JP5523716B2 - Antibacterial OP Varnish, Antibacterial Print, and Antibacterial Printing Method - Google Patents

Description

  The present invention is an antibacterial OP varnish agent that can be applied to the surface of a printed material (design printed surface) to protect the surface of the printed material and impart antibacterial properties and water repellency, and an antibacterial printed material using the same, and The present invention relates to an antibacterial printing method using an antibacterial OP varnish.

  There are countless microorganisms such as bacteria and mold in our living environment. In recent years, as people's awareness of hygiene has increased, not only in the medical field but also in various fields, it has been required to impart antiviral properties, antibacterial properties, and fungicidal properties to articles. In particular, it is widely required to impart antibacterial properties to articles that are directly touched by human hands. Goods that can be directly touched by human hands include printed materials, but in particular, materials such as guides and pamphlets that are placed in various facilities and public transportation are touched by an unspecified number of people. Therefore, there has been a demand for imparting antibacterial properties.

As a method for imparting antibacterial properties to printed matter, after printing an arbitrary design using printing ink on the surface of the paper to form a design printing layer, a powdered antibacterial agent dissolved in water is further added on the printed surface. An antibacterial treatment method for printed matter such as a cover of a notebook to be applied is disclosed (for example, see Patent Document 1).
In addition, 15 to 25% pigment, 25 to 30% synthetic resin, 20 to 25% drying oil, 15 to 20% petroleum solvent, 1 to 3% film strengthening agent, and 0. Silver or organic metal material having antibacterial performance in poorly soluble phosphate in 1 kg of printing ink composed to contain 5 to 2.5%, drying accelerator and other solvent 1 to 3% Using a printing ink with 2.5% powdered antibacterial agent intercalated with the substances benzalkonium and cetylpyridinium, offset printing of any design on the surface of the paper, the design printing layer An antibacterial treatment method for printed matter such as a notebook cover to be formed is disclosed (for example, see Patent Document 2).

Japanese Patent No. 3030310 Japanese Patent No. 3401571

  However, in the antibacterial treatment methods disclosed in Patent Documents 1 and 2, since a design is printed on paper or the like, an OP (overprint) varnish containing an antibacterial agent is simply applied to the printed surface. Water may permeate into the design print layer and paper, reducing the antibacterial effect.

  The present invention has been made in view of the above circumstances, and prevents external water from penetrating into the design printing layer and the printed material to prevent the antibacterial effect from decreasing, and maintains the antibacterial effect over a long period of time. It is an object to provide an antibacterial OP varnish that can be used, an antibacterial print using the same, and an antibacterial printing method using the antibacterial OP varnish.

The antibacterial OP varnish of the present invention comprises silver resin-zinc calcium phosphate and isopropyl alcohol with respect to 100 parts by mass of OP varnish containing a solid resin, a vegetable oil, a high boiling point petroleum solvent and a silicone oil as a water repellent. An antibacterial OP varnish formed by adding 2 to 5 parts by mass of an antibacterial agent containing the composition, wherein the solid resin content in the OP varnish is based on the total of all components constituting the OP varnish The content of the vegetable oil in the OP varnish is in the range of 18 to 30% by mass with respect to the total of all components constituting the OP varnish, The content of the high boiling point petroleum-based solvent is in the range of 38 to 50% by mass with respect to the total of all components constituting the OP varnish, and the content of the water repellent in the OP varnish is Configure OP Varnish It is 1-5 mass% with respect to the sum total of a component, and the content rate of the said silver oxide-zinc calcium phosphate in the said antibacterial agent is 25-27 mass% with respect to the sum total of all the components which comprise the said antibacterial agent. The content of the isopropyl alcohol in the antibacterial agent is in the range of 73 to 75% by mass with respect to the total of all components constituting the antibacterial agent.

  The antibacterial printed material of the present invention includes a printed material, a design printed layer formed on the surface of the printed material, at least a part of the surface of the designed printed layer opposite to the surface in contact with the printed material, and / or Or an antibacterial print layer provided with an antibacterial print layer covering at least a part of the surface of the substrate to be printed that is not in contact with the design print layer, wherein the antibacterial print layer is made of the antibacterial OP varnish of the present invention. Features.

  In the antibacterial printing method of the present invention, the surface A of the printed material is printed to form a design printed layer, and at least one of the surfaces of the designed printed layer opposite to the surface in contact with the printed material. And / or printing on at least part of the surface of the printed material that is not in contact with the design printed layer, and at least part of the surface of the design printed layer opposite to the surface that is in contact with the printed material And / or an antibacterial printing method comprising forming an antibacterial printing layer that covers at least a part of the surface of the substrate that is not in contact with the design printing layer, wherein the antibacterial OP of the present invention is used in the step B. The antibacterial printing layer is formed using a varnish agent.

  According to the antibacterial OP varnish of the present invention, the surface of the printed material is formed by the OP varnish, which is a component thereof, without impairing the color of the design print layer, that is, without damaging various print information displayed by the design print layer. The surface of the printed matter can be imparted with water repellency by the water repellent, and the antibacterial property can be imparted to the surface of the printed matter by the antibacterial agent. Therefore, according to the antibacterial OP varnish of the present invention, water from the outside is repelled by the water repellent effect of the antibacterial printing layer, so that the water soaks into the antibacterial printing layer, and consequently, the substrate to be printed and the design printing layer. It is possible to prevent the antibacterial effect of the printing layer from decreasing and maintain the antibacterial effect for a long time. In addition, since the antibacterial OP varnish of the present invention does not contain a component that adversely affects the human body, it is safe to apply it to things that are directly touched by human hands such as printed matter.

It is a schematic sectional drawing which shows 1st embodiment of the antimicrobial printed matter of this invention. It is a schematic sectional drawing which shows 2nd embodiment of the antimicrobial printed matter of this invention. It is a schematic diagram which shows one Embodiment of the antibacterial printing method of this invention, and is a schematic diagram which shows the form which applied offset printing as a printing method. In Example 1-1-Example 2-3, it is a graph which shows the relationship between the application amount (g) of an antimicrobial OP varnish agent, and the glossiness (glossiness difference) resulting from the antimicrobial printing layer of an antimicrobial printed matter.

Embodiments of an antibacterial OP varnish of the present invention, an antibacterial printed material using the same, and an antibacterial printing method using the antibacterial OP varnish will be described.
This embodiment is specifically described for better understanding of the gist of the invention, and does not limit the present invention unless otherwise specified.

"Antimicrobial OP Varnish"
The antibacterial OP varnish of the present invention contains silver oxide-zinc calcium phosphate and isopropyl alcohol with respect to 100 parts by mass of OP varnish containing a solid resin, vegetable oil, a high boiling point petroleum solvent and a water repellent. 2 to 5 parts by mass of an antibacterial agent is added.

In the antibacterial OP varnish of the present invention, the addition amount of the antibacterial agent with respect to 100 parts by mass of OP varnish is in the range of 2 to 5 parts by mass, and most preferably 3.5 parts by mass.
When the addition amount of the antibacterial agent relative to 100 parts by mass of the OP varnish is less than 2 parts by mass, the antibacterial effect of the antibacterial printing layer formed by the antibacterial OP varnish of the present invention is insufficient. On the other hand, when the added amount of the antibacterial agent exceeds 5 parts by mass, the printability is deteriorated.

  In the antibacterial OP varnish of the present invention, the solid resin content in the OP varnish is based on the total of all components (including solid resin, vegetable oil, high boiling petroleum solvent and water repellent) constituting the OP varnish. It is the range of 30-40 mass%.

  Moreover, the content rate of the vegetable oil in OP varnish is 18-22 mass% with respect to the sum total of all the components (A solid resin, a vegetable oil, a high boiling point petroleum solvent, and a water repellent agent) which comprise OP varnish. Yes, preferably in the range of 18-30% by weight.

  The content of the high boiling point petroleum solvent in the OP varnish is 38 to 50 mass with respect to the total of all components (including solid resin, vegetable oil, high boiling point petroleum solvent and water repellent) constituting the OP varnish. % Range.

The content of the water repellent in the OP varnish is 1 to 5% by mass with respect to the total of all components (including solid resin, vegetable oil, high-boiling petroleum solvent and water repellent) constituting the OP varnish. The range is most preferably 2% by mass.
When the content of the water repellent in the OP varnish is less than 1% by mass with respect to the total of all components constituting the OP varnish, the water repellency of the antibacterial printing layer formed by the antibacterial OP varnish of the present invention is insufficient. As a result, the antibacterial effect of the antibacterial printing layer becomes insufficient. On the other hand, if the content of the water repellent exceeds 5% by mass, the water repellent penetrates into the rubber forming the roller of the printing device, thereby accelerating the deterioration of the roller and making the printed surface of the printed material slippery. For this reason, deficiencies in post-processing may occur.

Further, the antibacterial OP varnish of the present invention may contain a film reinforcing agent and a drying accelerator.
When the antibacterial OP varnish of the present invention contains a film reinforcing agent, the content of the film reinforcing agent in the OP varnish is determined based on all components constituting the OP varnish (solid resin, vegetable oil, high-boiling petroleum solvent, film reinforcing agent and It is in the range of 8 to 10% by mass relative to the total of (including the water repellent).

  When the antibacterial OP varnish of the present invention contains a drying accelerator, the content of the drying accelerator in the OP varnish is determined by the total components constituting the OP varnish (solid resin, vegetable oil, high boiling petroleum solvent, water repellent and drying agent). It is in the range of 0.5 to 1% by mass with respect to the total of (including the accelerator).

In the antibacterial OP varnish of the present invention, the content of silver oxide-zinc calcium phosphate in the antibacterial agent is the sum of all components (including silver oxide-zinc calcium phosphate and isopropyl alcohol) constituting the antibacterial agent. It is the range of 25-27 mass% with respect to.
Since the content of silver oxide-zinc calcium phosphate in the antibacterial agent is within the above range, this antibacterial agent and the above OP varnish can be mixed uniformly, and as a result, each component is uniformly distributed. It becomes a mixed antibacterial OP varnish.

Moreover, the content rate of the isopropyl alcohol in an antibacterial agent is the range of 73-75 mass% with respect to the sum total of all the components (A silver oxide- zinc calcium phosphate and isopropyl alcohol are included) which comprise an antibacterial agent.
Since the content of isopropyl alcohol in the antibacterial agent is within the above range, this antibacterial agent and the above OP varnish can be uniformly mixed. As a result, the antibacterial OP in which each component is uniformly mixed It becomes a varnish.

  As the solid resin, a rosin-modified phenol resin, a petroleum-based resin, or the like is used. From the viewpoint of printing suitability, a rosin-modified phenol resin is mainly preferable.

  As the vegetable oil, a dry oil that is completely solidified in the air is used, for example, linseed oil, soybean oil, tung oil, coconut oil, shiso oil, walnut oil, coconut oil, safflower oil, sunflower oil, etc. From the viewpoint of properties and film, linseed oil, soybean oil, and tung oil are preferable.

  As the high-boiling petroleum solvent, an aroma-free solvent which is a solvent containing almost no aromatic component is preferable from the viewpoint of health and environment.

  As the water repellent, wax, fats and oils, pine resin, glue, tar, asphalt, mineral oil, metal soap, fatty acid, rubber, various plastics, silicone, fluororesin, etc. are used in various forms, but from the viewpoint of printing suitability Silicone and fluorine resin are preferable.

  As the film reinforcing agent, polyethylene wax, Teflon (registered trademark) wax, or the like is used.

  As the drying accelerator, cobalt naphthenate, manganese naphthenate, or the like is used.

The antibacterial OP varnish of the present invention is a surface of a printed material including various papers and / or a surface of the printed material formed on the surface of the printed material by a printing method on the side opposite to the surface in contact with the printed material. It is used for applying a printed layer on the surface (outermost surface) to form an antibacterial printing layer and producing a printed matter having a design printing layer and an antibacterial printing layer.
Therefore, since the antibacterial OP varnish of the present invention is composed of the above OP varnish and the antibacterial agent and is a colorless and transparent material, according to the antibacterial OP varnish of the present invention, without impairing the color of the design printing layer, That is, the surface of the printed matter (including the surface of the paper and the outermost surface of the design print layer) can be protected by the OP varnish, which is a component, without damaging various print information displayed by the design print layer. In addition, the water repellent which is a component of the antibacterial OP varnish of the present invention can impart water repellency to the surface of the printed matter (including the surface of the paper and the outermost surface of the design print layer). Furthermore, the antibacterial property can be imparted to the surface of the printed matter (including the surface of the paper and the outermost surface of the design print layer) by the antibacterial agent which is a component of the antibacterial OP varnish of the present invention.
Therefore, according to the antibacterial OP varnish of the present invention, water from the outside is repelled by the water repellent effect of the antibacterial printing layer, so that the water soaks into the antibacterial printing layer, and consequently, the substrate to be printed and the design printing layer. It is possible to prevent the antibacterial effect of the printing layer from decreasing and maintain the antibacterial effect for a long time. Moreover, even if microorganisms such as bacteria and mold adhere to the antibacterial printing layer, the growth of these microorganisms is suppressed by the antibacterial effect of the antibacterial printing layer.
In addition, since the antibacterial OP varnish of the present invention does not contain a component that adversely affects the human body, it is safe to apply it to things that are directly touched by human hands such as printed matter.

"Antimicrobial prints"
(1) First Embodiment FIG. 1 is a schematic cross-sectional view showing a first embodiment of the antibacterial printed material of the present invention.
The antibacterial printed material 10 of this embodiment includes a substrate 11, a design printing layer 12 formed on one surface 11 a of the substrate 11, and a surface of the design printing layer 12 opposite to the surface in contact with the substrate 11. A surface (hereinafter referred to as “one surface”) 12a is schematically configured from an antibacterial printed layer 13 formed so as to cover the entire surface.
Moreover, in this antibacterial printed matter 10, the antibacterial printed layer 13 is formed of the above-mentioned antibacterial OP varnish of the present invention.

The printed material 11 is not particularly limited as long as the antibacterial OP varnish of the present invention can be applied to the surface thereof, and examples thereof include paper generally used for printing.
Examples of the paper include non-coated paper such as high-quality paper, medium-quality paper, and reprinted paper, coated paper such as coated paper and art paper, recycled paper, and non-wood paper.
Further, the thickness of the paper is not particularly limited as long as it is equal to the thickness of the paper generally used for printing.

  The design print layer 12 is a layer that is formed using various printing inks and displays arbitrary print information (characters, symbols, figures, photographs, paintings, illustrations, etc.). The design printing layer 12 is a printing layer formed by various printing methods and composed of one layer or two or more layers formed using various printing inks.

  The printing ink for forming the design printing layer 12 is not particularly limited, and examples thereof include ink generally used in printing methods such as letterpress printing, offset printing, screen printing, and ink jet printing.

  According to the antibacterial printed material 10, the antibacterial printed layer 13 formed so as to cover the entire surface of the one surface 12a of the design printed layer 12 formed on the one surface 11a of the substrate 11 is the antibacterial OP varnish of the present invention. Since it consists of an agent, one surface 12a of the design printing layer 12 is protected without impairing the color of the design printing layer 12, and in addition, the one surface 12a of the design printing layer 12 has water repellency and antibacterial properties. ing. Accordingly, the antibacterial printing layer 13 repels water from the outside due to its water-repellent effect, so that the water soaks into the antibacterial printing layer 13, and consequently the substrate 11 or the design printing layer 12, and the antibacterial printing layer 13 has antibacterial properties. The effect can be prevented from decreasing and the antibacterial effect can be maintained for a long time. Moreover, even if microorganisms such as bacteria and mold adhere to the antibacterial printing layer 13, the growth of those microorganisms is suppressed by the antibacterial effect of the antibacterial printing layer 13.

In this embodiment, the antibacterial printed material 10 in which the design printing layer 12 is formed on the one surface 11a of the printing material 11 made of paper or the like is illustrated, but the antibacterial printed material of the present invention is not limited thereto. In the antibacterial printed material of the present invention, a design printed layer may be formed on the other surface of the printed material made of paper or the like.
Moreover, in this embodiment, although the antimicrobial printed matter 10 in which the antimicrobial printed layer 13 was formed so that only the one surface 12a of the design printing layer 12 might be covered was illustrated, the antimicrobial printed matter of this invention is not limited to this. In the antibacterial printed material of the present invention, an antibacterial printed layer may be provided so as to cover at least a part of the surface of the printed material on which the design printed layer is not formed. That is, for example, in the antibacterial printed material 10 shown in FIG. 1, the antibacterial printed layer 13 may be provided on one surface 11 a of the substrate 11 so as to cover a portion where the design printed layer 12 is not formed.

(2) Second Embodiment FIG. 2 is a schematic cross-sectional view showing a second embodiment of the antibacterial printed matter of the present invention.
2, the same components as those of the first embodiment shown in FIG. 1 are denoted by the same reference numerals, and the description thereof is omitted.
The antibacterial printed matter 20 of this embodiment is different from the antibacterial printed matter 10 of the first embodiment described above in that the antibacterial printed layer 23 is formed so as to partially cover one surface 12a of the design printed layer 12. Is a point.
Even in this antibacterial printed matter 20, the antibacterial printed layer 23 is formed of the above-described antibacterial OP varnish of the present invention.

  Even in this antibacterial printed matter 20, the same effect as the above-described antibacterial printed matter 10 is obtained.

"Antimicrobial printing method"
FIG. 3 is a schematic view showing an embodiment of the antibacterial printing method of the present invention, and is a view showing a form in which offset printing is applied as a printing method.
In the antibacterial printing method of this embodiment, an offset printing machine 30 is used.
The offset printing machine 30 includes a first ink roller 31, a second ink roller 32, a third ink roller 33, a fourth ink roller 34, and a fifth ink roller 35 in this order. It is made.

  In the antibacterial printing method according to this embodiment, the first ink roller 31 and the second ink roller 31 are formed on one surface 41a of the paper 41 while the paper 41 to be printed is conveyed by a conveyance device (not shown) of the offset printing machine 30. Printing ink is transferred in this order by the ink roller 32, the third ink roller 33, and the fourth ink roller 34, and four-color printing is performed (step A).

  In step A, the first ink roller 31, the second ink roller 32, the third ink roller 33, and the fourth ink roller 34 use one surface 41 a of the paper 41 using printing inks of different hues. Then, a design printing layer having a predetermined printing pattern is formed.

  Subsequent to step A, while transporting the paper 41 on which the four-color printing has been performed, the fifth ink roller 35 causes the design printing layer to face the surface opposite to the surface in contact with the paper 41 by the fifth ink roller 35. The antibacterial OP varnish of the present invention is transferred to form an antibacterial printed layer that covers the entire surface of the design printed layer opposite to the surface in contact with the paper 41 (step B), and the antibacterial printed matter 51 is obtained.

  According to the antibacterial printing method of this embodiment, after forming a design printing layer on one surface 41a of the paper 41 in step A, in step B, using the antibacterial OP varnish of the present invention, the design printing layer is formed. Since the antibacterial printing layer covering the entire surface opposite to the surface in contact with the paper 41 is formed, the antibacterial printing layer can always be formed on the outermost surface of the antibacterial printed matter 51 obtained by this antibacterial printing method. it can. Therefore, the obtained antibacterial printed matter 51 is protected on the surface opposite to the surface in contact with the paper 41 of the design printing layer without impairing the color of the design printing layer, and in addition, the paper 41 of the design printing layer. The surface opposite to the surface in contact with the surface has water repellency and antibacterial properties.

  In this embodiment, as an example of the printing method, an embodiment in which offset printing is applied has been described. However, the antibacterial printing method of the present invention is not limited to this. In the antibacterial printing method of the present invention, printing methods such as letterpress printing, screen printing, and ink jet printing can also be applied.

  Moreover, in this embodiment, although the case where the design printing layer was formed in one side 41a of the paper 41 in the process A was illustrated, the antibacterial printing method of the present invention is not limited to this. In the antibacterial printing method of the present invention, in step A, a design printing layer may be formed on the other surface of the paper (printed material).

  In this embodiment, the case where the antibacterial print layer is formed so as to cover the entire surface of the design print layer opposite to the surface in contact with the paper 41 in the step B is exemplified. The printing method is not limited to this. In the antibacterial printing method of the present invention, in step B, the antibacterial printing layer may be formed so as to cover at least a part of the surface on which the design printing layer of the paper (printed material) is not formed, In step B, the antibacterial print layer may be formed so as to cover a part of the surface of the design print layer opposite to the surface in contact with the paper (printed material).

  EXAMPLES Hereinafter, although an Example and a comparative example demonstrate this invention further more concretely, this invention is not limited to a following example.

Reference example
Four-color printing was performed on one side of an A4 size paper by offset printing to form a design printing layer, and a printed material α composed of the paper and the design printing layer was produced.
Next, the mass of the printed matter α was measured and found to be 6.26 g.
Next, the glossiness of the surface on which the design print layer of the paper was formed (design print surface) was measured. The glossiness was measured three times at four locations on the design printed surface using a glossmeter (trade name: glossmeter gloss checker IG-320, manufactured by HORIBA).

"Example 1-1"
The antibacterial OP varnish of the present invention is applied to the entire printed surface of the printed material α by offset printing and the antibacterial OP varnish of the present invention is applied to form the antibacterial printed layer. The paper, the design printed layer, and the antibacterial printed layer An antibacterial printed material β1 consisting of:
As the antibacterial OP varnish, silicone oil is used as the water repellent, and the content of the water repellant in the OP varnish is 2.0% by mass with respect to the total of all components constituting the OP varnish. What added 3.5 mass parts of antibacterial agents with respect to 100 mass parts was used.
Next, after measuring the mass of the antibacterial printed material β1, the mass difference between the printed material α and the antibacterial printed material β1 was calculated and found to be 0.27 g. This calculation result is an application amount (g) of the antibacterial OP varnish per unit area (the area of one surface of the A4 size paper is a unit area) in the A4 size antibacterial printed material β1.
Moreover, after measuring the glossiness of the surface on which the antibacterial printed layer of the antibacterial printed material β1 was formed in the same manner as in the reference example, the difference in glossiness between the printed material α and the antibacterial printed material β1 was calculated to be 3.92. . This calculation result (gloss degree difference) is attributed to the antibacterial printed layer of the antibacterial printed material β1.
Further, the antibacterial property of the antibacterial printed material β1 was evaluated according to Japanese Industrial Standard JIS Z 2801. The antibacterial property was evaluated for antibacterial activity against Staphylococcus aureus and antibacterial activity against Escherichia coli. In the antibacterial evaluation, a test piece having an antibacterial activity value of 2.0 or more with respect to a blank test piece (one having no antibacterial OP varnish applied) was evaluated as having an antibacterial effect (◯).
These results are shown in Table 1.

"Example 1-2"
The antibacterial OP varnish of the present invention is applied to the entire printed surface of the printed material α by offset printing and the antibacterial OP varnish of the present invention is applied to form the antibacterial printed layer. The paper, the design printed layer, and the antibacterial printed layer An antibacterial printed material β2 comprising:
As the antibacterial OP varnish, the same one as in Example 1-1 was used.
Next, after measuring the mass of the antibacterial printed material β2, the mass difference between the printed material α and the antibacterial printed material β2 was calculated, and as a result, it was 0.35 g. This calculation result is an application amount (g) of the antibacterial OP varnish per unit area (the area of one surface of the A4 size paper is a unit area) in the A4 size antibacterial printed material β2.
Moreover, after measuring the glossiness of the surface on which the antibacterial printed layer of the antibacterial printed material β2 was formed in the same manner as in the reference example, the glossiness difference between the printed material α and the antibacterial printed material β2 was calculated to be 9.93. . This calculation result (gloss difference) is attributed to the antibacterial printed layer of the antibacterial printed material β2.
In addition, the antibacterial property of the antibacterial printed material β2 was evaluated in the same manner as in Example 1-1.
These results are shown in Table 1.

"Example 1-3"
The antibacterial OP varnish of the present invention is applied to the entire printed surface of the printed material α by offset printing and the antibacterial OP varnish of the present invention is applied to form the antibacterial printed layer. The paper, the design printed layer, and the antibacterial printed layer An antibacterial printed material β3 consisting of:
As the antibacterial OP varnish, the same one as in Example 1-1 was used.
Next, after measuring the mass of the antibacterial printed material β3, the mass difference between the printed material α and the antibacterial printed material β3 was calculated, and it was 0.49 g. This calculation result is an application amount (g) of the antibacterial OP varnish per unit area (the area of one surface of the A4 size paper is a unit area) in the A4 size antibacterial printed material β3.
Moreover, after measuring the glossiness of the surface of the antibacterial printed material β3 on which the antibacterial printed layer was formed in the same manner as in the reference example, the difference in glossiness between the printed material α and the antibacterial printed material β3 was calculated to be 11.29. . This calculation result (gloss difference) is due to the antibacterial printed layer of the antibacterial printed matter β3.
Moreover, it carried out similarly to Example 1-1, and evaluated the antimicrobial property of antimicrobial printed matter (beta) 3.
These results are shown in Table 1.

"Example 2-1"
The antibacterial OP varnish of the present invention is applied to the entire surface of the printed surface of the printed material α by offset printing, and the antibacterial OP varnish of the present invention is applied to form the antibacterial printed layer. An antibacterial printed material γ1 consisting of:
As the antibacterial OP varnish, silicone oil is used as the water repellent, and the content of the water repellant in the OP varnish is 2.0% by mass with respect to the total of all components constituting the OP varnish. What added 1.5 mass parts of antibacterial agents with respect to 100 mass parts was used.
Next, after measuring the mass of the antibacterial printed material γ1, the mass difference between the printed material α and the antibacterial printed material γ1 was calculated, and as a result, it was 0.29 g. This calculation result is the application amount (g) of the antibacterial OP varnish per unit area (the area of one surface of the A4 size paper is a unit area) in the A4 size antibacterial printed material γ1.
Moreover, after measuring the glossiness of the surface on which the antibacterial printed layer γ1 of the antibacterial printed material γ1 was formed in the same manner as in the reference example, the glossiness difference between the printed material α and the antibacterial printed material γ1 was calculated to be 0.28. . This calculation result (gloss difference) is due to the antibacterial printed layer of the antibacterial printed material γ1.
Further, the antibacterial properties of the antibacterial printed material γ1 were evaluated in the same manner as in Example 1-1.
These results are shown in Table 2.

"Example 2-2"
The antibacterial OP varnish of the present invention is applied to the entire surface of the printed surface of the printed material α by offset printing, and the antibacterial OP varnish of the present invention is applied to form the antibacterial printed layer. An antibacterial printed material γ2 consisting of:
As the antibacterial OP varnish, the same one as in Example 2-1 was used.
Next, after measuring the mass of the antibacterial printed material γ2, the mass difference between the printed material α and the antibacterial printed material γ2 was calculated, and as a result, it was 0.36 g. This calculation result is an application amount (g) of the antibacterial OP varnish per unit area (the area of one surface of the A4 size paper is a unit area) in the A4 size antibacterial printed material γ2.
Moreover, after measuring the glossiness of the surface on which the antibacterial printed layer γ2 of the antibacterial printed material γ2 was formed in the same manner as in the reference example, the glossiness difference between the printed material α and the antibacterial printed material γ2 was calculated to be 10.00. . This calculation result (gloss difference) is due to the antibacterial printed layer of the antibacterial printed material γ2.
Further, the antibacterial properties of the antibacterial printed material γ2 were evaluated in the same manner as in Example 1-1.
These results are shown in Table 2.

"Example 2-3"
The antibacterial OP varnish of the present invention is applied to the entire printed surface of the printed material α by offset printing and the antibacterial OP varnish of the present invention is applied to form the antibacterial printed layer. The paper, the design printed layer, and the antibacterial printed layer An antibacterial printed material γ3 consisting of:
As the antibacterial OP varnish, the same one as in Example 2-1 was used.
Next, after measuring the mass of the antibacterial printed material γ3, the mass difference between the printed material α and the antibacterial printed material γ3 was calculated to be 0.44 g. This calculation result is the application amount (g) of the antibacterial OP varnish per unit area (the area of one surface of the A4 size paper is a unit area) in the A4 size antibacterial printed material γ3.
Moreover, after measuring the glossiness of the surface on which the antibacterial printed layer γ3 of the antibacterial printed material γ3 was formed in the same manner as in the reference example, the glossiness difference between the printed material α and the antibacterial printed material γ3 was calculated to be 11.84. . This calculation result (gloss difference) is due to the antibacterial printed layer of the antibacterial printed material γ3.
Moreover, it carried out similarly to Example 1-1, and evaluated the antimicrobial property of antimicrobial printed matter (gamma) 3.
These results are shown in Table 2.

From the results of Examples 1-1 to 2-3 shown in Table 1 and Table 2, it was confirmed that all of these antibacterial printed materials have an antibacterial effect.
Moreover, from the result of Example 1-1 to Example 2-3 shown in Table 1 and Table 2, it originates in the application amount (g) of the antibacterial OP varnish per unit area and the antibacterial printing layer of the antibacterial printed matter. A graph (FIG. 4) showing the relationship with the gloss level (gloss level difference) was created.
FIG. 4 is a graph showing the relationship between the application amount (g) of the antibacterial OP varnish per unit area and the glossiness (glossiness difference) due to the antibacterial printing layer of the antibacterial print, and the vertical axis represents the unit area. The coating amount (g) of the antibacterial OP varnish per hit, and the horizontal axis represents the glossiness (gloss difference) due to the antibacterial printing layer of the antibacterial printed matter. In the graph shown in FIG. 4, (◯) relates to Example 1, and (Δ) relates to Example 2.

From the graph of FIG. 4, it was found that the application amount of the antibacterial OP varnish per unit area and the glossiness (gloss difference) due to the antibacterial printing layer of the antibacterial printed matter are proportional. Therefore, it can be determined that the antibacterial printed matter satisfying this graph has an antibacterial effect.
Therefore, once the antibacterial OP varnish agent coating amount (g) and the relationship between the glossiness and the antibacterial properties of the antibacterial printed matter according to Japanese Industrial Standard JIS Z 2801 are investigated, It was suggested that the presence or absence of the antibacterial effect can be determined by measuring only the coating amount (g) and the glossiness. That is, according to Example 1-1 to Example 2-3, unlike the conventional case, several days or more are not required for confirmation of the antibacterial effect, and thus the cost can be reduced.

"Example 3"
The antibacterial OP varnish of the present invention is applied to the entire surface of one side of a square polyethylene film having a size of about 50 mm × 50 mm and a thickness of about 0.1 mm to form an antibacterial printing layer by offset printing. A square polyethylene film having a size of about 40 mm × 40 mm and a thickness of about 0.09 mm was disposed so as to cover the antibacterial printed layer, and a test piece a was prepared.
As the antibacterial OP varnish, silicone oil is used as the water repellent, and the content of the water repellant in the OP varnish is 2.0% by mass with respect to the total of all components constituting the OP varnish. What added 3.5 mass parts of antibacterial agents with respect to 100 mass parts was used.
About this test piece a, antibacterial activity test against Escherichia coli or Staphylococcus aureus according to Japanese Industrial Standards JIS Z 2801: 2000 “Antimicrobial Processed Products-Antibacterial Test Method / Antimicrobial Effect” 5.2 Plastic Product Test Method Went.
However, the test piece a was subjected to high-pressure steam sterilization (121 ° C., 15 minutes) and then subjected to the test.
In addition, the number of test pieces a used for the antibacterial activity test against each bacterium was three.
The results of the test are shown in Table 3.

The “antibacterial activity value (R)” shown in Table 3 is a numerical value defined by R = Log (B / A) −Log (C / A) = Log (B / C).
In this formula, A is an average value of the number of viable bacteria immediately after inoculation in a non-processed (no antibacterial OP varnish applied) test specimen, and B is an unprocessed (no antibacterial OP varnish applied) test The average value of the number of viable bacteria after 24 hours in the piece, C represents the average value of the number of viable bacteria after 24 hours in the test piece a to which the antibacterial OP varnish was applied.
If the antibacterial activity value (R) is 2.0 or more, it is determined that there is an antibacterial effect.

"Comparative example"
Applying an OP varnish added with an antibacterial agent to a conventional OP varnish by offset printing on the entire surface of one side of a square polyethylene film having a size of about 50 mm × 50 mm and a thickness of about 0.1 mm, An antibacterial printing layer was formed, and a square polyethylene film having a size of about 40 mm × 40 mm and a thickness of about 0.09 mm was arranged to cover the antibacterial printing layer, and a test piece b was produced.
As OP varnish, what added 3.5 mass parts of antibacterial agents with respect to 100 mass parts of OP varnish was used without including a water repellent.
As the antibacterial agent, the same one as that contained in the antibacterial OP varnish of the present invention was used.
About this test piece b, antibacterial activity test against Escherichia coli or Staphylococcus aureus according to Japanese Industrial Standards JIS Z 2801: 2000 “Antimicrobial Processed Products-Antibacterial Test Methods / Antimicrobial Effects” 5.2 Plastic Product Test Methods Went.
However, the test piece b was subjected to high-pressure steam sterilization (121 ° C., 15 minutes) and then subjected to the test.
Moreover, the number of the test pieces b used for the antibacterial activity test with respect to each bacterium was three.
Table 4 shows the test results.

From the results of Table 3, it was found that the test piece a has an antibacterial effect against Escherichia coli and Staphylococcus aureus.
Moreover, from the results of Table 4, it was found that the test piece b has an antibacterial effect against Escherichia coli but has no antibacterial effect against Staphylococcus aureus.
The antibacterial activity value (R) against E. coli of the test piece b is 2.9 to 3.6, whereas the antibacterial activity value (R) against E. coli of the test piece a is larger than 7, and the test piece a Since the antibacterial activity value (R) against Staphylococcus aureus was greater than 4.3, it was found that the test piece a had stronger antibacterial activity than the test piece b.

DESCRIPTION OF SYMBOLS 10 ... Antibacterial printed matter, 11 ... Printed material, 12 ... Design printing layer, 13, 23 ... Antibacterial printing layer, 30 ... Offset printing machine, 31 ... First ink roller, 32 ... Second ink roller, 33 ... Third ink roller, 34 ... Fourth ink roller, 35 ... Fifth ink roller, 41 ... Paper, 51 ... Antibacterial printed matter.

Claims (3)

2 antibacterial agents containing silver oxide-zinc calcium phosphate and isopropyl alcohol with respect to 100 parts by mass of OP varnish containing solid resin, vegetable oil, high boiling point petroleum solvent and silicone oil as water repellent. Antibacterial OP varnish formed by adding ~ 5 parts by mass,
The content of the solid resin in the OP varnish is in a range of 30 to 40% by mass with respect to the total of all components constituting the OP varnish,
The content of the vegetable oil in the OP varnish is in the range of 18 to 30% by mass with respect to the total of all components constituting the OP varnish,
The content of the high-boiling petroleum solvent in the OP varnish is in the range of 38 to 50% by mass with respect to the total of all components constituting the OP varnish,
The content of the water repellent in the OP varnish is 1 to 5% by mass with respect to the total of all components constituting the OP varnish,
The content of the silver oxide-zinc calcium phosphate in the antibacterial agent is in the range of 25 to 27% by mass with respect to the total of all the components constituting the antibacterial agent,
The antibacterial OP varnish characterized by the content rate of the said isopropyl alcohol in the said antibacterial agent being the range of 73-75 mass% with respect to the sum total of all the components which comprise the said antibacterial agent. The printed material, the design printed layer formed on the surface of the printed material, and at least a part of the surface of the designed printed layer opposite to the surface in contact with the printed material and / or the design of the printed material An antibacterial printed material comprising an antibacterial printed layer covering at least a part of a surface not in contact with the printed layer,
The antibacterial printed layer, comprising the antibacterial OP varnish according to claim 1. Printing on the surface of the substrate to be printed to form a design print layer, and at least a part of the surface of the design print layer opposite to the surface in contact with the substrate to be printed and / or of the substrate to be printed Printing is performed on at least a part of the surface not in contact with the design printing layer, and at least a part of the surface of the design printing layer opposite to the surface in contact with the printed material and / or the printed material. An antibacterial printing method comprising a step B of forming an antibacterial printing layer covering at least a part of a surface not in contact with the design printing layer,
In the said process B, the said antibacterial printing layer is formed using the antibacterial OP varnish of Claim 1, The antibacterial printing method characterized by the above-mentioned.

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