JP4731242B2 - Cosmetics suitable for base cosmetics having a pore correcting action - Google Patents
Cosmetics suitable for base cosmetics having a pore correcting action Download PDFInfo
- Publication number
- JP4731242B2 JP4731242B2 JP2005225089A JP2005225089A JP4731242B2 JP 4731242 B2 JP4731242 B2 JP 4731242B2 JP 2005225089 A JP2005225089 A JP 2005225089A JP 2005225089 A JP2005225089 A JP 2005225089A JP 4731242 B2 JP4731242 B2 JP 4731242B2
- Authority
- JP
- Japan
- Prior art keywords
- mass
- powder
- cosmetic
- cosmetics
- pores
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
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- 229940046009 vitamin E Drugs 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 229940046008 vitamin d Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000007680 β-tocopherol Nutrition 0.000 description 1
- 239000011590 β-tocopherol Substances 0.000 description 1
- 239000002478 γ-tocopherol Substances 0.000 description 1
- QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
本発明は、化粧料に関し、更に詳細には、毛穴補正用の下地化粧料に好適な化粧料に関する。
The present invention relates to cosmetics and more particularly to a suitable cosmetic foundation cosmetics pores complement Tadashiyo.
毛穴の存在は、顔の印象形成に於いて、大きな影響を与えるが、該影響は決して好ましいものとは言えない。「肌理の細やかな肌」、「もち肌」等の皮膚の喩えがプラスのものであるのに対し、「毛穴が目立つ」「夏みかん」等の例えは大きなマイナスイメージとなっていることがその証拠と言える。諸原材料の開発などの技術の進歩により、美白化粧料や保湿化粧料が充実してきた今、「毛穴」を目立たなくさせる技術の開発が、香粧品科学の分野では新たなテーマとなりつつある。 The presence of pores has a great influence on the formation of facial impressions, but this influence is not favorable. Evidence that skin metaphors such as “fine skin” and “moist skin” are positive, whereas illustrations such as “conspicuous pores” and “summer oranges” have a large negative image It can be said. With the advancement of technologies such as the development of various raw materials, whitening cosmetics and moisturizing cosmetics have been enriched. The development of technology that makes “pores” inconspicuous is becoming a new theme in the field of cosmetic science.
この様な、化粧料による毛穴に関する対応には2つの方向が存する。即ち、毛穴の形状を有効成分の投与によって縮小させる方向(例えば、特許文献1、特許文献2、特許文献3を参照)と、粉体などの光学的な効果を利用して、毛穴の存在を目立たなくさせる方法(例えば、特許文献4、特許文献5、特許文献6)である。この内、前者については、皮膚の表面形状そのものを大きく変えることを必要とするため、ある程度の効果を奏するものはあっても、満足が行くほど大きな効果を奏するものは存在していないのが現状である。又、後者に於いては、ある程度のメークテクニックがあれば、化粧直後はそこそこの効果を奏しても、経時的に効果を失する場合が少なくないし、メークテクニックのレベルによっては当初の効果さえもおぼつかない欠点が存した。又、更に、毛穴の充填物そのものが目立つと、毛穴の補正効果は損なわれるため、毛穴の充填物と皮膚との見た目の差を減じせしめる工夫も望まれていた。勿論、この様な光学効果に於いて、二酸化チタンや酸化亜鉛などの高隠蔽性粉体の隠蔽力に依存して毛穴に充填されている粉体と、皮膚との境界をカバーすることは、自然な見え方で毛穴を補正するという、本願の発明の主旨とは矛盾するものであり、好ましい対応とは言えない。 There are two directions for dealing with pores by cosmetics. That is, the presence of pores can be determined by utilizing the direction in which the pore shape is reduced by administration of an active ingredient (see, for example, Patent Document 1, Patent Document 2, and Patent Document 3) and optical effects such as powder. It is a method of making it inconspicuous (for example, Patent Document 4, Patent Document 5, Patent Document 6). Of these, the former requires that the surface shape of the skin itself be significantly changed, so there are currently some that have some effect, but none that have a satisfactory effect. It is. In the latter case, if there is a certain amount of make-up technique, even if it produces a decent effect immediately after makeup, there is little chance of losing the effect over time. There was a flaw that didn't make sense. Further, if the pore filling itself is conspicuous, the correction effect of the pores is impaired, and therefore, a device for reducing the difference in appearance between the pore filling and the skin has been desired. Of course, in such an optical effect, depending on the hiding power of highly hiding powder such as titanium dioxide and zinc oxide, covering the boundary between the powder filled in the pores and the skin, This is inconsistent with the gist of the present invention of correcting pores in a natural way and cannot be said to be preferable.
一方、粒径3〜20μmの球状粉体が、簡便性という面で、毛穴の充填に著しい効果を有することも、毛穴を充填すべき該粒径3〜20μmの球状粉体を含有する毛穴補正用の化粧料も全く知られていなかった。 On the other hand, the spherical powder having a particle size of 3 to 20 μm has a remarkable effect on filling pores in terms of simplicity, and the pore correction containing the spherical powder having a particle size of 3 to 20 μm to be filled with pores. No cosmetics for use were known.
他方、繊維状の二酸化チタンは既に開発され、その一部は化粧料原料として市販されている(例えば、特許文献7、特許文献8、特許文献9、特許文献10を参照)。しかしながら、このものが毛穴を充填すべき、粒径3〜20μmの球状粉体の毛穴充填作用を損なうことなく、かかる充填物と皮膚との境界とを目立たなくさせる作用が存することは全く知られていなかった。又、1)粒径3〜20μmの球状粉体0.005〜10質量%と、2)管状の繊維状二酸化チタン0.005〜10質量%とを含有する化粧料も全く知られていなかった。
On the other hand, fibrous titanium dioxide has already been developed, and a part thereof is commercially available as a cosmetic raw material (see, for example, Patent Document 7, Patent Document 8, Patent Document 9, and Patent Document 10). However, it is quite known that this has an effect of making the boundary between the filler and the skin inconspicuous without impairing the pore filling effect of the spherical powder having a particle diameter of 3 to 20 μm to fill the pores. It wasn't. Further, no cosmetics containing 1) 0.005 to 10% by mass of spherical powder having a particle size of 3 to 20 μm and 2) 0.005 to 10% by mass of tubular fibrous titanium dioxide have been known. .
本発明は、この様な状況下為されたものであり、毛穴の存在を自然な仕上がりで目立たなく見せる技術を提供することを課題とする。 The present invention has been made under such circumstances, and an object of the present invention is to provide a technique for making the presence of pores inconspicuous with a natural finish.
この様な状況に鑑みて、本発明者らは、毛穴の存在を自然な仕上がりで目立たなく見せる技術を求めて、鋭意研究努力を重ねた結果、1)粒径3〜20μmの球状粉体0.005〜10質量%と、2)管状の繊維状二酸化チタン0.005〜10質量%とを含有する化粧料がその様な特性を備えていることを見出し、発明を完成させるに至った。即ち、本発明は以下に示すとおりである。
(1)1)粒径3〜20μmの球状粉体0.005〜10質量%と、2)管状の繊維状二酸化チタン0.005〜10質量%とを含有することを特徴とする、化粧料。
(2)前記球状粉体が、少なくとも表面に多孔質層を有さない無水珪酸、架橋構造を有していても良いメチルポリシロキサン樹脂又はメチルフェニルポリシロキサン樹脂から選択されることを特徴とする、(1)に記載の化粧料。
(3)毛穴補正用の下地化粧料であることを特徴とする、(1)又は(2)に記載の化粧料。
(4)乳化剤形であることを特徴とする、(1)〜(3)何れかに記載の化粧料。
In view of such a situation, the present inventors have sought for a technique for making the presence of pores inconspicuous with a natural finish, and as a result of intensive research efforts, 1) a spherical powder having a particle size of 3 to 20 μm. The present inventors have found that a cosmetic containing 0.005 to 10% by mass and 2) 0.005 to 10% by mass of tubular fibrous titanium dioxide has such characteristics, and has completed the invention. That is, the present invention is as follows.
(1) Cosmetics characterized by containing 1) 0.005 to 10% by mass of spherical powder having a particle size of 3 to 20 μm and 2) 0.005 to 10% by mass of tubular fibrous titanium dioxide. .
(2) The spherical powder is selected from silicic anhydride having no porous layer on the surface, methylpolysiloxane resin or methylphenylpolysiloxane resin which may have a crosslinked structure, Cosmetics as described in (1).
(3 ) The cosmetic according to (1) or (2) , which is a base cosmetic for correcting pores.
(4 ) The cosmetic according to any one of (1) to ( 3 ) , wherein the cosmetic is in an emulsifier form.
本発明によれば、毛穴の存在を自然な仕上がりで目立たなく見せる技術を提供することができる。 According to the present invention, it is possible to provide a technique for making the presence of pores inconspicuous with a natural finish.
(1)本発明の化粧料の必須成分である球状粉体
本発明の化粧料は、粒径3〜20μm、より好ましくは4〜15μmの球状粉体を含有することを特徴とする。かかる球状粉体の素材としては、化粧料で使用されているものであれば特段の限定無く、例えば、シリカ、シリコーン、珪酸カルシウム、珪酸マグネシウム、炭酸カルシウム、炭酸マグネシウム、アクリル樹脂、ポリエチレン樹脂、ナイロン樹脂、シルクパウダー、硫酸バリウム、アルミナ等が好適に例示できる。これらはハイドロジェンメチルポリシロキサンの焼き付け、金属石鹸の被覆、アシル化アミノ酸塩の被覆等の表面処理が為されていても良い。これらの中でより好ましいものは、珪素−酸素結合における、酸素を置換する置換基として炭素数1〜4のアルキル基乃至はフェニル基を有していても良い、無水珪酸であり、この様なものとしては、具体的には、ガラス状或いは多孔質状のシリカ、メチルシロキサン網状重合体等のアルキルシロキサン網状重合体、高重合度のメチルポリシロキサン、メチルフェニルポリシロキサン、メチルポリシロキサン乃至はメチルフェニルポリシロキサンの部分架橋物などが例示でき、中でも、少なくとも表面に多孔質層を有さない無水珪酸、架橋構造を有していても良いメチルポリシロキサン樹脂又はメチルフェニルポリシロキサン樹脂であることが好ましい。この様な球状粉体は、既に市販されているもので、前記の粒度分布のものを使用することも出来るし、市販の粉
体を分級処理して、粒度を合わせ、使用することも出来る。分級前の市販の粉体としては、TORAY株式会社より販売されている「トレフィル」(高重合度メチルポリシロキサン)、東芝シリコーン株式会社から販売されている「トスパール」(メチルポリシロキサン網状重合体)等例示でき、既に分級されている市販の粉体としては、信越シリコーン株式会社から販売されている「シリコーンKSP300」((ジフェニルジメチコン/ビニルジフェニルジメチコン/シルセスキオキサン)クロスポリマー)、触媒化成工業株式会社から販売されている「HOLLOWY−N15」(表面に多孔質層を有さず、空気粒を内包したシリカ)等が特に好適に例示できる。中でも「シリコーンKSP300」と「HOLLOWY−N15」が特に好ましい。これらの粉体は、皮脂と混合しても光学効果の変化が極めて少ない。これらの球状粉体は唯一種を含有することも出来るし、二種以上を組み合わせて含有させることも出来る。かかる粉体の好ましい含有量は、顔の大きさや毛穴の状況によって異なるが、0.005〜10質量%であり、より好ましくは0.01〜1質量%である。これは、多すぎても、毛穴を充填しない球状粉体が存するようになり、化粧効果を損なう場合が存し、少なすぎると、毛穴を充填しきれず、毛穴を目立たなくさせる効果が損なわれる場合が存するためである。
(1) Spherical powder which is an essential component of the cosmetic of the present invention The cosmetic of the present invention is characterized by containing a spherical powder having a particle size of 3 to 20 μm, more preferably 4 to 15 μm. The material of the spherical powder is not particularly limited as long as it is used in cosmetics. For example, silica, silicone, calcium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, acrylic resin, polyethylene resin, nylon Resins, silk powder, barium sulfate, alumina and the like can be suitably exemplified. These may be subjected to surface treatment such as baking with hydrogen methylpolysiloxane, coating with metal soap, coating with acylated amino acid salt, or the like. Among these, more preferred is silicic anhydride, which may have an alkyl group having 1 to 4 carbon atoms or a phenyl group as a substituent for substituting oxygen in the silicon-oxygen bond. Specific examples include glassy or porous silica, alkylsiloxane network polymers such as methylsiloxane network polymers, methylpolysiloxanes with high polymerization degree, methylphenylpolysiloxanes, methylpolysiloxanes or methylpolysiloxanes. such as partially crosslinked products of phenyl polysiloxane can be exemplified, among others, it is at least silicic anhydride having no porous layer on the surface, it may have a cross-linking structure methylpolysiloxane resin or methylphenyl polysiloxane resin It is not preferred. Spherical powder such as this is, those that are already commercially available, also to be able to use a particle size distribution of the, by classification treatment a commercial powder, combined particle size, may be used . Commercially available powders before classification include "Trefill" (highly polymerized methylpolysiloxane) sold by TORAY, Inc. and "Tospearl" (methylpolysiloxane network polymer) sold by Toshiba Silicone, Inc. etc. can be exemplified, as commercially available powder that has already been classified, that is available from Shin-Etsu silicone Co., Ltd. "silicone KSP300" ((diphenyl dimethicone / vinyl diphenyl dimethicone / silsesquioxane) crosspolymer), manufactured by catalysts & “HOLLOWY-N15” (silica having no porous layer on the surface and enclosing air particles) and the like sold by a corporation can be particularly preferably exemplified. Among these, “silicone KSP300” and “HOLLOWY-N15” are particularly preferable. These powders have very little change in optical effect even when mixed with sebum. These spherical powders may contain only one species or may contain two or more species in combination. The preferable content of such powder varies depending on the size of the face and the condition of the pores, but is 0.005 to 10% by mass, more preferably 0.01 to 1% by mass. If there is too much, there will be a spherical powder that does not fill the pores, which may impair the makeup effect, if too little, the pores can not be filled and the effect of making the pores inconspicuous is impaired This is because there exists.
(2)本発明の化粧料の必須成分である管状の繊維状二酸化チタン
本発明の化粧料は、管状の繊維状二酸化チタンを0.005〜10質量%、好ましくは0.01〜5質量%含有することを特徴とする。かかる管状の繊維状二酸化チタンとは、円筒状の空隙を中心部付近に有するものである。かかる管状の繊維状二酸化チタンは、短径が0.1〜10μmに対し、長径が1〜500μmの形状を有することが好ましい。この様な管状の繊維状二酸化チタンには、市販されているものが存し、この様な市販品を購入して使用することも出来る。好ましい市販品としては、「中空酸化チタンファイバー」(触媒化成工業株式会社製)等が例示できる。
(2) The cosmetic cosmetic essential component is tubular fibrous titanium dioxide present invention of the present invention, the fiber-like titanium dioxide tubular 0.005 wt%, preferably from 0.01 to 5 It is characterized by containing mass%. The fibrous titanium dioxide of such tubular, is to also have a circular cylindrical gap around the central portion. Fibrous titanium dioxide of such tubular minor axis to 0.1 to 10 [mu] m, major axis preferably has a shape of 1 to 500 [mu] m. The fibrous titanium dioxide of such a tubular, resides those that are commercially available, can also be used to purchase such a commercially available product. As a preferable commercial product, “ hollow titanium oxide fiber” (manufactured by Catalyst Kasei Kogyo Co., Ltd.) and the like can be exemplified .
本発明の化粧料に於いて、前記管状の繊維状二酸化チタンは、唯一種を含有することも出来るし、二種以上を組み合わせて含有することも出来る。本発明の化粧料に於いて、かかる成分は、前記の含有量の範囲に於いて、自然なカバー力で前記球状粉体の毛穴の充填状況を目立ちにくくさせる作用を有する。加えて、かかる成分自体は毛穴に充填されないので、前記球状粉体の毛穴への充填を阻害しないし、どちらかというと、選択的に前記球状粉体が毛穴に充填するように促進する作用を有する。この為、かかる管状の繊維状二酸化チタンを含有せしめることにより、球状粉体の毛穴への充填を速やかに行える副次的効果も奏する。
In the cosmetic of the present invention, the fibrous titanium dioxide of said tubular also to be able to contain only species, may also contain a combination of two or more. In the cosmetic of the present invention, such a component has an effect of making the filling state of the pores of the spherical powder less noticeable with a natural covering force within the range of the content. In addition, since such a component itself is not filled into the pores, it does not hinder the filling of the spherical powder into the pores, or rather, it has an effect of promoting the selective filling of the spherical powder into the pores. Have. For this reason, by including such tubular fibrous titanium dioxide, there is also a secondary effect that can quickly fill the pores of the spherical powder.
(3)本発明の化粧料
本発明の化粧料は、前記必須成分を含有し、好ましくは、乳化剤形であることを特徴とする。勿論、固形白粉のような形態でも、皮膚に近い位置に投与されるものであれば本発明の効果を損なうことなく実用化できる。この様な製剤例としては、パウダーコントロールカラーなどが好ましく例示できる。又、パウダーファンデーションやツーウェイケーキであっても構わない。乳化の剤形は油中水乳化であっても、水中油乳化であっても、油中水中油乳化や水中油中水乳化等の多相乳化剤形であっても構わない。好ましい乳化形態は、粉体を含むことから、界面の複雑にならない水中油乳化剤形乃至は油中水乳化剤形である。これらの内、アンダーメークアップでは、毛穴に充填された状態の化粧持ちを維持させることから、油中水乳化剤形であることが好ましい。これらの乳化剤形では、乳化剤として、少なくとも1種のポリエーテル変性メチルポリシロキサンを含有することが好ましい。このものは部分的な架橋構造を有していても良い。かかる成分は唯一種を含有することも出来るし、二種以上を組み合わせて含有することも出来る。この様なポリエーテル変性メチルポリシロキサンとしては、市販品であれば、信越シリコーン株式会社製の「シリコーンKSG210」、「シリコーンKF6017」などが特に好適に例示できる。これは前記必須成分の粉体との相性による。かかるポリエーテル変性メチルシロキサンの好ましい含有量は1〜10質量%であり、より好ましくは2〜5質量%である。
(3) Cosmetics of this invention The cosmetics of this invention contain the said essential component, Preferably, it is an emulsifier form, It is characterized by the above-mentioned. Of course, even in the form of solid white powder, it can be put into practical use without impairing the effects of the present invention as long as it is administered at a position close to the skin. Preferred examples of such preparations include powder control colors. It may be a powder foundation or a two-way cake. The emulsified dosage form may be water-in-oil emulsification, oil-in-water emulsification, or multiphase emulsifier form such as oil-in-oil oil-in-water emulsification or water-in-oil-in-water emulsification. A preferred emulsified form is an oil-in-water emulsifier form or a water-in-oil emulsifier form that does not complicate the interface because it contains powder. Among these, the under-makeup is preferably in the form of a water-in-oil emulsifier because the makeup of the state filled in the pores is maintained. In these emulsifier forms, it is preferable to contain at least one polyether-modified methyl polysiloxane as an emulsifier. This may have a partial cross-linked structure. Such a component can contain only one species or a combination of two or more species. As such a polyether-modified methylpolysiloxane, “silicone KSG210” and “silicone KF6017” manufactured by Shin-Etsu Silicone Co., Ltd. can be particularly preferably exemplified as commercial products. This is due to the compatibility with the powder of the essential component. The preferable content of such polyether-modified methylsiloxane is 1 to 10% by mass, more preferably 2 to 5% by mass.
本発明の化粧料に於いては、前記必須成分の粉体以外に、必須成分に分類されない粉体成分を含有することも出来る。この様な粉体としては、表面を処理されていても良い、マイカ、タルク、カオリン、合成雲母等の体質粉体類、;表面を処理されていても良い、雲母チタン、魚燐箔、オキシ塩化ビスマス等のパール剤類;雲母チタンの内、被覆二酸化チタン量をコントロールして被覆し、干渉色を出させた虹彩箔、粒度を0.1〜2μmに揃えた微粒子二酸化チタン、金属塩を配位させたピラードクレー、4級アンモニウム塩などで有機変性した粘土鉱物等の特殊加工粉体類、;タルクを二酸化チタン、シリカアルミナで順次被覆した粉体のような複合粉体等が好適に例示できる。特に好ましいものは、粒度が異なるなど、本発明の化粧料の必須成分に属さない球状粉体と特殊加工粉体と複合粉体であり、本発明の化粧料に於いては、球状粉体と管状の繊維状二酸化チタンと特殊加工粉体と複合粉体のみで粉体が構成されていることが特に好ましい。 In the cosmetic of the present invention, in addition to the essential component powder, a powder component not classified as an essential component may be contained. Such powders may be treated on the surface, such as mica, talc, kaolin, synthetic mica, etc .; may be treated on the surface, mica titanium, fish phosphorus foil, oxy Pearl agents such as bismuth chloride; of mica titanium, coated with controlled amount of titanium dioxide, iris foil with interference color, fine particle titanium dioxide with a uniform particle size of 0.1-2μm, metal salt Preferred examples include specially processed powders such as coordinated pillared clay, clay minerals organically modified with quaternary ammonium salts, etc .; composite powders such as powders in which talc is sequentially coated with titanium dioxide and silica alumina. it can. Particularly preferred are spherical powders, specially processed powders, and composite powders that do not belong to the essential components of the cosmetics of the present invention, such as different particle sizes. In the cosmetics of the present invention, spherical powders and it is particularly preferred that the tubular fibrous titanium dioxide and special processing powder composite powder only in a powder is formed.
これら以外に、メークアップ化粧料であることから、本発明の化粧料は、更に色材を含有することが出来る。この様な色材としては、;表面を処理されていても良い、ベンガラ、黄酸化鉄、黒酸化鉄、酸化コバルト、群青、紺青の無機顔料類、;レーキ化されていても良い赤色202号、赤色228号、赤色226号、黄色4号、青色404号、黄色5号、赤色505号、赤色230号、赤色223号、橙色201号、赤色213号、黄色204号、黄色203号、青色1号、緑色201号、紫色201号、赤色204号等の有機色素類等が例示できる。 In addition to these, since it is a makeup cosmetic, the cosmetic of the present invention can further contain a coloring material. Examples of such coloring materials include: bengara, yellow iron oxide, black iron oxide, cobalt oxide, ultramarine blue, and bituminous inorganic pigments that may be treated on the surface; red No. 202 that may be raked. , Red 228, Red 226, Yellow 4, Blue 404, Yellow 5, Red 505, Red 230, Red 223, Orange 201, Red 213, Yellow 204, Yellow 203, Blue Organic pigments such as No. 1, Green 201, Purple 201, Red 204 and the like can be exemplified.
前記の成分以外に、本発明の化粧料では、通常化粧料で使用される任意の成分を含有することが出来る。この様な任意成分としては、例えば、マカデミアナッツ油、アボガド油、トウモロコシ油、オリーブ油、ナタネ油、ゴマ油、ヒマシ油、サフラワー油、綿実油、ホホバ油、ヤシ油、パーム油、液状ラノリン、硬化ヤシ油、硬化油、モクロウ、硬化ヒマシ油、ミツロウ、キャンデリラロウ、カルナウバロウ、イボタロウ、ラノリン、還元ラノリン、硬質ラノリン、ホホバロウ等のオイル、ワックス類;流動パラフィン、スクワラン、プリスタン、オゾケライト、パラフィン、セレシン、ワセリン、マイクロクリスタリンワックス等の炭化水素類;オレイン酸、イソステアリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、ウンデシレン酸等の高級脂肪酸類;セチルアルコール、ステアリルアルコール、イソステアリルアルコール、ベヘニルアルコール、オクチルドデカノール、ミリスチルアルコール、セトステアリルアルコール等の高級アルコール等;イソオクタン酸セチル、ミリスチン酸イソプロピル、イソステアリン酸ヘキシルデシル、アジピン酸ジイソプロピル、セバチン酸ジ−2−エチルヘキシル、乳酸セチル、リンゴ酸ジイソステアリル、ジ−2−エチルヘキサン酸エチレングリコール、ジカプリン酸ネオペンチルグリコール、ジ−2−ヘプチルウンデカン酸グリセリン、トリ−2−エチルヘキサン酸グリセリン、トリ−2−エチルヘキサン酸トリメチロールプロパン、トリイソステアリン酸トリメチロールプロパン、テトラ−2−エチルヘキサン酸ペンタンエリトリット等の合成エステル油類;ジメチルポリシロキサン、メチルフェニルポリシロキサン、ジフェニルポリシロキサン等の鎖状ポリシロキサン;オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサンシロキサン等の環状ポリシロキサン;アミノ変性ポリシロキサン、アルキル変性ポリシロキサン、フッ素変性ポリシロキサン等の変性ポリシロキサン等のシリコーン油等の油剤類;脂肪酸セッケン(ラウリン酸ナトリウム、パルミチン酸ナトリウム等)、ラウリル硫酸カリウム、アルキル硫酸トリエタノールアミンエーテル等のアニオン界面活性剤類;塩化ステアリルトリメチルアンモニウム、塩化ベンザルコニウム、ラウリルアミンオキサイド等のカチオン界面活性剤類;イミダゾリン系両性界面活性剤(2−ココイル−2−イミダゾリニウムヒドロキサイド−1−カルボキシエチロキシ2ナトリウム塩等)、ベタイン系界面活性剤(アルキルベタイン、アミドベタイン、スルホベタイン等)、アシルメチルタウリン等の両性界面活性剤類;ソルビタン脂肪酸エステル類(ソルビタンモノステアレート、セスキオレイン酸ソルビタン等)、グリセリン脂肪酸類(モノステアリン酸グリセリン等)、プロピレングリコール脂肪酸エステル類(モノステアリン酸プロピレングリコール等)、硬化ヒマシ油誘導体、グリセリンアルキルエーテル、POEソルビタン脂肪酸エステル類(POEソルビタンモノオレエート、モノステアリン酸ポリオキエチレンソルビタン等)、POEソルビット脂肪酸エステル類(POE−ソルビットモノラウレート等)、POEグリセリン脂肪酸エステル類(POE−グリセリンモノイソステアレート等)、POE脂肪酸エステル類(ポリエチレングリコールモノオレート、POEジステアレート等)、POEアルキルエーテル類(POE2−オクチルドデシルエーテル等)、POEアルキルフェニルエーテル類(POEノニルフェニルエーテル等)、プルロニック型類、POE・POPアルキルエーテル類(POE・POP2−デシルテトラデシルエーテル等)、テトロニック類、POEヒマシ油・硬化ヒマシ油誘導体(POEヒマシ油、POE硬化ヒマシ油等)、ショ糖脂肪酸エステル、アルキルグルコシド等の非イオン界面活性剤類;ポリエチレングリコール、グリセリン、1,3−ブチレングリコール、エリスリトール、ソルビトール、キシリトール、マルチトール、プロピレングリコール、ジプロピレングリコール、ジグリセリン、イソプレングリコール、1,2−ペンタンジオール、2,4−ヘキサンジオール、1,2−ヘキサンジオール、1,2−オクタンジオール等の多価アルコール類;ピロリドンカルボン酸ナトリウム、乳酸、乳酸ナトリウム等の保湿成分類;パラアミノ安息香酸系紫外線吸収剤;アントラニル酸系紫外線吸収剤;サリチル酸系紫外線吸収剤、;桂皮酸系紫外線吸収剤、;ベンゾフェノン系紫外線吸収剤;糖系紫外線吸収剤;2−(2’−ヒドロキシ−5’−t−オクチルフェニル)ベンゾトリアゾール、4−メトキシ−4’−t−ブチルジベンゾイルメタン等の紫外線吸収剤類;エタノール、イソプロパノール等の低級アルコール類;ビタミンA又はその誘導体、ビタミンB6塩酸塩、ビタミンB6トリパルミテート、ビタミンB6ジオクタノエート、ビタミンB2又はその誘導体、ビタミンB12、ビタミンB15又はその誘導体等のビタミンB類;α−トコフェロール、β−トコフェロール、γ−トコフェロール、ビタミンEアセテート等のビタミンE類、ビタミンD類、ビタミンH、パントテン酸、パンテチン、ピロロキノリンキノン等のビタミン類等;フェノキシエタノール等の抗菌剤などが好ましく例示できる。ここで、夏の紫外線などで損傷した皮膚に投与する蓋然性が高いことから、一過性の刺激を発現させる蓋然性の高いブチルパラベンは含有しないことが好ましく、この状況で防腐力を維持する目的から、フェノキシエタノールを0.01〜1質量%、より好ましくは0.3〜0.6質量%含有することが好ましい。 In addition to the above components, the cosmetic of the present invention can contain any component that is usually used in cosmetics. Examples of such optional ingredients include macadamia nut oil, avocado oil, corn oil, olive oil, rapeseed oil, sesame oil, castor oil, safflower oil, cottonseed oil, jojoba oil, coconut oil, palm oil, liquid lanolin, and hardened coconut oil. Oil, wax, oils such as beeswax, molasses, hydrogenated castor oil, beeswax, candelilla wax, carnauba wax, ibotarou, lanolin, reduced lanolin, hard lanolin, jojoba wax; , Hydrocarbons such as microcrystalline wax; higher fatty acids such as oleic acid, isostearic acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, undecylenic acid; cetyl alcohol, stearyl alcohol, isostearyl Higher alcohols such as alcohol, behenyl alcohol, octyldodecanol, myristyl alcohol, cetostearyl alcohol; cetyl isooctanoate, isopropyl myristate, hexyldecyl isostearate, diisopropyl adipate, di-2-ethylhexyl sebacate, cetyl lactate, malic acid Diisostearyl, di-2-ethylhexanoic acid ethylene glycol, dicaprate neopentyl glycol, di-2-heptylundecanoic acid glycerin, tri-2-ethylhexanoic acid glycerin, tri-2-ethylhexanoic acid trimethylolpropane, tri Synthetic ester oils such as trimethylolpropane isostearate and pentane erythritol tetra-2-ethylhexanoate; dimethylpolysiloxane, methylphenylpoly Chain polysiloxanes such as Loxane and diphenylpolysiloxane; Cyclic polysiloxanes such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and dodecamethylcyclohexanesiloxane; amino-modified polysiloxanes, alkyl-modified polysiloxanes, fluorine-modified polysiloxanes, etc. Oils such as silicone oils such as modified polysiloxanes; Anionic surfactants such as fatty acid soap (sodium laurate, sodium palmitate, etc.), potassium lauryl sulfate, trisulfamine amine alkyl sulfate; stearyltrimethylammonium chloride, benzaza chloride Cationic surfactants such as luconium and laurylamine oxide; imidazoline-based amphoteric surfactants (2-cocoyl-2-imidazolinium hydroxide-1-carb Ruboxyethyloxy disodium salt), betaine surfactants (alkyl betaine, amide betaine, sulfobetaine, etc.), amphoteric surfactants such as acylmethyl taurine; sorbitan fatty acid esters (sorbitan monostearate, sesquiolein) Sorbitan acid), glycerin fatty acids (glyceryl monostearate, etc.), propylene glycol fatty acid esters (propylene glycol monostearate, etc.), hardened castor oil derivatives, glycerin alkyl ethers, POE sorbitan fatty acid esters (POE sorbitan monooleate) , Monostearic acid polyoxyethylene sorbitan, etc.), POE sorbite fatty acid esters (POE-sorbite monolaurate, etc.), POE glycerin fatty acid esters (POE-glycerin mono) Sotearate, etc.), POE fatty acid esters (polyethylene glycol monooleate, POE distearate, etc.), POE alkyl ethers (POE2-octyldodecyl ether, etc.), POE alkyl phenyl ethers (POE nonyl phenyl ether, etc.), Pluronic types, POE -POP alkyl ethers (POE / POP2-decyltetradecyl ether, etc.), Tetronics, POE castor oil / hardened castor oil derivatives (POE castor oil, POE hardened castor oil, etc.), sucrose fatty acid esters, alkyl glucosides, etc. Nonionic surfactants: polyethylene glycol, glycerin, 1,3-butylene glycol, erythritol, sorbitol, xylitol, maltitol, propylene glycol, dipropylene glycol , Diglycerin, isoprene glycol, 1,2-pentanediol, 2,4-hexanediol, 1,2-hexanediol, 1,2-octanediol and other polyhydric alcohols; sodium pyrrolidonecarboxylate, lactic acid, sodium lactate Moisturizing ingredients such as: paraaminobenzoic acid UV absorbers; anthranilic acid UV absorbers; salicylic acid UV absorbers; cinnamic acid UV absorbers; benzophenone UV absorbers; sugar UV absorbers; UV absorbers such as (2′-hydroxy-5′-t-octylphenyl) benzotriazole and 4-methoxy-4′-t-butyldibenzoylmethane; lower alcohols such as ethanol and isopropanol; vitamin A or its Derivatives, vitamin B6 hydrochloride, vitamin B6 tripalmitate, vitamin B Vitamin B such as 6 dioctanoate, vitamin B2 or derivatives thereof, vitamin B12, vitamin B15 or derivatives thereof; vitamin E such as α-tocopherol, β-tocopherol, γ-tocopherol, vitamin E acetate, vitamin D, vitamin H Preferred examples include vitamins such as pantothenic acid, panthetin and pyrroloquinoline quinone; and antibacterial agents such as phenoxyethanol. Here, since it has a high probability of being administered to skin damaged by ultraviolet rays in summer, it is preferable not to contain butylparaben having a high probability of causing a transient irritation, and for the purpose of maintaining antiseptic power in this situation It is preferable to contain 0.01 to 1% by mass, more preferably 0.3 to 0.6% by mass of phenoxyethanol.
本発明の化粧料は、前記の必須成分や任意成分を常法に従って処理することにより製造することが出来る。本発明の化粧料としては、毛穴に必須成分の粉体を充填し、毛穴を目立たなくさせるための化粧料に適用することが好ましく、その為には、毛穴に対し、他の化粧料の影響を受けずに投与できる類の化粧料であることが好ましく、アンダーメークアップ化粧料やコントロールカラー化粧料などの下地化粧料に適用することが特に好ましい。 The cosmetic of the present invention can be produced by treating the essential components and optional components according to a conventional method. The cosmetic of the present invention is preferably applied to a cosmetic for filling pores with essential powders and making the pores inconspicuous. For this purpose, the effects of other cosmetics on the pores are preferred. It is preferable that it is a type of cosmetic that can be administered without receiving, and it is particularly preferable to apply it to base cosmetics such as under-makeup cosmetics and control color cosmetics.
以下に、本発明について、実施例を挙げて、更に詳細に説明を加えるが、本発明がかかる実施例にのみ限定されないことは言うまでもない。 Hereinafter, the present invention will be described in more detail with reference to examples, but it goes without saying that the present invention is not limited to such examples.
以下に示す処方に従って、本発明の化粧料であるアンダーメークアップ(油中水乳化剤形)を作成した。即ち、イ、ロ、ハの成分を80℃に加熱し、イの成分にニの成分を分散させ、これにロの成分を加え混練りし、これに徐々にハの成分を攪拌下加えて乳化し、攪拌冷却しアンダーメークアップ1を得た。同時に「HOLLOWY−N15」と「シリコーンKSP300」とを平均粒径40μmの(ジフェニルジメチコン/ビニルジフェニルジメチコン/シルセスキオキサン)クロスポリマーに置換した比較例1、「中空酸化チタンファイバー」を通常の二酸化チタンに置換した比較例2、「HOLLOWY−N15」と「シリコーンKSP300」とを平均粒径40μmの(ジフェニルジメチコン/ビニルジフェニルジメチコン/シルセスキオキサン)クロスポリマーに置換し、且つ、「中空酸化チタンファイバー」を通常の二酸化チタンに置換した比較例3も同様に作成した。 Under makeup (water-in-oil emulsifier form) which is a cosmetic of the present invention was prepared according to the formulation shown below. That is, the components (a), (b) and (c) are heated to 80 ° C., the component (d) is dispersed in the component (a), the component (b) is added and kneaded, and the components (c) are gradually added to the mixture with stirring. The mixture was emulsified, cooled with stirring, and Under Makeup 1 was obtained. At the same time, “HOLLOWY-N15” and “Silicone KSP300” were replaced with (diphenyldimethicone / vinyldiphenyldimethicone / silsesquioxane) crosspolymer having an average particle size of 40 μm. Comparative Example 2 substituted with titanium, “HOLLOWY-N15” and “silicone KSP300” were replaced with (diphenyldimethicone / vinyldiphenyldimethicone / silsesquioxane) crosspolymer having an average particle size of 40 μm, and “hollow titanium oxide” Comparative Example 3 in which “fiber” was replaced with ordinary titanium dioxide was also prepared in the same manner.
イ
「シリコーンKSG210」 3 質量%
「シリコーンKF6017」 3 質量%
ジメチコン 8 質量%
シクロメチコン 13.5質量%
蔗糖ステアリン酸モノエステル 0.5質量%
ロ
1,3−ブタンジオール 10 質量%
フェノキシエタノール 0.5質量%
ハ
水 56.08質量%
硫酸マグネシウム 0.5質量%
ニ
微粒子二酸化チタン(平均粒径1μm) 3 質量%
「オイルセンサーパウダー」 0.1質量%
(亜鉛配位ピラードクレイ;大東化成株式会社製)
「チミロンスプレンディッドレッド」 0.1質量%
(虹彩箔(赤);エンゲルハード社製)
「ベントン38V」 1.5質量%
(ジメチルジステアリルアンモニウムクロリド変性ヘクトライト;エレメンティス社製)
「カバーリーフAR−80」 0.1質量%
(タルクを二酸化チタン、シリカアルミナで順次被覆した粉体;触媒化成工業株式会社製)
シリカ(平均粒径50μm) 0.1質量%
「HOLLOWY−N15」 0.005質量%
「シリコーンKSP300」 0.005質量%
「中空酸化チタンファイバー」 0.01質量%
"Silicone KSG210" 3% by mass
"Silicone KF6017" 3 mass%
Dimethicone 8% by mass
Cyclomethicone 13.5% by mass
Sucrose stearate monoester 0.5% by mass
1,3-butanediol 10% by mass
Phenoxyethanol 0.5% by mass
Ha water 56.08 mass%
Magnesium sulfate 0.5% by mass
Two-particulate titanium dioxide (average particle size 1 μm) 3% by mass
"Oil sensor powder" 0.1% by mass
(Zinc coordination pillared clay; manufactured by Daito Kasei Co., Ltd.)
"Chimiron Splendid Red" 0.1% by mass
(Iris foil (red); made by Engelhard)
"Benton 38V" 1.5% by mass
(Dimethyl distearyl ammonium chloride modified hectorite; manufactured by Elementis)
"Cover leaf AR-80" 0.1% by mass
(Powder in which talc is sequentially coated with titanium dioxide and silica alumina; manufactured by Catalyst Kasei Kogyo Co., Ltd.)
Silica (average particle size 50 μm) 0.1% by mass
“HOLLOWY-N15” 0.005 mass%
“Silicone KSP300” 0.005 mass%
"Hollow titanium oxide fiber" 0.01% by mass
スコア1:非常に毛穴が目立つ
スコア2:毛穴が目立つ
スコア3:毛穴がやや目立つ
スコア4:毛穴が殆ど目立たない
スコア5:毛穴が目立たない
Score 1: very pores conspicuous score 2: pores conspicuous score 3: pores is somewhat conspicuous score 4: pores is hardly noticeable score 5: inconspicuous hair hole
(試験例1)
アンダーメークアップ1と比較例1、比較例2、比較例3とを用いて、毛穴への粉体の充填による、毛穴補正効果を調べた。即ち、毛穴の目立つパネラーを用い、洗顔後に顔の額、両頬、鼻の頭、顎先の5点に化粧料をおき、唯一度の擦過で化粧料を延展して、化粧料を塗布してもらい、化粧の前後における毛穴の周囲の状況をビデオマイクロスコープで撮影し、毛穴の目立ち状況を上記の基準に従って判定した。
(Test Example 1)
Using Under-Makeup 1, Comparative Example 1, Comparative Example 2, and Comparative Example 3, the pore correction effect by filling the pores with powder was examined. In other words, using a panel with conspicuous pores, put the cosmetic on the forehead, both cheeks, the head of the nose, and the tip of the chin after washing the face, apply the cosmetic by spreading the cosmetic with only one rubbing. The situation around the pores before and after makeup was photographed with a video microscope, and the conspicuous state of the pores was judged according to the above criteria.
結果を出現例数として表1に示す。これより、本発明の化粧料を用いることにより、毛穴が極めて目立たなくなっていることが判る。 The results are shown in Table 1 as the number of appearance examples. From this, it can be seen that pores are not very noticeable by using the cosmetic of the present invention.
下記に示す処方に従って、アンダーメークの剤形を水中油剤形に変え、アンダーメークアップ2を作成し、試験例1に従って評価したところ、スコア4であった。このことより、アンダーメークアップに於いては油中水剤形の方が粉体の充填が好ましいことが判る。 According to the prescription shown below, the undermake up dosage form was changed to an oil-in-water form, undermakeup 2 was prepared and evaluated according to Test Example 1. The score was 4. From this, it can be seen that in under-makeup, the water-in-oil dosage form is more preferably filled with powder.
イ
スクワラン 8 質量%
ホホバ油 2 質量%
ジメチコン 5 質量%
ステアリン酸 1.5質量%
グリセリルモノステアレート 2 質量%
セタノール 0.5質量%
ソルビタンジステアレート 0.5質量%
POE(45)ステアリン酸 1 質量%
ロ
1,3−ブタンジオール 10 質量%
フェノキシエタノール 0.5質量%
アルギニン 0.5質量%
水 63.58質量%
ハ
微粒子二酸化チタン(平均粒径0.01μm) 3 質量%
「オイルセンサーパウダー」 0.1質量%
「チミロンスプレンディッドレッド」 0.1質量%
「ベントン38」 1.5質量%
「カバーリーフAR−80」 0.1質量%
シリカ(平均粒径50μm) 0.1質量%
「HOLLOWY−N15」 0.005質量%
「シリコーンKSP300」 0.005質量%
「中空酸化チタンファイバー」 0.01質量%
Isquaran 8% by mass
Jojoba oil 2% by mass
Dimethicone 5% by mass
Stearic acid 1.5% by mass
Glyceryl monostearate 2% by mass
Cetanol 0.5% by mass
Sorbitan distearate 0.5% by mass
POE (45) stearic acid 1% by mass
1,3-butanediol 10% by mass
Phenoxyethanol 0.5% by mass
Arginine 0.5% by mass
63.58% by mass of water
C Fine particle titanium dioxide (average particle size 0.01 μm) 3% by mass
"Oil sensor powder" 0.1% by mass
"Chimiron Splendid Red" 0.1% by mass
"Benton 38" 1.5% by mass
"Cover leaf AR-80" 0.1% by mass
Silica (average particle size 50 μm) 0.1% by mass
“HOLLOWY-N15” 0.005 mass%
“Silicone KSP300” 0.005 mass%
"Hollow titanium oxide fiber" 0.01% by mass
以下に示す処方に従って、本発明の化粧料である、コントロールカラー(水中油乳化剤形)を作成した。即ち、イ、ロの成分を80℃に加熱し、イにハを加え、分散させた後、攪拌下ロを徐々に加え乳化し、攪拌冷却し、コントロールカラー1を得た。試験例1の方法で評価したところスコア5であった。同様の効果が認められた。 A control color (oil-in-water emulsifier form), which is a cosmetic of the present invention, was prepared according to the formulation shown below. That is, components (a) and (b) were heated to 80 ° C., (c) was added to (a) and dispersed, and then (b) was gradually added and emulsified with stirring, followed by stirring and cooling to obtain control collar 1. When evaluated by the method of Test Example 1, the score was 5. Similar effects were observed.
イ
スクワラン 8 質量%
ホホバ油 2 質量%
ジメチコン 5 質量%
ステアリン酸 1.5質量%
グリセリルモノステアレート 2 質量%
セタノール 0.5質量%
ソルビタンジステアレート 0.5質量%
POE(45)ステアリン酸 1 質量%
ロ
1,3−ブタンジオール 10 質量%
フェノキシエタノール 0.5質量%
アルギニン 0.5質量%
水 59.97質量%
ハ
微粒子二酸化チタン(平均粒径0.01μm) 7 質量%
赤色226号 0.03質量%
「オイルセンサーパウダー」 0.1質量%
「チミロンスプレンディッドレッド」 0.1質量%
「カバーリーフAR−80」 0.1質量%
「HOLLOWY−N15」 0.1質量%
「シリコーンKSP300」 0.1質量%
「中空酸化チタンファイバー」 1 質量%
Isquaran 8% by mass
Jojoba oil 2% by mass
Dimethicone 5% by mass
Stearic acid 1.5% by mass
Glyceryl monostearate 2% by mass
Cetanol 0.5% by mass
Sorbitan distearate 0.5% by mass
POE (45) stearic acid 1% by mass
1,3-butanediol 10% by mass
Phenoxyethanol 0.5% by mass
Arginine 0.5% by mass
Water 59.97 mass%
C Fine particle titanium dioxide (average particle size 0.01 μm) 7% by mass
Red No. 226 0.03% by mass
"Oil sensor powder" 0.1% by mass
"Chimiron Splendid Red" 0.1% by mass
"Cover leaf AR-80" 0.1% by mass
"HOLLOWY-N15" 0.1% by mass
"Silicone KSP300" 0.1% by mass
"Hollow titanium oxide fiber" 1% by mass
下記の処方に従って、実施例1と同様の操作で、本発明の化粧料である、油中水乳化剤形のコントロールカラー2を得た。試験例1の方法で評価したところスコア4であった。これより、コントロールカラーのように、色を補正する、顔料のような粉体を含む系に於いては、水中油乳化剤形の方が好ましいことが判る。 A control color 2 in the form of a water-in-oil emulsifier, which is a cosmetic of the present invention, was obtained in the same manner as in Example 1 according to the following formulation. When evaluated by the method of Test Example 1, the score was 4. From this, it can be seen that the oil-in-water emulsifier type is preferable in a system including a powder such as a pigment that corrects the color like the control color.
イ
「シリコーンKSG210」 3 質量%
「シリコーンKF6017」 3 質量%
ジメチコン 8 質量%
シクロメチコン 13.5質量%
蔗糖ステアリン酸モノエステル 0.5質量%
ロ
1,3−ブタンジオール 10 質量%
フェノキシエタノール 0.5質量%
ハ
水 52.47質量%
硫酸マグネシウム 0.5質量%
ニ
微粒子二酸化チタン(平均粒径0.01μm) 7 質量%
赤色226号 0.03質量%
「オイルセンサーパウダー」 0.1質量%
「チミロンスプレンディッドレッド」 0.1質量%
「カバーリーフAR−80」 0.1質量%
「HOLLOWY−N15」 0.1質量%
「シリコーンKSP300」 0.1質量%
「中空酸化チタンファイバー」 1 質量%
"Silicone KSG210" 3% by mass
"Silicone KF6017" 3 mass%
Dimethicone 8% by mass
Cyclomethicone 13.5% by mass
Sucrose stearate monoester 0.5% by mass
1,3-butanediol 10% by mass
Phenoxyethanol 0.5% by mass
Water 52.47% by mass
Magnesium sulfate 0.5% by mass
Two-particulate titanium dioxide (average particle size 0.01 μm) 7% by mass
Red No. 226 0.03% by mass
"Oil sensor powder" 0.1% by mass
"Chimiron Splendid Red" 0.1% by mass
"Cover leaf AR-80" 0.1% by mass
"HOLLOWY-N15" 0.1% by mass
"Silicone KSP300" 0.1% by mass
"Hollow titanium oxide fiber" 1% by mass
コントロールカラー2の処方系にドーズを取って、通常の粒度分布のシリカ(平均粒径50μm)を添加し、試験例1の方法での効果への影響を見た。結果を表2に示す。これより、シリカの添加は効果に影響を与えないことから、通常の粒度分布のシリカに於いて、粒径3〜20μmの粉体の分画の含有量は極めて少ないものと勘案される。 Dose was taken into the control color 2 formulation system, silica with an average particle size distribution (average particle size 50 μm) was added, and the effect on the effect of the method of Test Example 1 was observed. The results are shown in Table 2. Thus, since the addition of silica does not affect the effect, it is considered that the content of the fraction of powder having a particle size of 3 to 20 μm is extremely small in silica having a normal particle size distribution.
イ
「シリコーンKSG210」 3 質量%
「シリコーンKF6017」 3 質量%
ジメチコン 8 質量%
シクロメチコン 13.5質量%
蔗糖ステアリン酸モノエステル 0.5質量%
ロ
1,3−ブタンジオール 10 質量%
フェノキシエタノール 0.5質量%
ハ
水 表2に記載の質量%
硫酸マグネシウム 0.5質量%
ニ
微粒子二酸化チタン(平均粒径0.01μm) 7 質量%
赤色226号 0.03質量%
「オイルセンサーパウダー」 0.1質量%
「チミロンスプレンディッドレッド」 0.1質量%
「カバーリーフAR−80」 0.1質量%
「HOLLOWY−N15」 0.1質量%
「シリコーンKSP300」 0.1質量%
「中空酸化チタンファイバー」 1 質量%
シリカ(50μm) 表2に記載の質量%
"Silicone KF6017" 3 mass%
Dimethicone 8% by mass
Cyclomethicone 13.5% by mass
Sucrose stearate monoester 0.5% by mass
1,3-butanediol 10% by mass
Phenoxyethanol 0.5% by mass
C Water% by mass listed in Table 2
Magnesium sulfate 0.5% by mass
Two-particulate titanium dioxide (average particle size 0.01 μm) 7% by mass
Red No. 226 0.03% by mass
"Oil sensor powder" 0.1% by mass
"Chimiron Splendid Red" 0.1% by mass
"Cover leaf AR-80" 0.1% by mass
"HOLLOWY-N15" 0.1% by mass
"Silicone KSP300" 0.1% by mass
"Hollow titanium oxide fiber" 1% by mass
Silica (50 μm)% by mass shown in Table 2
コントロールカラー2の処方系にドーズを取って、「HOLLOWY−N15」の添加量を変え、試験例1の方法での効果への影響を見た。結果を表3に示す。これより、ある程度の量を超えると効果が頭打ちになることが判る。 Taking the dose to the control color 2 formulation system, the amount of “HOLLOWY-N15” added was changed, and the effect on the effect of the method of Test Example 1 was observed. The results are shown in Table 3. From this, it can be seen that the effect reaches a peak when a certain amount is exceeded.
イ
「シリコーンKSG210」 3 質量%
「シリコーンKF6017」 3 質量%
ジメチコン 8 質量%
シクロメチコン 13.5質量%
蔗糖ステアリン酸モノエステル 0.5質量%
ロ
1,3−ブタンジオール 10 質量%
フェノキシエタノール 0.5質量%
ハ
水 表3に記載の質量%
硫酸マグネシウム 0.5質量%
ニ
微粒子二酸化チタン(平均粒径0.01μm) 7 質量%
赤色226号 0.03質量%
「オイルセンサーパウダー」 0.1質量%
「チミロンスプレンディッドレッド」 0.1質量%
「カバーリーフAR−80」 0.1質量%
「HOLLOWY−N15」 表3に記載の質量%
「シリコーンKSP300」 0.1質量%
「中空酸化チタンファイバー」 1 質量%
"Silicone KSG210" 3% by mass
"Silicone KF6017" 3 mass%
Dimethicone 8% by mass
Cyclomethicone 13.5% by mass
Sucrose stearate monoester 0.5% by mass
1,3-butanediol 10% by mass
Phenoxyethanol 0.5% by mass
C Water% by mass listed in Table 3
Magnesium sulfate 0.5% by mass
Two-particulate titanium dioxide (average particle size 0.01 μm) 7% by mass
Red No. 226 0.03% by mass
"Oil sensor powder" 0.1% by mass
"Chimiron Splendid Red" 0.1% by mass
"Cover leaf AR-80" 0.1% by mass
"HOLLOWY-N15" The mass% described in Table 3
"Silicone KSP300" 0.1% by mass
"Hollow titanium oxide fiber" 1% by mass
実施例3のコントロールカラー1の「HOLLOWY−N15」と「シリコーンKSP300」とを他の3〜20μmの球状粉体に置換してその効果を調べた。結果を表4に示す。これより、「HOLLOWY−N15」や「シリコーンKSP300」にやや効果は劣るものの、同様の効果を奏していることが判る。 The control color 1 “HOLLOWY-N15” and “silicone KSP300” in Example 3 were replaced with other 3 to 20 μm spherical powders, and the effects were examined. The results are shown in Table 4. From this, it can be seen that although the effect is somewhat inferior to “HOLLOWY-N15” and “silicone KSP300”, the same effect is achieved.
(参考例1)
平均粒径50μmのシリカ1Kgを分級機(「スーパークラシファイアー」;日清エンジニアリング株式会社製)で分級し1.3gの平均粒径13μmの分画(粉体1)を得た。
(Reference Example 1)
1 kg of silica having an average particle size of 50 μm was classified by a classifier (“Super Classifier”; manufactured by Nissin Engineering Co., Ltd.) to obtain a fraction (powder 1) having an average particle size of 13 μm of 1.3 g.
(参考例2)
参考例1と同様に、ナイロンパウダー1Kgを処理し、平均粒径9μmの分画(粉体2)を0.9g得た。
(Reference Example 2)
In the same manner as in Reference Example 1, 1 kg of nylon powder was treated to obtain 0.9 g of a fraction (powder 2) having an average particle size of 9 μm.
(参考例3)
参考例1と同様に、メタクリル酸メチルパウダー1Kgを処理し、平均粒径12μmの分画(粉体3)を0.4g得た。
(Reference Example 3)
In the same manner as in Reference Example 1, 1 kg of methyl methacrylate powder was treated to obtain 0.4 g of a fraction (powder 3) having an average particle size of 12 μm.
イ
スクワラン 8 質量%
ホホバ油 2 質量%
ジメチコン 5 質量%
ステアリン酸 1.5質量%
グリセリルモノステアレート 2 質量%
セタノール 0.5質量%
ソルビタンジステアレート 0.5質量%
POE(45)ステアリン酸 1 質量%
ロ
1,3−ブタンジオール 10 質量%
フェノキシエタノール 0.5質量%
アルギニン 0.5質量%
水 59.97質量%
ハ
微粒子二酸化チタン(平均粒径0.01μm) 7 質量%
赤色226号 0.03質量%
「オイルセンサーパウダー」 0.1質量%
「チミロンスプレンディッドレッド」 0.1質量%
「カバーリーフAR−80」 0.1質量%
表4に記載の粉体 0.2質量%
「中空酸化チタンファイバー」 1 質量%
Isquaran 8% by mass
Jojoba oil 2% by mass
Dimethicone 5% by mass
Stearic acid 1.5% by mass
Glyceryl monostearate 2% by mass
Cetanol 0.5% by mass
Sorbitan distearate 0.5% by mass
POE (45) stearic acid 1% by mass
1,3-butanediol 10% by mass
Phenoxyethanol 0.5% by mass
Arginine 0.5% by mass
Water 59.97 mass%
C Fine particle titanium dioxide (average particle size 0.01 μm) 7% by mass
Red No. 226 0.03% by mass
"Oil sensor powder" 0.1% by mass
"Chimiron Splendid Red" 0.1% by mass
"Cover leaf AR-80" 0.1% by mass
Powders listed in Table 4 0.2% by mass
"Hollow titanium oxide fiber" 1% by mass
下記に示す処方に従って、プレストパウダータイプのパウダーコントロールカラーを作成した。即ち、イの成分をヘンシェルミキサーで混合し、0.9mm丸穴スクリーンを装着したパルベライザーで粉砕し、しかる後に、ヘンシェルミキサーで混合しながら、ロの成分を噴霧してコーティングし、1mmヘリングボーンスクリーンを装着したパルベライザーで粉砕し、金皿に詰めて、加圧成型し、本発明の化粧料であるパウダーコントロールカラーを得た。このものを実施例1の試験例2の方法で評価したところ、スコア4であった。パウダーコントロールカラーでも効果を奏することが判る。 According to the prescription shown below, a pressed powder type powder control color was prepared. In other words, the component a is mixed with a Henschel mixer, pulverized with a pulverizer equipped with a 0.9 mm round hole screen, and then mixed with the Henschel mixer while spraying the component b, and coated with a 1 mm herringbone screen. Was pulverized with a palverizer equipped with, packed in a metal pan, and pressure-molded to obtain a powder control color which is a cosmetic of the present invention. When this was evaluated by the method of Test Example 2 of Example 1, it was score 4. It can be seen that the powder control color is also effective.
イ
ハイドロジェンメチルポリシロキサン3%焼付セリサイト 30 質量%
ハイドロジェンメチルポリシロキサン3%焼付マイカ 20 質量%
ハイドロジェンメチルポリシロキサン3%焼付タルク 18 質量%
「オイルセンサーパウダー」 1 質量%
「中空酸化チタンファイバー」 10 質量%
「HOLLOWY−N15」 5 質量%
「シリコーンKSP300」 5 質量%
「チミロンスプレンディッドレッド」 1 質量%
ロ
ジメチコン 5 質量%
フェニルメチコン 5 質量%
Dihydrogenmethylpolysiloxane 3% Baking sericite 30% by mass
Hydrogen methyl polysiloxane 3% baking mica 20% by mass
Hydrogenmethylpolysiloxane 3% baked talc 18% by mass
"Oil sensor powder" 1% by mass
"Hollow titanium oxide fiber" 10% by mass
"HOLLOWY-N15" 5 mass%
"Silicone KSP300" 5 mass%
"Chimiron Splendid Red" 1 mass%
Logimethicone 5% by mass
Phenylmethicone 5% by mass
本発明は下地化粧料に応用できる。 The present invention can be applied to a base cosmetic.
Claims (4)
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WO1999011574A1 (en) * | 1997-09-02 | 1999-03-11 | Ishihara Sangyo Kaisha, Ltd. | Hollow fine powder, flaky fine titanium oxide powder prepared by pulverizing said hollow fine powder, and process for preparing the both |
JPH11349442A (en) * | 1998-06-01 | 1999-12-21 | Pola Chem Ind Inc | Wrinkle and pore-masking cosmetic |
JP2001002522A (en) * | 1999-06-17 | 2001-01-09 | Kao Corp | Cosmetic |
JP2001002530A (en) * | 1999-06-17 | 2001-01-09 | Kao Corp | Cosmetic |
JP2003137549A (en) * | 2001-10-30 | 2003-05-14 | Catalysts & Chem Ind Co Ltd | Method for manufacturing tubular titanium oxide grain and tubular titanium oxide |
JP2004315416A (en) * | 2003-04-15 | 2004-11-11 | Naris Cosmetics Co Ltd | Powder composition |
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WO1999011574A1 (en) * | 1997-09-02 | 1999-03-11 | Ishihara Sangyo Kaisha, Ltd. | Hollow fine powder, flaky fine titanium oxide powder prepared by pulverizing said hollow fine powder, and process for preparing the both |
JPH11349442A (en) * | 1998-06-01 | 1999-12-21 | Pola Chem Ind Inc | Wrinkle and pore-masking cosmetic |
JP2001002522A (en) * | 1999-06-17 | 2001-01-09 | Kao Corp | Cosmetic |
JP2001002530A (en) * | 1999-06-17 | 2001-01-09 | Kao Corp | Cosmetic |
JP2003137549A (en) * | 2001-10-30 | 2003-05-14 | Catalysts & Chem Ind Co Ltd | Method for manufacturing tubular titanium oxide grain and tubular titanium oxide |
JP2004315416A (en) * | 2003-04-15 | 2004-11-11 | Naris Cosmetics Co Ltd | Powder composition |
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