JP3629400B2 - Hair manucia remover and hair manucia set comprising it - Google Patents
Hair manucia remover and hair manucia set comprising it Download PDFInfo
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- JP3629400B2 JP3629400B2 JP2000117348A JP2000117348A JP3629400B2 JP 3629400 B2 JP3629400 B2 JP 3629400B2 JP 2000117348 A JP2000117348 A JP 2000117348A JP 2000117348 A JP2000117348 A JP 2000117348A JP 3629400 B2 JP3629400 B2 JP 3629400B2
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- hair
- manucia
- remover
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- carbonate
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Description
【０００１】
【発明の属する技術分野】
本発明は、ヘアマニュキア用のリムーバー及びこれを構成要素とするヘアマニュキアセットに関する。
【０００２】
【従来の技術】
毛髪はハードケラチンで構成されるキューティクルの積層した形状をしており、この様な毛髪に着色を行う場合には、ケラチンの硬い組織が障害となり、着色成分の毛髪表面への吸着や内部への浸透が均一になりにくく、その為、色味ののりのムラや、染色ムラなどが生じやすく、その改善が望まれていた。この様な問題を解決する手段として、本発明者らは、アラビノース、リキソース、リボース、キシロース、トリメチロールプロパン、トリメチロールエタン、ジプロピレングリコール、ジグリセリン、エリスリトール、スレイトール、トリメチロールプロパン、トリメチロールエタン等のエーテル結合を０乃至は１個有する、炭素数４以上の多価アルコール及び／又は炭酸エチレンや炭酸プロピレン等の炭酸アルキレンを含有させることにより、ヘアマニュキアの染毛成分である、酸性染料の毛髪内部への浸透を促進し、堅牢でムラのない染毛が為し得ることを見い
だした。しかしながら、この様に堅牢でムラのない染毛料が開発されたことにより、新たな問題が生じた。即ち、この様に染色が堅牢であるが故に、毛髪以外の皮膚の部分に誤って塗布されて染色されると、これを落とすことが非常に困難な場合があることである。染色深度が深い故に、従来のヘアマニュキア用のリムーバーでは充分に落とせない場合があるのである。即ち、染色深度の深いヘアマニュキア用のリムーバーの開発が望まれていた。
【０００３】
一方、ヘアマニュキア用のリムーバーにおいて、アラビノース、リキソース、リボース、キシロース、トリメチロールプロパン、トリメチロールエタン、ジプロピレングリコール、ジグリセリン、エリスリトール、スレイトール、トリメチロールプロパン、トリメチロールエタン等のエーテル結合を０乃至は１個有する、炭素数４以上の多価アルコールと炭酸アルキレンから選ばれる１種乃至は２種以上とを含有したものは知られていないし、この様なリムーバーが染色深度の深いヘアマニュキアの除去・補正用に優れていることも全く知られていない。かかるヘアマニュキア用のリムーバーと染色深度の深いヘアマニュキアを組み合わせてヘアマニュキアセットして用いることも全く知られていない。
【０００４】
【発明が解決しようとする課題】
本発明はこの様な状況下為されたものであり、染色深度の深いヘアマニュキア用のリムーバーを開発し、染色深度の深い染毛料の特性を生かした実用的なヘアマニュキアセットを提供することを課題とする。
【０００５】
【課題の解決手段】
この様な状況に鑑みて、本発明者らは、染色深度の深いヘアマニュキア用のリムーバーを開発し、染色深度の深い染毛料の特性を生かした実用的なヘアマニュキアセットを提供すべく鋭意研究努力を重ねた結果、エーテル結合を０乃至は１個有する、炭素数４以上の多価アルコールから選ばれる１種乃至は２種以上と炭酸アルキレンから選ばれる１種乃至は２種以上とを含有することを特徴とする、ヘアマニュキア用のリムーバーに優れたリムーブ作用を見いだし、このものと染色深度の深い、エーテル結合を０乃至は１個有する、炭素数４以上の多価アルコールから選ばれる１種乃至は２種以上及び／又は炭酸アルキレンから選ばれる１種乃至は２種以上を含有するヘアマニュキアとを組み合わせることにより、上記課題のヘアマニュキアセットが得られることを見いだし、発明を完成させるに至った。即ち、本発明は、以下に示す技術に関するものである。
（１）エーテル結合を０乃至は１個有する、炭素数４以上の多価アルコールから選ばれる１種乃至は２種以上と炭酸アルキレンから選ばれる１種乃至は２種以上とを含有することを特徴とする、ヘアマニュキア用のリムーバー。
（２）エーテル結合を０乃至は１個有する、炭素数４以上の多価アルコールが、アラビノース、リキソース、リボース、キシロース、トリメチロールプロパン、トリメチロールエタン、ジプロピレングリコール、ジグリセリン、エリスリトール、スレイトール、トリメチロールプロパン又はトリメチロールエタンであることを特徴とする、（１）に記載のヘアマニュキア用のリムーバー。
（３）エーテル結合を０乃至は１個有する、炭素数４以上の多価アルコールの含有量が、総量で０．０１〜１０重量％であることを特徴とする、（１）又は（２）に記載のヘアマニュキア用のリムーバー。
（４）炭酸アルキレンが、炭酸エチレン及び／又は炭酸プロピレンである、（１）〜（３）何れか１項に記載のヘアマニュキア用のリムーバー。
（５）炭酸アルキレンの含有量が、総量で０．０１〜１０重量％であることを特徴とする
、（１）〜（４）何れか１項に記載のヘアマニュキア用のリムーバー。
（６）エーテル結合を０乃至は１個有する、炭素数４以上の多価アルコールから選ばれる１種乃至は２種以上及び／又は炭酸アルキレンから選ばれる１種乃至は２種以上を含有するヘアマニュキアと（１）〜（５）何れか１項に記載のヘアマニュキア用のリムーバーとからなる、ヘアマニュキアセット。
（７）ヘアマニュキアに於ける、エーテル結合を０乃至は１個有する、炭素数４以上の多価アルコールが、アラビノース、リキソース、リボース、キシロース、トリメチロールプロパン、トリメチロールエタン、ジプロピレングリコール、ジグリセリン、エリスリトール、スレイトール、トリメチロールプロパン又はトリメチロールエタンであることを特徴とする、（６）に記載のヘアマニュキアセット。
（８）ヘアマニュキアに於ける、炭酸アルキレンが炭酸エチレン及び／又は炭酸プロピレンであることを特徴とする、（６）又は（７）に記載のヘアマニュキアセット。
以下、本発明について、実施の形態を中心に詳細に説明を加える。
【０００６】
【発明の実施の形態】
（１）本発明のヘアマニュキア用のリムーバーの必須成分である多価アルコール
本発明のヘアマニュキア用のリムーバーはエーテル結合を０乃至は１個有する、炭素数４以上の多価アルコールから選ばれる１種乃至は２種以上含有することを特徴とする。この様な多価アルコールとしては、環状構造を有するものであっても、分岐構造を有するものであっても、直鎖状のものであっても良く、好ましい炭素数としては４〜１２であり、更に好ましくは、４〜６である。これは浸透促進性が分子の立体的形状よりもサイズによって異なるためである。又、この様な多価アルコールに於けるエーテル結合は０乃至は１個であることが必要である。これは、この様なエーテル結合が多数存在する多糖類やポリエチレングリコールのような水溶性高分子においては前記浸透性促進効果が得られない場合があるからである。この様な多価アルコールの内で、好ましいものとしては、例えば、アラビノース、リキソース、リボース、キシロース、トリメチロールプロパン、トリメチロールエタン、ジプロピレングリコール、ジグリセリン、エリスリトール、スレイトール、ペンタエリスリトール、１，２−ペンタンジオール、トリメチロールプロパン又はトリメチロールエタンが例示できる。ここで、これらの多価アルコールは光学異性体の存在するものがあるが、この様な場合、本発明に於いてはそれぞれの光学異性体のみを用いることも可能であるし、ラセミ体の形態で用いることもできる。この様な多価アルコールは本発明のヘアマニュキア用のリムーバーに於いては、唯１種を含有させることも可能であるし、２種以上組み合わせて含有させることも可能である。本発明のヘアマニュキア用のリムーバーに於ける、これら多価アルコールの好ましい含有量は、総量で０．０１〜１０重量％であり、更に好ましくは０．５〜５重量％である。これは、この様な多価アルコールは多すぎても効果が頭打ちになる場合があり、少なすぎると効果が発現しない場合があるからである。
【０００７】
（２）本発明のヘアマニュキア用のリムーバーの必須成分である、炭酸アルキレン
本発明のヘアマニュキア用のリムーバーは、炭酸アルキレンから選ばれる１種乃至は２種以上を含有することを特徴とする。本発明で使用する炭酸アルキレンとしては、炭酸メチレン、炭酸エチレン、炭酸プロピレン、炭酸ブチレンなど炭酸と炭素数１〜４の直鎖乃至は分岐のアルキレングリコールとのエステルが好ましく、中でも、炭酸エチレンと炭酸プロピレンが溶剤特性の点で好ましく、その中でも炭酸プロピレンが特に好ましい。これらは化粧料の原料として市販されており、その入手は容易である。これら炭酸アルキレンは、本発明のヘアマニュキア用のリムーバーに於いては、唯１種を含有させることも可能であるし、２種以上組み合わせて含有させることも可能である。本発明のヘアマニュキア用のリムーバーに於ける、これら炭酸アルキレンの好ましい含有量は、総量で０．０１〜１０重量％であり、更に好ましくは０．５〜５重量％である。これは、この様な炭酸アルキレンは多すぎても効果が頭打ちになる場合があり、少なすぎると効果が発現しない場合があるからである。
【０００８】
（３）本発明のヘアマニュキア用のリムーバー
本発明のヘアマニュキア用のリムーバーは、上記のエーテル結合を０乃至は１個有する、炭素数４以上の多価アルコールと炭酸アルキレンとを含有し、毛髪の染色時に皮膚など染着した染色組成物を除去するための組成物であり、通常は化粧料に分類される。従って、上記必須成分である、エーテル結合を０乃至は１個有する、炭素数４以上の多価アルコール類及び炭酸アルキレン以外に通常化粧料などで使用される任意成分を含有することが出来る。この様な任意成分としては、例えば、スクワラン、ワセリン、マイクロクリスタリンワックス等の炭化水素類、ホホバ油、カルナウバワックス，オレイン酸オクチルドデシル等のエステル類、オリーブ油、牛脂、椰子油等のトリグリセライド類、ステアリン酸、オレイン酸、リチノレイン酸等の脂肪酸、オレイルアルコール、ステアリルアルコール、オクチルドデカノール等の高級アルコール、スルホコハク酸エステルやポリオキシエチレンアルキル硫酸ナトリウム等のアニオン界面活性剤類、アルキルベタイン塩等の両性界面活性剤類、ジアルキルアンモニウム塩等のカチオン界面活性剤類、ソルビタン脂肪酸エステル、脂肪酸モノグリセライド、これらのポリオキシエチレン付加物、ポリオキシエチレンアルキルエーテル、ポリオキシエチレン脂肪酸エステル等の非イオン界面活性剤類、ポリエチレングリコール、グリセリン、１，３−ブタンジオール等の多価アルコール類、増粘・ゲル化剤、酸化防止剤、紫外線吸収剤、色材、防腐剤、粉体等を含有することができる。これら任意の成分と必須成分とを常法に従って処理することにより、本発明のヘアマニュキア用のリムーバーは製造することが出来る。
【０００９】
（４）本発明のヘアマニュキアセット
本発明のヘアマニュキアセットは、上記ヘアマニュキア用のリムーバーと上記に示すエーテル結合を０乃至は１個有する、炭素数４以上の多価アルコールから選ばれる１種乃至は２種以上及び／又は炭酸アルキレンから選ばれる１種乃至は２種以上を含有するヘアマニュキアとを構成要素とする。前記ヘアマニュキアにおける、上記の多価アルコール及び／又は炭酸アルキレンの好ましい含有量はヘアマニュキアリムバーに於ける含有量に準じる。この様なヘアマニュキアに於いては、使用する染料としては酸性染料を含有することが特に好ましい。酸性染料としては、化粧料などで使用されているものであれば特段の限定無く使用でき、例えば、橙色２０５号、茶色４０１号、紫色４０１号などが好ましく例示できる。かかる酸性染料の好ましい含有量は、総量で０．１〜１０重量％であり、更に好ましくは０．５〜５重量％である。ここで組成物としては、化粧料分類のものでも雑貨分類のものでも何れも良いが、化粧料分類のものに適用するのが好ましい。その他には化粧料で通常用いられる任意成分を含有することが出来る。かかる任意成分としては、ヘアマニュキアリムーバーの任意成分に準じれば良い。これらを常法に従って処理することにより、かかるヘアマニュキアは製造できる。
【００１０】
＜製造例１＞
以下に示す処方に従って、本発明のヘアマニュキアセットのヘアマニュキアを作成した。即ち、処方成分を室温にて攪拌可溶化し、ヘアマニュキアを得た。このヘアマニュキアを用いて、白髪の染毛試験を行った。白髪の毛束（１０ｇ）を測色後、へマニュキアで処理し、余分なヘアマニュキアをシャンプーにより除去した後、再び測色し、処理の前後の明度差（ΔＬ値）を算出した。この時、同時に上記本発明のヘアマニュキアセットのヘアマニュキアの必須成分である多価アルコールを水に置換した対照例１とグリセリンに置換した比較例１とプロピレングリコールに置換した比較例２と従来のベンジルアルコールを使用した参考例１も同様に作成し、同様に試験した。結果を表１に示す。これより、本発明のヘアマニュキアセットのヘアマニュキアは染毛性に優れることがわかる。これは、本発明のヘアマニュキアセットのヘアマニュキアの必須成分であるエーテル結合を０乃至は１個有する、炭素数４以上の多価アルコールと炭酸アルキレンにより、毛髪中への染料の浸透が促進された為である。（表中の成分の単位は重量部を表す。）
【００１１】
【表１】
この様に本発明のヘアマニュキアセットのヘアマニュキアは優れた染毛性を有する。本発明のヘアマニュキア用のリムーバーにより、非適用部位への誤塗布を修正できるようになったことにより、上記のような優れた特性を生かすことが出来るようになる。
【００１３】
【実施例】
以下に実施例を挙げて、本発明について更に詳細に説明を加えるが、本発明がこれら実施例にのみ限定されないことは言うまでもない。
【００１４】
＜実施例１＞
下記に示す処方に従ってヘアマニュキア用のリムーバーを作成した。即ち、処方成分を攪拌可溶化しリムーバーを得た。同時に本発明のリムーバーのキシリトールと炭酸プロピレンを水に置換した対照例２とキシリトールを炭酸プロピレンに置換した比較例３と炭酸プロピレンをキシリトールに置換した比較例４とを作成し、上記製造例１のヘアマニュキアに対する除去効果をブタの皮膚を用いて評価した。評価方法はブタ皮膚に製造例１のヘアマニュキアを０．０５ｍｌ塗布し、これをリムーバー５ｍｌを含浸させたコットンで拭き取り、未処理の皮膚との色差（ΔＥ値）を測定した。実施例１のリムバーが０．２であるのに対し、対照例２が１．６であり、比較例３が０．４であり、比較例４が０．４であり、本発明のリムーバーのリムーブ力の優秀性が証明された。この効果が上記本発明の必須成分である多価アルコールであるキシリトールと炭酸アルキレンである炭酸プロピレンとの相乗作用であることもわかる。
トリメチルグリシン ３ 重量部
エタノール ５ 重量部
ベンジルアルコール １０ 重量部
キシリトール ２ 重量部
炭酸プロピレン ２ 重量部
水 ７８ 重量部
【００１５】
＜実施例２＞
実施例１のリムーバーのキシリトールを他の多価アルコールに替えて実施例１と同様の検討を行った。結果を表２に示す。これより、本発明のリムーバーは何れもリムーブ力に優れることが明白である。
【００１６】
【表２】
＜実施例３＞
実施例１の本発明のヘアマニュキア用のリムーバーの炭酸プロピレンを炭酸エチレンに置換してたものを同様に作成した。このものを同様に染着除去試験を行ったところ、ΔＥ値は０．２であり、炭酸エチレンでも炭酸プロピレン同様の効果が得られることがわかった。
【００１８】
＜実施例４＞
実施例１のヘアマニュキア用のリムーバーと製造例１のヘアマニュキアとを組み合わせて本発明のヘアマニュキアセットとした。このものについて、ヘアマニュキアの使用者２０名を使用して、１ヶ月の使用テストを行い、使用性を評価した。評価基準は＋＋：非常によい、＋：良い、±：やや良い及びー：よくないであった。結果を出現例数として表３に示す。これより、本発明の本発明のヘアマニュキアセットは優れたリムーブ力を有するリムーバーの存在により、染色深度の深いヘアマニュキアの特性を生かせるが故に優れた使用性と染色性が実使用で認められている。
【００１９】
【表３】
【発明の効果】
本発明によれば、染色深度の深いヘアマニュキア用のリムーバーを開発し、染色深度の深い染毛料の特性を生かした実用的なヘアマニュキアセットを提供することが出来る。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a hair manicure remover and a hair manicure set comprising the same.
[0002]
[Prior art]
The hair has a laminated shape of cuticles composed of hard keratin, and when coloring such hair, the hard tissue of keratin becomes an obstacle, and the coloring component is adsorbed on the hair surface and absorbed into the hair. The permeation is difficult to be uniform, and therefore, uneven coloring and uneven dyeing are likely to occur, and improvement has been desired. To solve such problems, the present inventors have arabinose, lyxose, ribose, xylose, trimethylolpropane, trimethylolethane, Jipuropirengu recall, diglycerol, erythritol, threitol, trimethylol propane, trimethylol ethane Of acid dyes, which are hair dye components of hair manucia by containing polyhydric alcohols having 4 or more carbon atoms and / or alkylene carbonates such as ethylene carbonate and propylene carbonate, having 0 to 1 ether bonds such as It has been found that the penetration into the inside of the hair is promoted and the hair can be dyed firmly and without unevenness. However, new problems have arisen due to the development of such a robust and uniform hair dye. That is, since the dyeing is robust in this way, it may be very difficult to remove it when it is applied and dyed by mistake on the skin other than the hair. Because of the deep dyeing depth, a conventional hair manicure remover may not be able to remove it sufficiently. That is, it has been desired to develop a remover for hair manucia having a deep dyeing depth.
[0003]
On the other hand, in remover for hair manicure, arabinose, lyxose, ribose, xylose, trimethylolpropane, trimethylolethane, Jipuropirengu recall, diglycerol, erythritol, threitol, trimethylol propane, or 0 an ether bond such as trimethylolethane Is not known to contain one or more selected from polyhydric alcohols having 4 or more carbon atoms and alkylene carbonate, and such a remover removes hair manucia having a deep dyeing depth. -It is not known at all that it is excellent for correction. It is not known at all to use a hair manicure set by combining such a hair manicure remover and a hair manicure having a deep dyeing depth.
[0004]
[Problems to be solved by the invention]
The present invention has been made under such circumstances, and has developed a remover for hair manucia having a deep dyeing depth, and provides a practical hair manucia set that takes advantage of the properties of hair dyes having a deep dyeing depth. Let it be an issue.
[0005]
[Means for solving problems]
In view of such circumstances, the present inventors have developed a remover for hair manucia with a deep dyeing depth, and eagerly researched to provide a practical hair manicure set that takes advantage of the properties of hair dyes with a deep dyeing depth. As a result of repeated efforts, it contains 1 or 2 or more selected from polyhydric alcohols having 4 or more carbon atoms and 0 or 1 ether bond, and 1 or 2 or more selected from alkylene carbonate characterized by, find the remove action superior to remover for hair manicure, deep this as the dyeing depth, 0 to ether bonds is one perforated, 1 selected from polyhydric alcohols having 4 or more carbon atoms By combining with a hair manucia containing one or more species selected from two or more species and / or alkylene carbonate, It found that Tsu door can be obtained, and have completed the invention. That is, this invention relates to the technique shown below.
(1) 1 type or 2 types or more selected from polyhydric alcohols having 4 or more carbon atoms and 0 or 1 ether bond, and 1 type or 2 types or more selected from alkylene carbonate. Characteristic remover for hair manukia.
(2) is 0 to the ether bond to one Yes, polyhydric alcohols having 4 or more carbon atoms is, arabinose, lyxose, ribose, xylose, trimethylolpropane, trimethylolethane, Jipuropirengu recall, diglycerol, erythritol, threitol, The remover for hair manukia according to (1), which is trimethylolpropane or trimethylolethane.
(3) The content of the polyhydric alcohol having 0 or 1 ether bond and having 4 or more carbon atoms is 0.01 to 10% by weight in total, (1) or (2) A hair manicure remover as described in 1.
(4) The hair manukia remover according to any one of (1) to (3), wherein the alkylene carbonate is ethylene carbonate and / or propylene carbonate.
(5) The remover for hair manucia according to any one of (1) to (4), wherein the total content of alkylene carbonate is 0.01 to 10% by weight.
(6) Hair having 1 to 2 or more selected from polyhydric alcohols having 4 or more carbon atoms and / or alkylene carbonate having 0 to 1 ether bond and / or selected from alkylene carbonate. A hair manucia set comprising a manucia and a remover for hair manucia according to any one of (1) to (5).
(7) in the hair manicure, or 0 ether linkages is one organic polyhydric alcohol having 4 or more carbon atoms is, arabinose, lyxose, ribose, xylose, trimethylolpropane, trimethylolethane, Jipuropirengu recall, di The hair manucia set according to (6), which is glycerin, erythritol, threitol, trimethylolpropane or trimethylolethane.
(8) The hair manucia set according to (6) or (7), wherein the alkylene carbonate in hair manucia is ethylene carbonate and / or propylene carbonate.
Hereinafter, the present invention will be described in detail with a focus on embodiments.
[0006]
DETAILED DESCRIPTION OF THE INVENTION
(1) Polyhydric alcohol which is an essential component of the remover for hair manucia of the present invention The remover for hair manucia of the present invention is selected from polyhydric alcohols having 0 to 1 ether bonds and having 4 or more carbon atoms. It is characterized by containing two or more species. Such a polyhydric alcohol may have a cyclic structure, a branched structure, or a straight chain, and preferably has 4 to 12 carbon atoms. More preferably, it is 4-6. This is because the penetration promoting property differs depending on the size rather than the three-dimensional shape of the molecule. In addition, the number of ether bonds in such a polyhydric alcohol needs to be 0 or 1. This is because the permeability promoting effect may not be obtained in a water-soluble polymer such as a polysaccharide or polyethylene glycol having a large number of such ether bonds. Among such polyhydric alcohols, preferred are, for example, arabinose, lyxose, ribose, xylose, trimethylolpropane, trimethylolethane, Jipuropirengu recall, diglycerol, erythritol, threitol, pentaerythritol, 1,2 -Pentanediol, trimethylolpropane or trimethylolethane can be exemplified. Here, some of these polyhydric alcohols have optical isomers. In such a case, in the present invention, it is possible to use only the respective optical isomers, or the racemic form. Can also be used. Such a polyhydric alcohol can be contained only in one kind in the hair manicure remover of the present invention, or can be contained in combination of two or more kinds. The preferred content of these polyhydric alcohols in the hair manicure remover of the present invention is 0.01 to 10% by weight, more preferably 0.5 to 5% by weight. This is because the effect may reach its peak even when there are too many such polyhydric alcohols, and the effect may not be exhibited when there are too few such alcohols.
[0007]
(2) Alkylene carbonate which is an essential component of the hair manicure remover of the present invention The hair manicure remover of the present invention contains one or more selected from alkylene carbonate. The alkylene carbonate used in the present invention is preferably an ester of carbonic acid such as methylene carbonate, ethylene carbonate, propylene carbonate, butylene carbonate and a linear or branched alkylene glycol having 1 to 4 carbon atoms. Propylene is preferred in terms of solvent properties, and propylene carbonate is particularly preferred among them. These are marketed as raw materials for cosmetics and are easily available. In the hair manicure remover of the present invention, these alkylene carbonates can contain only one kind, or two or more kinds in combination. The content of these alkylene carbonates in the hair manicure remover of the present invention is preferably 0.01 to 10% by weight, more preferably 0.5 to 5% by weight. This is because the effect may reach its peak even if there is too much such alkylene carbonate, and the effect may not be manifested if it is too small.
[0008]
(3) Remover for hair manucia of the present invention A remover for hair manucia of the present invention contains a polyhydric alcohol having 4 or more carbon atoms having 0 to 1 ether bond and alkylene carbonate, and hair. It is a composition for removing the dyed composition dyed on the skin at the time of dyeing, and is usually classified as a cosmetic. Therefore, in addition to the essential components, which are 0 to 1 ether bonds, polyhydric alcohols having 4 or more carbon atoms, and alkylene carbonate, optional components usually used in cosmetics and the like can be contained. Such optional components include, for example, hydrocarbons such as squalane, petrolatum, microcrystalline wax, esters such as jojoba oil, carnauba wax, octyldodecyl oleate, triglycerides such as olive oil, beef tallow, coconut oil, Fatty acids such as stearic acid, oleic acid, lithinoleic acid, higher alcohols such as oleyl alcohol, stearyl alcohol, octyldodecanol, anionic surfactants such as sulfosuccinic acid ester and sodium polyoxyethylene alkyl sulfate, and amphoteric compounds such as alkyl betaine salts Surfactants, cationic surfactants such as dialkyl ammonium salts, sorbitan fatty acid esters, fatty acid monoglycerides, polyoxyethylene adducts thereof, polyoxyethylene alkyl ethers, polyoxyethylenes Nonionic surfactants such as len fatty acid esters, polyhydric alcohols such as polyethylene glycol, glycerin, 1,3-butanediol, thickening / gelling agents, antioxidants, ultraviolet absorbers, colorants, preservatives , Powder and the like can be contained. By treating these optional components and essential components according to a conventional method, the remover for hair manucia of the present invention can be produced.
[0009]
(4) The hair manucia set of the present invention The hair manucia set of the present invention is one selected from polyhydric alcohols having 4 or more carbon atoms, having 0 to 1 ether bond as described above and the above-mentioned remover for hair manucia. Or a hair manucia containing one or more selected from two or more and / or alkylene carbonate. The preferred content of the polyhydric alcohol and / or alkylene carbonate in the hair manucia is in accordance with the content in the hair manucum rim bar. In such a hair manucia, it is particularly preferable that the dye to be used contains an acid dye. The acid dye can be used without particular limitation as long as it is used in cosmetics and the like. For example, orange 205, brown 401, purple 401 and the like can be preferably exemplified. The preferable content of the acid dye is 0.1 to 10% by weight, more preferably 0.5 to 5% by weight in total. Here, the composition may be of the cosmetic classification or the miscellaneous goods classification, but is preferably applied to the cosmetic classification. In addition, an optional component usually used in cosmetics can be contained. Such optional components may be in accordance with the optional components of the hair manicure remover. By treating these in accordance with conventional methods, such hair manucia can be produced.
[0010]
<Production Example 1>
According to the formulation shown below, a hair manucia of the hair manucia set of the present invention was prepared. That is, the prescription ingredients were stirred and solubilized at room temperature to obtain hair manucia. Using this hair manucia, a hair coloring test for gray hair was performed. After measuring the color of the white hair bundle (10 g), it was treated with hemanuquisia, excess hair manucia was removed by shampooing, and then colorimetry was performed again to calculate the lightness difference (ΔL value) before and after the treatment. At the same time, Comparative Example 1 in which the polyhydric alcohol, which is an essential component of the hair manucia of the hair manucia set of the present invention, was replaced with water, Comparative Example 1 in which glycerin was replaced, Comparative Example 2 in which propylene glycol was replaced, and the conventional Reference Example 1 using benzyl alcohol was similarly prepared and tested in the same manner. The results are shown in Table 1. From this, it can be seen that the hair manucia of the hair manucia set of the present invention is excellent in hair dyeing properties. This is because the penetration of the dye into the hair is promoted by the polyhydric alcohol having 4 or more carbon atoms and the alkylene carbonate having 0 to 1 ether bond, which is an essential component of the hair manucia of the hair manucia set of the present invention. Because of it. (The unit of the component in a table | surface represents a weight part.)
[0011]
[Table 1]
As described above, the hair manucia of the hair manucia set of the present invention has excellent hair dyeing properties. With the hair manicure remover of the present invention, it becomes possible to correct erroneous application to a non-application site, thereby making it possible to take advantage of the excellent characteristics as described above.
[0013]
【Example】
Hereinafter, the present invention will be described in more detail with reference to examples, but it is needless to say that the present invention is not limited to these examples.
[0014]
<Example 1>
A hair manicure remover was prepared according to the formulation shown below. That is, the formulation components were solubilized with stirring to obtain a remover. At the same time, Comparative Example 2 in which xylitol and propylene carbonate of the remover of the present invention were replaced with water, Comparative Example 3 in which xylitol was replaced with propylene carbonate, and Comparative Example 4 in which propylene carbonate was replaced with xylitol were prepared. The removal effect on hair manucia was evaluated using pig skin. In the evaluation method, 0.05 ml of hair manucia of Production Example 1 was applied to pig skin, wiped with cotton impregnated with 5 ml of remover, and the color difference (ΔE value) from untreated skin was measured. The rim bar of Example 1 is 0.2, whereas Control Example 2 is 1.6, Comparative Example 3 is 0.4, and Comparative Example 4 is 0.4. The excellence of remove power was proved. It can also be seen that this effect is a synergistic effect of xylitol, which is a polyhydric alcohol, which is an essential component of the present invention, and propylene carbonate, which is an alkylene carbonate.
Trimethylglycine 3 parts by weight Ethanol 5 parts by weight Benzyl alcohol 10 parts by weight Xylitol 2 parts by weight Propylene carbonate 2 parts by weight Water 78 parts by weight
<Example 2>
The same examination as in Example 1 was performed by replacing xylitol of the remover of Example 1 with another polyhydric alcohol. The results are shown in Table 2. From this, it is clear that all the removers of the present invention are excellent in removing force.
[0016]
[Table 2]
<Example 3>
A hair manicure remover of Example 1 in which propylene carbonate was replaced with ethylene carbonate was similarly prepared. When this was subjected to a dyeing removal test in the same manner, the ΔE value was 0.2, and it was found that ethylene carbonate could provide the same effect as propylene carbonate.
[0018]
<Example 4>
The hair manucia set of the present invention was combined with the hair manucia remover of Example 1 and the hair manucia of Production Example 1. About this thing, the usage test of one month was performed using 20 users of hair manukia, and usability was evaluated. The evaluation criteria were ++: very good, +: good, ±: slightly good and-: not good. The results are shown in Table 3 as the number of appearance examples. As a result, the hair manicure set of the present invention of the present invention, due to the presence of a remover having an excellent removing power, allows the use of the characteristics of hair manukia with a deep dyeing depth, so that excellent usability and dyeability are recognized in actual use. Yes.
[0019]
[Table 3]
【The invention's effect】
ADVANTAGE OF THE INVENTION According to this invention, the remover for hair manucia with a deep dyeing depth can be developed, and the practical hair manicure set which utilized the characteristic of the hair dye with a deep dyeing depth can be provided.
Claims (3)
１）アラビノース、リキソース、リボース、キシロース、トリメチロールプロパン、エリスリトール及びペンタエリスリトールから選択される多価アルコールと、２）炭酸エチレン又は炭酸プロピレンを含有するリムーバー。 (1) For hair manucia containing polyhydric alcohol selected from arabinose, lyxose, ribose, xylose, trimethylolpropane, trimethylolethane, dipropylene glycol, diglycerin and erythritol, and (2) ethylene carbonate or propylene carbonate Remover,
1) A remover containing polyhydric alcohol selected from arabinose, lyxose, ribose, xylose, trimethylolpropane, erythritol and pentaerythritol, and 2) ethylene carbonate or propylene carbonate .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000117348A JP3629400B2 (en) | 2000-04-19 | 2000-04-19 | Hair manucia remover and hair manucia set comprising it |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000117348A JP3629400B2 (en) | 2000-04-19 | 2000-04-19 | Hair manucia remover and hair manucia set comprising it |
Publications (3)
| Publication Number | Publication Date |
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| JP2001302460A JP2001302460A (en) | 2001-10-31 |
| JP2001302460A5 JP2001302460A5 (en) | 2004-11-18 |
| JP3629400B2 true JP3629400B2 (en) | 2005-03-16 |
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| Application Number | Title | Priority Date | Filing Date |
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| JP2000117348A Expired - Fee Related JP3629400B2 (en) | 2000-04-19 | 2000-04-19 | Hair manucia remover and hair manucia set comprising it |
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| US10434051B2 (en) | 2014-12-19 | 2019-10-08 | The Procter And Gamble Company | Shaping keratin fibers using arabinose and ethylene carbonate |
| US10568826B2 (en) | 2014-12-19 | 2020-02-25 | The Procter And Gamble Company | Shaping keratin fibres using a pretreatment and a protein crosslinking composition |
| US10729630B2 (en) | 2013-12-19 | 2020-08-04 | The Procter & Gamble Company | Shaping keratin fibres using an active agent comprising at least two functional groups selected from: —C(OH)- and —C(=O)OH |
| US10912726B2 (en) | 2013-12-19 | 2021-02-09 | The Procter And Gamble Company | Shaping keratin fibres using a reducing composition and a fixing composition |
| US10945931B2 (en) | 2015-06-18 | 2021-03-16 | The Procter And Gamble Company | Shaping keratin fibres using dialdehyde compounds |
| US11096879B2 (en) | 2013-12-19 | 2021-08-24 | The Procter And Gamble Plaza | Shaping keratin fibres using an active agent comprising a functional group selected from the group consisting of: -C(=O)-, -C(=O)-H, and -C(=O)-O- |
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| JP3629392B2 (en) * | 1999-12-09 | 2005-03-16 | ポーラ化成工業株式会社 | Hair manucia remover and hair manucia set with it as a component |
| JP6810525B2 (en) * | 2016-02-29 | 2021-01-06 | ホーユー株式会社 | Acid hair dye composition |
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| US10729630B2 (en) | 2013-12-19 | 2020-08-04 | The Procter & Gamble Company | Shaping keratin fibres using an active agent comprising at least two functional groups selected from: —C(OH)- and —C(=O)OH |
| US10912726B2 (en) | 2013-12-19 | 2021-02-09 | The Procter And Gamble Company | Shaping keratin fibres using a reducing composition and a fixing composition |
| US11096879B2 (en) | 2013-12-19 | 2021-08-24 | The Procter And Gamble Plaza | Shaping keratin fibres using an active agent comprising a functional group selected from the group consisting of: -C(=O)-, -C(=O)-H, and -C(=O)-O- |
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