JPS56152830A - High-molecular liquid crystal - Google Patents
High-molecular liquid crystalInfo
- Publication number
- JPS56152830A JPS56152830A JP5696880A JP5696880A JPS56152830A JP S56152830 A JPS56152830 A JP S56152830A JP 5696880 A JP5696880 A JP 5696880A JP 5696880 A JP5696880 A JP 5696880A JP S56152830 A JPS56152830 A JP S56152830A
- Authority
- JP
- Japan
- Prior art keywords
- molecular
- liquid crystal
- molecular liquid
- alkanediol
- molded
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Liquid Crystal Substances (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
PURPOSE: To produce a high-molecular substance having a polyurethane bond, which can be molded and processed into film, fiber, etc. and yet shows a liquid crystal behavior, by the polymerization reaction of o-toluidine isocyanate and an α,ω-alkanediol.
CONSTITUTION: o-Toluidine isocyanate is dissolved in a solvent, such as purified anisole. To this solution is added an α,ω-alkanediol of formula I (n≥5), e.g., 1,6-hexanediol or 1,12-dodecanediol, and the mixture is reacted with heating. The resultant is then cooled, and a diluting solvent, such as acetone, is added so as to separate the reaction product in the form of a solid, which is collected by separation from the liquid phase. Subsequently, the product is further purified by reprecipitation or other means to give the object high-molecular liquid crystals with their main chain structure composed of repeating units of formula II. The resulting high- molecular liquid crystals can readily be molded and processed into film, fiber, etc. and have the possibility for extensive application in the field of electronics, etc.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5696880A JPS56152830A (en) | 1980-04-28 | 1980-04-28 | High-molecular liquid crystal |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5696880A JPS56152830A (en) | 1980-04-28 | 1980-04-28 | High-molecular liquid crystal |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS56152830A true JPS56152830A (en) | 1981-11-26 |
JPS6251292B2 JPS6251292B2 (en) | 1987-10-29 |
Family
ID=13042316
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP5696880A Granted JPS56152830A (en) | 1980-04-28 | 1980-04-28 | High-molecular liquid crystal |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS56152830A (en) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4745137A (en) * | 1986-06-25 | 1988-05-17 | The Dow Chemical Company | Polyurethanes prepared from solutions or dispersions of polymers of rigid polyaromatic monomers in polyols |
US4745136A (en) * | 1986-06-25 | 1988-05-17 | The Dow Chemical Company | Polyurethanes prepared from dispersions or solutions of cholesterol or cholestanol-containing polymers in a polyol |
US4745135A (en) * | 1986-06-25 | 1988-05-17 | The Dow Chemical Company | Polyurethanes prepared from liquid crystal-containing polyols |
US4798849A (en) * | 1986-06-25 | 1989-01-17 | The Dow Chemical Company | Organic polymers containing dispersed liquid crystalline filler polymers |
US4861803A (en) * | 1986-06-25 | 1989-08-29 | The Dow Chemical Company | Organic polymers reinforced with rigid rod micro fillers |
US4962163A (en) * | 1989-01-17 | 1990-10-09 | The Dow Chemical Company | Vinyl ester resins containing mesogenic/rigid rodlike moieties |
US5024785A (en) * | 1989-01-17 | 1991-06-18 | The Dow Chemical Company | Liquid crystal/rigid rodlike polymer modified epoxy/vinyl ester resins |
US5164464A (en) * | 1989-01-17 | 1992-11-17 | The Dow Chemical Company | Vinyl ester resins containing mesogenic/rigid rodlike moieties |
US5262509A (en) * | 1990-08-03 | 1993-11-16 | The Dow Chemical Company | Mesogenic glycidyl amines |
US5276184A (en) * | 1990-08-03 | 1994-01-04 | The Dow Chemical Company | Sulfonamide compounds containing mesogenic moieties |
US5296570A (en) * | 1990-08-03 | 1994-03-22 | The Dow Chemical Company | Curable mixtures of mesogenic epoxy resins and mesogenic polyamines and cured compositions |
US5360884A (en) * | 1990-08-03 | 1994-11-01 | The Dow Chemical Company | Mesogenic glycidyl amine blends |
US5362822A (en) * | 1990-08-03 | 1994-11-08 | The Dow Chemical Company | Mesogenic adducts |
US5391651A (en) * | 1990-08-03 | 1995-02-21 | The Dow Chemical Company | Curable mixtures of mesogenic epoxy resins and mesogenic polyamines and cured compositions |
US5414125A (en) * | 1990-08-03 | 1995-05-09 | The Dow Chemical Company | Diamino-alpha-alkylstilbenes |
-
1980
- 1980-04-28 JP JP5696880A patent/JPS56152830A/en active Granted
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4745137A (en) * | 1986-06-25 | 1988-05-17 | The Dow Chemical Company | Polyurethanes prepared from solutions or dispersions of polymers of rigid polyaromatic monomers in polyols |
US4745136A (en) * | 1986-06-25 | 1988-05-17 | The Dow Chemical Company | Polyurethanes prepared from dispersions or solutions of cholesterol or cholestanol-containing polymers in a polyol |
US4745135A (en) * | 1986-06-25 | 1988-05-17 | The Dow Chemical Company | Polyurethanes prepared from liquid crystal-containing polyols |
US4798849A (en) * | 1986-06-25 | 1989-01-17 | The Dow Chemical Company | Organic polymers containing dispersed liquid crystalline filler polymers |
US4861803A (en) * | 1986-06-25 | 1989-08-29 | The Dow Chemical Company | Organic polymers reinforced with rigid rod micro fillers |
US4962163A (en) * | 1989-01-17 | 1990-10-09 | The Dow Chemical Company | Vinyl ester resins containing mesogenic/rigid rodlike moieties |
US5024785A (en) * | 1989-01-17 | 1991-06-18 | The Dow Chemical Company | Liquid crystal/rigid rodlike polymer modified epoxy/vinyl ester resins |
US5164464A (en) * | 1989-01-17 | 1992-11-17 | The Dow Chemical Company | Vinyl ester resins containing mesogenic/rigid rodlike moieties |
US5262509A (en) * | 1990-08-03 | 1993-11-16 | The Dow Chemical Company | Mesogenic glycidyl amines |
US5276184A (en) * | 1990-08-03 | 1994-01-04 | The Dow Chemical Company | Sulfonamide compounds containing mesogenic moieties |
US5296570A (en) * | 1990-08-03 | 1994-03-22 | The Dow Chemical Company | Curable mixtures of mesogenic epoxy resins and mesogenic polyamines and cured compositions |
US5360884A (en) * | 1990-08-03 | 1994-11-01 | The Dow Chemical Company | Mesogenic glycidyl amine blends |
US5362822A (en) * | 1990-08-03 | 1994-11-08 | The Dow Chemical Company | Mesogenic adducts |
US5391651A (en) * | 1990-08-03 | 1995-02-21 | The Dow Chemical Company | Curable mixtures of mesogenic epoxy resins and mesogenic polyamines and cured compositions |
US5414125A (en) * | 1990-08-03 | 1995-05-09 | The Dow Chemical Company | Diamino-alpha-alkylstilbenes |
US5602211A (en) * | 1990-08-03 | 1997-02-11 | The Dow Chemical Company | Adducts of epoxy resins and active hydrogen containing compounds containing mesogenic moieties |
Also Published As
Publication number | Publication date |
---|---|
JPS6251292B2 (en) | 1987-10-29 |
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