JPS5599909A - Surface sizing agent for paper making and its preparation - Google Patents
Surface sizing agent for paper making and its preparationInfo
- Publication number
- JPS5599909A JPS5599909A JP741779A JP741779A JPS5599909A JP S5599909 A JPS5599909 A JP S5599909A JP 741779 A JP741779 A JP 741779A JP 741779 A JP741779 A JP 741779A JP S5599909 A JPS5599909 A JP S5599909A
- Authority
- JP
- Japan
- Prior art keywords
- monomer
- sizing agent
- acrylic
- vinyl
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004513 sizing Methods 0.000 title abstract 2
- 239000000178 monomer Substances 0.000 abstract 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 3
- 229920002554 vinyl polymer Polymers 0.000 abstract 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 2
- 239000012670 alkaline solution Substances 0.000 abstract 2
- 125000005907 alkyl ester group Chemical group 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 150000007519 polyprotic acids Polymers 0.000 abstract 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- 238000012661 block copolymerization Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000005187 foaming Methods 0.000 abstract 1
Landscapes
- Paper (AREA)
- Graft Or Block Polymers (AREA)
Abstract
PURPOSE: To prepare a novel sizing agent having excellent printability, etc., by the bulk-terpolymerization of a styrene-type monomer, an unsaturated polybasic acid and an acrylic monomer at specific ratios followed by the block-copolymerization of the polymer with a vinyl monomer in an aqueous alkaline solution.
CONSTITUTION: (a) A styrene-type monomer, (b) an α,β-unsaturated polybasic acid (1W16C alkyl ester) monomer and (c) one or more acrylic monomers selected from (meth)acrylic acid (1W4C alkyl ester), diglycidyl (meth)acrylate and acrylonitrile are bulk terpolymerized at molar ratios (a):(b):(c) of 1W2:0.1W0.9:0.9W 0.1. The polymer is dissolved in an aqueous alkaline solution and block copolymerized with one or more vinyl monomers selected from the component (a), (b), (c), acrylamide and vinyl acetate-type monomers.
EFFECT: Almost free from foaming and free from gum-up in use.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP741779A JPS5599909A (en) | 1979-01-25 | 1979-01-25 | Surface sizing agent for paper making and its preparation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP741779A JPS5599909A (en) | 1979-01-25 | 1979-01-25 | Surface sizing agent for paper making and its preparation |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5599909A true JPS5599909A (en) | 1980-07-30 |
JPS5724363B2 JPS5724363B2 (en) | 1982-05-24 |
Family
ID=11665286
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP741779A Granted JPS5599909A (en) | 1979-01-25 | 1979-01-25 | Surface sizing agent for paper making and its preparation |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5599909A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60185894A (en) * | 1984-03-05 | 1985-09-21 | 三菱製紙株式会社 | Production of neutral paper |
JPS63175013A (en) * | 1987-01-14 | 1988-07-19 | Showa Denko Kk | Coating composition for recording paper |
JP2005054346A (en) * | 2003-07-22 | 2005-03-03 | Oji Cornstarch Co Ltd | Surface-sized pressed paper and method for making the same |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4817561B2 (en) * | 2001-09-25 | 2011-11-16 | ハリマ化成株式会社 | Surface sizing agent for papermaking and method for producing the same |
-
1979
- 1979-01-25 JP JP741779A patent/JPS5599909A/en active Granted
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60185894A (en) * | 1984-03-05 | 1985-09-21 | 三菱製紙株式会社 | Production of neutral paper |
JPH0368158B2 (en) * | 1984-03-05 | 1991-10-25 | Mitsubishi Paper Mills Ltd | |
JPS63175013A (en) * | 1987-01-14 | 1988-07-19 | Showa Denko Kk | Coating composition for recording paper |
JP2005054346A (en) * | 2003-07-22 | 2005-03-03 | Oji Cornstarch Co Ltd | Surface-sized pressed paper and method for making the same |
JP4528032B2 (en) * | 2003-07-22 | 2010-08-18 | 王子コーンスターチ株式会社 | Surface size press paper and method for producing the same |
Also Published As
Publication number | Publication date |
---|---|
JPS5724363B2 (en) | 1982-05-24 |
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