JP2010270402A - 物品の磨耗性能を改良するコーティングおよび物品のコーティング方法 - Google Patents
物品の磨耗性能を改良するコーティングおよび物品のコーティング方法 Download PDFInfo
- Publication number
- JP2010270402A JP2010270402A JP2010202706A JP2010202706A JP2010270402A JP 2010270402 A JP2010270402 A JP 2010270402A JP 2010202706 A JP2010202706 A JP 2010202706A JP 2010202706 A JP2010202706 A JP 2010202706A JP 2010270402 A JP2010270402 A JP 2010270402A
- Authority
- JP
- Japan
- Prior art keywords
- coating
- article
- carbide particles
- range
- cobalt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 98
- 239000011248 coating agent Substances 0.000 title claims abstract description 83
- 238000007747 plating Methods 0.000 claims abstract description 42
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000126 substance Substances 0.000 claims abstract description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 4
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 claims abstract description 4
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims abstract description 4
- 235000011007 phosphoric acid Nutrition 0.000 claims abstract description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 4
- 239000011574 phosphorus Substances 0.000 claims abstract description 4
- 229910021446 cobalt carbonate Inorganic materials 0.000 claims abstract description 3
- 239000002245 particle Substances 0.000 claims description 59
- 238000000034 method Methods 0.000 claims description 22
- 229910017052 cobalt Inorganic materials 0.000 claims description 21
- 239000010941 cobalt Substances 0.000 claims description 21
- 239000011159 matrix material Substances 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 20
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 19
- UFGZSIPAQKLCGR-UHFFFAOYSA-N chromium carbide Chemical compound [Cr]#C[Cr]C#[Cr] UFGZSIPAQKLCGR-UHFFFAOYSA-N 0.000 claims description 15
- 229910003470 tongbaite Inorganic materials 0.000 claims description 15
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 14
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 14
- SIBIBHIFKSKVRR-UHFFFAOYSA-N phosphanylidynecobalt Chemical compound [Co]#P SIBIBHIFKSKVRR-UHFFFAOYSA-N 0.000 claims description 6
- 239000000446 fuel Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 3
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 3
- 229910001096 P alloy Inorganic materials 0.000 claims 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract description 13
- 229910052804 chromium Inorganic materials 0.000 abstract description 9
- 239000011651 chromium Substances 0.000 abstract description 9
- 238000009713 electroplating Methods 0.000 abstract description 2
- 239000002253 acid Substances 0.000 abstract 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 4
- 238000007772 electroless plating Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- QDWJUBJKEHXSMT-UHFFFAOYSA-N boranylidynenickel Chemical compound [Ni]#B QDWJUBJKEHXSMT-UHFFFAOYSA-N 0.000 description 3
- 229910000152 cobalt phosphate Inorganic materials 0.000 description 3
- ZBDSFTZNNQNSQM-UHFFFAOYSA-H cobalt(2+);diphosphate Chemical compound [Co+2].[Co+2].[Co+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O ZBDSFTZNNQNSQM-UHFFFAOYSA-H 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000001878 scanning electron micrograph Methods 0.000 description 3
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 230000004580 weight loss Effects 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 231100001261 hazardous Toxicity 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 238000007751 thermal spraying Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- OFNHPGDEEMZPFG-UHFFFAOYSA-N phosphanylidynenickel Chemical compound [P].[Ni] OFNHPGDEEMZPFG-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C26/00—Coating not provided for in groups C23C2/00 - C23C24/00
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D15/00—Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
- C25D15/02—Combined electrolytic and electrophoretic processes with charged materials
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
- C25D21/10—Agitating of electrolytes; Moving of racks
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/562—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of iron or nickel or cobalt
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/08—Electroplating with moving electrolyte e.g. jet electroplating
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/48—After-treatment of electroplated surfaces
- C25D5/50—After-treatment of electroplated surfaces by heat-treatment
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F15—FLUID-PRESSURE ACTUATORS; HYDRAULICS OR PNEUMATICS IN GENERAL
- F15B—SYSTEMS ACTING BY MEANS OF FLUIDS IN GENERAL; FLUID-PRESSURE ACTUATORS, e.g. SERVOMOTORS; DETAILS OF FLUID-PRESSURE SYSTEMS, NOT OTHERWISE PROVIDED FOR
- F15B15/00—Fluid-actuated devices for displacing a member from one position to another; Gearing associated therewith
- F15B15/08—Characterised by the construction of the motor unit
- F15B15/14—Characterised by the construction of the motor unit of the straight-cylinder type
- F15B15/1423—Component parts; Constructional details
- F15B15/1428—Cylinders
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F15—FLUID-PRESSURE ACTUATORS; HYDRAULICS OR PNEUMATICS IN GENERAL
- F15B—SYSTEMS ACTING BY MEANS OF FLUIDS IN GENERAL; FLUID-PRESSURE ACTUATORS, e.g. SERVOMOTORS; DETAILS OF FLUID-PRESSURE SYSTEMS, NOT OTHERWISE PROVIDED FOR
- F15B15/00—Fluid-actuated devices for displacing a member from one position to another; Gearing associated therewith
- F15B15/08—Characterised by the construction of the motor unit
- F15B15/14—Characterised by the construction of the motor unit of the straight-cylinder type
- F15B15/1423—Component parts; Constructional details
- F15B15/1457—Piston rods
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F41—WEAPONS
- F41A—FUNCTIONAL FEATURES OR DETAILS COMMON TO BOTH SMALLARMS AND ORDNANCE, e.g. CANNONS; MOUNTINGS FOR SMALLARMS OR ORDNANCE
- F41A21/00—Barrels; Gun tubes; Muzzle attachments; Barrel mounting means
- F41A21/22—Barrels which have undergone surface treatment, e.g. phosphating
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F15—FLUID-PRESSURE ACTUATORS; HYDRAULICS OR PNEUMATICS IN GENERAL
- F15B—SYSTEMS ACTING BY MEANS OF FLUIDS IN GENERAL; FLUID-PRESSURE ACTUATORS, e.g. SERVOMOTORS; DETAILS OF FLUID-PRESSURE SYSTEMS, NOT OTHERWISE PROVIDED FOR
- F15B2215/00—Fluid-actuated devices for displacing a member from one position to another
- F15B2215/30—Constructional details thereof
- F15B2215/305—Constructional details thereof characterised by the use of special materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9335—Product by special process
- Y10S428/934—Electrical process
- Y10S428/935—Electroplating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12576—Boride, carbide or nitride component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12639—Adjacent, identical composition, components
- Y10T428/12646—Group VIII or IB metal-base
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/1266—O, S, or organic compound in metal component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12931—Co-, Fe-, or Ni-base components, alternative to each other
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/256—Heavy metal or aluminum or compound thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/259—Silicic material
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrochemistry (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- General Engineering & Computer Science (AREA)
- Fluid Mechanics (AREA)
- Plasma & Fusion (AREA)
- Electroplating Methods And Accessories (AREA)
- Chemically Coating (AREA)
- Coating By Spraying Or Casting (AREA)
Abstract
【解決手段】 本発明は、コーティングするべき物品を備えるステップと、約180〜210g/lの塩化コバルト、約0.05〜2.0g/lの炭酸コバルト、約45〜55g/lのオルトリン酸、および約5.0〜15.0g/lの亜リン酸からなる化学組成を有するめっき浴溶液を設けるステップと、このめっき浴溶液と接触するように物品を配置して、物品にコーティングを積層するように電流を加えるステップと、を含む。
【選択図】図4
Description
本発明のコーティングを、Tribaly T−400プラズマ溶射コーティングと比較して、試験した。このTribaly T−400プラズマ溶射コーティングは、特定用途においてクロムめっきに代替する方法として現在用いられている。試験では、アクチュエータのボア部を有する試験用ハウジングをコーティングし、油圧アクチュエータの寿命を推定するように、ボア部内のピストンを十分な回数往復させた。この場合、アクチュエータのピストンヘッドを、炭化タングステン−コバルトコーティングを用いたHVOF(高速酸素燃料)でコーティングした。アクチュエータのボア部の母材は、チタンとし、ピストンヘッドのシールは、PTFEベースのエラストマーで被覆されたキャップシールとし、アクチュエータ試験用の流体は、ジェット燃料と一致する性質の脂肪族炭化水素とした。ピストンヘッドは、500ポンドの荷重でアクチュエータのボア部に対して側面荷重をかけ、ピストンヘッドのシール全体の圧力差は、2800psiだった。ピストンの移動は、−0.010〜+0.010インチのディザ(dithering)、および−0.25〜+0.25インチのストロークとした。Tribaloyコーティングは、コーティングの損壊によって、試験終了時に破損した。このような破損によって、ピストンヘッドの位置で、コーティングは0.0030〜0.0035インチ磨耗し、コーティングが薄い層にさけた箇所の残ったコーティングの厚みは、0.0005〜0.0010インチだった。PTFEキャップシールの重量損失は、0.1102gだった。(1)炭化クロム粒子を有するコーティング、および(2)炭化珪素粒子を有するコーティングを用いて、本発明のコーティングを試験した。図5は、炭化クロム含有コーティングを示す。図6は、炭化珪素含有コーティングを示す。これらの顕微鏡写真は、断面図の写真である。両方のコーティングは、400°F(約204°C)で、1時間熱処理した。同一の試験条件において、炭化クロム含有コーティングは、ピストンの接触部で、深さが0.000004インチの磨耗を示し、シールの重量損失は、0.0188gの減少となった。炭化珪素粒子含有コーティングは、ピストンヘッドで、0.000008インチの磨耗を示し、シールの重量損失は、0.1363gの増加となった。従って、炭化珪素粒子含有コーティングは、完璧な耐摩耗性を示した。炭化クロム含有コーティングは、特に、シール用途に適している。
Claims (29)
- 550〜1000HVの範囲の硬度のコバルト材料マトリックスと、
このコバルト材料マトリックス中の複数のカーバイド粒子と、
を含むことを特徴とする物品の磨耗性能を改良するコーティング。 - 上記コバルト材料マトリックスが、コバルト−リン合金を含むことを特徴とする請求項1に記載の物品の磨耗性能を改良するコーティング。
- 最終的なコーティング中の上記リンが、4.0〜6.0重量%の範囲で存在することを特徴とする請求項2に記載の物品の磨耗性能を改良するコーティング。
- 上記カーバイド粒子が、炭化クロム粒子および炭化珪素粒子からなる群から選択されることを特徴とする請求項1に記載の物品の磨耗性能を改良するコーティング。
- 上記カーバイド粒子が、15〜30体積%の範囲で存在することを特徴とする請求項1に記載の物品の磨耗性能を改良するコーティング。
- 上記カーバイド粒子の各々が、2.0〜10μmの範囲の平均粒子寸法を有することを特徴とする請求項1に記載の物品の磨耗性能を改良するコーティング。
- 上記コーティングが、550〜650HVの範囲の硬度を有することを特徴とする請求項1に記載の物品の磨耗性能を改良するコーティング。
- 上記コーティングが、650〜1000HVの範囲の硬度を有することを特徴とする請求項1に記載の物品の磨耗性能を改良するコーティング。
- 550〜1000HVの範囲の硬度を有するコバルト材料マトリックスと、このコバルト材料マトリックス中に複数のカーバイド粒子と、を備えるコーティングを有する物品。
- アクチュエータのボア部を含むことを特徴とする請求項9に記載の物品。
- プロペラのドーム部を含むことを特徴とする請求項9に記載の物品。
- プロペラのヨーク部を含むことを特徴とする請求項9に記載の物品。
- プロペラの反トルクアーム部を含むことを特徴とする請求項9に記載の物品。
- 燃料制御用ボア部を含むことを特徴とする請求項9に記載の物品。
- ガン・バレルを含むことを特徴とする請求項9に記載の物品。
- 上記コバルト材料マトリックスが、コバルト−リン合金を含むことを特徴とする請求項9に記載の物品。
- 最終的なコーティング中に上記リンが、4.0〜6.0重量%存在することを特徴とする請求項16に記載の物品。
- 上記カーバイド粒子が、炭化クロム粒子および炭化珪素粒子からなる群から選択されることを特徴とする請求項9に記載の物品。
- 上記カーバイド粒子が、15〜30体積%の範囲で存在することを特徴とする請求項9に記載の物品。
- 上記カーバイド粒子の各々が、2.0〜10μmの範囲の平均粒子寸法を有することを特徴とする請求項9に記載の物品。
- 上記コーティングが、550〜650HVの範囲の硬度を有することを特徴とする請求項9に記載の物品。
- 上記コーティングが、650〜1000HVの範囲の硬度を有することを特徴とする請求項9に記載の物品。
- コーティングするべき物品を設けるステップと、
約180〜210g/lの塩化コバルト、約0.05〜2.0g/lの炭酸コバルト、約45〜55g/lのオルトリン酸および約5.0〜15.0g/lの亜リン酸からなる化学組成を有するめっき浴溶液を備えるステップと、
上記めっき浴溶液と接触するように上記物品を配置して、上記物品に上記コーティングが積層するように電流を流すステップと、を備えるとともに、
上記めっき浴溶液を備えるステップが、上記めっき浴溶液内に、最終的なコーティング中にカーバイド粒子が約15〜30体積%となるのに、十分な量のカーバイド粒子を配置するステップをさらに備える
ことを特徴とする物品のコーティング方法。 - 約65〜85°Cの温度範囲に上記めっき浴を維持することを特徴とする請求項23に記載の物品のコーティング方法。
- 約0.7〜1.7のpHに上記めっき浴を維持することを特徴とする請求項23に記載の物品のコーティング方法。
- 上記電流を流すステップが、約45〜350アンペア/平方フィートの範囲の電流密度で流すことを特徴とする請求項23に記載の物品のコーティング方法。
- 上記電流を流すステップが、消耗可能なコバルト材料または不活性な材料から形成されるアノードを、上記めっき浴中に浸すことを特徴とする請求項23に記載の物品のコーティング方法。
- 上記めっき浴から上記物品を取り出し、約200〜400°Cの温度範囲、約1.0〜2.0時間の時間範囲で、上記めっきコーティングされた上記物品を熱処理することをさらに含む請求項23に記載の物品のコーティング方法。
- コーティング中に上記カーバイド粒子が均一に分散するように、上記めっき浴溶液内で上記カーバイド粒子を攪拌させることをさらに含む請求項23に記載の物品のコーティング方法。
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US76300906P | 2006-01-26 | 2006-01-26 | |
US60/763,009 | 2006-01-26 | ||
US11/653,525 US7897265B2 (en) | 2006-01-26 | 2007-01-16 | Low cost, environmentally favorable, chromium plate replacement coating for improved wear performance |
US11/653,525 | 2007-01-16 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2007014446A Division JP4644214B2 (ja) | 2006-01-26 | 2007-01-25 | 物品の磨耗性能を改良するコーティングおよび物品のコーティング方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2010270402A true JP2010270402A (ja) | 2010-12-02 |
JP5114539B2 JP5114539B2 (ja) | 2013-01-09 |
Family
ID=38285896
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2007014446A Active JP4644214B2 (ja) | 2006-01-26 | 2007-01-25 | 物品の磨耗性能を改良するコーティングおよび物品のコーティング方法 |
JP2010202706A Active JP5114539B2 (ja) | 2006-01-26 | 2010-09-10 | 物品の磨耗性能を改良するコーティングおよび物品のコーティング方法 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2007014446A Active JP4644214B2 (ja) | 2006-01-26 | 2007-01-25 | 物品の磨耗性能を改良するコーティングおよび物品のコーティング方法 |
Country Status (3)
Country | Link |
---|---|
US (2) | US7897265B2 (ja) |
EP (1) | EP1813697B1 (ja) |
JP (2) | JP4644214B2 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019187250A1 (ja) * | 2018-03-28 | 2019-10-03 | Jx金属株式会社 | Coアノード及びCoアノードを用いた電気Coめっき方法 |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070170068A1 (en) * | 2006-01-24 | 2007-07-26 | Usc, Llc | Electrocomposite coatings for hard chrome replacement |
US8202627B2 (en) * | 2006-01-24 | 2012-06-19 | Usc, Llc | Electrocomposite coatings for hard chrome replacement |
US8088498B2 (en) | 2007-05-23 | 2012-01-03 | Hamilton Sundstrand Corporation | Electro-formed sheath for use on airfoil components |
US7955721B2 (en) | 2008-01-16 | 2011-06-07 | Hamilton Sundstrand Corporation | Article having cobalt-phosphorous coating and method for heat treating |
US8177953B2 (en) * | 2008-12-17 | 2012-05-15 | Hamilton Sundstrand Corporation | Method and apparatus for evaluation of coated parts |
JP5722791B2 (ja) * | 2008-12-23 | 2015-05-27 | オーチス エレベータ カンパニーOtis Elevator Company | 昇降路内のシーブの表面再形成 |
US8852751B2 (en) * | 2009-09-25 | 2014-10-07 | Hamilton Sundstrand Corporation | Wear resistant device and process therefor |
US8991299B2 (en) | 2011-07-06 | 2015-03-31 | Hamilton Sundstrand Corporation | Reinforced thermoplastic actuator with wear resistant plastic liner |
US9890460B2 (en) * | 2013-09-27 | 2018-02-13 | United Technologies Corporation | Self-peening feedstock materials for cold spray deposition |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63197662A (ja) * | 1987-02-10 | 1988-08-16 | Teikoku Piston Ring Co Ltd | 通電転写型記録ヘツド |
JPS63206479A (ja) * | 1987-02-20 | 1988-08-25 | Matsushita Refrig Co | 摺動部材 |
JPH04268273A (ja) * | 1991-02-25 | 1992-09-24 | Seiko Epson Corp | 磁気テープカセットのテープガイドブロック |
JPH06316791A (ja) * | 1993-04-27 | 1994-11-15 | Teikoku Piston Ring Co Ltd | アルミニウム合金製摺動部材の表面処理方法 |
JP2000219997A (ja) * | 1998-11-26 | 2000-08-08 | Osaka Gas Co Ltd | タ―ビン燃焼部用部材 |
Family Cites Families (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2643221A (en) * | 1950-11-30 | 1953-06-23 | Us Army | Electrodeposition of phosphorusnickel and phosphorus-cobalt alloys |
US2594933A (en) * | 1950-12-07 | 1952-04-29 | Int Nickel Co | Process for electrodepositing hard nickel plate |
US3152974A (en) * | 1962-07-18 | 1964-10-13 | Hughes Aircraft Co | Electroplating magnetic cobalt alloys |
US3753667A (en) * | 1968-01-16 | 1973-08-21 | Gen Am Transport | Articles having electroless metal coatings incorporating wear-resisting particles therein |
US3637471A (en) * | 1969-01-29 | 1972-01-25 | Burroughs Corp | Method of electrodepositing ferromagnetic alloys |
CH623851A5 (ja) * | 1975-10-04 | 1981-06-30 | Akzo Nv | |
US4153453A (en) * | 1976-03-01 | 1979-05-08 | The International Nickel Company, Inc. | Composite electrodeposits and alloys |
US4305792A (en) * | 1977-12-21 | 1981-12-15 | Bristol Aerojet Limited | Processes for the electrodeposition of composite coatings |
JPS54145335A (en) * | 1978-05-02 | 1979-11-13 | Kobe Steel Ltd | Surface reforming of metal molding |
US4381227A (en) * | 1980-07-31 | 1983-04-26 | Norton Company | Process for the manufacture of abrasive-coated tools |
US4673468A (en) * | 1985-05-09 | 1987-06-16 | Burlington Industries, Inc. | Commercial nickel phosphorus electroplating |
US4528070A (en) * | 1983-02-04 | 1985-07-09 | Burlington Industries, Inc. | Orifice plate constructions |
US5966585A (en) * | 1984-09-18 | 1999-10-12 | Union Carbide Coatings Service Corporation | Titanium carbide/tungsten boride coatings |
JPS61177400A (ja) * | 1985-01-31 | 1986-08-09 | Riken Corp | ピストンリング |
DE3545826A1 (de) * | 1984-12-24 | 1986-06-26 | Kabushiki Kaisha Riken, Tokio/Tokyo | Kolbenring |
JPS63282295A (ja) * | 1987-05-15 | 1988-11-18 | Riken Corp | 耐摩耗表面層 |
JPS6445764U (ja) * | 1987-09-11 | 1989-03-20 | ||
FR2665185B1 (fr) | 1990-07-26 | 1992-10-16 | Snecma | Revetement anti-usure sur un substrat a base titane. |
US5178643A (en) * | 1991-05-21 | 1993-01-12 | Sunnen Products Company | Process for plating super abrasive materials onto a honing tool |
GB9216706D0 (en) * | 1992-08-06 | 1992-09-23 | Baj Ltd | Electrodeposited composite coatings |
JPH0633300A (ja) * | 1992-07-14 | 1994-02-08 | Seiko Epson Corp | 共析めっき方法 |
JP3333025B2 (ja) * | 1993-12-08 | 2002-10-07 | 日本パーカライジング株式会社 | 金属材料の電気複合めっき方法および装置 |
US5881972A (en) * | 1997-03-05 | 1999-03-16 | United Technologies Corporation | Electroformed sheath and airfoiled component construction |
AT404471B (de) * | 1997-04-28 | 1998-11-25 | Busatis Gmbh | Hartstoffbeschichtung für messer oder schneiden |
DE19741028C1 (de) * | 1997-09-18 | 1998-11-05 | Rheinmetall Ind Ag | Vorrichtung zum Härten der Innenkontur eines Waffenrohres mit Laserstrahlung |
US6607614B1 (en) * | 1997-10-20 | 2003-08-19 | Techmetals, Inc. | Amorphous non-laminar phosphorous alloys |
EP0984082A1 (de) * | 1998-09-01 | 2000-03-08 | Metallveredlung GmbH & Co. KG | Verfahren zum Beschichten von Werkstücken |
JP2003328184A (ja) * | 2002-05-16 | 2003-11-19 | Ebara Corp | 微細回路配線形成方法およびこれに用いる装置 |
BR0215787B1 (pt) | 2002-06-25 | 2013-12-03 | Processo para eletrodeposição catódica de um material metálico selecionado em um substrato permanente ou temporário e microcomponente produzido por um processo de eletrodeposição de pulso | |
JP3954958B2 (ja) * | 2002-11-26 | 2007-08-08 | 古河テクノリサーチ株式会社 | 抵抗層付き銅箔及び抵抗層付き回路基板材料 |
US20050112399A1 (en) * | 2003-11-21 | 2005-05-26 | Gray Dennis M. | Erosion resistant coatings and methods thereof |
US7815784B2 (en) * | 2004-06-23 | 2010-10-19 | Advanced Components & Materials, Inc. | Electro-composite coating for flexible seals and method of applying the same |
US20060251910A1 (en) | 2005-05-06 | 2006-11-09 | Lancsek Thomas S | Composite electroless plating |
US20070170068A1 (en) * | 2006-01-24 | 2007-07-26 | Usc, Llc | Electrocomposite coatings for hard chrome replacement |
-
2007
- 2007-01-16 US US11/653,525 patent/US7897265B2/en active Active
- 2007-01-25 JP JP2007014446A patent/JP4644214B2/ja active Active
- 2007-01-26 EP EP07250326.1A patent/EP1813697B1/en active Active
-
2010
- 2010-09-10 JP JP2010202706A patent/JP5114539B2/ja active Active
-
2011
- 2011-01-05 US US12/984,775 patent/US8246807B2/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63197662A (ja) * | 1987-02-10 | 1988-08-16 | Teikoku Piston Ring Co Ltd | 通電転写型記録ヘツド |
JPS63206479A (ja) * | 1987-02-20 | 1988-08-25 | Matsushita Refrig Co | 摺動部材 |
JPH04268273A (ja) * | 1991-02-25 | 1992-09-24 | Seiko Epson Corp | 磁気テープカセットのテープガイドブロック |
JPH06316791A (ja) * | 1993-04-27 | 1994-11-15 | Teikoku Piston Ring Co Ltd | アルミニウム合金製摺動部材の表面処理方法 |
JP2000219997A (ja) * | 1998-11-26 | 2000-08-08 | Osaka Gas Co Ltd | タ―ビン燃焼部用部材 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019187250A1 (ja) * | 2018-03-28 | 2019-10-03 | Jx金属株式会社 | Coアノード及びCoアノードを用いた電気Coめっき方法 |
KR20200128097A (ko) * | 2018-03-28 | 2020-11-11 | 제이엑스금속주식회사 | Co 애노드 및 Co 애노드를 사용한 전기 Co 도금 방법 |
KR102435667B1 (ko) | 2018-03-28 | 2022-08-25 | 제이엑스금속주식회사 | Co 애노드 및 Co 애노드를 사용한 전기 Co 도금 방법 |
Also Published As
Publication number | Publication date |
---|---|
EP1813697B1 (en) | 2014-07-16 |
US8246807B2 (en) | 2012-08-21 |
EP1813697A3 (en) | 2008-08-27 |
US7897265B2 (en) | 2011-03-01 |
US20070172695A1 (en) | 2007-07-26 |
US20110114495A1 (en) | 2011-05-19 |
JP4644214B2 (ja) | 2011-03-02 |
JP2007197831A (ja) | 2007-08-09 |
EP1813697A2 (en) | 2007-08-01 |
JP5114539B2 (ja) | 2013-01-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5114539B2 (ja) | 物品の磨耗性能を改良するコーティングおよび物品のコーティング方法 | |
US11242613B2 (en) | Electrodeposited, nanolaminate coatings and claddings for corrosion protection | |
CA2763985C (en) | Electrodeposited metallic materials comprising cobalt | |
US8367217B2 (en) | Electrodeposited metallic-materials comprising cobalt on iron-alloy substrates with enhanced fatigue performance | |
US8309233B2 (en) | Electrodeposited metallic-materials comprising cobalt on ferrous-alloy substrates | |
Rezagholizadeh et al. | Electroless Ni-P/Ni-BB 4 C duplex composite coatings for improving the corrosion and tribological behavior of Ck45 steel | |
TWI711720B (zh) | 金屬模具成型面之表面材料及金屬模具成型面之表面處理方法 | |
Manjunatha et al. | The effect of sealing on the wear behaviour of plasma sprayed Mo coating | |
Trebuňa et al. | Evaluating the Replacement of Galvanic Cr Coatings. | |
CN109423632B (zh) | 将结构坚硬的、耐磨的金属涂层沉积在衬底上 | |
Martinkovič et al. | The characterization of electroplated Cr coating | |
US20240026556A1 (en) | Articles comprising thermally stable, grain-refined alloys | |
CN101781786A (zh) | 一种陶瓷复合合金涂层油墨刮刀及其制造方法 | |
WO2024130228A1 (en) | Weapons and weapon components including surface coatings | |
KR101967422B1 (ko) | 금속 용사코팅된 알루미늄 소재 및 그 용사코팅방법 | |
Bidmead | Engineering Plating | |
Krishnamurthy et al. | Tribological behavior of plasma sprayed Al2O3 and ZrO2 5CaO coatings on Al-6061 substrate | |
JPH04246181A (ja) | チタン含有金属材料の表面処理方法 | |
Quets | Advanced Thermal Spray Coatings for Fatigue Sensitive Applications | |
Zha et al. | Study on Replacement of EHC Using HVOF Sprayed Coatings |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100910 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20100910 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20120925 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20121015 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20151019 Year of fee payment: 3 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5114539 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |