JP4968747B2 - Iii−v族化合物半導体素子 - Google Patents
Iii−v族化合物半導体素子 Download PDFInfo
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- JP4968747B2 JP4968747B2 JP2009022950A JP2009022950A JP4968747B2 JP 4968747 B2 JP4968747 B2 JP 4968747B2 JP 2009022950 A JP2009022950 A JP 2009022950A JP 2009022950 A JP2009022950 A JP 2009022950A JP 4968747 B2 JP4968747 B2 JP 4968747B2
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- 239000004065 semiconductor Substances 0.000 title claims description 67
- 150000001875 compounds Chemical class 0.000 title claims description 27
- 230000004888 barrier function Effects 0.000 claims description 31
- 239000001257 hydrogen Substances 0.000 claims description 31
- 229910052739 hydrogen Inorganic materials 0.000 claims description 31
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 28
- 229910052751 metal Inorganic materials 0.000 claims description 26
- 239000002184 metal Substances 0.000 claims description 25
- 150000004767 nitrides Chemical class 0.000 claims description 24
- 238000001179 sorption measurement Methods 0.000 claims description 17
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 8
- 239000000758 substrate Substances 0.000 claims description 8
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 5
- 150000004678 hydrides Chemical class 0.000 claims description 5
- 229910017109 AlON Inorganic materials 0.000 claims description 4
- 229910016036 BaF 2 Inorganic materials 0.000 claims description 4
- 229910004261 CaF 2 Inorganic materials 0.000 claims description 4
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 4
- 229910052689 Holmium Inorganic materials 0.000 claims description 4
- 229910052779 Neodymium Inorganic materials 0.000 claims description 4
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 4
- 229910052772 Samarium Inorganic materials 0.000 claims description 4
- -1 SrF 2 Inorganic materials 0.000 claims description 4
- 229910052771 Terbium Inorganic materials 0.000 claims description 4
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 4
- GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 claims description 4
- 229910052788 barium Inorganic materials 0.000 claims description 4
- 229910052792 caesium Inorganic materials 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 229910052735 hafnium Inorganic materials 0.000 claims description 4
- 229910052746 lanthanum Inorganic materials 0.000 claims description 4
- 229910052744 lithium Inorganic materials 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- 229910052706 scandium Inorganic materials 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 229910052712 strontium Inorganic materials 0.000 claims description 4
- 229910052727 yttrium Inorganic materials 0.000 claims description 4
- 229910052726 zirconium Inorganic materials 0.000 claims description 4
- 229910052691 Erbium Inorganic materials 0.000 claims description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 3
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 3
- 229910052693 Europium Inorganic materials 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 135
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 22
- 229910002704 AlGaN Inorganic materials 0.000 description 18
- 239000010408 film Substances 0.000 description 10
- 238000009792 diffusion process Methods 0.000 description 9
- 230000007423 decrease Effects 0.000 description 7
- 239000011241 protective layer Substances 0.000 description 7
- 238000005229 chemical vapour deposition Methods 0.000 description 5
- 230000007547 defect Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000005669 field effect Effects 0.000 description 4
- 238000001004 secondary ion mass spectrometry Methods 0.000 description 4
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical group [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010894 electron beam technology Methods 0.000 description 3
- 229910052733 gallium Inorganic materials 0.000 description 3
- 229910052738 indium Inorganic materials 0.000 description 3
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 239000002019 doping agent Substances 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000001451 molecular beam epitaxy Methods 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 229910052716 thallium Inorganic materials 0.000 description 2
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 2
- 230000005533 two-dimensional electron gas Effects 0.000 description 2
- 238000001771 vacuum deposition Methods 0.000 description 2
- 229910000980 Aluminium gallium arsenide Inorganic materials 0.000 description 1
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 1
- LULLIKNODDLMDQ-UHFFFAOYSA-N arsenic(3+) Chemical compound [As+3] LULLIKNODDLMDQ-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000002109 crystal growth method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910052594 sapphire Inorganic materials 0.000 description 1
- 239000010980 sapphire Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/778—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface
- H01L29/7786—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with direct single heterostructure, i.e. with wide bandgap layer formed on top of active layer, e.g. direct single heterostructure MIS-like HEMT
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- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- Ceramic Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Junction Field-Effect Transistors (AREA)
Description
図1は、本発明に密接に関連する参考例によるIII族窒化物半導体HFETを模式的断面図で示している。このHFET素子には、高抵抗Si基板102上に順次積層されたバッファ層103、厚さ1μmのi型GaNチャネル層104、および厚さ30nmのアンドープAlGaNバリア層105を含むエピタキシャルウェハが利用された。AlGaNバリア層105中のIII族元素におけるAl組成比は、25%に設定された。AlGaNバリア層105の表面上には、ソース電極106、ゲート電極107、ドレイン電極108が形成された。ソース電極106とドレイン電極108はHf/Al/Hf/Auの積層構造を有するオーミック電極であり、ゲート電極107はWNをベースとしたショットキー電極である。
図2は、本発明の実施例によるIII族窒化物半導体HFETを模式的断面図で示している。本実施例は、参考例に比べて、SiO2絶縁層109とHfO2水素吸着層110とが一体化された一体化層209として形成されていることのみにおいて異なっている。この一体化層209は200nmの厚さを有し、ソース電極106、ゲート電極107、およびドレイン電極108の各電極上面の少なくとも一部領域に開口が設けられた。
Claims (4)
- 基板と、
前記基板の上方に設けられたチャネル層と、
前記チャネル層上にヘテロ界面を形成するように設けられたバリア層と、
前記バリア層上に設けられた複数の電極と、
前記バリア層の上面において前記電極の領域の少なくとも一部を除く全面を覆うように設けられた絶縁層と水素吸着層とが一体化された一体化層を含み、
前記一体化層内へ一体化された前記水素吸着層に含まれる金属元素の濃度は、その一体化層の上面側において高められており、
前記一体化層内へ一体化された前記絶縁層は、Si、Si 3 N 4 、SiO 2 、TiO 2 、ZrO 2 、HfO 2 、MgF 2 、CaF 2 、SrF 2 、BaF 2 、Al 2 O 3 、V 2 O 5 、Nb 2 O 5 、Ta 2 O 5 、AlON、およびZnOからなる群より選択された誘電体を含み、
前記一体化層内へ一体化された前記水素吸着層は、Li、Na、Mg、K、Ca、Sc、Ti、Rb、Sr、Y、Zr、Cs、Ba、La、Hf、Ta、Ce、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Ho、およびErからなる群より選択された金属元素を含み、前記選択された金属元素の酸化物、窒化物、またはフッ化物からなることを特徴とするIII−V族化合物半導体素子。 - 前記チャネル層および前記バリア層はIII−V族化合物半導体からなることを特徴とする請求項1に記載のIII−V族化合物半導体素子。
- 前記チャネル層および前記バリア層はIII族窒化物からなることを特徴とする請求項2に記載のIII−V族化合物半導体素子。
- 前記一体化層内へ一体化された前記水素吸着層に含まれる金属元素は、前記一体化層内へ一体化された前記絶縁層に含まれる金属元素に比べて、小さい水素化物生成熱を有することを特徴とする請求項1から3のいずれかに記載のIII−V族化合物半導体素子。
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009022950A JP4968747B2 (ja) | 2009-02-03 | 2009-02-03 | Iii−v族化合物半導体素子 |
US12/656,481 US8368168B2 (en) | 2009-02-03 | 2010-02-01 | III-V-group compound semiconductor device |
CN201010109010A CN101794814A (zh) | 2009-02-03 | 2010-02-01 | 第ⅲ-ⅴ族化合物半导体器件 |
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JP2009022950A JP4968747B2 (ja) | 2009-02-03 | 2009-02-03 | Iii−v族化合物半導体素子 |
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JP2010182750A JP2010182750A (ja) | 2010-08-19 |
JP4968747B2 true JP4968747B2 (ja) | 2012-07-04 |
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US (1) | US8368168B2 (ja) |
JP (1) | JP4968747B2 (ja) |
CN (1) | CN101794814A (ja) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
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JP5702058B2 (ja) * | 2009-08-28 | 2015-04-15 | 日本碍子株式会社 | 半導体素子用エピタキシャル基板、半導体素子、および、半導体素子用エピタキシャル基板の作製方法 |
JP5308290B2 (ja) * | 2009-09-15 | 2013-10-09 | 日本碍子株式会社 | 半導体素子用エピタキシャル基板、ショットキー接合構造、およびショットキー接合構造の漏れ電流抑制方法 |
US8994073B2 (en) * | 2012-10-04 | 2015-03-31 | Cree, Inc. | Hydrogen mitigation schemes in the passivation of advanced devices |
US9812338B2 (en) | 2013-03-14 | 2017-11-07 | Cree, Inc. | Encapsulation of advanced devices using novel PECVD and ALD schemes |
US9991399B2 (en) | 2012-10-04 | 2018-06-05 | Cree, Inc. | Passivation structure for semiconductor devices |
US9029914B2 (en) * | 2012-11-26 | 2015-05-12 | Triquint Semiconductor, Inc. | Group III-nitride-based transistor with gate dielectric including a fluoride -or chloride- based compound |
US9444001B1 (en) | 2013-06-28 | 2016-09-13 | Hrl Laboratories, Llc | Low cost, high performance barrier-based position sensitive detector arrays |
CN103500763B (zh) * | 2013-10-15 | 2017-03-15 | 苏州晶湛半导体有限公司 | Ⅲ族氮化物半导体器件及其制造方法 |
JP6444789B2 (ja) * | 2015-03-24 | 2018-12-26 | 株式会社東芝 | 半導体装置及びその製造方法 |
JP6567468B2 (ja) * | 2016-06-20 | 2019-08-28 | 株式会社東芝 | 半導体装置、電源回路、及び、コンピュータ |
JP6618944B2 (ja) * | 2017-03-10 | 2019-12-11 | 株式会社東芝 | 半導体装置及び電気装置 |
US11011614B2 (en) * | 2018-06-29 | 2021-05-18 | Taiwan Semiconductor Manufacturing Company, Ltd. | High electron mobility transistor (HEMT) device and method of forming same |
WO2023035104A1 (en) * | 2021-09-07 | 2023-03-16 | Innoscience (Suzhou) Technology Co., Ltd. | Semiconductor device and method for manufacturing the same |
CN116581217B (zh) * | 2023-07-13 | 2023-09-12 | 江西兆驰半导体有限公司 | 发光二极管外延片及其制备方法、发光二极管 |
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US6316793B1 (en) * | 1998-06-12 | 2001-11-13 | Cree, Inc. | Nitride based transistors on semi-insulating silicon carbide substrates |
JP5646798B2 (ja) * | 1999-11-11 | 2014-12-24 | ピーエスフォー ルクスコ エスエイアールエルPS4 Luxco S.a.r.l. | 半導体集積回路装置の製造方法 |
JP4308485B2 (ja) | 2002-07-08 | 2009-08-05 | パナソニック株式会社 | 容量素子の製造方法 |
US7026665B1 (en) * | 2003-09-19 | 2006-04-11 | Rf Micro Devices, Inc. | High voltage GaN-based transistor structure |
JP2005286135A (ja) | 2004-03-30 | 2005-10-13 | Eudyna Devices Inc | 半導体装置および半導体装置の製造方法 |
JP2006222389A (ja) * | 2005-02-14 | 2006-08-24 | Toshiba Corp | 半導体記憶装置及びその製造方法 |
JP2007096178A (ja) * | 2005-09-30 | 2007-04-12 | Toshiba Corp | 半導体装置およびその製造方法 |
WO2008151138A1 (en) * | 2007-06-01 | 2008-12-11 | The Regents Of The University Of California | P-gan/algan/aln/gan enhancement-mode field effect transistor |
JP2008305993A (ja) * | 2007-06-07 | 2008-12-18 | Nec Electronics Corp | 半導体装置及びその製造方法 |
US7985986B2 (en) * | 2008-07-31 | 2011-07-26 | Cree, Inc. | Normally-off semiconductor devices |
JP2010040842A (ja) * | 2008-08-06 | 2010-02-18 | Nec Electronics Corp | 半導体レーザ |
US20100270591A1 (en) * | 2009-04-27 | 2010-10-28 | University Of Seoul Industry Cooperation Foundation | High-electron mobility transistor |
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2009
- 2009-02-03 JP JP2009022950A patent/JP4968747B2/ja active Active
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2010
- 2010-02-01 CN CN201010109010A patent/CN101794814A/zh active Pending
- 2010-02-01 US US12/656,481 patent/US8368168B2/en active Active
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US20100193839A1 (en) | 2010-08-05 |
CN101794814A (zh) | 2010-08-04 |
JP2010182750A (ja) | 2010-08-19 |
US8368168B2 (en) | 2013-02-05 |
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