JP5236394B2 - Polybutylene terephthalate resin composition and thin-walled molded article - Google Patents

Description

  The present invention relates to a polybutylene terephthalate resin composition excellent in fluidity and a thin molded article. More specifically, it has excellent fluidity, such as switches, capacitors, connectors, integrated circuits (ICs), relays, resistors, light emitting diodes (LEDs), coil bobbins and peripheral devices, electrical and electronic parts such as housings, etc. The present invention relates to a polybutylene terephthalate resin composition suitable for injection molded products and a thin molded product.

  Polybutylene terephthalate resin has excellent mechanical properties, electrical properties, heat resistance, weather resistance, water resistance, chemical resistance, and solvent resistance, so it can be used as an engineering plastic for automotive parts, electrical / electronic parts, etc. It is widely used for applications. Such polybutylene terephthalate resin is used alone in various molded products, but depending on the application field, talc is blended for the purpose of improving its properties, for example, mechanical properties, particularly rigidity (flexural modulus). It is known.

  However, the composition containing talc is excellent in the effect of improving the rigidity, but has a problem that the tensile elongation is lowered. Although higher tensile elongation can be expected by using higher molecular weight polybutylene terephthalate resin, it is thin, plate-shaped or box-shaped, such as micro switch case, small coil bobbin, thin connector, disk cartridge In a shutter or the like, there is a problem of molding failure (insufficient filling of a molded product mold) due to a decrease in fluidity, and a material with improved fluidity has been desired.

  Patent Document 1 discloses a composition containing specific talc as a crystallization nucleating agent, and it is said that such a composition is excellent in improving crystallization characteristics. No information is given about the fluidity of the product.

  As a technique for improving the fluidity of polybutylene terephthalate resin, for example, Patent Document 2 discloses a polybutylene terephthalate resin composition in which polybutylene terephthalates having different viscosities (number average molecular weights) are blended at a predetermined ratio. Yes. This document describes that the resin composition improves the repeated fatigue resistance of the molded body and has high fluidity in a molten state. However, the resin composition of this document is inferior to the case of using a high-viscosity polybutylene terephthalate alone in terms of the elongation of the resin and the like.

  It is also known to add a fluidity improver to the polybutylene terephthalate resin in order to improve fluidity. For example, Patent Document 3 discloses a resin composition obtained by mixing a specific aromatic polybasic acid ester as a fluidity improver with a thermoplastic polyester resin mainly composed of polytetramethylene terephthalate. However, in the resin composition described in this document, the mechanical strength tends to be slightly lowered as compared with the case where no fluidity improver is added.

  In addition, in order to improve fluidity, resin flowability improvers are generally used. However, the use of such resin flowability improvers may cause bleeding and peeling of the molded product surface layer. In addition, a decrease in mechanical strength cannot be avoided.

On the other hand, Patent Document 4 discloses a composition comprising a fatty acid ester mainly composed of a polyhydric alcohol selected from glycerin and pentaerythritol and a fatty acid having 12 or more carbon atoms. In this document, it is described that the resin composition is excellent in moldability, in particular, pellet biteability during injection molding, and has excellent moldability. It is not described at all.
JP-A-57-14653 (Claims) JP 5-179114 A (claims, paragraph [0005]) JP-A-61-85467 (Claims) JP-A-4-120162 (Claims)

  An object of the present invention is to provide a polybutylene terephthalate resin composition excellent in mechanical strength, maintaining toughness and having improved fluidity (melt fluidity), and a molded product thereof.

  As a result of intensive studies to solve the above problems, the present inventors have found that a polybutylene terephthalate resin composition that can achieve the above-mentioned object by combining a polybutylene terephthalate resin, talc, and a specific glycerin fatty acid ester. As a result, the present invention was completed.

That is, the present invention
(A) For 100 parts by weight of polybutylene terephthalate resin,
(B) 0.01-5 parts by weight of talc,
(C) Polybutylene comprising glycerin and / or a dehydration condensate thereof and a fatty acid having 12 or more carbon atoms, and blending 0.05 to 5 parts by weight of a glycerin fatty acid ester having a hydroxyl value measured by the method described herein of 200 or more A terephthalate resin composition and a molded product thereof.

  The polybutylene terephthalate resin composition of the present invention is excellent in mechanical strength and toughness and fluidity during melt molding. The polybutylene terephthalate resin composition of the present invention has electrical and electronic components such as switches, capacitors, connectors, integrated circuits (ICs), relays, resistors, light emitting diodes (LEDs), coil bobbins and peripheral devices, and housings because of their characteristics. It is suitable for.

[Polybutylene terephthalate resin composition]
(A) Polybutylene terephthalate resin
(A) The polybutylene terephthalate resin is a heat containing at least a polymerization component of terephthalic acid (terephthalic acid or an ester-forming derivative thereof) and an alkylene glycol having 4 carbon atoms (1,4-butanediol) or an ester-forming derivative thereof. It is a plastic resin.

  The polybutylene terephthalate resin (PBT resin) as the base resin is mainly composed of butylene terephthalate [for example, 50% by weight or more (for example, 55 to 100% by weight), preferably 60% by weight or more (for example, 65 to 100%). Weight polyester) (polybutylene terephthalate) or copolyester (butylene terephthalate copolymer or polybutylene terephthalate copolyester) and the like. .

  Examples of the copolymerizable monomer in the copolyester (butylene terephthalate copolymer or modified PBT resin) (hereinafter sometimes simply referred to as a copolymerizable monomer) include dicarboxylic acid components excluding terephthalic acid, 1,4- Examples include diols other than butanediol, oxycarboxylic acid components, and lactone components. The copolymerizable monomers can be used alone or in combination of two or more.

Dicarboxylic acids (or dicarboxylic acid components or dicarboxylic acids) include aliphatic dicarboxylic acids (for example, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, undecanedicarboxylic acid, dodecanedicarboxylic acid, hexadecandioyl carboxylic acid, C _{4 to 40} dicarboxylic acids such as dimer acid, preferably C _{4 to 14} dicarboxylic acids), alicyclic dicarboxylic acid component (e.g., hexahydrophthalic acid, hexahydroisophthalic acid, hexahydroterephthalic acid, hymic _C8-12 dicarboxylic acid such as acid), aromatic dicarboxylic acid components excluding terephthalic acid (for example, naphthalenedicarboxylic acid such as phthalic acid, isophthalic acid, 2,6-naphthalenedicarboxylic acid, 4,4′-diphenyldicarboxylic acid) , 4,4'-Diphenoxyether dicarboxylic acid Acid, 4,4'-diphenyl ether dicarboxylic acid, 4,4'-diphenylmethane dicarboxylic acid, 4,4' C _{8 to 16} dicarboxylic acids such as diphenyl ketone dicarboxylic acid), or reactive derivatives thereof (e.g., lower alkyl ester (dimethyl phthalate, and phthalic acid or C _{1 to 4} alkyl esters of isophthalic acid, such as dimethyl isophthalate (DMI)), acid chloride, ester formable derivatives such as acid anhydrides) and the like. Furthermore, you may use together polyvalent carboxylic acid, such as trimellitic acid and pyromellitic acid, or its ester formation derivative (alcohol ester etc.) etc. as needed. When such a polyfunctional compound is used in combination, a branched polybutylene terephthalate resin can also be obtained.

Diols (or diol components or diols) include, for example, aliphatic alkanediols excluding 1,4-butanediol [for example, alkanediols (for example, ethylene glycol, trimethylene glycol, propylene glycol, neopentyl glycol, hexanediol ( 1,6-hexanediol, etc.), octanediol (1,3-octanediol, 1,8-octanediol, etc.), lower alkanediols such as decanediol, preferably linear or branched C _2-12 alkanes Diols, more preferably linear or branched C _2-10 alkane diols); (poly) oxyalkylene glycols (eg glycols having a plurality of oxy C _2-4 alkylene units, eg diethylene glycol, dipropylene glycol) Ditetramethylene glycol , Triethylene glycol, tripropylene glycol, polytetramethylene glycol, etc.)], alicyclic diols (eg, 1,4-cyclohexanediol, 1,4-cyclohexanedimethanol, hydrogenated bisphenol A, etc.), aromatic Diols [for example, dihydroxy C _6-14 arenes such as hydroquinone, resorcinol, naphthalenediol; biphenols (such as 4,4′-dihydroxybiphenyl); bisphenols; xylylene glycol, etc.], and reactive derivatives thereof ( For example, ester-forming derivatives such as alkyl, alkoxy or halogen-substituted products). Furthermore, if necessary, a polyol such as glycerin, trimethylolpropane, trimethylolethane, pentaerythritol, or an ester-forming derivative thereof may be used in combination. When such a polyfunctional compound is used in combination, a branched polybutylene terephthalate resin can also be obtained.

Examples of the bisphenols include bis (4-hydroxyphenyl) methane (bisphenol F), 1,1-bis (4-hydroxyphenyl) ethane (bisphenol AD), 1,1-bis (4-hydroxyphenyl) propane, , 2-bis (4-hydroxyphenyl) propane (bisphenol A), 2,2-bis (4-hydroxy-3-methylphenyl) propane, 2,2-bis (4-hydroxyphenyl) butane, 2,2- Bis (hydroxyaryl) C ₁ such as bis (4-hydroxyphenyl) -3-methylbutane, 2,2-bis (4-hydroxyphenyl) hexane, 2,2-bis (4-hydroxyphenyl) -4-methylpentane _{~ 6} alkanes, 1,1-bis (4-hydroxyphenyl) cyclopentane, 1,1-bis (4-hydro) Bis (hydroxyaryl) C _4-10 cycloalkane such as xylphenyl) cyclohexane, 4,4′-dihydroxydiphenyl ether, 4,4′-dihydroxydiphenyl sulfone, 4,4′-dihydroxydiphenyl sulfide, 4,4′-dihydroxydiphenyl Examples thereof include ketones and their alkylene oxide adducts. The alkylene oxide adduct, bisphenol (e.g., bisphenol A, bisphenol AD, bisphenol F) C _{2 to 3} alkylene oxide adduct of, for example, 2,2-bis [4- (2-hydroxyethoxy) phenyl] propane , Diethoxylated bisphenol A (EBPA), 2,2-bis [4- (2-hydroxypropoxy) phenyl] propane, dipropoxylated bisphenol A, and the like. The added mole number of alkylene oxide ( _C2-3 alkylene oxide such as ethylene oxide or propylene oxide) is about 1 to 10 moles, preferably about 1 to 5 moles relative to each hydroxy group.

Examples of the oxycarboxylic acid (or oxycarboxylic acid component or oxycarboxylic acid) include oxycarboxylic acids such as oxybenzoic acid, oxynaphthoic acid, hydroxyphenylacetic acid, glycolic acid, oxycaproic acid, or derivatives thereof. . Lactones include C _3-12 lactones such as propiolactone, butyrolactone, valerolactone, caprolactone (eg, ε-caprolactone, etc.), and the like.

Among these copolymerizable monomers, preferably diols [C _2-6 alkylene glycol (such as linear or branched alkylene glycol such as ethylene glycol, trimethylene glycol, propylene glycol, hexanediol), and the number of repetitions] Polyoxy C _2-4 alkylene glycol (such as diethylene glycol) having about 2 to 4 oxyalkylene units, bisphenols (such as bisphenols or their alkylene oxide adducts)], dicarboxylic acids [C _6-12 aliphatic dicarboxylic acids (adipine) Acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, etc.), asymmetric aromatic dicarboxylic acids in which the carboxyl group is substituted at the asymmetric position of the arene ring, 1,4-cyclohexanedimethanol, etc.].

  Among these compounds, aromatic compounds such as alkylene oxide adducts of bisphenols (particularly bisphenol A), and asymmetric aromatic dicarboxylic acids [phthalic acid, isophthalic acid and reactive derivatives thereof (dimethylisophthalic acid (DMI), etc.) And the like, etc.] are preferred.

  The polybutylene terephthalate resin is preferably a homopolyester (polybutylene terephthalate) and / or a copolymer (polybutylene terephthalate copolyester), and the polybutylene terephthalate resin usually has a ratio (modification amount) of a copolymerizable monomer. 45 mol% or less (for example, about 0 to 45 mol%), preferably 35 mol% or less (for example, about 0 to 35 mol%), more preferably 30 mol% or less (for example, about 0 to 30 mol%). It may be a homo or copolyester (particularly a homopolyester).

  In the copolymer, the proportion of the copolymerizable monomer can be selected, for example, from the range of about 0.01 to 30 mol%, and is usually 1 to 30 mol%, preferably 3 to 25 mol%, more preferably 5 to 5 mol%. It is about 20 mol% (for example, 5 to 15 mol%). In addition, when a homopolyester (polybutylene terephthalate) and a copolymer (copolyester) are used in combination, the proportion of the homopolyester and the copolyester is such that the proportion of the copolymerizable monomer is relative to the total monomers. The range is about 0.1 to 30 mol% (preferably 1 to 25 mol%, more preferably 5 to 25 mol%). Usually, the former / the latter = 99/1 to 1/99 (weight ratio), preferably It can be selected from a range of about 95/5 to 5/95 (weight ratio), more preferably about 90/10 to 10/90 (weight ratio).

  The intrinsic viscosity (IV) of the polybutylene terephthalate resin is preferably 1.0 dL / g or less, and more preferably 0.9 dL / g or less. By blending polybutylene terephthalate resins having different intrinsic viscosities, for example, by blending polybutylene terephthalate resins with intrinsic viscosities of 1.2 dL / g and 0.8 dL / g, an intrinsic viscosity of 1.0 dL / g or less is achieved. Also good. The intrinsic viscosity (IV) can be measured, for example, in O-chlorophenol at a temperature of 35 ° C. When a polybutylene terephthalate resin having an intrinsic viscosity in such a range is used, it is easy to efficiently achieve sufficient toughness and a reduced melt viscosity. If the intrinsic viscosity is too large, the melt viscosity at the time of molding becomes high, and in some cases, there is a possibility of causing poor resin flow and poor filling in the molding die.

As the polybutylene terephthalate resin, a commercially available product may be used, and terephthalic acid or a reactive derivative thereof and 1,4-butanediol and, if necessary, a monomer copolymerizable with a conventional method such as transesterification, You may use what was manufactured by copolymerization (polycondensation) by the direct esterification method etc.
(B) Talc In the present invention, (B) talc is an essential component, and the rigidity of the polybutylene terephthalate resin can be improved by adding (B) talc. (B) The type of talc and the like are not particularly limited, but use of compressed fine powder talc is preferable because it has high uniform dispersibility and can improve kneading workability. Particularly preferable is compressed fine talc having an average particle size of 1 to 8 μm.

The blending amount of (B) talc is 0.01 to 5 parts by weight, preferably 0.1 to 4 parts by weight, particularly preferably 0.3 to 3 parts by weight with respect to 100 parts by weight of (A) polybutylene terephthalate resin. When the amount is too small, the effect of improving the rigidity is not sufficient. When the amount is excessively added, the formability is inferior and the toughness is decreased.
(C) Glycerin fatty acid ester The feature of the present invention is that a polybutylene terephthalate resin is combined with a specific glycerin fatty acid ester. Usually, when a fluidity improver or the like is added to a polybutylene terephthalate resin, even if the fluidity can be improved, a decrease in properties such as mechanical strength and toughness of the polybutylene terephthalate resin itself cannot be avoided. In the present invention, by using a specific glycerin fatty acid ester, the fluidity of the polybutylene terephthalate resin composition can be efficiently improved while maintaining the above characteristics at a high level. In addition, by combining with talc, the rigidity of the resin composition or its molded product can be improved, and the effect of improving such rigidity is not reduced by the use of glycerin fatty acid ester, so mechanical strength and toughness It is possible to achieve both balance and improvement of fluidity in a balanced manner.

  (C) Glycerin fatty acid ester is an ester composed of glycerin and / or a dehydration condensate thereof and a fatty acid having 12 or more carbon atoms. Examples of the fatty acid having 12 or more carbon atoms constituting the ester include lauric acid, oleic acid, palmitic acid, stearic acid, 12-hydroxystearic acid, behenic acid, and montanic acid, and preferably fatty acids having 12 to 32 carbon atoms. Particularly preferably, fatty acids having 12 to 22 carbon atoms are used, and lauric acid, stearic acid, 12-hydroxystearic acid or behenic acid is particularly preferred. Those having less than 12 carbon atoms are not preferable because the heat resistance may be lowered, and those having more than 32 carbon atoms are not preferable because the effect of improving fluidity is small.

  The (C) glycerin fatty acid ester used in the present invention can be produced by a method known per se. The (C) glycerin fatty acid ester used in the present invention is prepared by adjusting the esterification so that the hydroxyl value measured by the method described below is 200 or more, and preferably has a hydroxyl value of 250 or more. When the hydroxyl value is less than 200, the effect of improving the fluidity is small, which is not preferable.

  Examples of preferred esters include glycerol monostearate, glycerol monobehenate, diglycerol monostearate, triglycerol monostearate, tetraglycerol stearic acid partial ester, decaglycerol lauric acid partial ester, glycerol mono 12-hydroxystearate, etc. Is mentioned.

(C) The compounding quantity of glycerol fatty acid ester is 0.05-5 weight part with respect to 100 weight part of (A) polybutylene terephthalate resin, Preferably it is 0.5-3 weight part. (C) If the blending amount of glycerin fatty acid ester is less than 0.05 parts by weight, the effect of improving the fluidity may not be sufficiently obtained, and if it exceeds 5 parts by weight, the amount of gas generation increases with molding, There is a risk of damage to the appearance and mold contamination.
(D) Polycarbonate resin The resin composition of the present invention may contain a polycarbonate resin for the purpose of improving mechanical strength within the range not impairing the effects of the present invention.

  (D) Polycarbonate resin is a solvent method, that is, a reaction between a dihydric phenol and a carbonate precursor such as phosgene in the presence of a known acid acceptor, molecular weight modifier or the like in a solvent such as methylene chloride, or It can be produced by a transesterification reaction between a monohydric phenol and a carbonate precursor such as diphenyl carbonate. Here, the dihydric phenol that can be suitably used includes bisphenols, and 2,2-bis (4-hydroxyphenyl) propane, that is, bisphenol A is particularly preferable. Further, a part or all of bisphenol A may be substituted with another dihydric phenol. Examples of dihydric phenols other than bisphenol A include hydroquinone, 4,4-dihydroxydiphenyl, bis (4-hydroxyphenyl) alkane, bis (4-hydroxyphenyl) cycloalkane, bis (4-hydroxyphenyl) sulfide, bis Compounds such as (4-hydroxyphenyl) ether, or halogenated bisphenols such as bis (3,5-dibromo-4-hydroxyphenyl) propane and bis (3,5-dichloro-4-hydroxyphenyl) propane Can be mentioned. These dihydric phenols may be a dihydric phenol homopolymer or two or more copolymers. Furthermore, the polycarbonate resin used in the present invention may be a thermoplastic random branched polycarbonate obtained by reacting a polyfunctional aromatic compound with a dihydric phenol and / or a carbonate precursor.

  In the present invention, the proportion of (D) polycarbonate resin is 10 to 100 parts by weight, preferably 20 to 90 parts by weight, particularly preferably 30 to 80 parts by weight, based on 100 parts by weight of (A) polybutylene terephthalate resin. . If it is less than 10 parts by weight, sufficient mechanical strength may not be obtained, and if it exceeds 100 parts by weight, the characteristics of the polybutylene terephthalate resin may be impaired.

  When (D) a polycarbonate resin is included, a phosphorus stabilizer is suitably used for the purpose of suppressing the transesterification reaction with (A) polybutylene terephthalate resin. Phosphorus stabilizers include inorganic phosphorus stabilizers (alkali metal or alkaline earth metal phosphates, etc.) and organic phosphorus stabilizers (organic phosphites, organic phosphates, organic phosphonates, organic And at least one selected from phosphonous acid esters and the like. The phosphorus stabilizer may be either liquid or solid.

  In addition, the resin composition of this invention may contain other resin (thermoplastic resin etc.) and various additives in the range which does not impair the effect of this invention as needed. Examples of the other resins include polyester resins other than polybutylene terephthalate resins, polyolefin resins, polystyrene resins, polyamide resins, polyacetals, polyarylene oxides, polyarylene sulfides, and fluorine resins. Further, copolymers such as acrylonitrile-styrene resin, acrylonitrile-butadiene-styrene resin, and ethylene-ethyl acrylate resin are also exemplified. These other resins may be used alone or in combination of two or more.

  Further, as additives, organic fillers (for example, high melting point aromatic polyester fibers, liquid crystalline polyester fibers, aromatic polyamide fibers, fluororesin fibers, polyimide fibers, etc.), stabilizers other than the above phosphorus stabilizers ( Antioxidants, ultraviolet absorbers, heat stabilizers, etc.), antistatic agents, flame retardants, flame retardant aids, thermoplastic elastomers, colorants (dyes, pigments, etc.), lubricants, plasticizers, lubricants, release agents And crystal nucleating agents. Moreover, in the resin composition of this invention, you may use fluorine-type compounds, such as polytetrafluoroethylene, as a dripping prevention agent (dripping prevention agent) at the time of combustion. These additives are used alone or in combination of two or more.

  The polybutylene terephthalate resin composition of the present invention may be a powder / particle mixture or a molten mixture (such as pellets). In particular, since the resin composition of the present invention is excellent in melt fluidity, each component [(A) polybutylene terephthalate resin, (B) talc, (C) glycerin fatty acid ester, and blended as necessary (D) Polycarbonate resin or other components] can be efficiently obtained as a molten mixture (melt kneaded material). Moreover, you may use for the manufacture of a molded object as it is with the resin composition of this invention in the form of a mixture (for example, a granular material or a molten mixture).

And the fluidity | liquidity of such a resin composition of this invention can reflect the melt viscosity under the conditions under a fixed piston flow shear rate as a parameter | index. For example, the melt viscosity of the resin composition of the present invention is 160 Pa · s or less, preferably 150 Pa · s or less, more preferably 140 Pa · s or less (for example, 50 to 140 Pa) at a shear rate of 1000 sec ⁻¹ at a temperature of 260 ° C.・ It can also be s). The measurement results are obtained in units of Pa · s as described above. The lower the numerical value, the better the fluidity during melting and the better fluidity during molding.

In general, a melt index measured by ASTM D-1238 under conditions of 235 ° C and a load of 2160g is used as an index of fluidity. The shear rate is different. On the other hand, the melt viscosity measurement index under a constant piston flow is considered to be an index closer to the actual flow characteristics considering that actual injection molding is performed with a constant piston flow. In the present invention, the melt viscosity under such a constant shear rate condition is used as an index of fluidity.
[Molded body]
Since the resin composition of the present invention is excellent in melt fluidity as described above, it has good moldability and is useful for producing a molded article or molded article having high mechanical strength and heat resistance. .

  In particular, it is suitable for producing a molded product having a thin portion. For example, in injection molding at a cylinder temperature of 260 ° C. and a mold temperature of 65 ° C., which are manufacturing conditions for injection molding of ordinary polybutylene terephthalate resin, it becomes possible to mold an injection molded product having a thickness of 0.5 mm or less. .

  In some cases, the flow length at a thickness of 0.5 mm is required to be 40 mm or more. With the resin composition of the present invention, a flow length of 40 mm or more is also possible.

  Thin parts having a thickness of 0.5 mm or less in a part of the molded product include connectors, switches, capacitors, integrated circuits (ICs), relays, resistors, light emitting diodes (LEDs), coil bobbins and their peripheral devices. Or a housing is illustrated.

  The molded body (or molded product) is composed of each component [(A) polybutylene terephthalate resin, (B) talc, (C) glycerin fatty acid ester and (D) polycarbonate resin or other components blended as necessary]. Further, it can be produced by molding the resin composition by a conventional method. For example, in the molded product of the present invention, i) a method in which each component is mixed and then kneaded and extruded by an extruder (single screw or twin screw extruder) to prepare pellets, and then molded, ii) pellets having different compositions once (Master batch) is prepared, and the pellets are mixed (diluted) in a predetermined amount and subjected to molding, and after molding, a molded product having the desired composition is obtained. Iii) One or more of each component is directly charged into a molding machine Any of them can be used. Further, mixing a part of the resin component as a fine powder with other components and adding it is a preferable method for uniformly blending these components. In addition, the above-described filler and the like can be added at any time to obtain a desired composition.

  In addition to injection molding, the molded body is easily kneaded by a conventional molding method such as extrusion molding, compression molding, blow molding, vacuum molding, rotational molding, gas injection molding, etc. by melt-kneading the polybutylene terephthalate resin composition. And a molded product can be obtained efficiently. In particular, injection molding is preferred.

Hereinafter, the present invention will be described in more detail by way of examples, but the present invention is not limited thereto.
Examples 1-10, Comparative Examples 1-6
Each resin composition was dry blended at the mixing ratio shown in Tables 1 and 2, and melt-kneaded at 250 ° C using a twin screw extruder (manufactured by Nippon Steel Co., Ltd.) having a 30mmφ screw, then pelletized and tested. A piece was made and each evaluation was performed. The results are shown in Tables 1 and 2.

Moreover, the detail of the used component and the measuring method of physical property evaluation are as follows.
・ (A) Polybutylene terephthalate resin
(A-1) Polybutylene terephthalate (Intrinsic viscosity IV = 0.69 dL / g, manufactured by Wintech Polymer Co., Ltd.)
(A-2) Polybutylene terephthalate (Intrinsic viscosity IV = 0.875dL / g, manufactured by Wintech Polymer Co., Ltd.)
(A-3) Polyester elastomer (“Nuberan P4110AN” manufactured by Teijin Chemicals Ltd.)
・ (B) Talc Talc (Hayashi Kasei Co., Ltd. “Micron White 5000A”, average particle size 5μm)
・ (C) Glycerin fatty acid ester
(C-1) Glycerol monostearate (Hydroxyl value 330, “Electro Stripper TS-5” manufactured by Kao Corporation)
(C-2) Glycerol monobehenate (Hydroxyl value 300, “Riquemar B-100” manufactured by Riken Vitamin Co., Ltd.)
(C-3) Triglycerin stearic acid partial ester (hydroxyl value 280, "Rikemar AF-70" manufactured by Riken Vitamin Co., Ltd.)
(C-4) Decaglycerin lauric acid partial ester (hydroxyl value 600, “Poem L-021” manufactured by Riken Vitamin Co., Ltd.)
(C-5) Glycerol mono 12-hydroxystearate (hydroxyl value 420, “Rikemar HC-100” manufactured by Riken Vitamin Co., Ltd.)
(C-6) Glycerol tristearate (hydroxyl value 87, “Poem S-95” manufactured by Riken Vitamin Co., Ltd.)
(D) Polycarbonate resin Polycarbonate resin (“Panlite CM-1000” manufactured by Teijin Chemicals Ltd.)
・ Other components Antioxidant IRGANOX1010 (manufactured by Ciba Specialty Chemicals) is added in 0.1 parts by weight to all examples and comparative examples.

Phosphoric stabilizer ADK STAB PEP-30 (manufactured by ADEKA) is added in 0.1 part by weight to Example 9 and Comparative Example 6 in which (D) polycarbonate resin is added.
<Hydroxyl value>
It was measured by the oil chemistry association method 2,4,9,2-71 hydroxyl value (pyridine / acetic anhydride method).
<Melt viscosity>
The obtained pellets were dried at 140 ° C. for 3 hours, and then measured using a Capillograph 1B (manufactured by Toyo Seiki Seisakusho) at a furnace temperature of 260 ° C. and a capillary φ1 mm × 20 mmL at a shear rate of 1000 sec ⁻¹ . The lower the value, the better the fluidity during melting and the better fluidity during molding.
<Tensile strength, elongation>
The obtained pellets were dried at 140 ° C. for 3 hours, and an ASTM No. 4 type tensile test piece was produced by injection molding at a molding temperature of 260 ° C. and a mold temperature of 80 ° C. The obtained test piece was evaluated according to the evaluation criteria defined in ASTM D638.
<Bending strength, flexural modulus>
The obtained pellets were dried at 140 ° C. for 3 hours, then injection molded at a molding temperature of 260 ° C. and a mold temperature of 80 ° C. to produce bending test pieces, which were evaluated according to the evaluation criteria defined in ISO178.
<Thin wall fluidity>
The obtained pellets were dried at 140 ° C. for 3 hours, and then a bar flow molded product having a thickness of 0.5 mm and a width of 5 mm was molded, and the flow length was judged. The injection conditions were evaluated at a cylinder pressure of 260 ° C., a mold temperature of 65 ° C., an injection speed of 70 mm / s, and a holding pressure of 2 levels (50 MPa, 100 MPa).

Claims (6)

(A) For 100 parts by weight of polybutylene terephthalate resin,
(B) 0.01 to 1 part by weight of talc,
(C) Glycerin and / or its dehydration condensate and a fatty acid having 12 to 22 carbon atoms, and 0.05 to 5 parts by weight of a glycerin fatty acid ester having a hydroxyl value measured by the pyridine / acetic anhydride method of 200 or more. A thin-walled molded article comprising a polybutylene terephthalate resin composition,
Switches, capacitors, connectors, integrated circuits (ICs), relays, resistors, light-emitting diodes (LEDs), coil bobbins and their peripheral devices or housings that have a thickness of 0.5 mm or less in a part of the molded product A thin-walled molded product.   Furthermore, the thin molded article which consists of a polybutylene terephthalate resin composition of Claim 1 formed by mix | blending (D) polycarbonate resin 10-100 weight part.   (B) A thin molded article comprising the polybutylene terephthalate resin composition according to claim 1 or 2, wherein the talc has an average particle diameter of 1 to 8 µm.   (C) The fatty acid which comprises glycerol fatty acid ester is lauric acid, a stearic acid, or behenic acid, The thin molded article which consists of a polybutylene terephthalate resin composition in any one of Claims 1-3. The thin-walled molded article comprising the polybutylene terephthalate resin composition according to any one of claims 1 to 4, wherein a measured value of melt viscosity at a shear rate of 1000 sec ^-1 at a temperature of 260 ° C is 140 Pa · s or less.   The thin molded article comprising the polybutylene terephthalate resin composition according to any one of claims 1 to 5, wherein a flow length at a thickness of 0.5 mm is 40 mm or more in injection molding at a cylinder temperature of 260 ° C and a mold temperature of 65 ° C.