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FR3029913B1 - Procede de crotonisation de 2-octanone - Google Patents

Procede de crotonisation de 2-octanone Download PDF

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Publication number
FR3029913B1
FR3029913B1 FR1462490A FR1462490A FR3029913B1 FR 3029913 B1 FR3029913 B1 FR 3029913B1 FR 1462490 A FR1462490 A FR 1462490A FR 1462490 A FR1462490 A FR 1462490A FR 3029913 B1 FR3029913 B1 FR 3029913B1
Authority
FR
France
Prior art keywords
octanone
cutting process
crotonization
reaction
octanol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1462490A
Other languages
English (en)
Other versions
FR3029913A1 (fr
Inventor
Jean-Philippe Gillet
Muriel Saintagne
Laurie Verne
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Arkema France SA
Carbonisation et Charbons Actifs CECA SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France SA, Carbonisation et Charbons Actifs CECA SA filed Critical Arkema France SA
Priority to FR1462490A priority Critical patent/FR3029913B1/fr
Priority to CN201510940432.5A priority patent/CN105688984B/zh
Publication of FR3029913A1 publication Critical patent/FR3029913A1/fr
Application granted granted Critical
Publication of FR3029913B1 publication Critical patent/FR3029913B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/88—Separation; Purification; Use of additives, e.g. for stabilisation by treatment giving rise to a chemical modification of at least one compound
    • C07C29/92—Separation; Purification; Use of additives, e.g. for stabilisation by treatment giving rise to a chemical modification of at least one compound by a consecutive conversion and reconstruction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/54—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of compounds containing doubly bound oxygen atoms, e.g. esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/373—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by introduction of functional groups containing oxygen only in doubly bound form

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La présente invention concerne l'utilisation d'un phénate de métal alcalin comme catalyseur de la réaction de crotonisation de 2-octanone, ainsi que le procédé de crotonisation de 2-octanone dans un mélange réactionnel comprenant du 2-octanol.
FR1462490A 2014-12-16 2014-12-16 Procede de crotonisation de 2-octanone Active FR3029913B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR1462490A FR3029913B1 (fr) 2014-12-16 2014-12-16 Procede de crotonisation de 2-octanone
CN201510940432.5A CN105688984B (zh) 2014-12-16 2015-12-16 用于2-辛酮的丁烯醛化的方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1462490 2014-12-16
FR1462490A FR3029913B1 (fr) 2014-12-16 2014-12-16 Procede de crotonisation de 2-octanone

Publications (2)

Publication Number Publication Date
FR3029913A1 FR3029913A1 (fr) 2016-06-17
FR3029913B1 true FR3029913B1 (fr) 2018-07-06

Family

ID=52988179

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1462490A Active FR3029913B1 (fr) 2014-12-16 2014-12-16 Procede de crotonisation de 2-octanone

Country Status (2)

Country Link
CN (1) CN105688984B (fr)
FR (1) FR3029913B1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115974649B (zh) * 2022-12-28 2024-06-21 丰益高分子材料（连云港）有限公司 一种仲辛醇的制造方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2074528A (en) * 1935-02-06 1937-03-23 Rohm & Haas Purification of capryl alcohol
GB585316A (en) * 1944-06-01 1947-02-04 Nat Oil Prod Co Improvements in or relating to the purification of capryl alcohol
CN1114490C (zh) * 2000-05-12 2003-07-16 石油大学(华东) 一种仲辛酮加氢制仲辛醇的方法及催化剂
CN1151112C (zh) * 2000-07-13 2004-05-26 中国石油化工股份有限公司 从有机混合物中提纯2-辛醇和2-辛酮的方法
CN100494135C (zh) * 2005-12-29 2009-06-03 邵阳市化工研究所 一种甲庚醇脱除硫化物的方法

Also Published As

Publication number Publication date
CN105688984B (zh) 2019-06-18
FR3029913A1 (fr) 2016-06-17
CN105688984A (zh) 2016-06-22

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