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JPS5740442A - Production of glycolic ester and ether - Google Patents

Production of glycolic ester and ether

Info

Publication number
JPS5740442A
JPS5740442A JP55114936A JP11493680A JPS5740442A JP S5740442 A JPS5740442 A JP S5740442A JP 55114936 A JP55114936 A JP 55114936A JP 11493680 A JP11493680 A JP 11493680A JP S5740442 A JPS5740442 A JP S5740442A
Authority
JP
Japan
Prior art keywords
acid
formaldehyde
glycolic
ester
ether
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP55114936A
Other languages
Japanese (ja)
Other versions
JPS6366310B2 (en
Inventor
Hirosuke Wada
Akio Baba
Noboru Wada
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Industries Ltd filed Critical Mitsubishi Chemical Industries Ltd
Priority to JP55114936A priority Critical patent/JPS5740442A/en
Priority to DE19813107518 priority patent/DE3107518A1/en
Publication of JPS5740442A publication Critical patent/JPS5740442A/en
Publication of JPS6366310B2 publication Critical patent/JPS6366310B2/ja
Granted legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: The reaction between formaldehyde, a caboxylic ester and carbon monoxide in the presence of a strong acid catalyst produces the titled compound used as industrial intermediate of glycolic acid or cellosolves in high yield.
CONSTITUTION: The reaction between formaldehyde such as gaseous formaldehyde or trioxane, a carboxylic ester such as of 1W6C aliphatic acid or monochloroacetic acid, and carbon monoxide is conducted in the presence of a catalyst of strong acid such as hydrochloric acid, hydrobromic acid or trifluoroacetic acid at 25W250°C, preferably 50W200°C to produce the objective compound. The amount of the strong acid is 0.1W1,000meq/mol of formaldehyde. The resultant glycolic ester is hydrolyzed to give glycolic acid, hydrogenated to give ethylene and the hydrogenation of an ether of glycolic acid gives a cellosolve.
COPYRIGHT: (C)1982,JPO&Japio
JP55114936A 1980-02-29 1980-08-21 Production of glycolic ester and ether Granted JPS5740442A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP55114936A JPS5740442A (en) 1980-08-21 1980-08-21 Production of glycolic ester and ether
DE19813107518 DE3107518A1 (en) 1980-02-29 1981-02-27 Process for the preparation of esters and ethers of glycolic acid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP55114936A JPS5740442A (en) 1980-08-21 1980-08-21 Production of glycolic ester and ether

Publications (2)

Publication Number Publication Date
JPS5740442A true JPS5740442A (en) 1982-03-06
JPS6366310B2 JPS6366310B2 (en) 1988-12-20

Family

ID=14650319

Family Applications (1)

Application Number Title Priority Date Filing Date
JP55114936A Granted JPS5740442A (en) 1980-02-29 1980-08-21 Production of glycolic ester and ether

Country Status (1)

Country Link
JP (1) JPS5740442A (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59139341A (en) * 1983-01-20 1984-08-10 Mitsubishi Gas Chem Co Inc Production of hydroxycarboxylic acid derivative
JPS59161328A (en) * 1983-03-01 1984-09-12 Mitsubishi Gas Chem Co Inc Preparation of hydroxycarbonic acid derivative
JPS62231106A (en) * 1986-03-31 1987-10-09 Shimadzu Corp Optical displacement gauge
US8466328B2 (en) 2010-08-18 2013-06-18 Eastman Chemical Company Method for recovery and recycle of ruthenium homogeneous catalysts
US8703999B2 (en) 2012-03-27 2014-04-22 Eastman Chemical Company Hydrocarboxylation of methylene dipropionate in the presence of propionic acid and a heterogeneous catalyst
US8709376B2 (en) 2010-09-23 2014-04-29 Eastman Chemical Company Process for recovering and recycling an acid catalyst
US8765999B2 (en) 2012-03-27 2014-07-01 Eastman Chemical Company Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and a homogeneous catalyst
US8785686B2 (en) 2010-09-23 2014-07-22 Eastman Chemical Company Process for recovering and recycling an acid catalyst
US8829234B2 (en) 2012-03-27 2014-09-09 Eastman Chemical Company Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and heterogeneous catalyst
US8829248B2 (en) 2010-08-18 2014-09-09 Eastman Chemical Company Method for recovery and recycle of ruthenium homogeneous catalysts
US8927766B2 (en) 2012-03-27 2015-01-06 Eastman Chemical Company Hydrocarboxylation of methylene dipropionate in the presence of a propionic acid and a homogeneous catalyst
US9040748B2 (en) 2012-06-08 2015-05-26 Eastman Chemical Company Hydrocarboxylation of aqueous formaldehyde using a dehydrating recycle stream to decrease water concentration
US9227896B2 (en) 2010-08-18 2016-01-05 Eastman Chemical Company Process for the separation and purification of a mixed diol stream

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59139341A (en) * 1983-01-20 1984-08-10 Mitsubishi Gas Chem Co Inc Production of hydroxycarboxylic acid derivative
JPS59161328A (en) * 1983-03-01 1984-09-12 Mitsubishi Gas Chem Co Inc Preparation of hydroxycarbonic acid derivative
JPS62231106A (en) * 1986-03-31 1987-10-09 Shimadzu Corp Optical displacement gauge
US8829248B2 (en) 2010-08-18 2014-09-09 Eastman Chemical Company Method for recovery and recycle of ruthenium homogeneous catalysts
US8466328B2 (en) 2010-08-18 2013-06-18 Eastman Chemical Company Method for recovery and recycle of ruthenium homogeneous catalysts
US10329230B2 (en) 2010-08-18 2019-06-25 Eastman Chemical Company Process for the separation and purification of a mixed diol stream
US8779214B2 (en) 2010-08-18 2014-07-15 Eastman Chemical Company Methods for recovery and recycle of ruthenium homogenous catalysts
US9227896B2 (en) 2010-08-18 2016-01-05 Eastman Chemical Company Process for the separation and purification of a mixed diol stream
US8709376B2 (en) 2010-09-23 2014-04-29 Eastman Chemical Company Process for recovering and recycling an acid catalyst
US8785686B2 (en) 2010-09-23 2014-07-22 Eastman Chemical Company Process for recovering and recycling an acid catalyst
US8765999B2 (en) 2012-03-27 2014-07-01 Eastman Chemical Company Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and a homogeneous catalyst
US8927766B2 (en) 2012-03-27 2015-01-06 Eastman Chemical Company Hydrocarboxylation of methylene dipropionate in the presence of a propionic acid and a homogeneous catalyst
US8829234B2 (en) 2012-03-27 2014-09-09 Eastman Chemical Company Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and heterogeneous catalyst
US8703999B2 (en) 2012-03-27 2014-04-22 Eastman Chemical Company Hydrocarboxylation of methylene dipropionate in the presence of propionic acid and a heterogeneous catalyst
US9040748B2 (en) 2012-06-08 2015-05-26 Eastman Chemical Company Hydrocarboxylation of aqueous formaldehyde using a dehydrating recycle stream to decrease water concentration

Also Published As

Publication number Publication date
JPS6366310B2 (en) 1988-12-20

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