JPS5757882A - Black or blue rhodium coated articles, production thereof and plating bath used therefor - Google Patents
Black or blue rhodium coated articles, production thereof and plating bath used thereforInfo
- Publication number
- JPS5757882A JPS5757882A JP13403880A JP13403880A JPS5757882A JP S5757882 A JPS5757882 A JP S5757882A JP 13403880 A JP13403880 A JP 13403880A JP 13403880 A JP13403880 A JP 13403880A JP S5757882 A JPS5757882 A JP S5757882A
- Authority
- JP
- Japan
- Prior art keywords
- plating bath
- black
- articles
- salt
- blue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000007747 plating Methods 0.000 title abstract 8
- 238000004519 manufacturing process Methods 0.000 title 1
- 229910052703 rhodium Inorganic materials 0.000 title 1
- 239000010948 rhodium Substances 0.000 title 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 title 1
- 150000003839 salts Chemical class 0.000 abstract 5
- 239000000654 additive Substances 0.000 abstract 3
- 230000000996 additive effect Effects 0.000 abstract 3
- 150000001735 carboxylic acids Chemical class 0.000 abstract 3
- 230000002378 acidificating effect Effects 0.000 abstract 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 235000011054 acetic acid Nutrition 0.000 abstract 1
- 150000001243 acetic acids Chemical class 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 235000010233 benzoic acid Nutrition 0.000 abstract 1
- 150000001559 benzoic acids Chemical class 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 abstract 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 1
Landscapes
- Eyeglasses (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Abstract
PURPOSE: To obtain titled articles which have specular gloss on the surfaces of the articles to be treated, exhibit a black or blue color and have superior adhesive strength and corrosion resistance by using an ordinary acidic Rh plating bath contained with an org. carboxylic acid (salt) as an additive.
CONSTITUTION: The plating bath prepd. by contg. an org. carboxylic acid (salt) as an additive in an ordinary acidic Rh plating bath is used in applying plating treatment on the surfaces of decorative articles, particularly, spectacles, watches, personal ornaments, dinner ware, and the like. As a result, the black or blue Rh plated articles consisting of applying plating exhibiting a black or blue color on the surfaces of said articles to be treated are obtained. Ordinary Rh salts, for example, surfaces, phosphates and the like are used for the Rh salt used for said plating bath. As the additive, for example, acetic acids, benzoic acids, etc. are used for the org. carboxylic acid (salt). Further, it is preferable to use the plating bath at ≤6pH.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13403880A JPS5757882A (en) | 1980-09-25 | 1980-09-25 | Black or blue rhodium coated articles, production thereof and plating bath used therefor |
| DE8181107517T DE3176572D1 (en) | 1980-09-25 | 1981-09-22 | Rhodium-plated article with black or blue color, process for making the same and bath therefor |
| EP19810107517 EP0048929B1 (en) | 1980-09-25 | 1981-09-22 | Rhodium-plated article with black or blue color, process for making the same and bath therefor |
| US06/304,939 US4416742A (en) | 1980-09-25 | 1981-09-23 | Process and electrolytic bath for making a rhodium-plated article having a black or blue color |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13403880A JPS5757882A (en) | 1980-09-25 | 1980-09-25 | Black or blue rhodium coated articles, production thereof and plating bath used therefor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5757882A true JPS5757882A (en) | 1982-04-07 |
Family
ID=15118910
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13403880A Pending JPS5757882A (en) | 1980-09-25 | 1980-09-25 | Black or blue rhodium coated articles, production thereof and plating bath used therefor |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5757882A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58126870U (en) * | 1982-02-22 | 1983-08-29 | 株式会社 ミヤマエ | Improved putter head |
| WO2001016403A1 (en) * | 1999-09-01 | 2001-03-08 | Merck Patent Gmbh | Galvanizing solution for the galvanic deposition of copper |
| JP2003147572A (en) * | 2001-10-02 | 2003-05-21 | Shipley Co Llc | Plating bath and method for depositing metallic layer on substrate |
| JP2014108427A (en) * | 2012-11-30 | 2014-06-12 | Eurecat Sa | Method for preparing supported metal catalysts for hydrogenating unsaturated hydrocarbons |
-
1980
- 1980-09-25 JP JP13403880A patent/JPS5757882A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58126870U (en) * | 1982-02-22 | 1983-08-29 | 株式会社 ミヤマエ | Improved putter head |
| WO2001016403A1 (en) * | 1999-09-01 | 2001-03-08 | Merck Patent Gmbh | Galvanizing solution for the galvanic deposition of copper |
| US6858123B1 (en) | 1999-09-01 | 2005-02-22 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Galvanizing solution for the galvanic deposition of copper |
| JP2003147572A (en) * | 2001-10-02 | 2003-05-21 | Shipley Co Llc | Plating bath and method for depositing metallic layer on substrate |
| JP2014108427A (en) * | 2012-11-30 | 2014-06-12 | Eurecat Sa | Method for preparing supported metal catalysts for hydrogenating unsaturated hydrocarbons |
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