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GB1100398A - Copolymers of vinylidene chloride and acrylic esters and an application thereof - Google Patents

Copolymers of vinylidene chloride and acrylic esters and an application thereof

Info

Publication number
GB1100398A
GB1100398A GB4068265A GB4068265A GB1100398A GB 1100398 A GB1100398 A GB 1100398A GB 4068265 A GB4068265 A GB 4068265A GB 4068265 A GB4068265 A GB 4068265A GB 1100398 A GB1100398 A GB 1100398A
Authority
GB
United Kingdom
Prior art keywords
copolymers
vinylidene chloride
application
acrylic esters
added
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4068265A
Inventor
Brian George Elgood
Graham Brown
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Scott Bader Co Ltd
Original Assignee
Scott Bader Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Scott Bader Co Ltd filed Critical Scott Bader Co Ltd
Priority to GB4068265A priority Critical patent/GB1100398A/en
Priority to DE19661645385 priority patent/DE1645385A1/en
Priority to NL6613418A priority patent/NL6613418A/xx
Priority to FR77387A priority patent/FR1501047A/en
Publication of GB1100398A publication Critical patent/GB1100398A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/02—Monomers containing chlorine
    • C08F214/04—Monomers containing two carbon atoms
    • C08F214/08—Vinylidene chloride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

Copolymers of 40-75% molar vinylidene chloride and 60-25% acrylic ester are prepared by emulsion polymerization using "delayed addition" technique; less than 20% of the monomers is added initially and the remainder added over a period exceeding one hour. The surface-active agent may also be added step-wise. In some examples a small amount of acrylamide with or without acrylic acid is also present and in another a mixture of two esters, methyl and butyl acrylates, is used. Sodium persulphate and sodium metabisulphite are used as catalyst. The polymer emulsion is used for coating and a paint composition exemplified also contains titanium dioxide, tetrasodium pyrophosphate and polyvinylalcohol.
GB4068265A 1965-09-23 1965-09-23 Copolymers of vinylidene chloride and acrylic esters and an application thereof Expired GB1100398A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
GB4068265A GB1100398A (en) 1965-09-23 1965-09-23 Copolymers of vinylidene chloride and acrylic esters and an application thereof
DE19661645385 DE1645385A1 (en) 1965-09-23 1966-09-16 Process for the preparation of a copolymer by emulsion polymerization of vinylidene chloride and one or more acrylic esters
NL6613418A NL6613418A (en) 1965-09-23 1966-09-22
FR77387A FR1501047A (en) 1965-09-23 1966-09-23 Copolymer of vinylidene chloride and acrylic esters

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB4068265A GB1100398A (en) 1965-09-23 1965-09-23 Copolymers of vinylidene chloride and acrylic esters and an application thereof

Publications (1)

Publication Number Publication Date
GB1100398A true GB1100398A (en) 1968-01-24

Family

ID=10416103

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4068265A Expired GB1100398A (en) 1965-09-23 1965-09-23 Copolymers of vinylidene chloride and acrylic esters and an application thereof

Country Status (1)

Country Link
GB (1) GB1100398A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0034952A2 (en) * 1980-02-25 1981-09-02 EASTMAN KODAK COMPANY (a New Jersey corporation) Heat-developable electrically activatable recording material
US5424347A (en) * 1989-12-28 1995-06-13 American National Can Company MA-PVDC formulations, films, and structures which maintain high barrier properties after retorting

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0034952A2 (en) * 1980-02-25 1981-09-02 EASTMAN KODAK COMPANY (a New Jersey corporation) Heat-developable electrically activatable recording material
EP0034952A3 (en) * 1980-02-25 1982-12-15 EASTMAN KODAK COMPANY (a New Jersey corporation) Heat-developable electrically activatable recording material
US5424347A (en) * 1989-12-28 1995-06-13 American National Can Company MA-PVDC formulations, films, and structures which maintain high barrier properties after retorting

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