JP2009540565A - 半導体膜の選択的なエピタキシャル形成 - Google Patents
半導体膜の選択的なエピタキシャル形成 Download PDFInfo
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Abstract
【選択図】図5A
Description
本出願は、2006年6月7日付け出願の米国仮特許出願第60/811,703号に対する、米国特許法第119条(e)に基づく優先権の利益を主張する。
現在、混合基板のリセスされたソース/ドレイン領域等の露出された半導体ウィンドウ内に、引張歪みSi:C薄膜を選択的に形成するための技術が開発されている。このような選択的な形成は、例えば、(a)シリコン前駆物質としてトリシランを使用して、混合基板上へSi:C薄膜をブランケット堆積し、かつ(b)混合基板の絶縁体部分上へ結果的に形成される非エピタキシャル層を、選択的にエッチングすることによって達成することが可能である。任意選択として、ステップ(a)および(b)は、リセスされたソース/ドレイン領域上にエピタキシャル薄膜の目標厚さが達成されるまでサイクル的に反復される。
Claims (46)
- 半導体ウィンドウ内に半導体材料を選択的に形成する方法であって、
絶縁表面と単結晶半導体表面とを備える基板を、化学気相蒸着チャンバ内に設ける工程と、
前記絶縁表面上の非エピタキシャル半導体材料と前記単結晶半導体表面上のエピタキシャル半導体材料との厚さの比が約1.6:1未満となるように、前記基板の前記絶縁表面上および前記単結晶半導体表面上へ、半導体材料をブランケット堆積する工程と、
前記絶縁表面から前記非エピタキシャル半導体材料を選択的に除去する工程とを含み、
ブランケット堆積する前記工程と、選択的に除去する前記工程とを、前記化学気相蒸着チャンバ内で実行する方法。 - ブランケット堆積する前記工程と選択的に除去する前記工程とを複数のサイクルで反復する工程をさらに含み、各サイクルが、前記単結晶半導体表面上のエピタキシャル材料に厚さを追加する、請求項1記載の方法。
- 前記半導体材料は炭素ドープシリコンを含む、請求項2記載の方法。
- 前記炭素ドープシリコンは約0.1原子%〜3.6原子%の置換炭素を含む、請求項3記載の方法。
- 前記単結晶半導体表面はリセスされたソース/ドレイン領域を含み、前記エピタキシャル材料は中間のチャネル領域上へ応力を加える、請求項2記載の方法。
- 選択的に除去する前記工程は、前記リセスされたソース/ドレイン領域の側壁からエピタキシャル材料を除去し、且つ、前記リセスされたソース/ドレイン領域の底部にエピタキシャル材料を残す工程を含む、請求項5記載の方法。
- ブランケット堆積する前記工程は、非選択的に堆積する工程を含む、請求項2記載の方法。
- ブランケット堆積する前記工程は、ハロゲン化物を用いずに気相ソースをフローする工程を含む、請求項2記載の方法。
- ブランケット堆積する前記工程は、前記絶縁表面上へ、圧倒的に非晶質である半導体材料を形成する工程を含む、請求項2記載の方法。
- ブランケット堆積する前記工程の各々は、前記絶縁表面上の非エピタキシャル物質と前記単結晶半導体表面上のエピタキシャル材料との厚さの比を、約1.0:1〜約1.3:1で堆積する、請求項2記載の方法。
- 前記エピタキシャル材料は、インサイチュ燐および炭素ドープシリコンを含む、請求項2記載の方法。
- 前記エピタキシャル材料は約0.4mΩ・cm〜2mΩ・cmの抵抗率を有する、請求項11記載の方法。
- ブランケット堆積する前記工程と選択的に除去する工程とは共に、互いに±10℃の範囲内で実行される、請求項2記載の方法。
- ブランケット堆積する前記工程と選択的に除去する工程とは共に、互いに±5℃の範囲内で実行される、請求項2記載の方法。
- 選択的に除去する前記工程は、ゲルマニウムソースおよびハロゲン化物ソースを前記化学気相蒸着チャンバ内へフローする工程を含む、請求項1記載の方法。
- ブランケット堆積する前記工程は、トリシランを前記化学気相蒸着チャンバ内へフローする工程を含む、請求項1記載の方法。
- ブランケット堆積する前記工程は、適切な炭素ソースおよび適切な電気的ドーパントソースを、前記化学気相蒸着チャンバ内へフローする工程をさらに含む、請求項16記載の方法。
- エピタキシャル半導体材料を選択的に形成する方法であって、
基板の単結晶半導体領域上へエピタキシャル材料を形成し、かつ前記基板の絶縁領域上へ非エピタキシャル材料を形成するために、半導体材料をブランケット堆積する工程と、
ブランケット堆積された前記半導体材料を、ハロゲン化物ソースおよびゲルマニウムソースを含むエッチング化学物質に露出することにより、前記絶縁領域上から前記非エピタキシャル材料を選択的に除去する工程と、
ブランケット堆積する前記工程と選択的に除去する前記工程とを、少なくとも一度反復する工程とを含む方法。 - ブランケット堆積する前記工程は、前記基板を収容する化学気相蒸着チャンバ内へトリシランをフローする工程を含む、請求項18記載の方法。
- ブランケット堆積する前記工程は、各サイクルにおいて約1nm〜10nmで堆積する工程を含む、請求項18記載の方法。
- ブランケット堆積する前記工程および選択的に除去する工程は、化学気相蒸着チャンバ内で実行される等温および等圧プロセスである、請求項18記載の方法。
- 前記半導体領域はリセスされた領域を含む、請求項18記載の方法。
- 前記リセスされた領域内の前記エピタキシャル材料は、前記基板の隣接する領域に歪みを加える、請求項22記載の方法。
- 前記半導体材料は炭素ドープシリコンを含む、請求項18記載の方法。
- 基板上の選択される位置にシリコン含有材料を形成する方法であって、
単結晶半導体の露出されたウィンドウを複数のフィールド分離領域間に有する基板を設ける工程と、
前記基板上へトリシランをフローすることにより、単結晶材料の前記ウィンドウおよび前記フィールド分離領域上へ、シリコン含有材料をブランケット堆積する工程と、
前記フィールド分離領域上から前記シリコン含有材料を選択的に除去する工程と、
ブランケット堆積する前記工程と選択的に除去する前記工程とを複数回のサイクルで反復する工程とを含む方法。 - 前記シリコン含有材料をブランケット堆積する前記工程は、前記基板上へ、トリシランを用いて炭素ソース蒸気をフローする工程を含み、前記シリコン含有材料は炭素ドープシリコンを含む、請求項25記載の方法。
- 選択的に除去する前記工程は、単結晶半導体の前記ウィンドウ上からエピタキシャル材料を除去する工程よりも速い速度で、前記フィールド分離領域上から非エピタキシャル材料をエッチングする工程を含む、請求項26記載の方法。
- 前記ウィンドウはリセスを備え、選択的に除去する前記工程は、前記リセスの側壁からエピタキシャル材料を除去し、且つ、前記リセスの底部にエピタキシャル材料を残す工程をさらに含む、請求項27記載の方法。
- 選択的に除去する前記工程は、前記基板をハロゲン化物エッチャントおよびゲルマニウムソースに露出する工程を含む、請求項25記載の方法。
- 単結晶半導体の前記ウィンドウは、前記フィールド分離領域の上面に対してリセスを備える、請求項25記載の方法。
- ブランケット堆積する前記工程および選択的に除去する前記工程は、等温および/または等圧条件下で実行される、請求項25記載の方法。
- ブランケット堆積する前記工程および選択的に除去する前記工程は、前記シリコン含有材料の、毎分約4nm〜11nmの正味の成長速度を提供する、請求項25記載の方法。
- エピタキシャル半導体材料を選択的に形成する方法であって、
絶縁領域と当該絶縁領域内に形成される半導体ウィンドウとを、基板に提供する工程と、
前記絶縁領域上へ非晶質半導体材料を堆積し、かつ前記半導体ウィンドウ上へエピタキシャル半導体材料を堆積する工程と、
前記絶縁領域上から前記非晶質半導体材料を選択的にエッチングし、且つ、前記半導体ウィンドウ内に少なくとも幾分かのエピタキシャル半導体材料を残す工程と、
ブランケット堆積する前記工程と選択的に除去する前記工程とを、複数回のサイクルで反復する工程とを含む方法。 - 前記半導体ウィンドウは、前記絶縁領域の上面から下方にリセスを備え、反復する前記工程は、前記リセスをエピタキシャル半導体材料で充填する工程を含む、請求項33記載の方法。
- 堆積する前記工程は、前記リセスを炭素ドープシリコンで充填して、リセスされたソース/ドレイン構造を形成する工程を含む、請求項34記載の方法。
- 堆積する前記工程は、前記リセスされたソース/ドレイン構造へ、電気的ドーパントをインサイチュ供給する工程をさらに含む、請求項35記載の方法。
- 堆積する前記工程は、炭素ドープシリコンを形成する工程を含む、請求項35記載の方法。
- 堆積する前記工程は、前記炭素ドープシリコン上へ、炭素フリーのキャップ層を形成する工程をさらに含む、請求項37記載の方法。
- 反復する前記工程は、隆起されたソース/ドレイン構造を形成する工程を含む、請求項33記載の方法。
- 堆積する前記工程は、燐および炭素ドープシリコンを堆積する工程を含む、請求項33記載の方法。
- 前記半導体ウィンドウは、前記絶縁領域の上面から下方にリセスを備え、前記リセス内の前記エピタキシャル半導体材料は、隣接する領域に横方向の引張歪みを加える、請求項33記載の方法。
- 前記隣接する領域はトランジスタチャネル領域である、請求項41記載の方法。
- 選択的に除去する前記工程は、前記リセスの側壁からエピタキシャル材料を除去し、且つ、前記リセスの底部にエピタキシャル材料を残す工程をさらに含む、請求項41記載の方法。
- 選択的にエッチングする前記工程は、前記基板を塩素ソースおよびゲルマニウムソースに露出する工程を含む、請求項33記載の方法。
- 堆積の各工程において、前記絶縁領域上の非晶質半導体材料と前記半導体ウィンドウ上の前記エピタキシャル半導体材料との厚さの比が約1.6:1未満である、請求項33記載の方法。
- 前記比は約1.0:1〜1.3:1である、請求項45記載の方法。
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US20070287272A1 (en) | 2007-12-13 |
KR101544931B1 (ko) | 2015-08-17 |
US8278176B2 (en) | 2012-10-02 |
US9312131B2 (en) | 2016-04-12 |
TW200805460A (en) | 2008-01-16 |
US20120244688A1 (en) | 2012-09-27 |
CN101454874B (zh) | 2011-03-23 |
KR20140089404A (ko) | 2014-07-14 |
WO2007145758A2 (en) | 2007-12-21 |
WO2007145758A3 (en) | 2008-02-07 |
EP2022083A2 (en) | 2009-02-11 |
KR20090037424A (ko) | 2009-04-15 |
TWI404123B (zh) | 2013-08-01 |
KR101521878B1 (ko) | 2015-05-20 |
CN101454874A (zh) | 2009-06-10 |
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