KR101932256B1 - Composition for cold-resistant and heat-resistant cable - Google Patents
Composition for cold-resistant and heat-resistant cable Download PDFInfo
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- KR101932256B1 KR101932256B1 KR1020170009547A KR20170009547A KR101932256B1 KR 101932256 B1 KR101932256 B1 KR 101932256B1 KR 1020170009547 A KR1020170009547 A KR 1020170009547A KR 20170009547 A KR20170009547 A KR 20170009547A KR 101932256 B1 KR101932256 B1 KR 101932256B1
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- 239000000203 mixture Substances 0.000 title claims abstract description 35
- 239000005038 ethylene vinyl acetate Substances 0.000 claims abstract description 18
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims abstract description 18
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims abstract description 17
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 10
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000003063 flame retardant Substances 0.000 claims abstract description 9
- 238000004132 cross linking Methods 0.000 claims abstract description 8
- 239000003381 stabilizer Substances 0.000 claims abstract description 8
- 239000004014 plasticizer Substances 0.000 claims abstract description 5
- 229920005989 resin Polymers 0.000 claims abstract description 5
- 239000011347 resin Substances 0.000 claims abstract description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical group [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 10
- 239000003963 antioxidant agent Substances 0.000 claims description 10
- 230000003078 antioxidant effect Effects 0.000 claims description 10
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 8
- SAOKZLXYCUGLFA-UHFFFAOYSA-N bis(2-ethylhexyl) adipate Chemical compound CCCCC(CC)COC(=O)CCCCC(=O)OCC(CC)CCCC SAOKZLXYCUGLFA-UHFFFAOYSA-N 0.000 claims description 8
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical group C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 6
- UUNBFTCKFYBASS-UHFFFAOYSA-N C(CCCCCCC)C=1C(=C(C=CC1)NC1=CC=CC=C1)CCCCCCCC Chemical compound C(CCCCCCC)C=1C(=C(C=CC1)NC1=CC=CC=C1)CCCCCCCC UUNBFTCKFYBASS-UHFFFAOYSA-N 0.000 claims description 6
- XSAOTYCWGCRGCP-UHFFFAOYSA-K aluminum;diethylphosphinate Chemical compound [Al+3].CCP([O-])(=O)CC.CCP([O-])(=O)CC.CCP([O-])(=O)CC XSAOTYCWGCRGCP-UHFFFAOYSA-K 0.000 claims description 6
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 6
- WVGXBYVKFQJQGN-UHFFFAOYSA-N 1-tert-butylperoxy-2-propan-2-ylbenzene Chemical compound CC(C)C1=CC=CC=C1OOC(C)(C)C WVGXBYVKFQJQGN-UHFFFAOYSA-N 0.000 claims description 5
- -1 3,5-di-tert-butyl- Benzyl Chemical group 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims description 5
- 239000003607 modifier Substances 0.000 claims description 5
- UIYCHXAGWOYNNA-UHFFFAOYSA-N vinyl sulfide Chemical group C=CSC=C UIYCHXAGWOYNNA-UHFFFAOYSA-N 0.000 claims description 5
- 239000011787 zinc oxide Substances 0.000 claims description 5
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 claims description 4
- 229940067572 diethylhexyl adipate Drugs 0.000 claims description 3
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims 2
- 238000000034 method Methods 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 abstract description 2
- 229920002554 vinyl polymer Polymers 0.000 abstract description 2
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 5
- 238000005336 cracking Methods 0.000 description 5
- 230000032683 aging Effects 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- UJAWGGOCYUPCPS-UHFFFAOYSA-N 4-(2-phenylpropan-2-yl)-n-[4-(2-phenylpropan-2-yl)phenyl]aniline Chemical compound C=1C=C(NC=2C=CC(=CC=2)C(C)(C)C=2C=CC=CC=2)C=CC=1C(C)(C)C1=CC=CC=C1 UJAWGGOCYUPCPS-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 239000010425 asbestos Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 229910052895 riebeckite Inorganic materials 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- PJPGMULJEYSZBS-UHFFFAOYSA-N (+)-streptol Natural products OCC1=CC(O)C(O)C(O)C1O PJPGMULJEYSZBS-UHFFFAOYSA-N 0.000 description 1
- BKUSIKGSPSFQAC-RRKCRQDMSA-N 2'-deoxyinosine-5'-diphosphate Chemical compound O1[C@H](CO[P@@](O)(=O)OP(O)(O)=O)[C@@H](O)C[C@@H]1N1C(NC=NC2=O)=C2N=C1 BKUSIKGSPSFQAC-RRKCRQDMSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- VFBJXXJYHWLXRM-UHFFFAOYSA-N 2-[2-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]ethylsulfanyl]ethyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCCSCCOC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 VFBJXXJYHWLXRM-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920003317 Fusabond® Polymers 0.000 description 1
- 229920003346 Levapren® Polymers 0.000 description 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000011491 glass wool Substances 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- MVAOEXBRERPGIT-UHFFFAOYSA-N octamine Chemical compound N.N.N.N.N.N.N.N MVAOEXBRERPGIT-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000004154 testing of material Methods 0.000 description 1
- PJPGMULJEYSZBS-VZFHVOOUSA-N valienol Chemical compound OCC1=C[C@H](O)[C@H](O)[C@@H](O)[C@@H]1O PJPGMULJEYSZBS-VZFHVOOUSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/307—Other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/06—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/16—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen
- C09K15/18—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen containing an amine or imine moiety
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/20—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/02—Inorganic materials
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/06—Organic materials
- C09K21/10—Organic materials containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/06—Organic materials
- C09K21/12—Organic materials containing phosphorus
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
- Insulated Conductors (AREA)
Abstract
본 발명은 내한성 및 내열성 전선용 조성물에 관한 것으로, 상기 내한성 및 내열성 전선용 조성물은 전선용 조성물 전체 중량에 대하여 기재 수지로써 70% 비닐아세테이트 함유 에틸렌비닐아세테이트 19 내지 22 중량%, 에틸렌비닐아세테이트 기반 개질제 2 내지 5 중량%, 45% 비닐아세테이트 함유 에틸렌비닐아세테이트 6 내지 9 중량%, 난연제 48 내지 51 중량%, 가소제 11 내지 13 중량%, 안정제 0.5 내지 2.5 중량%, 산화방지제 0.5 내지 2.5 중량%, 가공조제 0.5 내지 1.5 중량%, 가교제 1.5 내지 2.5 중량%, 가교조제 0.5 내지 1.5 중량%를 포함하는 것일 수 있다.
본 발명에 따른 전선용 조성물은 내열성 및 내한성이 우수하여 다양한 환경 및 용도의 전선에 적용할 수 있으며, 특히 선박용 또는 해양용 전선으로 적용할 수 있다.The present invention relates to a composition for cold-resistant and heat-resistant wires, wherein the composition for cold-resistant and heat-resistant wires comprises 19 to 22% by weight of ethylene vinyl acetate containing 70% vinyl acetate as a base resin, ethylene vinyl acetate- From 2 to 5% by weight, from 6 to 9% by weight of ethylene vinyl acetate containing 45% vinyl acetate, from 48 to 51% by weight of a flame retardant, from 11 to 13% by weight of a plasticizer, from 0.5 to 2.5% by weight of a stabilizer, 0.5 to 1.5% by weight of a preparation, 1.5 to 2.5% by weight of a crosslinking agent, and 0.5 to 1.5% by weight of a crosslinking auxiliary.
The wire composition according to the present invention is excellent in heat resistance and cold resistance, and can be applied to electric wires of various environments and uses, and can be applied particularly to marine or marine wires.
Description
본 발명은 내한성 및 내열성 전선용 조성물에 관한 것이다.The present invention relates to a composition for cold-resistant and heat-resistant wires.
내열 전선이란, 내열성의 절연물로 피복한 절연 전선을 말한다(화학대사전, 2001. 5. 20., 세화). 절연 전선의 최고 사용 온도는 주위 온도에 전류에 의한 온도 상승을 가한 값이 절연물의 최고 사용 온도를 넘지 않는 것이 필요하고, 내열 고무, 석면이나 유리솜을 감거나, 이것들에 규소 수지를 함침시켜 내열성 있는 절연물로 하고, 주위 온도를 단열하기 위해 유리솜이나 석면으로 감싸 제조한다.A heat-resistant wire refers to an insulated wire covered with a heat-resistant insulating material (Chemical Bulletin, May 20, 2001, SeAH). It is necessary that the maximum operating temperature of the insulated wire does not exceed the maximum use temperature of the insulator by applying the temperature rise by the current to the ambient temperature, and the heat resistant rubber, asbestos or glass wool is wound, It is made of insulating material and wrapped with glass cloth or asbestos to insulate the ambient temperature.
최근에는 도체 위에 고강도 실리콘 고무를 압출 또는 그라스피버를 이중 편조하여 실리콘 바니쉬로 표면처리함으로써 -60~200℃를 견디는 실리콘 전선 등이 개발되고 있으며 이와 같이 내열성 및 내한성이 우수한 전선은 발전기, 전동기 차량, 선박 등의 인출선, 점화용 배선, 전기선, 중장비용 케이블 등으로 사용된다.In recent years, silicon wires which are resistant to -60 to 200 ° C have been developed by extruding high-strength silicon rubber on a conductor or by double-braiding a glass fiber and then treating the surface with a silicon varnish. As such, wires having excellent heat resistance and cold resistance are used in generators, It is used for outgoing lines such as ships, ignition wiring, electric wires, cables for heavy equipment.
본 발명의 목적은 내한성 및 내열성 전선용 조성물을 제공하는 것으로, 상기 내한성 및 내열성 전선용 조성물은 전선용 조성물 전체 중량에 대하여 기재 수지로써 70% 비닐아세테이트 함유 에틸렌비닐아세테이트 19 내지 22 중량%, 에틸렌비닐아세테이트 기반 개질제 2 내지 5 중량%, 45% 비닐아세테이트 함유 에틸렌비닐아세테이트 6 내지 9 중량%, 난연제 48 내지 51 중량%, 가소제 11 내지 13 중량%, 안정제 0.5 내지 2.5 중량%, 산화방지제 0.5 내지 2.5 중량%, 가공조제 0.5 내지 1.5 중량%, 가교제 1.5 내지 2.5 중량%, 가교조제 0.5 내지 1.5 중량%를 포함하는 것일 수 있다.An object of the present invention is to provide a composition for cold-resistant and heat-resistant wires, wherein the composition for cold-resistant and heat-resistant wires comprises 19 to 22% by weight of ethylene vinyl acetate containing 70% vinyl acetate as a base resin, 2 to 5 wt% acetate based modifier, 6 to 9 wt% ethylene vinyl acetate containing 45% vinyl acetate, 48 to 51 wt% flame retardant, 11 to 13 wt% plasticizer, 0.5 to 2.5 wt% stabilizer, 0.5 to 2.5 wt% antioxidant , 0.5 to 1.5 wt% of a processing aid, 1.5 to 2.5 wt% of a crosslinking agent, and 0.5 to 1.5 wt% of a crosslinking auxiliary.
본 발명은 내한성 및 내열성 전선용 조성물로,The present invention relates to a composition for cold-resistant and heat-
상기 내한성 및 내열성 전선용 조성물은 전선용 조성물 전체 중량에 대하여 기재 수지로써 70% 비닐아세테이트 함유 에틸렌비닐아세테이트 19 내지 22 중량%, 에틸렌비닐아세테이트 기반 개질제 2 내지 5 중량%, 45% 비닐아세테이트 함유 에틸렌비닐아세테이트 6 내지 9 중량%, 난연제 48 내지 51 중량%, 가소제 11 내지 13 중량%, 안정제 0.5 내지 2.5 중량%, 산화방지제 0.5 내지 2.5 중량%, 가공조제 0.5 내지 1.5 중량%, 가교제 1.5 내지 2.5 중량%, 가교조제 0.5 내지 1.5 중량%를 포함하는 것인 내한성 및 내열성 전선용 조성물을 제공한다.The composition for cold-resistant and heat-resistant wires is characterized by comprising 19 to 22% by weight of ethylene vinyl acetate containing 70% vinyl acetate as a base resin, 2 to 5% by weight of ethylene vinyl acetate-based modifier, ethylene vinyl acetate containing 45% A stabilizer, 0.5 to 2.5 wt%, an antioxidant, 0.5 to 2.5 wt%, a processing aid, 0.5 to 1.5 wt%, a crosslinking agent, 1.5 to 2.5 wt% By weight, and 0.5 to 1.5% by weight of a crosslinking auxiliary.
상기 난연제는 마그네슘 디히드록시드, 알루미늄 디에틸포스피네이트, 알루미늄 트리하이드록사이드 또는 멜라민 시아누레이트로 이루어지는 군으로부터 선택되는 어느 하나 이상인 것일 수 있다.The flame retardant may be at least one selected from the group consisting of magnesium dihydroxide, aluminum diethylphosphinate, aluminum trihydroxide or melamine cyanurate.
상기 가소제는 디에틸헥실아디페이트 또는 프탈산디이소데실인 것일 수 있다.The plasticizer may be diethylhexyl adipate or diisodecyl phthalate.
상기 안정제는 징크옥사이드인 것일 수 있다.The stabilizer may be zinc oxide.
상기 산화방지제는 티오디에틸렌 비스[3-, 3,5- 디-tert-부틸-4-히드록시페닐 프로피오네이트], 4,4'- 비스 (알파, 알파- 디메틸벤질) 디페닐아민, 모노옥틸 및 디옥틸 디페닐아민으로 이루어지는 군으로부터 선택되는 어느 하나 이상인 것일 수 있다.Examples of the antioxidant include thiodiethylene bis [3-, 3,5-di-tert-butyl-4-hydroxyphenylpropionate], 4,4'-bis (alpha, Mono-octyl, and dioctyl diphenylamine.
상기 가공조제는 지방산 칼슘염인 것일 수 있다.The processing aid may be a fatty acid calcium salt.
상기 가교제는 트리알릴이소시아누레이트인 것일 수 있다.The crosslinking agent may be triallyl isocyanurate.
상기 가교조제는 비스(tert- 부틸 퍼옥시-2-이소프로필)벤젠인 것일 수 있다.The crosslinking assistant may be bis (tert-butylperoxy-2-isopropyl) benzene.
상기 내한성 및 내열성 전선용 조성물은 선박용 또는 해양용인 것일 수 있다.The composition for cold-resistant and heat-resistant wires may be marine or marine.
본 발명에 따른 전선용 조성물은 내열성 및 내한성이 우수하여 다양한 환경 및 용도의 전선에 적용할 수 있으며, 특히 선박용 또는 해양용 전선으로 적용할 수 있다.The wire composition according to the present invention is excellent in heat resistance and cold resistance, and can be applied to electric wires of various environments and uses, and can be applied particularly to marine or marine wires.
본 발명은 내한성 및 내열성 전선용 조성물로, 상기 내한성 및 내열성 전선용 조성물은 전선용 조성물 전체 중량에 대하여 기재 수지로써 70% 비닐아세테이트 함유 에틸렌비닐아세테이트 19 내지 22 중량%, 에틸렌비닐아세테이트 기반 개질제 2 내지 5 중량%, 45% 비닐아세테이트 함유 에틸렌비닐아세테이트 6 내지 9 중량%, 난연제 48 내지 51 중량%, 가소제 11 내지 13 중량%, 안정제 0.5 내지 2.5 중량%, 산화방지제 0.5 내지 2.5 중량%, 가공조제 0.5 내지 1.5 중량%, 가교제 1.5 내지 2.5 중량%, 가교조제 0.5 내지 1.5 중량%를 포함하는 것인 내한성 및 내열성 전선용 조성물을 제공한다.The present invention relates to a composition for cold-resistant and heat-resistant wire, wherein the composition for cold-resistant and heat-resistant wire comprises 19 to 22% by weight of ethylene vinyl acetate containing 70% vinyl acetate as a base resin, ethylene vinyl acetate- A stabilizer, 0.5 to 2.5% by weight, an antioxidant of 0.5 to 2.5% by weight, a processing aid of 0.5 to 5% by weight, a vinyl acetate-containing ethylene vinyl acetate of 6 to 9% by weight, a flame retardant of 48 to 51% To 1.5% by weight of a crosslinking agent, 1.5 to 2.5% by weight of a crosslinking agent, and 0.5 to 1.5% by weight of a crosslinking auxiliary.
상기 난연제는 마그네슘 디히드록시드, 알루미늄 디에틸포스피네이트, 알루미늄 트리하이드록사이드 또는 멜라민 시아누레이트로 이루어지는 군으로부터 선택되는 어느 하나 이상인 것일 수 있으며, 상기 난연제는 바람직하게는 마그네슘 디히드록시드 36 내지 39 중량%, 알루미늄 디에틸포스피네이트 6 내지 9 중량% 및 멜라민 시아누레이트 2 내지 5 중량%로 이루어지는 것일 수 있으나, 이에 한정되지 않는다.The flame retardant may be one or more selected from the group consisting of magnesium dihydroxide, aluminum diethylphosphinate, aluminum trihydroxide or melamine cyanurate, and the flame retardant is preferably magnesium dihydroxide 36 to 39% by weight, aluminum diethylphosphinate 6 to 9% by weight, and melamine cyanurate 2 to 5% by weight, but is not limited thereto.
상기 가소제는 디에틸헥실아디페이트 또는 프탈산디이소데실인 것일 수 있다.The plasticizer may be diethylhexyl adipate or diisodecyl phthalate.
상기 안정제는 징크옥사이드인 것일 수 있다.The stabilizer may be zinc oxide.
상기 산화방지제는 티오디에틸렌 비스[3-, 3,5- 디-tert-부틸-4-히드록시페닐 프로피오네이트], 4,4'- 비스 (알파, 알파- 디메틸벤질) 디페닐아민, 모노옥틸 및 디옥틸 디페닐아민으로 이루어지는 군으로부터 선택되는 어느 하나 이상인 것일 수 있으며, 상기 산화방지제는 바람직하게는 티오디에틸렌 비스[3-, 3,5- 디-tert-부틸-4-히드록시페닐 프로피오네이트] 0.5 내지 1.5 중량%, 4,4'- 비스 (알파, 알파- 디메틸벤질) 디페닐아민 0.5 내지 1.5 중량%, 모노옥틸 및 디옥틸 디페닐아민 0.5 내지 1.5 중량%으로 이루어지는 것일 수 있으나, 이에 한정되지 않는다.Examples of the antioxidant include thiodiethylene bis [3-, 3,5-di-tert-butyl-4-hydroxyphenylpropionate], 4,4'-bis (alpha, Mono-octyl, and dioctyl diphenylamine, and the antioxidant is preferably at least one selected from the group consisting of thiodiethylene bis [3-, 3,5-di-tert-butyl- 0.5 to 1.5% by weight of 4,4'-bis (alpha, alpha-dimethylbenzyl) diphenylamine, 0.5 to 1.5% by weight of monooctyl and dioctyldiphenylamine But is not limited thereto.
상기 가공조제는 지방산 칼슘염인 것일 수 있다.The processing aid may be a fatty acid calcium salt.
상기 가교제는 트리알릴이소시아누레이트인 것일 수 있다.The crosslinking agent may be triallyl isocyanurate.
상기 가교조제는 비스(tert- 부틸 퍼옥시-2-이소프로필)벤젠인 것일 수 있다.The crosslinking assistant may be bis (tert-butylperoxy-2-isopropyl) benzene.
본 발명에 따른 내한성 및 내열성 전선용 조성물은 상온에서의 인장강도가 12.5 N/㎟, 신장율이 450%이고, 열노화 후 인장강도 변화 잔율이 127%, 신장율 변화 잔율이 85%이며, -40℃에서 내한성이 우수하고, 산소지수가 34%로 난연성이 우수하므로, 인장강도, 신장율, 내열성, 내한성 및 난연성을 종합적으로 고려하였을 때, 다양한 환경 및 용도의 전선에 적용할 수 있으며, 특히 선박용 또는 해양용 전선에 적용할 수 있다.The composition for cold-resistant and heat-resistant wire according to the present invention has a tensile strength at room temperature of 12.5 N / mm < 2 >, an elongation percentage of 450%, a tensile strength change rate after heat aging of 127% And the oxygen index is 34% and the flame retardancy is excellent. Therefore, when the tensile strength, elongation, heat resistance, cold resistance and flame retardancy are collectively considered, they can be applied to electric wires of various environments and applications, It can be applied to electric wire.
이하, 본 발명의 이해를 돕기 위하여 실시예를 들어 상세하게 설명하기로 한다. 다만 하기의 실시예는 본 발명의 내용을 예시하는 것일 뿐 본 발명의 범위가 하기 실시예에 한정되는 것은 아니다. 본 발명의 실시예는 당업계에서 평균적인 지식을 가진 자에게 본 발명을 보다 완전하게 설명하기 위해 제공되는 것이다.BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail with reference to the following examples. However, the following examples are intended to illustrate the contents of the present invention, but the scope of the present invention is not limited to the following examples. Embodiments of the present invention are provided to more fully describe the present invention to those skilled in the art.
<< 실시예Example 1> 내한성 및 내열성 전선용 조성물 제조 1> Composition for cold-resistant and heat-resistant wire
70% 비닐아세테이트 함유 에틸렌비닐아세테이트(Ethylene Vinyl Acetate 70%VA content, Levapren 700HV, Laxess, 독일), 에틸렌비닐아세테이트 기반 개질제(functionalized ethylene vinyl acetate (EVA) based modifiers for coupling, Fusabond MC-250D, Dow, 미국), 45% 비닐아세테이트 함유 에틸렌비닐아세테이트(Ethylene Vinyl Acetate 45%VA content, EVAFLEX EV45LX, Dow, 미국), 난연제인 마그네슘 디히드록시드(Magnesium dihydroxide surface modified, PFR-5V, 포스코켐텍, 한국), 알루미늄 트리하이드록사이드(Aluminum trihydroxide surfaced modified, Tajima-A, 나노테크, 한국), 알루미늄 디에틸포스피네이트(Aluminum diethylphosphinate, OMP-800, 유니브샬켐텍, 한국), 멜라민 시아누레이트(Melamine cyanurate, MC-110, 유니브샬켐텍, 한국), 가소제인 디에틸헥실아디페이트(DIOCTYL ADIPATE, DI-2-ETHYLHEXYL ADIPATE[DEHA], DOA, 애경유화, 한국), 프탈산디이소데실(DIISODECYL PHTHALATE, DIDP, 애경유화, 한국), 안정제인 징크옥사이드(zinc oxide, 한일아연화, 한국), 산화방지제인 티오디에틸렌 비스[3-, 3,5- 디-tert-부틸-4-히드록시페닐 프로피오네이트](Thiodiethylene bis[3-, 3,5-di-tert-butyl-4-hydroxyphenyl propionate], SONGNOX® 1035, 송원산업, 한국), 4,4'- 비스 (알파, 알파- 디메틸벤질) 디페닐아민(4,4’-Bis (alpha, alpha-dimethylbenzyl) diphenylamine, Neogard 445, 유니로얄, USA), 모노옥틸 및 디옥틸 디페닐아민(MONOOCTYL AND DIOCTYL DIPHENYLAMINE, Octamine, 유니로얄, USA), 가공조제인 지방산 칼슘염(Calcium Soap and fatty acids, WB-16, 스트락톨, 독일), 가교제인 트리알릴이소시아누레이트(triallyl isocyanurate, TAIC, 일본유화, 일본), 가교조제인 비스(tert- 부틸 퍼옥시-2-이소프로필)벤젠(Bis(tert-butylperoxy-2-isopropyl)benzene, Luperox F40P, AKEMA, 프랑스)를 하기 표 1에 따라 혼합하여, 실시예 1의 전선용 조성물 및 비교예 1~10의 전선용 조성물을 제조하였다.(Ethylene vinyl acetate-based modifiers for coupling, Fusabond MC-250D, Dow, Germany), 70% vinyl acetate containing ethylene vinyl acetate (70% VA content, Levapren 700HV, Laxess, Germany) (Ethylene Vinyl Acetate 45% VA content, EVAFLEX EV45LX, Dow, USA), 45% vinyl acetate-containing magnesium dihydroxide (PFR-5V, POSCO Chemtech, Korea) , Aluminum trihydroxide surfactant modified (Tajima-A, Nanotech, Korea), aluminum diethylphosphinate (OMP-800, UNIVERSAL CHEMTECH, Korea), melamine cyanurate , DI-2-ETHYLHEXYL ADIPATE (DEHA), DOA, Ake Kyung Oil Company, Korea), diisodecyl phthalate (DII SODECYL PHTHALATE, DIDP, Ake Kyung Oil Company, Korea), stabilizer zinc oxide (Hanil Zhenhua, Korea), antioxidant thiodiethylene bis [3- 3,5-di-tert- 4-hydroxyphenyl propionate], SONGNOX® 1035, Songwon Industrial Co., Korea), 4,4'-bis (alpha, alpha-dimethyl (4,4'-bis (alpha, alpha-dimethylbenzyl) diphenylamine, Neogard 445, Uniroyal, USA), monooctyl and dioctyl diphenylamine, Octamine, Uniroyal, USA ), A processing aid such as calcium soap and fatty acids (WB-16, Streptol, Germany), a crosslinking agent triallyl isocyanurate (TAIC, Japan Oil Company, Japan) (tert-butylperoxy-2-isopropyl) benzene, Luperox F40P, AKEMA, France) were mixed according to the following Table 1, And wire compositions of Comparative Examples 1 to 10 were prepared.
(단위: g)Example 1
(Unit: g)
15.0
<< 실시예Example 2> 전선용 조성물의 물성 평가 2> Evaluation of physical properties of composition for wire
실시예 1의 전선용 조성물 및 대조군으로 비교예 1~10의 전선용 조성물에 대하여 상온에서의 인장강도 및 신장율, 열노화한 후의 인장강도 변화 잔율 및 신장율 변화 잔율, -40℃에서의 내한성, 난연성을 평가하였다.The tensile strength and elongation at room temperature, the tensile strength change ratio and the elongation percentage residual rate after heat aging, the cold resistance at -40 DEG C, the flame retardancy .
구체적으로, 각 전선용 조성물을 ASTM D638 규격으로 가공한 후 만능재료시험기(HTE-5000N, Haunsfiels)를 이용하여 인장강도 및 신장율을 측정하였다.Specifically, each wire composition was processed to ASTM D638 standard, and tensile strength and elongation were measured using a universal material testing machine (HTE-5000N, Haunsfiels).
각 전선용 조성물을 180℃에서 168시간 동안 열노화한 후 측정한 인장강도 및 신장율을 열노화 전의 인장강도 및 신장율과 비교하여 인장강도 변화 잔율 및 신장율 변화 잔율을 산출하였다.The composition for each wire was thermally aged at 180 ° C for 168 hours, and then the tensile strength and elongation were compared with the tensile strength and elongation before heat aging to calculate the residual tensile strength change and elongation percentage.
각 전선용 조성물의 내한성은 -40℃에서 확인하였다.The cold resistance of each wire composition was confirmed at -40 占 폚.
난연성은 각 전선용 조성물의 산소지수를 ASTM D2863에 따라 산소지수 가연도 시험기(Oxygen Index Flammability Tester No. 214, Yasuda, 일본)로 측정하여 확인하였다.The flame retardancy was determined by measuring the oxygen index of each wire composition with an Oxygen Index Flammability Tester No. 214, Yasuda, Japan according to ASTM D2863.
그 결과, 하기 표 2와 같이 인장강도, 신장율, 내열성, 내한성 및 난연성을 종합적으로 고려하였을 때, 실시예 1의 전선용 조성물이 비교예 1~10의 전선용 조성물에 비해 내열성 및 내한성이 우수하여 다양한 환경 및 용도의 전선에 적용할 수 있음을 확인하였다.As a result, when the tensile strength, elongation, heat resistance, cold resistance and flame retardancy were comprehensively considered as shown in Table 2, the wire composition of Example 1 was superior in heat resistance and cold resistance to the wire compositions of Comparative Examples 1 to 10 And it can be applied to electric wires of various environments and applications.
Room temperature
Claims (9)
상기 내한성 및 내열성 전선용 조성물은 전선용 조성물 전체 중량에 대하여 기재 수지로써 70% 비닐아세테이트 함유 에틸렌비닐아세테이트 19 내지 22 중량%,
에틸렌비닐아세테이트 기반 개질제 2 내지 5 중량%, 45% 비닐아세테이트 함유 에틸렌비닐아세테이트 6 내지 9 중량%, 난연제 48 내지 51 중량%, 가소제로서 디에틸헥실아디페이트 11 내지 13 중량%, 안정제 0.5 내지 2.5 중량%, 산화방지제 0.5 내지 2.5 중량%, 가공조제 0.5 내지 1.5 중량%, 가교제 1.5 내지 2.5 중량%, 가교조제 0.5 내지 1.5 중량%를 포함하는 것인 내한성 및 내열성 전선용 조성물.As a composition for cold and heat resistant wires,
The composition for a cold-resistant and heat-resistant wire preferably comprises 19 to 22% by weight of ethylene vinyl acetate containing 70% vinyl acetate as a base resin,
2 to 5% by weight of an ethylene vinyl acetate-based modifier, 6 to 9% by weight of ethylene vinyl acetate containing 45% vinyl acetate, 48 to 51% by weight of a flame retardant, 11 to 13% by weight of diethylhexyl adipate as a plasticizer, By weight of the antioxidant, 0.5 to 2.5% by weight of the antioxidant, 0.5 to 1.5% by weight of the processing aid, 1.5 to 2.5% by weight of the crosslinking agent, and 0.5 to 1.5% by weight of the crosslinking auxiliary.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100691067B1 (en) * | 2005-06-08 | 2007-03-09 | 엘에스전선 주식회사 | Flame retardant non-halogen wire coating material composition and electric wire for railway vehicle using same |
| KR101290831B1 (en) | 2011-11-14 | 2013-07-29 | 대우조선해양 주식회사 | Cables for using marine and off-shore ballast pump |
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| KR100691067B1 (en) * | 2005-06-08 | 2007-03-09 | 엘에스전선 주식회사 | Flame retardant non-halogen wire coating material composition and electric wire for railway vehicle using same |
| KR101290831B1 (en) | 2011-11-14 | 2013-07-29 | 대우조선해양 주식회사 | Cables for using marine and off-shore ballast pump |
| KR101467971B1 (en) * | 2013-05-31 | 2014-12-02 | 김영두 | Composition for cable |
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