KR100664737B1 - Yield increase and quality improvement of agricultural products by rare earth fertilizer - Google Patents
Yield increase and quality improvement of agricultural products by rare earth fertilizer Download PDFInfo
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- KR100664737B1 KR100664737B1 KR1020050047463A KR20050047463A KR100664737B1 KR 100664737 B1 KR100664737 B1 KR 100664737B1 KR 1020050047463 A KR1020050047463 A KR 1020050047463A KR 20050047463 A KR20050047463 A KR 20050047463A KR 100664737 B1 KR100664737 B1 KR 100664737B1
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- 229910052761 rare earth metal Inorganic materials 0.000 title claims abstract description 102
- 239000003337 fertilizer Substances 0.000 title claims abstract description 56
- 150000002910 rare earth metals Chemical class 0.000 title abstract description 82
- 238000000034 method Methods 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 19
- 235000013399 edible fruits Nutrition 0.000 claims abstract description 19
- 235000009566 rice Nutrition 0.000 claims abstract description 19
- 235000013311 vegetables Nutrition 0.000 claims abstract description 14
- 238000007865 diluting Methods 0.000 claims abstract description 11
- 240000007594 Oryza sativa Species 0.000 claims description 16
- 240000008042 Zea mays Species 0.000 claims description 13
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 13
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 13
- 235000005822 corn Nutrition 0.000 claims description 13
- 235000015503 Sorghum bicolor subsp. drummondii Nutrition 0.000 claims description 9
- 244000170625 Sudangrass Species 0.000 claims description 9
- 235000011684 Sorghum saccharatum Nutrition 0.000 claims description 7
- 240000006394 Sorghum bicolor Species 0.000 claims description 6
- 229910052684 Cerium Inorganic materials 0.000 claims description 5
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 5
- 229910052691 Erbium Inorganic materials 0.000 claims description 5
- 229910052693 Europium Inorganic materials 0.000 claims description 5
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- 229910052746 lanthanum Inorganic materials 0.000 claims description 5
- 229910052706 scandium Inorganic materials 0.000 claims description 5
- 229910052765 Lutetium Inorganic materials 0.000 claims description 4
- 229910052727 yttrium Inorganic materials 0.000 claims description 3
- 235000014443 Pyrus communis Nutrition 0.000 claims 1
- 239000006166 lysate Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 22
- 239000000126 substance Substances 0.000 abstract description 3
- 208000035240 Disease Resistance Diseases 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 150000002823 nitrates Chemical class 0.000 abstract description 2
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- 238000003900 soil pollution Methods 0.000 abstract description 2
- 241000209094 Oryza Species 0.000 abstract 3
- 238000011282 treatment Methods 0.000 description 33
- 235000003953 Solanum lycopersicum var cerasiforme Nutrition 0.000 description 14
- 240000003040 Solanum lycopersicum var. cerasiforme Species 0.000 description 14
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- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 description 5
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- 244000025254 Cannabis sativa Species 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
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- 244000081841 Malus domestica Species 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 244000200882 Setaria barbata Species 0.000 description 2
- 235000001561 Setaria barbata Nutrition 0.000 description 2
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- 210000003608 fece Anatomy 0.000 description 2
- 229910052747 lanthanoid Inorganic materials 0.000 description 2
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- 238000011160 research Methods 0.000 description 2
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- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
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- 239000003153 chemical reaction reagent Substances 0.000 description 1
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- 229930002869 chlorophyll b Natural products 0.000 description 1
- NSMUHPMZFPKNMZ-VBYMZDBQSA-M chlorophyll b Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C=O)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 NSMUHPMZFPKNMZ-VBYMZDBQSA-M 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
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- 230000001186 cumulative effect Effects 0.000 description 1
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- 235000019441 ethanol Nutrition 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 235000008216 herbs Nutrition 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
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- 239000000463 material Substances 0.000 description 1
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- 244000005700 microbiome Species 0.000 description 1
- LFLZOWIFJOBEPN-UHFFFAOYSA-N nitrate, nitrate Chemical compound O[N+]([O-])=O.O[N+]([O-])=O LFLZOWIFJOBEPN-UHFFFAOYSA-N 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G7/00—Botany in general
- A01G7/06—Treatment of growing trees or plants, e.g. for preventing decay of wood, for tingeing flowers or wood, for prolonging the life of plants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Ecology (AREA)
- Forests & Forestry (AREA)
- Pest Control & Pesticides (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Botany (AREA)
- Environmental Sciences (AREA)
- Fertilizers (AREA)
- Cultivation Of Plants (AREA)
Abstract
본 발명은 사료 작물에 대하여 희토류 원소로 이루어진 비료를 물에 희석하여 20ppm 또는 800ppm의 농도로 맞추어 사용하는 방법 및 과수, 채소 또는 벼에 사용하는 방법에 관한 것으로, 상세하게는 본 발명의 희토비료를 사료작물에 살포할 경우 사료작물 종자의 출현율 및 출현속도를 증가시켜 사료작물의 수량을 증대시키게 하며, 또한 과수, 채소 또는 벼의 생장을 촉진시키며 그 품질을 향상시킨다. 희토는 자연계에 보편적으로 존재하는 것으로서 내병성 및 내환경성증진, 농약 잔류량 및 질산염의 강하효과가 있기에 농약에 대해 안정적으로 작물을 재배할 수 있을 뿐만 아니라 화학비료와 같이 토양오염의 염려가 없이 작물의 품질향상 및 증대된 수량으로 수확할 수 있어 작물의 재배에 용이하게 이용할 수 있다.The present invention relates to a method of diluting a fertilizer consisting of rare earth elements in a feed crop to water at a concentration of 20 ppm or 800 ppm, and to a method for using fruit trees, vegetables or rice, and in particular, the rare earth fertilizer of the present invention. When applied to feed crops, the yield and feed rate of feed crop seeds are increased to increase the yield of feed crops, and also to promote the growth and quality of fruit trees, vegetables or rice. Rare earth is universally present in nature and has the effect of increasing disease resistance and environmental resistance, pesticide residues and nitrates, which makes it possible to cultivate crops stably against pesticides and to improve the quality of crops without fear of soil pollution such as chemical fertilizers. Improved and increased yields allow easy utilization of crops.
희토, 사료작물, 과수, 채소, 벼, 비료 Rare earth, fodder crops, fruit trees, vegetables, rice, fertilizer
Description
본 발명은 사료 작물에 대하여 희토류 원소로 이루어진 비료를 물에 희석하여 20ppm 또는 800ppm의 농도로 맞추어 사용함으로서 사료작물의 수량을 증대시키는 방법에 관한 것이다. 또한, 희토류 원소로 이루어진 비료를 600-1300배의 물에 희석하여 과수, 채소 또는 벼에 살포하여 농산물의 수량 및 품질을 향상시키는 사용방법에 관한 것이다.The present invention relates to a method of increasing the yield of feed crops by diluting fertilizers of rare earth elements with water at a concentration of 20 ppm or 800 ppm for feed crops. The present invention also relates to a use method of diluting a fertilizer consisting of rare earth elements in 600-1300 times of water and spraying it on fruit trees, vegetables or rice to improve the yield and quality of agricultural products.
비료는 토양의 생산력을 유지 또는 증진시키고, 작물을 잘 생장시키기 위하여 토양 또는 식물에 투입하는 영양물질과 직접적으로는 작물의 영양물질이 되지는 않더라도 토양의 물리적 화학성 등을 개선하고 유용한 미생물들을 증진시키며, 토양중에 식물에 이용될 수 없는 형태로 있는 양분을 이용이 가능한 형태로 바꾸어 준다든지, 유독성 물질의 독성을 저감시키는 등 간접적으로 작물의 생육에 도움을 주는 물질을 통틀어 일컫는다.Fertilizers help maintain or enhance soil productivity, improve the physical chemistry of soils, even if they are not directly nutrients to soils or plants to grow crops, and improve useful microorganisms. In other words, it refers to a substance that helps indirectly grow crops, such as converting nutrients in a form that cannot be used in plants in the soil to a form that can be used or reducing toxicity of toxic substances.
최근 환경과 건강에 대한 관심이 높아지면서 친환경 농법에 의한 농산물 생 산이 최근 확대일로에 있다. 안전 농산물에 대한 수요증가와 국제적으로 강화되고 있는 농업환경 관련 규제가 앞으로는 친환경농업으로 갈 수 밖에 없는 상황이다. 여러 가지 친환경 농법 중 최근 희토에 대한 관심이 많아지면서 희토에 의한 친환경 농산물 생산에 대한 연구가 가축, 사료작물. 채소, 과수 및 경종작물 등 농업전반에 걸쳐 활발하게 진행되고 있다.As interest in the environment and health has increased recently, the production of agricultural products by eco-friendly farming methods has recently been expanding. Increasing demand for safe agricultural products and the tightening international regulations on agri-environment will lead to eco-friendly agriculture. Recently, as interest in rare earths has increased among various eco-friendly farming methods, research on the production of eco-friendly agricultural products by rare earths has been carried out in livestock and feed crops. It is active throughout agriculture, including vegetables, fruit trees and seed crops.
희토류(稀土類, rare earth elements, REE)는 원소 주기율표의 원자번호 57부터 71까지의 란탄족(lanthanides) 원소 15가지(La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu)와 원자번호 21인 Scandium(Sc)과 39인 Yterium(Y)을 합친 총 17개 원소를 통틀어 말하는 것이다. 희토류 원소는 자연계 중에 보편적으로 존재하는데 토양중에는 0.015~0.025%가 함유되어 있으며, 물, 공기, 동식물체(0.002~0.057%)에도 미량이 함유되어 있다. 최근 희토류는 일반적으로 촉매, 자석, 야금, 유리 및 세라믹, 전자기술 또는 초전도체 분야에서 각광받는 소재로서 이용되고 있으나, 농업에 접목하여 연구는 활발히 하고 있으나 그 성과는 아직 주목할 만 하지 못하다.Rare earth elements (REE) are 15 lanthanides elements (La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy) from atomic number 57 to 71 of the periodic table of the elements. , Ho, Er, Tm, Yb, Lu), and the total 17 elements of the atomic number 21 Scandium (Sc) and 39 Yterium (Y). Rare earth elements are commonly present in nature. Soil contains 0.015 to 0.025%, and traces of water, air and animals and plants (0.002 to 0.057%) are also very small. Recently, rare earths are generally used as materials in the fields of catalysts, magnets, metallurgy, glass and ceramics, electronic technology or superconductors, but researches are actively conducted in conjunction with agriculture, but the results are not remarkable yet.
이에 본 발명자들은 희토류 원소로 이루어진 비료가 사료작물, 과수, 채소 또는 벼에 미치는 영향을 실험하여 사료작물에 대하여 생장, 수량증대, 품질향상 등에 탁월한 효과가 있음을 확인함으로서 본 발명을 완성하였다.The present inventors have completed the present invention by confirming that the fertilizer consisting of rare earth elements on the feed crops, fruit trees, vegetables or rice, have an excellent effect on growth, yield, quality improvement, etc. for feed crops.
본 발명의 목적은 사료 작물에 대하여 희토류 원소로 이루어진 비료를 물에 희석하여 20ppm 또는 800ppm의 농도로 맞추어 사용함으로서 사료작물의 수량을 증대시키는 방법을 제공하는 것이다. 또한, 희토류 원소로 이루어진 비료를 600-1300배의 물에 희석하여 과수, 채소 또는 벼에 살포하여 농산물의 수량 및 품질을 향상시키는 방법을 제공하는 것이다.It is an object of the present invention to provide a method of increasing the yield of feed crops by diluting fertilizers of rare earth elements in water and using them at a concentration of 20 ppm or 800 ppm. In addition, to provide a method of improving the yield and quality of agricultural products by diluting the fertilizer consisting of rare earth elements in 600-1300 times of water and sprayed on fruit trees, vegetables or rice.
상기 목적을 달성하기 위하여, 본 발명은 사료 작물에 대하여 희토류 원소로 이루어진 비료를 물에 희석하여 20ppm 또는 800ppm의 농도로 맞추어 사용함으로서 사료작물의 수량을 증대시키는 방법을 제공한다.In order to achieve the above object, the present invention provides a method for increasing the yield of feed crops by using a fertilizer consisting of rare earth elements for feed crops by diluting in water to a concentration of 20ppm or 800ppm.
상기 사료 작물은 옥수수, 수수, 이탈리안라이그라스, 수단그라스 등이 포함된다.The feed crops include corn, sorghum, Italian lygras, Sudangrass and the like.
또한, 본 발명은 희토류 원소로 이루어진 비료를 600-1300배의 물에 희석하여 과수, 채소 또는 벼에 살포하여 농산물의 수량 및 품질을 향상시키는 방법을 제공한다.In addition, the present invention provides a method for improving the yield and quality of agricultural products by diluting the fertilizer consisting of rare earth elements in 600-1300 times of water to spray on fruit trees, vegetables or rice.
상기 희토류 원소는 La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Sc 및 Y로 이루어진 군으로부터 선택된 1종 이상의 원소를 포함하는 것을 의미한다.The rare earth element includes one or more elements selected from the group consisting of La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Sc, and Y it means.
이하, 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.
본 발명은 사료 작물에 대하여 희토류 원소로 이루어진 비료를 물에 희석하 여 20ppm 또는 800ppm의 농도로 맞추어 사용함으로서 사료작물의 수량을 증대시키는 방법으로, 상기 사료작물에 살포하는 경우는 근부처리, 수면처리, 엽면처리 등이 가능하며, 사료작물의 종자를 상기 비료희석용액에 침지한 후에 음건하여 종자를 토양에 파종할 수 있다. 본 발명의 비료만을 사용할 수도 있으며, 일반적인 비료와 함께 사용이 가능하다.The present invention is a method of increasing the yield of feed crops by diluting the fertilizer consisting of rare earth elements to water at a concentration of 20ppm or 800ppm for feed crops, and when spraying the feed crops, root treatment and sleep treatment. , Foliar treatment, etc., and soak the seeds of the feed crop in the fertilizer dilution solution and then soak the seeds in the soil. Only the fertilizer of the present invention can be used, it can be used with a general fertilizer.
상기 희토류 원소는 원소 주기율표의 원자번호 57부터 71까지의 란탄족(lanthanides) 원소 15가지(La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu), 원자번호 21인 스칸디움(Sc) 및 원자번호 39인 이테리움(Y)으로 이루어진 군으로부터 선택된 1종 이상의 원소를 포함하는 것을 의미한다.The rare earth elements are 15 kinds of lanthanide elements (La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb) from atomic number 57 to 71 of the periodic table of the elements. , Lu), scandium (Sc) with atomic number 21, and iterium (Y) with atomic number 39, means one or more elements selected from the group consisting of.
상기 사료작물은 가축에게 먹이기 위하여 재배되는 작물로서, 영양가가 높고 가축의 기호성이 좋으며 단위면적당 생산량도 많아야 하며, 그 종류는 약 400여 종이 있으며 일반적으로 목초류, 풋베기작물, 근채류로 크게 분류하고 있다. 목초류에는 오처드그라스, 이탈리안라이그라스, 수단그라스, 티머시, 톨페스큐, 레드톱 등의 화본과 목초와 레드클로버, 화이트 클로버, 앨팰퍼, 헤어리베치 등의 콩과 목초가 있으며, 풋베기 작물에는 풋베기 옥수수, 풋베기수수, 풋베기호밀, 풋베기콩 등과 같은 식용작물이 있으며, 근채류에는 사료용 비트, 사료용 순무 등이 포함된다. 본 발명의 비료는 상기 사료작물에 모두 이용가능하며, 바람직하게는 옥수수, 수수, 이탈리안그라스, 수단그라스 등에 이용가능하다.The feed crop is a cultivated crop for feeding livestock, has high nutritional value, good palatability, and high yield per unit area. The species is about 400 species, and is generally classified into grasses, green crops, and root vegetables. have. Herbs include orchards such as Orchardgrass, Italian Ryegrass, Sudangrass, Timothy, Tolsquescuis, and Redtop, as well as soybeans and grasses such as grasses, red clover, white clover, al-palfer, and hair lybech. Edible crops such as corn, green sorghum, green buckwheat rye, green stalk beans, etc., and root vegetables include feed beets, feed turnips, and the like. The fertilizer of the present invention can be used for all the feed crops, preferably corn, sorghum, Italian grass, Sudangrass and the like.
또한, 본 발명은 희토류 원소로 이루어진 비료를 600-1300배의 물에 희석하여 과수, 채소 또는 벼에 살포하여 농산물의 수량 및 품질을 향상시키는 사용방법 을 제공한다.In addition, the present invention provides a use method of improving the yield and quality of agricultural products by diluting the fertilizer consisting of rare earth elements in 600-1300 times of water to spray on fruit trees, vegetables or rice.
이하, 본 발명을 하기의 실시예 및 실험예에 의하여 상세히 설명한다. 다만, 하기의 실시예 및 실험예는 본 발명의 예시이며, 본 발명의 권리범위가 이에 의하여 한정되지 아니한다.Hereinafter, the present invention will be described in detail by the following Examples and Experimental Examples. However, the following Examples and Experimental Examples are examples of the present invention, and the scope of the present invention is not limited thereto.
실시예 1. 희토류 원소를 포함하는 비료의 제조Example 1 Preparation of Fertilizer Including Rare Earth Elements
희토원료를 물에 희석하여 20, 50, 100, 300, 800, 1000, 1300 ppm 농도로 제조하였다.Rare earth raw materials were diluted in water to prepare 20, 50, 100, 300, 800, 1000, 1300 ppm concentration.
실험예 1. 사료작물의 출현에 미치는 영향Experimental Example 1. Effect on the appearance of feed crops
전북대학교 사료작물학 실험실에서 2001년 11월 12일에 상기 실시예 1에서 제조한 희토 0, 50, 100, 300, 500, 800ppm 용액에 옥수수와 이탈리안라이그라스 종자를 각각 6시간동안 침지한 다음 실온에서 음건하여 실험에 사용하였다. 버미큐라이트(Bermiculite)를 2cm 깊이로 채운 직경 20cm 패트리 디쉬에 100립씩 초종당 4반복으로 파종한 다음 1cm깊이로 복토하여 단단하게 눌러 주었다. 수분은 발아에 충분하도록 일정량을 공급하였으며, 2∼3일 간격으로 보충하여 주었다. 매일 일정한 시간에 출현된 개체수를 조사하여 Hsu 등(1984)의 로지스틱 모델(logistic model)을 적용하여 하기 수학식 1 및 2를 이용하여 사료작물의 출현력을 산출하였다. 하기 수학식 1의 CER은 Cumulative Emergence Percentage, ER은 Emergence Rate이다.Corn and Italian lygrase seeds were soaked for 6 hours in a rare earth 0, 50, 100, 300, 500, and 800 ppm solution prepared in Example 1 on November 12, 2001 in Chonbuk National University, and then at room temperature. The shade was used for the experiment. Vermiculite was seeded in 4 repetitions per plant in 20 cm diameter Petri dishes filled with 2 cm deep, and then covered with 1 cm deep and pressed firmly. Moisture was supplied in sufficient amount to germinate, and supplemented every two to three days. By examining the number of individuals appeared at a certain time every day, the logistic model of Hsu et al. (1984) was applied to calculate the appearance power of feed crops using Equations 1 and 2 below. CER of Equation 1 is Cumulative Emergence Percentage, and ER is Emergence Rate.
상기 실험 수행의 결과, 하기 표 1 및 표 2에서 보는 바와 같이 옥수수의 경우 출현속도는 희토 300ppm에서 4.9% 향상되었으며 최대출현속도도 무처리구 5.9에 비해 300ppm 처리구에서는 8.1로 37.3%가 향상되었다(p<0.01). 총 출현율의 50%에 도달하는 일수는 희토 처리로 0.4일이 단축되어 옥수수 종자에 300ppm의 희토를 처리함으로서 단시일 내에 많은 종자가 출현되고 출현에 소요되는 일수도 단축시키는 효과가 있음을 확인할 수 있었다.As a result of the experiment, as shown in Table 1 and Table 2, the appearance rate of corn was improved 4.9% in rare earth 300ppm, and the maximum emergence rate was 37.3% in 8.1 in 300ppm treated area compared with 5.9 (p < 0.01). The number of days reaching 50% of the total appearance rate was shortened by 0.4 days by rare earth treatment. By treating 300 ppm of rare earth in corn seeds, many seeds appeared in a short time and the number of days required for emergence was also shortened.
이탈리안라이그라스 종자의 경우, 희토농도 800ppm에서 총 출현율은 11.6%, 출현속도는 9.5%가 향상되어 가장 높은 효과가 나타남을 확인할 수 있었다.In the case of Italian Ryegrass seeds, the total appearance rate was 11.6% and the appearance rate was improved by 9.5% at the rare earth concentration of 800ppm.
실험예 2. 사료작물의 수량에 미치는 영향Experimental Example 2. Effect on the yield of feed crops
상토에 옥수수, 수수, 이탈리안라이그라스 종자를 2002년 4월 6일에 파종하여 정착된 유식물을 5월 1일에 이식하여 양액재배하였다. Lincoln액을 사용하여 양액재배(DFT 방식)하였는데 용액조성은 하기 표 3과 같다. 초종별로 4 반복, 반복당 8주씩 난괴법으로 배치하여 재배하였다. 상기 실시예 1에서 제조한 희토 0, 20, 50, 100, 300, 800ppm 용액을 5월 4일과 5월 22일에 각각 엽면살포하여 6월 17일에 수확하였다.Corn, sorghum, and Italian lygras seeds were sown on April 6, 2002, and seedlings settled were transplanted on May 1, and nutrient-cultivated. The nutrient solution cultivation (DFT method) using Lincoln solution, the solution composition is shown in Table 3. 4 repetitions for each species, 8 weeks per repetition was arranged by cultivation method. Rare earth 0, 20, 50, 100, 300, 800ppm solution prepared in Example 1 was harvested on June 17 by foliar spray on May 4 and May 22, respectively.
상기 실험 수행의 결과, 하기 표 4 내지 표 6에서 보는 바와 같이 옥수수의 경우 옥수수의 지상부와 지하부 생육이 크게 향상되었으며 희토농도가 300ppm일 때 가장 좋은 결과를 나타났으며, 300ppm 처리로 옥수수 지상부와 지하부 생장량은 건물중이 무처리구에 비해 각각 25.9%와 79.5%가 증가하여 지상부에 비해 지하부 생육이 크게 향상됨을 확인할 수 있었다(표 4 참조). As a result of the experiment, as shown in Tables 4 to 6 below, the growth of the ground and underground parts of corn was greatly improved, and the best results were obtained when the rare earth concentration was 300 ppm, and the corn ground and underground parts were treated with 300 ppm. Growth rate of the building increased 25.9% and 79.5%, respectively, compared to the untreated area, and it was confirmed that the growth of the underground part was significantly improved compared to the ground part (see Table 4).
수단그라스의 경우 희토농도가 증가할수록 생육이 크게 향상되어 800ppm에서 생장이 가장 우수하였는바, 800ppm 처리로 수단그라스의 지상부와 지하부 건물중은 무처리에 비해 각각 64.8% 및 138.9%의 향상효과를 보여주었으며 통계적으로도 유의성(p<0.001)이 매우 높음을 확인할 수 있었다.In the case of Sudangrass, as the rare earth concentration increased, the growth was the highest at 800 ppm. The 800 ppm treatment resulted in 64.8% and 138.9% improvement in the ground and underground buildings of Sudangrass, respectively. Statistical significance was also found to be very high (p <0.001).
이탈리안라이그라스의 경우에는 옥수수와 수단그라스에 비해 희토 처리효과가 현저하지는 않으나 희토 300ppm 처리로 지상부 건물중은 48.8%, 지하부는 21.4%가 향상됨을 확인할 수 있었다. 상기의 결과를 종합하여 본 결과 옥수수와 수단그라스의 경우는 희토 처리로 인하여 지상부보다는 지하부의 생육이 크게 향상되나, 이탈리안라이그라스의 경우에는 지하부보다 지상부의 생육이 향상됨을 확인할 수 있었다.In the case of Italian lygras, the rare earth treatment effect was not as remarkable as that of corn and sudangrass, but the rare earth 300ppm treatment improved 48.8% in the above-ground buildings and 21.4% in the underground. As a result of the synthesis of the above results, the growth of the subterranean portion of the corn and Sudangrass due to the rare earths significantly improved than the ground portion, it was confirmed that the growth of the ground portion than the underground portion in the case of Italian Ryegrass.
실험예 3. 사과의 생장 및 품질에 미치는 영향Experimental Example 3. Effect on Growth and Quality of Apples
전북 정읍시 이평면 도계리 소재 사과농장에서 희토비료를 처리하지 않은 대조구와 상기 실시예 1에서 제조한 희토비료를 처리한 희토처리구로 처리당 1,000평씩 구분하였다. 사과품종은 희상(조생종)이며 희토(동성엔씨티, 전북 정읍) 시용은 2003년 4월 15일에 상기 희토의 1,000배액을, 6월 7일에 800배액, 8월 8일에 600배액을 각각 엽면살포하여 사과의 생장 및 품질에 미치는 영향을 관찰하였다.In the apple farm in Dogye-ri, Ipyeong-myeon, Jeongeup-si, Jeollabuk-do, the control was not treated with the rare earth fertilizer and the rare earth fertilizer treated with the rare earth fertilizer prepared in Example 1 by 1,000 pyeong per treatment. Apple varieties are rare (early varieties), and rare earth (Dongsung NC City, Jeonbuk Jeongeup) application is 1,000 times of rare earth on April 15, 2003, 800 times on June 7, and 600 times on August 8. Leaf spraying was observed to influence the growth and quality of apples.
사과 과피색은 색차계(NR-1, Nippon, Denshoku)를 사용하여 red∼green, +70 ∼ -70의 범위에서 측정하였다. 당도측정은 Hand Refractometer(Atago N-1α, Japan)를 사용하였으며, 잎 두께는 Digimatic Caliper(Mitutoyo, Japan)를 이용하였다.Apple skin color was measured in the range of red to green and +70 to -70 using a color difference meter (NR-1, Nippon, Denshoku). The glucose content was measured using a Hand Refractometer (Atago N-1α, Japan) and the leaf thickness was measured using a Digimatic Caliper (Mitutoyo, Japan).
상기실험 수행의 결과, 하기 표 7에서 보는 바와 같이 본 발명의 희토비료를 처리한 군에서는 사과 잎의 폭과 길이가 커졌으며, 잎의 두께도 본 발명의 희토비료를 처리하지 않은 대조구의 0.41mm에 비해 희토 처리구는 0.45mm로 9.8%가 더 두꺼워졌다. 잎의 무게는 희토처리로 14.3%가 더 무거워져서 광합성에 유리한 조건이 되었다. 또한 하기 표 8에서 보는 바와 같이 개당 사과 무게의 경우 대조구는 평균 173.6g이었으며 희토처리구는 평균 189.3g으로 9.3%가 더 무거워졌다. 또한 희토처리로 사과의 경도가 증가하여 맛이 좋아지고 저장성도 증가하였으며, 당도가 22.3% 증가하였다. 사과 과피색의 적색도는 대조규의 21.8에 비해 희토처리구는 31.5로 희토처리를 함으로서 사과의 색깔이 더 붉어지고 선명하여져 종합적으로 사과의 품질이 향상되었음을 확인할 수 있었다. As a result of the above experiment, in the group treated with the rare earth fertilizer of the present invention, as shown in Table 7, the width and length of the apple leaves were increased, and the thickness of the leaves was 0.41 mm of the control without the rare earth fertilizer of the present invention. The rare earth treated area was 0.45mm thicker than 9.8%. The leaves weighed 14.3% heavier with rare earths, making them a favorable condition for photosynthesis. In addition, as shown in Table 8, the average apple weight per control was 173.6 g, and the rare earth treatment was 189.3 g, which was 9.3% heavier. In addition, the hardness of the apples increased with the rare earth treatment, which improved the taste and shelf life and increased the sugar content by 22.3%. The redness of apple skin color was 31.5 in rare earth treated area compared to 21.8 of control, so the color of apple became redder and clearer.
실험예 4. 방울토마토의 생장 및 품질에 미치는 영향Experimental Example 4. Effect on the growth and quality of cherry tomato
전북 장수군 소재 가나안 프러그에서 구입한 방울토마토(var. 꼬꼬방울) 모종을 전북 전주시 호성동 3가 114번지 소재 비닐하우스 포장에 2004년 4월 6일에 정식하였다. 주폭 35cm, 휴폭 50cm 간격으로 대조구, 희토처리구로 구분하여 처리당 4반복, 반복당 12주씩 난괴법으로 배치하였다. 농가관행으로 시비관리 및 측지 제거작업을 하였다. 희토비료의 1회 살포는 희토(동성엔씨티, 전북 정읍)의 1,300배액을 2004년 4월 6일에 엽면살포하였고, 2회와 3회는 1,000배액을 4월 21일과 5월 10일에 각각 엽면살포 하였다. 물은 토양의 수분상태를 관찰하면서 보충하였으며, 1차수확은 6월 14일에, 2차수확은 6월 28일에 하였다. 수확한 방울 토마토의 잎 및 줄기의 두께는 Digimatic Caliper(Mitutoyo, Japan)를 이용하여, 방울 토마토의 당도 측정은 Hand Refractometer (Atago N-1α, Japan)를, 방울 토마토의 경도는 Fudoh Rheo Meter(Rheotech, Japan)를 사용하여 과육의 경도를 측정하였다.Cherry tomatoes (var. Cocculi) seedlings purchased from the Canaan Frog, Jangsu-gun, Jeonbuk, were formally packaged on April 6, 2004 in a plastic house packaging at 3ga, Hoseong-dong, Jeonju-si, Jeonbuk-si. At the interval of 35cm in circumference and 50cm in width, the control and rare earth treatments were divided into 4 repetitions per treatment and 12 weeks per repetition. As farm practices, fertilization management and geodetic removal were performed. One-time spraying of rare earth fertilizers spread 1,300 times of rare earth (Dongsung NC City, Jeongeup, Jeonbuk) on April 6, 2004, and 2 times and 3 times of 1,000 times on April 21 and May 10, respectively. Foliar sprayed. Water was supplemented by observing soil moisture conditions, with primary harvesting on June 14 and secondary harvesting on June 28. The thickness of the leaves and stems of the harvested cherry tomatoes was measured using Digimatic Caliper (Mitutoyo, Japan), and the sugar content of the cherry tomatoes was measured using a Hand Refractometer (Atago N-1α, Japan), while the hardness of the cherry tomatoes was Fudoh Rheo Meter (Rheotech). , Japan) was used to measure the hardness of the pulp.
상기 실험 수행의 결과, 하기 표 9에서 보는 바와 같이 방울토마토에 본 발명의 희토비료를 처리한 결과 평균 절간 길이가 짧아졌으며, 제1화방경과 제2화방경의 높이가 낮아졌으며 줄기의 직경이 커지고 잎이 두꺼워졌음을 확인할 수 있었다. 또한 하기 표 10에서 보는 바와 같이 희토 처리는 방울토마토의 수확과수를 늘리고 수량도 크게 많아졌다. 제1화방의 수확과수는 희토 처리가 대조구에 비해 24%가 증가되었고, 수량도 약 21%가 증수되었다. 제2화방에서도 마찬가지로 희토 처리는 수확과수와 수량을 크게 증가시켰다(p<0.01). 식물체당 총 수량에서는 희토처리구는 대조구에 비해 약 19%의 수량이 증가되었는 바, 본 발명의 희토비료는 방울토마토의 생육에 영향을 미쳐 방울토마토의 수확량을 증가시킴을 확인할 수 있었다. As a result of the experiment, as shown in Table 9, the result of treatment of the rare earth fertilizer of the present invention in cherry tomatoes, the average intercution length was shortened, the height of the first and second flower diameters was lowered, the diameter of the stem was larger and the leaves This thickening was confirmed. In addition, as shown in Table 10 below, the rare earth treatment increased the fruit yield of cherry tomatoes and increased the yield. Harvesting fruit of the first flower garden was increased by 24% in rare earths and 21% in yield. Similarly in the second flower garden, rare earth treatments significantly increased the yields and yields (p <0.01). In the total yield per plant, the rare earth treatment was increased by about 19% of the yield compared to the control. The rare earth fertilizer of the present invention was confirmed to increase the yield of cherry tomatoes by affecting the growth of cherry tomatoes.
하기 표 11에서 보는 바와 같이 방울토마토의 개당 평균무게(1과중)는 대조구가 9.66g인 반면 희토처리구는 10.24g으로 약 6%가 더 무거웠다. 희토처리로 토마토의 당도가 증가되었으며, 과일의 경도도 유의하게(p<0.01) 증가되어 본 발명의 희토비료가 방울 토마토의 품질을 향상시킴을 확인할 수 있었다.As shown in Table 11 below, the average weight of the cherry tomatoes (1 overweight) was 9.66 g in the control, while the rare earth treated was 10.24 g, which was about 6% heavier. Rare earth treatment increased the sugar content of the tomato, fruit hardness was also significantly increased (p <0.01) was confirmed that the rare earth fertilizer of the present invention improves the quality of cherry tomatoes.
실험예 5. 벼의 생장 및 수량에 미치는 영향Experimental Example 5. Effects on Rice Growth and Yield
본 발명의 희토비료가 벼의 생육 및 수량에 미치는 영향을 관찰하기 위하여 하기와 같은 실험을 수행하였다.In order to observe the effect of the rare earth fertilizer of the present invention on the growth and yield of rice was carried out the following experiment.
본 발명의 희토비료를 처리하지 않은 대조구와 본 발명의 희토비료를 처리한 희토처리구 각각 1,200평에 N-P-K 비율이 23-9-14인 복합비료를 10a당 1포씩 기비로 2003년 6월 12일에 시비하여 6월 14일에 모내기(품종명: 밀양 142호)를 하였다. 6월 21일에는 요소비료를 10a당 20kg씩 분얼기 비료로 살포하였으며 8월 5일에 이삭거름으로 복합비료(18-0-16)를 10a당 20kg씩 시비하였다. 상기 실시예 1에서 제조한 희토 1,000배액을 7월 20일, 8월 20일, 9월 18일에 3회에 걸쳐 엽면살포하였다.On June 12, 2003, a mixed fertilizer having an NPK ratio of 23-9-14 was added to 1,200 pyeong each of the control group not treated with the rare earth fertilizer and rare earth fertilizer treated with the present invention. It was planted on June 14 and planted (variety name: Miryang 142). On June 21, 20 kg of urea fertilizer was sprayed with a manure fertilizer and 10 kg of compound fertilizer (18-0-16) was fertilized with ear manure on 5 August. The rare earth 1,000 times liquid prepared in Example 1 was foliarly sprayed three times on July 20, August 20, and September 18.
벼 잎의 엽록소 함량을 측정하기 위하여 생초 1g을 80% 에틸알콜 20ml로 추출하여 80% 아세톤을 가한 용액을 UV Visible Spectrophotometer(Pharmacia Biotech, England)로 663 및 645nm에서 각각 클로로필-a와 b를 측정하여(농기연법, 1975) Bruinsma 방법(1961)으로 계산하였다. 질산태 질소를 측정하기 위하여 Paul 및 Carlson 방법(1968)을 수정하여 분석하였는데, 65℃에서 건조한 40mesh 크기의 시료 500mg에 이온수 100ml를 첨가하여 1분간 혼합한 다음 활성탄 4g을 넣어 잘 혼합하여 여과하였다. 여과액 25ml에 Nitraver 5 Nitrate Reagent Power Pillow 1개를 넣고 즉시 뚜껑을 닫은 후 정확히 1분간 흔들어 NeoMet Ion Meter(Multi-Analyzer, Istek Inc.)의 nitrate electrode로 mV가를 측정한 다음 semi-logarithmic graph를 이용하여 질산태질소 함량을 산출하였다. In order to measure the chlorophyll content of rice leaves, 1 g of raw grass was extracted with 20 ml of 80% ethyl alcohol, and 80% acetone was added to the chlorophyll-a and b at 663 and 645 nm using UV Visible Spectrophotometer (Pharmacia Biotech, England). (Agrotechnical method, 1975) Calculated by Bruinsma method (1961). In order to measure nitrogen nitrate, Paul and Carlson method (1968) was modified and analyzed. 500 mg of 40-mesh sample dried at 65 ° C. was added to 100 ml of ionized water for 1 minute, and then mixed with 4 g of activated carbon and filtered well. Add 1 Nitraver 5 Nitrate Reagent Power Pillow to 25 ml of the filtrate, immediately close the lid, shake it for exactly 1 minute, measure the mV value with the nitrate electrode of NeoMet Ion Meter (Multi-Analyzer, Istek Inc.), and then use the semi-logarithmic graph. The nitrogen nitrate content was calculated.
상기 실험 수행의 결과, 하기 표 12에서 보는 바와 같이 잎 두께는 대조구 0.534mm에 비해 희토처리구의 두께는 0.626mm로 본 발명의 희토비료를 처리한 경우에는 잎이 두꺼워지고, 엽폭 및 엽장 역시 희토 처리로 큰폭으로 커졌음을 확인할 수 있었다. 벼의 줄기나 이삭직경은 약간 커지긴 하였으나 통계적인 유의성은 없었다. 또한 하기 표 13에서 보는 바와 같이 항도복성은 대조구 355.4, 희토 처리구 436.9g으로 본 발명의 희토비료를 처리한 희토처리구가 22.9% 더 도복에 강함을 확인할 수 있었다.As a result of the above experiment, as shown in Table 12, the leaf thickness is 0.626 mm in the thickness of the rare earth treated group compared to the control 0.534 mm, and when the rare earth fertilizer of the present invention is treated, the leaf becomes thick, and the leaf width and the leaf length are also rare earth treated. It can be confirmed that the significantly increased. The stem and ear diameter of rice grew slightly, but there was no statistical significance. In addition, as shown in Table 13, the anti-recoverability of the control group 355.4, 436.9g rare earth treatment was confirmed that the rare earth treatment treated with the rare earth fertilizer of the present invention 22.9% more resistant to dobok.
벼 잎의 엽록소 함량 및 질산태질소 함량의 경우, 하기 표 14에서 보는 바와 같이 엽록소 함량은 대조구와 희토처리구가 각각 9.7과 12.2㎍/㎖으로 본 발명의 희토비료 처리구가 25.8% 증가되었음을 확인할 수 있었고, 질산태질소는 본 발명의 희토비료처리로 대조구에 비해 31.8%가 감소됨을 확인할 수 있었다. 한편 벼의 수량의 경우, 하기 표 15에서 보는 바와 같이 이삭당 평균 정조수는 대조구 105.7개에 비해 희토구는 118.2개 이었으며, 유효분얼경 수는 대조구는 포기당 13.2개이었으며 희토구는 15.3개이었다. 반면 포기당 무효분얼경 수는 대조구는 0.9개이었으나 희토구는 0.3개로 본 발명의 희토비료처리로 양분이 유효분얼경 발생과 정조생산에 효과적으로 활용되었음을 알 수 있었다. 단보당 정조생산량에 있어서는 대조구 750kg에 비해 희토 처리구 860kg으로 약 15%의 증수효과가 있음을 확인할 수 있었다.In the case of chlorophyll content and nitrate nitrate content of rice leaves, as shown in Table 14, the chlorophyll content of the control and the rare earth treatments were 9.7 and 12.2 ㎍ / ml, respectively, and it was confirmed that the rare earth fertilizer treatment of the present invention was increased by 25.8%. , Nitrogen nitrate was found to be reduced by 31.8% compared to the control by the rare earth fertilizer treatment of the present invention. On the other hand, as shown in Table 15, the average purified water per ear was 118.2 rare earths compared to 105.7 control, the effective number of grains was 13.2 per abandonment and 15.3 rare earths. On the other hand, the number of invalid powders per abandonment was 0.9, but the rare earths were 0.3. As a result of the rare earth fertilizer treatment of the present invention, it was found that the nutrients were effectively used for the generation of effective powders and in crude production. In the crude production per Danbo, it was confirmed that the increase of about 15% was achieved with 860kg of rare earth treatment compared to 750kg of control.
상술한 바와 같이, 본 발명은 사료 작물에 대하여 희토류 원소로 이루어진 비료를 물에 희석하여 20ppm 또는 800ppm의 농도로 맞추어 사용함으로서 사료작물의 수량을 증대시키는 방법 및 희토류 원소로 이루어진 비료를 600-1300배의 물에 희석하여 과수, 채소 또는 벼에 살포하여 농산물의 수량 및 품질을 향상시키는 사용방법을 제공한다. 본 발명의 희토비료를 옥수수, 이탈리안라이그라스, 수수, 수단그라스 등의 사료작물에 살포할 경우 사료작물 종자의 출현율 및 출현속도를 증가시켜 사료작물의 수량을 증가시킨다. 또한 과수, 채소 또는 벼에 사용할 경우 생장을 촉진시키고 품질을 향상시킨다. 희토는 자연계에 보편적으로 존재하는 것으로서 내병성 및 내환경성증진, 농약 잔류량 및 질산염의 강하효과가 있기에 농약에 대해 안정적으로 작물을 재배할 수 있을 뿐만 아니라 화학비료와 같이 토양오염의 염려가 없이 작물의 품질향상 및 증대된 수량으로 수확할 수 있어 작물의 재배에 용이하게 이용할 수 있다.As described above, the present invention is a method for increasing the yield of feed crops by diluting the fertilizer made of rare earth elements in water to a concentration of 20ppm or 800ppm for feed crops and 600-1300 times the fertilizer made of rare earth elements It is diluted with water and sprayed on fruit trees, vegetables or rice to provide a method of improving the yield and quality of agricultural products. When the rare earth fertilizer of the present invention is applied to feed crops such as corn, Italian lygras, sorghum and sudangrass, the yield and feed rate of feed crop seeds are increased to increase the yield of feed crops. It also promotes growth and improves quality when used on fruit trees, vegetables or rice. Rare earth is universally present in nature and has the effect of increasing disease resistance and environmental resistance, pesticide residues and nitrates, which makes it possible to cultivate crops stably against pesticides and to improve the quality of crops without fear of soil pollution such as chemical fertilizers. Improved and increased yields allow easy utilization of crops.
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CN102577945A (en) * | 2012-01-31 | 2012-07-18 | 玉林市林业科学研究所 | Method for preventing gum trees from being vitrified in successive transfer culture |
CN102726184A (en) * | 2012-05-29 | 2012-10-17 | 四川省川草生态草业科技开发有限责任公司 | Method for improving quality and yield of Aubade floribunda ryegrass seeds |
CN113615513A (en) * | 2021-09-16 | 2021-11-09 | 山西省农业科学院作物科学研究所 | Rapid, efficient and low-cost triticale breeding method |
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2005
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KR100897243B1 (en) | 2008-01-23 | 2009-05-14 | 허삼남 | Liquid Rare Earth Fertilizer Formulation |
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