JPS6012780A - Accumulation system solar battery - Google Patents
Accumulation system solar batteryInfo
- Publication number
- JPS6012780A JPS6012780A JP58120556A JP12055683A JPS6012780A JP S6012780 A JPS6012780 A JP S6012780A JP 58120556 A JP58120556 A JP 58120556A JP 12055683 A JP12055683 A JP 12055683A JP S6012780 A JPS6012780 A JP S6012780A
- Authority
- JP
- Japan
- Prior art keywords
- solar battery
- plate
- solar cell
- substance
- electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000009825 accumulation Methods 0.000 title 1
- 230000005611 electricity Effects 0.000 claims description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 239000007772 electrode material Substances 0.000 claims 1
- 229910000743 fusible alloy Inorganic materials 0.000 claims 1
- -1 polypropylene Polymers 0.000 abstract description 7
- 239000003792 electrolyte Substances 0.000 abstract description 5
- 229910021417 amorphous silicon Inorganic materials 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 229910001261 rose's metal Inorganic materials 0.000 abstract description 4
- 239000004743 Polypropylene Substances 0.000 abstract description 3
- 229920001155 polypropylene Polymers 0.000 abstract description 3
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 abstract description 3
- 239000007784 solid electrolyte Substances 0.000 abstract description 3
- 239000003822 epoxy resin Substances 0.000 abstract description 2
- 229920000647 polyepoxide Polymers 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 abstract description 2
- 239000010409 thin film Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract 3
- 238000010276 construction Methods 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 238000003475 lamination Methods 0.000 abstract 1
- 229910001416 lithium ion Inorganic materials 0.000 abstract 1
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 abstract 1
- 229910001486 lithium perchlorate Inorganic materials 0.000 abstract 1
- 239000007774 positive electrode material Substances 0.000 description 6
- 239000007773 negative electrode material Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229920000265 Polyparaphenylene Polymers 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000003990 capacitor Substances 0.000 description 2
- 229920001940 conductive polymer Polymers 0.000 description 2
- 230000001678 irradiating effect Effects 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 229910001128 Sn alloy Inorganic materials 0.000 description 1
- DUCFBDUJLLKKPR-UHFFFAOYSA-N [O--].[Zn++].[Ag+] Chemical compound [O--].[Zn++].[Ag+] DUCFBDUJLLKKPR-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- OJIJEKBXJYRIBZ-UHFFFAOYSA-N cadmium nickel Chemical compound [Ni].[Cd] OJIJEKBXJYRIBZ-UHFFFAOYSA-N 0.000 description 1
- 229910001914 chlorine tetroxide Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Chemical compound [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/0445—PV modules or arrays of single PV cells including thin film solar cells, e.g. single thin film a-Si, CIS or CdTe solar cells
- H01L31/046—PV modules composed of a plurality of thin film solar cells deposited on the same substrate
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Sustainable Development (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Life Sciences & Earth Sciences (AREA)
- Power Engineering (AREA)
- Sustainable Energy (AREA)
- Secondary Cells (AREA)
- Photovoltaic Devices (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は太陽電池に蓄電池あるいは蓄電器を一体化して
蓄エネルギー機能を付加した体積効率にすぐれた蓄電式
太陽電池に係る。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a storage type solar cell with excellent volumetric efficiency, which has an energy storage function added by integrating a storage battery or a power storage device into a solar cell.
従来例の構成とその問題点
太陽電池は、本来、太陽光が照射されているときに発電
機能を有するものであり、従来の使われ方としては、電
卓用の電源のように光照射時にのみ使う用途が主であっ
た。蓄電が必要な場合は、ニッケル・カドミウム蓄電池
や酸化銀−亜鉛二次電池を別に設けて、これらに一旦充
電して使用する方法がとられていた。したがって、回路
的にも複雑となり、蓄電用の電池スペースが必要であっ
た。Conventional configurations and their problems Solar cells originally have a power generation function when sunlight is irradiating them, but in the past, they were used to generate power only when sunlight is irradiating them, such as as a power source for a calculator. The main purpose was to use it. When storage of electricity was required, a method was used in which a nickel-cadmium storage battery or a silver-zinc oxide secondary battery was provided separately, and these batteries were charged once before use. Therefore, the circuit becomes complicated and a battery space for storing electricity is required.
発明の目的
本発明は上記欠点を除去するために、太陽電池の受光面
とは反対面に板状の蓄電池或は蓄電器を一体化して、太
陽電池に蓄電機能を伺加するこヒ2目的ヒレ←骨→→、
スペースファクターに優れた蓄電式太陽電池オ得、te
r)用途拡大左期待ずぎるものである。Purpose of the Invention In order to eliminate the above-mentioned drawbacks, the present invention integrates a plate-shaped storage battery or electricity storage device on the surface opposite to the light-receiving surface of the solar cell, thereby adding a power storage function to the solar cell. ←bone→→,
Storage type solar cell advantage with excellent space factor, te
r) Expansion of applications This is something that we can all look forward to.
発明の構成
本発明は、平板型太陽電池に、蓄電池や蓄電器のような
蓄電機能を持つ素子″l積層一体化して極めて小型に、
かつ太陽電池の用途拡大をはかるものである。Structure of the Invention The present invention integrates a flat solar cell with an element having a power storage function, such as a storage battery or a capacitor, to make it extremely compact.
It also aims to expand the uses of solar cells.
実施例の説明
図面は本発明の一実施例の構成を示すものである。1〜
4は太陽電池の構成要素であり、絶縁層4上に複数の電
極層3゜〜34および複数のアモルファスシリコン層2
1〜24があり、さらに、その上に複数の透明電極層1
1〜14を設けて複数の太陽電池を形成している。この
複数の太陽電池は直列接続して所定の電圧を得ている。DESCRIPTION OF THE EMBODIMENTS The drawings show the configuration of one embodiment of the present invention. 1~
4 is a component of a solar cell, which includes a plurality of electrode layers 3° to 34 and a plurality of amorphous silicon layers 2 on an insulating layer 4.
1 to 24, and a plurality of transparent electrode layers 1 thereon.
1 to 14 are provided to form a plurality of solar cells. The plurality of solar cells are connected in series to obtain a predetermined voltage.
5〜1oは蓄電池を構成するものであり、6は正極活物
質、7はイオン導電性の電解質、8は負極活物質である
。そして6,9は電流コレクタ板でアシ、太陽電池と蓄
電池が並列接続されるように、電流コレクタ5と電極3
.とか、また電流コレクタ9と電極3゜が電気的接続さ
れている0なお1oは電流コレクタ板6,9を絶縁支持
するとともに活物質等を封入する絶縁樹脂である。5 to 1o constitute a storage battery, 6 is a positive electrode active material, 7 is an ion conductive electrolyte, and 8 is a negative electrode active material. 6 and 9 are current collector plates, and the current collector 5 and electrode 3 are connected so that the solar cell and the storage battery are connected in parallel.
.. Further, the current collector 9 and the electrode 3° are electrically connected to each other, and 1o is an insulating resin that insulates and supports the current collector plates 6 and 9 and encapsulates the active material and the like.
さらに具体的に説明する0
太陽電池部分については、通常の方法に基すいてステン
レス材等から電流コレクタ板6上にエポキシ樹脂などで
絶縁層4を形成し、その上に電極3としてアルミニウム
層、次にP−I−Nアモルファスシリコン層、さらにI
TOなどの透明電極層1をプラズマ法で積層して、集積
型(この場合4セル直列)の太陽電池を作る0
蓄電池の電極端子となる電流コレクタ板6はステンレス
板とし、その片面に正極活物質としてWO3層を蒸着す
る。一方電流コレクタ板9はニッケル板としその片面に
負極活物質としてローズ合金層を溶着させ、さらに、そ
の表面にリチウム金属薄膜を張りつける。I ML t
ClO4/炭酸プロピレンを含浸してポリプロピレン
不織布の両側に前記正極活物質と負極活物質を対向させ
る0これらの操作は乾燥雰囲気中で行なう。More specifically, regarding the solar cell part, an insulating layer 4 is formed using an epoxy resin or the like on a current collector plate 6 made of stainless steel or the like based on a normal method, and an aluminum layer is formed as an electrode 3 on top of the insulating layer 4. Next, a P-I-N amorphous silicon layer, then an I
Transparent electrode layers 1 such as TO are laminated by a plasma method to create an integrated solar cell (4 cells in series in this case). The current collector plate 6, which serves as the electrode terminal of the storage battery, is a stainless steel plate, and a positive electrode active layer is placed on one side of the current collector plate 6. A layer of WO3 is deposited as a material. On the other hand, the current collector plate 9 is a nickel plate, and a rose alloy layer as a negative electrode active material is welded to one side of the plate, and a lithium metal thin film is further bonded to the surface thereof. I ML t
Impregnating with ClO4/propylene carbonate, the positive electrode active material and negative electrode active material are placed on both sides of the polypropylene nonwoven fabric. These operations are performed in a dry atmosphere.
このように正極活物質6としては、T I S 21″
Nb S e s 、 Cr 30a 、IVloOs
などの層間化合物や、ポリアセチレン、ポリパラフェニ
レンなどのいわゆる合成金属と称されるイオンドープ・
アンドープ型の導電性高分子などが用いられる。電解質
7としてはポリプロピレン不織布にI M L z C
A O4/炭酸プロピレン溶媒を含浸させたもの、ある
いはLiIなとの固体電解質などを用いることが出来る
。In this way, as the positive electrode active material 6, T I S 21''
NbSes, Cr30a, IVloOs
intercalation compounds such as ions, synthetic metals such as polyacetylene, polyparaphenylene,
An undoped conductive polymer or the like is used. As the electrolyte 7, a polypropylene nonwoven fabric was used.
A solid electrolyte such as one impregnated with A O4/propylene carbonate solvent or LiI can be used.
負極活物質8としてはアルカリ金属、とくにリチウム金
属イオンの吸蔵、放出を行なう材料で望ましくはSn、
Cd、Pb、Biなどを主体とする可融合金が用いられ
る。The negative electrode active material 8 is a material that absorbs and desorbs alkali metal, especially lithium metal ions, and is preferably Sn,
Fusible metals mainly composed of Cd, Pb, Bi, etc. are used.
このようにすれば、光発電素子部の厚みが0.5祁以下
、下部の蓄電池部分を入れた全体の厚みも2閣以下とな
る蓄電機能付太陽電池を得ることができる。In this way, it is possible to obtain a solar cell with a power storage function in which the thickness of the photovoltaic element part is 0.5 mm or less, and the total thickness including the lower storage battery part is 2 mm or less.
図にはアモルファスシリコン太陽電池4セルを直列にし
た構造例を示したが、この場合、光照射時の出力電圧は
約2.8vを示し、この電圧で無負荷時には、裏面の蓄
電池を充電することができる。The figure shows an example of a structure in which four amorphous silicon solar cells are connected in series. In this case, the output voltage when irradiated with light is about 2.8V, and when there is no load at this voltage, the storage battery on the back side is charged. be able to.
この時の蓄電池は正極電極料にWO3を用い、負極電極
に可融合金の一種であるローズメタル(Bi、 ・Pb
、 Sn合金)を用いて対応できる。The storage battery at this time used WO3 as the positive electrode material, and rose metal (Bi, ・Pb), which is a type of fusible metal, as the negative electrode.
, Sn alloy).
なお、上記構成材料については、上記のものに限定され
るものでないことは云うまでもない。たとえば絶縁層と
電流コレクタ板6の代わりにアルミニウム箔などのメタ
ルと樹脂フィルムのラミネート板を用いることが出来る
。また正極材料Vvo3の代わりにポリパラフェニレン
などを用いることができる。この場合は、蓄電池という
よりは蓄電器的な作動特性を示す。また電解質7として
実施例の液にポリメタクリル酸メチルなどを加えて固形
化すること、さらには固体電解質あるいはイオン導電性
高分子膜を用い素子全体をソリッドステート化して信頼
性を向上することなどが可能である。また蓄電池の代シ
に蓄電器を用いてもよく、要は蓄電機能があればよい。It goes without saying that the above-mentioned constituent materials are not limited to those mentioned above. For example, instead of the insulating layer and the current collector plate 6, a laminate plate of metal such as aluminum foil and a resin film can be used. Moreover, polyparaphenylene or the like can be used instead of the positive electrode material Vvo3. In this case, the battery exhibits operating characteristics more like a capacitor than a storage battery. Furthermore, it is possible to solidify the electrolyte 7 by adding polymethyl methacrylate or the like to the liquid of the example, and to improve reliability by making the entire device solid-state using a solid electrolyte or an ion-conductive polymer membrane. It is possible. Moreover, a power storage device may be used in place of a storage battery, and in short, it is sufficient as long as it has a power storage function.
発明の効果
従来の太陽電池の厚みを少し増すだけでスペースファク
ターにすぐれた蓄電式太陽電池を得ることができ、太陽
電池の用途拡大をはかれる。Effects of the Invention By slightly increasing the thickness of a conventional solar cell, a storage type solar cell with an excellent space factor can be obtained, and the uses of solar cells can be expanded.
図面は本発明の一実施例の蓄電式太陽電池の構成図であ
る。
1〜1 ・・・・・・透明電極、21〜24・・・・・
・アモルフ 4
アスシリコン層、3o〜34・・・・・・電極、4・・
・・・・絶縁板、5,9・・・・・・電流コレクタ板、
6・・・・・・正極活物質、7・・・・・・電解質、8
・・・・・負極活物質、10・・・・・・絶縁物質。The drawing is a configuration diagram of a storage type solar cell according to an embodiment of the present invention. 1-1...Transparent electrode, 21-24...
・Amorph 4 Assilicon layer, 3o-34... Electrode, 4...
...Insulating plate, 5,9...Current collector plate,
6... Positive electrode active material, 7... Electrolyte, 8
...Negative electrode active material, 10...Insulating material.
Claims (1)
電機能を持つ素子を固定し、一体化したことを特徴とす
る蓄電式太陽電池。 @)太陽電池の一方の電極と蓄電機能を有する素子の一
方の電流コレクタを共用したことを特徴とする特許請求
の範囲第1項記載の蓄電式太陽電池。 (3)蓄電機能を有する素子は一方の電極材料がアルカ
リ金属の吸蔵放出を行なう可融合金であることを特徴と
する特許請求の範囲第1項記載の蓄電式太陽電池。[Scope of Claims] (1) An electricity storage type solar cell characterized in that a plate-shaped element having an electricity storage function is fixed and integrated on the surface opposite to the light-receiving surface of a flat plate solar cell. @) The storage type solar cell according to claim 1, characterized in that one electrode of the solar cell and one current collector of an element having a storage function are shared. (3) The storage type solar cell according to claim 1, wherein one electrode material of the element having a storage function is a fusible alloy that absorbs and releases an alkali metal.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58120556A JPS6012780A (en) | 1983-07-01 | 1983-07-01 | Accumulation system solar battery |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58120556A JPS6012780A (en) | 1983-07-01 | 1983-07-01 | Accumulation system solar battery |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS6012780A true JPS6012780A (en) | 1985-01-23 |
Family
ID=14789224
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP58120556A Pending JPS6012780A (en) | 1983-07-01 | 1983-07-01 | Accumulation system solar battery |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6012780A (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6260272A (en) * | 1985-09-10 | 1987-03-16 | Casio Comput Co Ltd | Solar battery |
US4740431A (en) * | 1986-12-22 | 1988-04-26 | Spice Corporation | Integrated solar cell and battery |
JPS63314874A (en) * | 1987-06-17 | 1988-12-22 | Matsushita Electric Ind Co Ltd | Solar battery power supply |
JPH01205572A (en) * | 1988-02-12 | 1989-08-17 | Elna Co Ltd | Energy storage device |
JPH04122006U (en) * | 1991-04-19 | 1992-10-30 | 和彦 熱田 | Clay material cutting and conveying device |
WO2003050886A3 (en) * | 2001-12-13 | 2003-11-06 | Siemens Ag | Thin layer energy system |
JP2015146453A (en) * | 2010-12-22 | 2015-08-13 | アナログ ディヴァイスィズ インク | Vertically integrated system |
US10730743B2 (en) | 2017-11-06 | 2020-08-04 | Analog Devices Global Unlimited Company | Gas sensor packages |
US11587839B2 (en) | 2019-06-27 | 2023-02-21 | Analog Devices, Inc. | Device with chemical reaction chamber |
US12117415B2 (en) | 2017-05-15 | 2024-10-15 | Analog Devices International Unlimited Company | Integrated ion sensing apparatus and methods |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56152278A (en) * | 1980-04-28 | 1981-11-25 | Sanyo Electric Co Ltd | Device for generating photo-electromotive force |
-
1983
- 1983-07-01 JP JP58120556A patent/JPS6012780A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56152278A (en) * | 1980-04-28 | 1981-11-25 | Sanyo Electric Co Ltd | Device for generating photo-electromotive force |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6260272A (en) * | 1985-09-10 | 1987-03-16 | Casio Comput Co Ltd | Solar battery |
US4740431A (en) * | 1986-12-22 | 1988-04-26 | Spice Corporation | Integrated solar cell and battery |
JPS63314874A (en) * | 1987-06-17 | 1988-12-22 | Matsushita Electric Ind Co Ltd | Solar battery power supply |
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