기 중으로의 탈출을 허용하는 유형의 베이스라인 코팅 작업과 비교하여, VOC를 지구의 대기 중으로 방출시키는 것을 감소시키는 결과로서, VOC 세액 공제(tax credit) 또는 다른 법적 이익(legal benefit)을 얻기 위한 방법으로서,
(a) 현존 코팅 조성물로 기재를 코팅하는 것을 포함하는 현존 작업으로부터 VOC의 베이스라인 방출을 확립하는 단계;
(b)
(i) (1) 하이드로플루오로에틸렌들, 하이드로플루오로프로펜들, 하이드로플루오로뷰텐들, 하이드로플루오로펜텐들 및 이들의 조합들로 이루어진 군으로부터 선택되는 제 1 모노머, (2) 바이닐 에스테르(들)를 포함하는 제 2 모노머, 및 (3) 바이닐 에테르 모노머의 적어도 일부가 하이드록실 기-함유 바이닐 에테르인 바이닐 에테르(들)를 포함하는 제 3 모노머의 공중합화에 의해 하나 이상의 플루오로코폴리머들을 제공하는 단계;
(ii) 휘발성 유기 화합물들(VOCs)을 포함하는, 하나 이상의 상기 플루오로코폴리머를 위한 캐리어를 제공하는 단계; 및
(iii) 상기 플루오로코폴리머가 코팅 조성물의 적어도 70 중량%를 차지하고, 상기 캐리어의 VOC가 코팅 조성물의 30 중량% 이하가 되도록 상기 플루오로코폴리머들 중 하나 이상을 상기 캐리어와 조합하는 단계
를 포함하는 단계들에 의해 형성되는 감소된 VOC 코팅 조성물을 제공하는 단계;
(c) 상기 제공 단계(b)의 상기 감소된 VOC 코팅 조성물로 기재를 코팅하는 단계; 및
(d) 상기 캐리어 내의 상기 VOC를 대기 중으로 증발시킴으로써 보호 폴리머 층을 상기 기재 위에 형성하고 상기 기재에 부착시키며, 이로 인해 보호 코팅이 형성되고, 상기 감소된 VOC 코팅 조성물을 사용하여 방출된 VOC가 VOC의 상기 베이스라인 방출과 비교하여 감소되는 단계; 및
(e) 상기 코팅 작업으로부터 방출된 VOC에서의 상기 감소에 적어도 부분적으로 기초하여, 세액 공제 또는 다른 법적 이익에 대한 청구를 정부 기관에 제출하는 단계
를 포함하는 방법.
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CN107073903B (zh) | 2019-07-12 |
US11111405B2 (en) | 2021-09-07 |
EP3194165A1 (en) | 2017-07-26 |
JP6706249B2 (ja) | 2020-06-03 |
EP3194165B1 (en) | 2021-03-03 |
KR20170052588A (ko) | 2017-05-12 |
WO2016040525A1 (en) | 2016-03-17 |
US20220041884A1 (en) | 2022-02-10 |
CN107073903A (zh) | 2017-08-18 |
US11667806B2 (en) | 2023-06-06 |
JP2017534438A (ja) | 2017-11-24 |
CA2959412A1 (en) | 2016-03-17 |
CN110079169A (zh) | 2019-08-02 |
US20170247562A1 (en) | 2017-08-31 |
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