FR2992208A1 - COSMETIC COMPOSITION COMPRISING INSOLUBLE SOLID PARTICLES, A NON-LIQUID FATTY BODY, A SURFACTANT - Google Patents

Abstract

The present invention relates to a cosmetic composition comprising at least one non-liquid fatty substance, at least one surfactant, solid particles that are insoluble in water, the weight ratio surfactant (s) / insoluble solid particles being greater than or equal to 1, the content total weight of surfactant (s) and insoluble solid particles being less than or equal to 3% relative to the total weight of the composition.

Description

The present invention relates to a cosmetic composition comprising insoluble solid particles, at least one non-liquid fatty substance, at least one surfactant, as well as the use of a cosmetic composition comprising at least one non-liquid solid substance. such a composition for the hair treatment, in particular for the treatment of keratinous fibers and in particular for maintaining / shaping the hair. Hair styling products are mainly in the form of more or less viscous pastes that are applied to the hair with the hands.

It is generally sought to obtain repositionable hairstyles with or without an aesthetic effect such as a matifying or shiny effect. However, styling waxes are often sticky and greasy. EP 2 394 631 describes a matte styling composition comprising waxes, surfactants and fillers, the composition leaving no visible residue after drying. This type of composition, however, leads to a residual sticky effect on the hair and elimination with water is not easy. In addition, the fixing level is low. There is therefore a real need to have a cosmetic composition that has good styling and cosmetic properties, and that overcomes the disadvantages mentioned above. The Applicant has discovered that by combining insoluble solid particles, a non-liquid fat and a surfactant in a particular weight ratio it was possible to obtain styling waxes with improved use qualities and improved styling performance.

The subject of the present invention is therefore a cosmetic composition, at least one non-liquid fatty substance, at least one surfactant, solid particles that are insoluble in water, different from fatty substances, the weight ratio surfactant (s) / insoluble solid particles being greater than or equal to 1, the total content by weight of surfactant (s) and insoluble solid particles being less than or equal to 3% relative to the total weight of the composition. The cosmetic composition is preferably a styling and / or conditioning composition for keratinous fibers, in particular for styling keratinous fibers, in particular human keratinous fibers such as the hair. The invention also relates to a process for the cosmetic treatment of keratin fibers, in particular for maintaining and / or shaping keratinous fibers, using the cosmetic composition as defined above.

The subject of the invention is also the use of a composition as defined above for the hair treatment, in particular for the treatment of keratin fibers and in particular for maintaining and / or shaping the hair. The composition obtained makes it possible to obtain a good level of fixation of the hairstyle and the hair is not very tacky and has a smooth feel, without residues. The composition is easily removed with water. Other objects, features, aspects and advantages of the invention will emerge even more clearly on reading the description and examples which follow.

In what follows the expression "at least one" is equivalent to the expression "one or more". The composition according to the invention comprises solid particles that are insoluble in water. For the purposes of the present invention, the term "water insoluble compound" means a compound whose solubility in water at 25 ° C. and at atmospheric pressure is less than 0.1%, better still less than 0.001%. Advantageously, the particle or particles have a number-average primary size ranging from 0.001 to 1000 μm, preferably from 0.01 to 700 μm, more preferably from 0.5 to 200 μm.

For the purposes of the present invention, the term "primary particle size" means the maximum dimension that can be measured between two diametrically opposite points of an individual particle. The size of the particles can be determined by transmission electron microscopy or from the measurement of the specific surface area by the BET method or from a laser granulometry. Preferably, the particles of the invention are not colored pigments. The particles used in the cosmetic composition may have different shapes, for example a form of spheres, flakes, needles or platelets and preferably they are substantially spherical.

The particle or particles may be solid, hollow or porous. When the particles are hollow, they comprise at least one continuous envelope (or a surface layer) and at least one cavity. The envelope of the particles is preferably flexible to lend itself to mechanical deformation. For the purposes of the present invention, the term "porous particles", particles having a structure having pores in varying number and size. Porosity associated with particle size can be characterized quantitatively from the measurement of specific surface area by the BET method. Preferably, the porous particles have a specific surface greater than or equal to 1 m 2 / g, preferably greater than or equal to 2 m 2 / g, and even more preferably greater than or equal to 4 m 2 / g. The specific surface is determined according to the BET method (BRUNAUEREMMET-TELLER) described in "The Journal of the American Chemical Society", vol.60, page 309 February 1938 and corresponds to the international standard ISO 5794/1 (Appendix D). The specific surface area determined by the BET method corresponds to the total specific surface, including micropores, of the organic particles considered. The composition comprises particles of one or more polymeric organic compounds and / or particles of one or more inorganic compounds.

The particles of one or more polymeric organic compounds may consist of crosslinked polymers or not. These polymers are preferably in a vitreous state, that is to say they have a glass transition temperature significantly higher than the ambient temperature or the temperature of use (for example the temperature of the human body). When the particles of one or more organic compounds are hollow, they comprise at least one continuous envelope (or a surface layer) and at least one cavity. The envelope of the particles is preferably flexible to lend itself to mechanical deformation. It generally comprises at least one homopolymer or copolymer polymer formed from ethylenically unsaturated monomers. The monomers used may in particular be esters of methacrylic or acrylic acid, such as methyl acrylate and methacrylate, vinylidene chloride, acrylonitrile, styrene and its derivatives.

The particles of one or more organic compounds used in the cosmetic composition according to the invention may be chosen from polyamide powders, acrylic polymer powders, especially crosslinked sodium polyacrylate, polymethyl methacrylate, acrylic copolymer powders. , especially of polymethyl methacrylate / ethylene glycol dimethacrylate, allyl polymethyl methacrylate / ethylene glycol dimethacrylate, ethylene glycol dimethacrylate / lauryl methacrylate copolymer, polyacrylate / alkyl acrylate, polystyrene powders, powders of polyethylene, especially polyethylene / acrylic acid, silicone resin microbeads. By way of non-limiting example, the following may be mentioned as organic particles according to the invention: polyamide powders (Nylon 0), for example those marketed under the names "ORGASOL 4000" and "ORGASOL 2002 UD NAT COS 204" By the company ATOCHEM, the acrylic polymer powders, in particular crosslinked sodium polyacrylate, such as for example those sold under the name ASAP 10 2000 by the company CHEMOAL or HYSORB M7055 for the BASF company, of polymethyl methacrylate, as for example examples those sold under the name "COVABEAD LH85" "COVABEAD PMMA" by the company SENSIENT or those sold under the name "MICROPEARL MHB", "MICROPEARLO M 100", "MICROPEARLO M 310" marketed by the company MATSUMOTO, - powders acrylic copolymers, especially polymethyl methacrylate / ethylene glycol dimethacrylate, as they are sold under the name "Dow Corning 5640 Microsponge Skin Oil Adsorber" by the company Dow Corning, or those sold under the name "Ganzpearl GMP-0800" by the company Aica Kogyo, of allyl polymethacrylate / ethylene dimethacrylate glycol, such as those sold under the name "Polypropore L200" or "Polypropore E200" marketed by AMCOL, of ethylene glycol dimethacrylate / lauryl methacrylate copolymer, such as those sold by "Polytrap 6603" by the company Dow Corning, polyacrylate / ethylhexylacrylate such as those sold under the name "TECHPOLYMER ACX 8060" by the company SEKISUI, - polystyrene powders such as those sold under the name "POLYSPHERE 3000 SPI" by the company PRESPERESE, 30 - polystyrene powders / dinvinylbenzene, such as those sold under the name "TECHPOLYM" ER SBX8 by the company SEKISUI, the styrene / acrylate copolymer powders, for instance those sold under the name Sunspheres POVVDER by the company Rohm & Haas, the polyethylene powders, in particular the polyethylene / acrylic acid powders marketed under the name "FLOBEADS" by the company SUMITOMO, or the polyethylene balls marketed under the name "MICROPOLY 220 L" by the company MICRO POVVDERS, - silicone resin microbeads, such as those sold under the names "TOSPEARL" by the company TOSHIBA SILICONE , in particular "TOSPEARL® 240A" and "TOSPEARL® 120A", - microspheres of expanded terpolymer of vinylidene chloride, acrylonitrile and methyl methacrylate, sold under the trademark EXPANCEL by Nobel Casco and in particular under the references 551 DE 12, 551 DE 20, 551 DE 50, 461 DE 50 and 642 VVE 50, 551 DE 80. Preferably The organic particles used in the composition according to the invention are chosen from polyamide powders, crosslinked sodium polyacrylate powders and polyethylene powders, and polymethyl methacrylate powders. The organic particle (s) may optionally be surface treated with a hydrophobic treating agent. Thus, the organic particles can be rendered hydrophobic by coating or chemical grafting by products such as: silicones, such as meticones or dimethicones, amino acids, N-acyl amino acids or their salts, metal soaps such as aluminum dimyristate, hydrogenated tallow glutamate aluminum salt, fluorinated derivatives, such as, for example, perfluoroalkyl phosphates, perfluoroalkyl silanes, hexafluoropropylene polyoxides, polyorganosiloxanes comprising perfluoroalkyl perfluoropolyether groups, lecithin, isopropyl triisostearoyl titanate, - fatty acids such as stearic acid. The term alkyl mentioned in the compounds mentioned above may in particular denote a linear, branched or cyclic alkyl group comprising from 1 to 30 carbon atoms, in particular from 5 to 16 carbon atoms. The N-acyl amino acids may comprise an acyl group comprising from 8 to 22 carbon atoms, for example a 2-ethyl hexanoyl, caproyl, lauroyl, myristoyl, palmitoyl, stearoyl and cocoyl group. The salts of these compounds may be aluminum, magnesium, calcium, zirconium, sodium, or potassium zinc salts. The amino acid can be, for example, lysine, glutamic acid or alanine.

By way of example, mention may be made of microspheres of methyl poly methacrylate coated with isopropyl triisostearyl titanate of size 2-15 pm marketed by Kobo under the reference BPA-515.

The particles of one or more inorganic compounds used in the cosmetic composition according to the invention may be chosen from metal particles, oxides, inorganic salts, carbides, nitrides, sulphides and hydroxides. By metal particles is meant particles formed by metals selected from alkaline earth metals, transition metals, rare earth metals and alloys of these metals. The metals used are, in particular, boron, aluminum, copper, cadmium, selenium, silver, gold, indium, iron, platinum, nickel, molybdenum, silicon, titanium, tungsten, antimony, palladium, zinc, tin and alloys of these metals. Among these metals, gold, silver, platinum, cadmium, selenium and the alloys of these metals are particularly preferred. The particles of one or more inorganic compounds may also be oxides. The oxides of the elements of columns 1 to 14 of the periodic table of elements may be mentioned. In particular, there may be mentioned the oxides of titanium, zinc, cerium, zirconium, aluminum and bismuth oxychloride. Among these compounds, zinc oxide is particularly preferred. Particles of one or more inorganic compounds can be inorganic salts. In particular mention may be made of barium sulfate, calcium carbonate, calcium sulfate, calcium phosphate and magnesium hydrocarbonate.

Among these compounds, calcium carbonate is preferred. The particles of one or more inorganic compounds may be carbides, nitrides, borides, sulfides and hydroxides. Among the particles of one or more mineral compounds belonging to the species described above, mention may also be made of clays, silicates, alumina, silica, kaolin and hydroxyapatite. In particular, the usable silicas may be natural and untreated. The silicas proposed under the names Silliston N85, Silliston N87, Sillitin N82, Sillitin V85 and Sillitin V88 by the company Hoffmann Mineral or Sunsil 130 by the company SUNJIN CHEMICAL, MSS-500-3 H by the company Kobo can thus be mentioned. SUNSPHERE H 51 by the company AGC SI-TECH, the hollow particles of amorphous silica of ellipsoidal shape marketed by Kobo under the reference silica shells. They can be fumed. The fumed silicas can be obtained by high temperature hydrolysis of a volatile silicon compound in an oxyhydrogen flame, producing a finely divided silica. This process makes it possible in particular to obtain hydrophilic silicas which have a large number of silanol groups on their surface. It is possible to chemically modify the surface of said silica, by chemical reaction generating a decrease in the number of silanol groups. In particular, it is possible to substitute silanol groups with hydrophobic groups: a hydrophobic silica is then obtained. The hydrophobic groups may be: (a) trimethylsiloxyl groups, which are especially obtained by treatment of fumed silica in the presence of hexamethyldisilazane. Silicas thus treated are called "silica silylate" according to the CTFA (6th edition, 1995). ; (b) dimethylsilyloxyl or polydimethylsiloxane groups, which are especially obtained by treating fumed silica in the presence of polydimethylsiloxane or dimethyldichlorosilane. Silicas thus treated are known as "Silica dimethyl silylate" according to the CTFA (6th edition, 1995).

In particular, among the hydrophobic silicas, mention may be made of silica aerogels. Aerogels are ultra-light porous materials, the first of which were made by Kristler in 1932. They are generally synthesized by a sol-gel process in a liquid medium and then dried by extraction of a supercritical fluid. The most commonly used supercritical fluid is supercritical CO2. This type of drying avoids the contraction of the pores and the material. Other types of drying also make it possible to obtain porous materials from gel, namely (i) drying by freeze drying, consisting of solidifying at low temperature the gel and then subliming the solvent and (ii) drying by evaporation . The materials thus obtained are called cryogels and xerogels respectively. The sol-gel process and the various dryings are described in detail in Brinker CJ, and Scherer G.VV., Sol-Gel Science: New York: Academic Press, 1990. By "hydrophobic silica" is meant any silica whose surface is treated with silylating agents, for example with halogenated silanes such as alkylchlorosilanes, siloxanes, in particular dimethylsiloxanes such as hexamethyldisiloxane, or silazanes, so as to functionalize the OH groups by Si silyl groups. Rn, for example trimethylsilyl groups. Preferably, the hydrophobic airgel particles that can be used in the present invention advantageously have a specific surface per unit mass (SM) ranging from 500 to 1500 m 2 / g, preferably from 600 to 1200 m 2 / g and better still from 600 to at 800 m 2 / g and / or have an oil absorption capacity measured at VVET POINT ranging from 5 to 18 ml / g of particles, preferably from 6 to 15 ml / g and better still from 8 to 12 ml / g. . The absorption capacity measured at VVet Point, and denoted VVp, corresponds to the amount of oil that must be added to 100 g of particles to obtain a homogeneous paste. It is measured according to the so-called VVet Point method or method for determining the setting of powder oil according to the principle described in standard NF T 30-022. It corresponds to the quantity of oil adsorbed on the available surface of the powder and / or absorbed by the powder by measuring the VVet Point, described below: A quantity m = 2 g of powder is placed on a glass plate and then the oil (isononyl isononanoate) is added dropwise. After addition of 4 to 5 drops of oil in the powder, mixing is carried out with a spatula and oil is added until the formation of oil and powder conglomerates. From this moment, the oil is added one drop at a time and then triturated with the spatula. The addition of oil is stopped when a firm and smooth paste is obtained. This paste should be spread on the glass plate without cracks or lumps. The volume Vs (expressed in ml) of oil used is then noted. The oil intake corresponds to the ratio Vs / m.

The hydrophobic silica airgel particles used according to the present invention are preferably silylated silica airgel particles (INCI name silica silylate). The preparation of hydrophobic silica airgel particles surface-modified by silylation is further described in US 7,470,725.

Hydrophobic silica aerogels particles surface-modified with trimethylsilyl groups will be used in particular. The hydrophobic airgel particles which can be used in the present invention advantageously have a size, expressed as the average diameter (D [0.5]), of less than 1500 μm and preferably of from 1 to 30 μm, preferably of 5 μm. at 25 μm, more preferably 5 to 20 μm and even more preferably 5 to 15 μm.

The specific surface area per unit mass can be determined by the nitrogen absorption method called the BET method (BRUNAUER - EMMET - TELLER) described in "The Journal of the American Chemical Society", vol. 60, page 309, February 1938 and corresponding to the international standard ISO 5794/1 (Appendix D). The BET surface area corresponds to the total specific surface area of the particles under consideration. The sizes of the airgel particles according to the invention can be measured by static light scattering using a MasterSizer 2000 commercial particle size analyzer from Malvern. The data is processed on the basis of Mie scattering theory. This theory, which is accurate for isotropic particles, makes it possible to determine, in the case of non-spherical particles, an "effective" diameter of particles. This theory is particularly described in Van de Hulst, H.C., "Light Scattering by Small Particles," Chapters 9 and 10, VViley, New York, 1957.

According to an advantageous embodiment, the hydrophobic airgel particles used in the present invention have a specific surface per unit mass (SM) ranging from 600 to 800 m 2 / g and a size expressed in volume mean diameter (D [0] , 5]) ranging from 5 to 20 μm, more preferably from 5 to 15 μm. According to a preferred embodiment, the VM-2270, whose particles have an average size ranging from 5 to 15 microns and a specific surface per unit mass ranging from 600 to 800 m 2 / g, will be used more particularly. The hydrophobic airgel particles used in the present invention may advantageously have a packed density p ranging from 0.04 g / cm 3 to 0.10 g / cm 3, preferably from 0.05 g / cm 3 to 0.08 g / cm 3 .

In the context of the present invention, this density can be assessed according to the following protocol, called the packed density protocol: 40 g of powder are poured into a graduated cylinder and the test piece is placed on a STAV 2003 STAMPF VOLUMETER device. . The test piece is then subjected to a series of 2500 settlements (this operation is repeated until the difference in volume between two consecutive tests is less than 2%); then the final volume Vf of packed powder is measured directly on the specimen. The packed density is determined by the ratio mass (m) / Vf, in this case 40 / Vf (Vf being expressed in cm3 and m in g). According to one embodiment, the hydrophobic airgel particles used in the present invention have a specific surface area per volume unit SV ranging from 5 to 60 m 2 / cm 3, preferably from 10 to 50 m 2 / cm 3 and better still from 15 to 40 m 2 / cm 3. m2 / CM3. The specific surface per unit volume is given by the relation: SV = SM * p where p is the packed density expressed in g / cm 3 and SM is the specific surface per unit mass expressed in m2 / g, as defined above. . According to a preferred embodiment, the hydrophobic airgel particles according to the invention have a specific surface per unit mass (SM) ranging from 500 to 1500 m 2 / g, preferably from 600 to 1200 m 2 / g and better still from 600 to at 800 m2 / g, and a size expressed in mean diameter (D [0.5]) ranging from 1 to 30 pm and / or an oil absorption capacity measured at VVET POINT ranging from 5 to 18 ml / g particles, preferably 6 to 15 ml / g and more preferably 8 to 12 ml / g. Examples of hydrophobic silica aerogels that may be used in the invention include, for example, the aerogel sold under the name VM-2260 (INCI name Silica silylate), by the company Dow Corning, whose particles have an average particle size. about 1000 microns and a specific surface area per unit mass from 600 to 800 m 2 / g. There may also be mentioned the aerogels marketed by Cabot under the references AEROGEL TLD 201, AEROGEL OGD 201 and AEROGEL TLD 203, 20 ENOVA AEROGEL MT 1100, ENOVA AEROGEL MT 1200. More particularly, the airgel marketed under the name VM- 2270 (INCI name Silica silylate), by the company Dow Corning, whose particles have an average size ranging from 5 to 15 microns and a specific surface per unit mass ranging from 600 to 800 m2 / g. The mineral particles according to the invention may also be clay particles. Clays are already well known products, which are described for example in the book "Mineralogy of clays, S. Caillere, S. Hénin, M. Rautureau, 30 2nd edition 1982, Masson", whose teaching is here included for reference. The clays are silicates containing a cation which may be chosen from calcium, magnesium, aluminum, sodium, potassium and lithium cations and their mixtures. Examples of such products include clays of the family of smectites such as montmorillonites, hectorites, bentonites, beidellites, saponites, as well as vermiculite family, stevensite, chlorite.

The clays can be of natural or synthetic origin. Preferably, clays are used which are cosmetically compatible and acceptable with keratin fibers such as the hair. The clay may be selected from montmorrilonite, bentonite, hectorite, attapulgite, sepiolite, and mixtures thereof. Preferably, the clay is a bentonite or a hectorite. The clays can be chosen from organophilic clays. The organophilic clays are clays modified with a chemical compound chosen from quaternary amines, tertiary amines, amino acetates, imidazolines, amine soaps, fatty sulphates, alkyl aryl sulphonates, amine oxides, and mixtures thereof. Preferably, the organophilic clays according to the invention are clays modified with a chemical compound chosen from quaternary amines. As organophilic clays, mention may be made of quaternium-18 bentonites such as those sold under the names Bentone 3, Bentone 38, Bentone 38V by Elementis, Tixogel VP by United catalyst, Claytone 34, Claytone 40, Claytone XL by the company Southern Clay Company; stearalkonium bentonites such as those sold under the names Bentone 27V by Elementis, Tixogel LG by United Catalyst, Claytone AF, Claytone APA by Southern Clay and quaternium-18 / benzalkonium bentonite such as those sold under the names Claytone HT, Claytone PS by Southern Clay. The organophilic clay is in particular chosen from modified hectorites such as hectorite modified with C10-C12 fatty acid ammonium chloride, especially distearyl dimethyl ammonium chloride and benzyldimethyl ammonium stearyl chloride. Preferably, the particles of one or more inorganic compounds are chosen from calcium carbonate, silica and in particular silica aerogels. Preferably, the composition according to the invention may comprise from 0.01 to 1% by weight, preferably from 0.1 to 0.7 (Yo, and even more preferably from 0.2 to 0.5% by weight of insoluble solid particles, relative to the total weight of said composition The composition according to the invention also comprises at least one non-liquid fatty substance.

By non-liquid fats is meant in the sense of the invention a non-liquid fats at 25 ° C and at atmospheric pressure. By non-liquid is preferably meant a solid compound or a compound having a viscosity greater than 2 Pas at a temperature of 25 ° C and a shear rate of 1 s-1. More particularly, non-liquid fatty substances are chosen from fatty alcohols, fatty acid esters and / or fatty alcohol esters, waxes of animal, vegetable, mineral or synthetic origin, silicone resins or gums, fatty, non-liquid and preferably solid ethers.

The non-liquid fatty alcohols that are suitable for carrying out the invention are more particularly chosen from saturated or unsaturated alcohols, preferably saturated, linear or branched, preferably linear, containing from 8 to 30 carbon atoms. For example, cetyl alcohol, stearyl alcohol, behenyl alcohol and mixtures thereof (cetylstearyl alcohol for example) may be mentioned.

As regards the fatty acid esters and / or non-liquid fatty alcohols, mention may be made in particular of solid esters derived from C 8 -C 26 fatty acids and C 8 -C 26 fatty alcohols. Among these esters, mention may be made of octyldodecyl behenate; isocetyl behenate and stearyl octanoate; octyl octanoate; cetyl octanoate; decyl oleate; myristyl stearate; octyl palmitate; octyl pelargonate; octyl stearate; alkyl myristates such as cetyl, mirystyl, stearyl myristate; hexyl stearate. Of all the additional esters mentioned above, it is preferred to use myristyl, cetyl, stearyl palmitates, alkyl myristates such as cetyl myristate and myristyl stearyl myristate. The wax or waxes that may be used in a composition according to the invention may be hydrocarbon-based, esterified, fluorinated and / or silicone-coated. The wax or waxes that may be used in the composition according to the invention may be chosen, in particular, from waxes of mineral origin such as paraffin wax, ozokerite, ceresin or microcrystalline waxes, for example the microcrystalline waxes having a melting point of greater than 85 ° C., such as the H I-MICO products 1070, 1080, 1090 and 3080 marketed by the company Nippon Seiro, waxes of plant origin such as carnauba wax, wax of candellila such as that marketed under the reference SP 75 G by the company STRAHL & PITSCH, alfa wax, olive wax, rice wax such as that marketed under the reference NC 1720 by the company CERA RICA NODA, the sunflower seed wax marketed by KOSTER KEUNEN under the reference sunflower wax, hydrogenated jojoba wax or absolute waxes of flowers such as the essential wax of blackcurrant flower; res of animal origin such as beeswax, or modified beeswax (cerabellina); other waxes or waxy raw materials that can be used according to the invention are especially marine waxes, polyethylene waxes or polyolefin waxes in general, such as α-olefin oligomers such as the PERFORMA V® 825, 103 and 260 polymers marketed by NEW PHASE TECHNOLOGIES, ethylene-propylene copolymers such as PERFORMALENE® EP 700, Fischer-Tropsch waxes. Mention may also be made of silicone waxes such as alkyl or alkoxy dimethicone having from 16 to 45 carbon atoms, and fluorinated waxes. According to a particular embodiment, the wax used in a composition according to the invention has a melting point greater than 35 ° C., better than 40 ° C. or even 45 ° C., or even 55 ° C. Preferably, the wax or waxes are chosen from waxes of animal origin, such as beeswax, or modified beeswaxes (cerabellina). The silicone resins or gums may be chosen from polydialkylsiloxanes, especially polydimethylsiloxanes (PDMSs), and organomodified polysiloxanes comprising at least one functional group chosen from poly (oxyalkylene) groups, amino groups and alkoxy groups. The silicone gums that can be used in accordance with the invention are in particular polydialkylsiloxanes, preferably polydimethylsiloxanes having high average molecular weights of between 200,000 and 1,000,000 used alone or in a mixture in a solvent. This solvent may be chosen from volatile silicones, polydimethylsiloxane (PDMS) oils, polyphenylmethylsiloxane (PPMS) oils, isoparaffins, polyisobutylenes, methylene chloride, pentane, dodecane, tridecane or their mixtures.

More particularly useful products according to the invention are mixtures such as: - mixtures formed from a hydroxyl end-of-the-chain polydimethylsiloxane, or dimethiconol (CTFA) and a cyclic polydimethylsiloxane also called cyclomethicone (CTFA) such that the product Q2 1401 marketed by Dow Corning; mixtures of a polydimethylsiloxane gum and a cyclic silicone such as the product SF 1214 Silicone Fluid from the company General Electric, this product is an SF 30 gum corresponding to a dimethicone, having a number average molecular weight of 500,000 solubilized in oil SF 1202 Silicone Fluid corresponding to decamethylcyclopentasiloxane; mixtures of two PDMSs of different viscosities, and more particularly of a PDMS gum and a PDMS oil, such as the product SF 1236 from the company General Electric. The product SF 1236 is the mixture of an SE 30 gum defined above having a viscosity of 20 m 2 / s and an SF 96 oil with a viscosity of 5 × 10 6 m 2 / s. This product preferably comprises 15% of SE 30 gum and 85% of an SF 96 oil. The organopolysiloxane resins used in accordance with the invention are crosslinked siloxane systems containing the units: R25iO2 / 2, R35iO1 / 2, R5iO3 / 2 and 5iO4 / 2 wherein R represents an alkyl having 1 to 16 carbon atoms. Among these products, those that are particularly preferred are those in which R denotes a lower C 1 -C 4 alkyl group, more particularly methyl. Among these resins may be mentioned the product marketed under the name "Dow Corning 593" or those sold under the names "Silicone Fluid SS 4230 and SS 4267" by the company General Electric and which are silicones of dimethyl / trimethyl siloxane structure. Mention may also be made of the trimethylsiloxysilicate type resins sold in particular under the names X22-4914, X21-5034 and X215037 by the company Shin-Etsu. The non-liquid fatty ethers are chosen from dialkyl ethers and in particular dicetyl ether and distearyl ether, alone or as a mixture. Preferably, the non-liquid fatty substance is chosen from mineral, animal or vegetable waxes. Preferably, the non-liquid fatty substance is chosen from waxes of animal origin such as beeswax, or modified beeswaxes (cerabellina). The content of non-liquid fatty substance (s) varies preferably from 0.01 to 10%, preferably from 1 to 9%, better still from 2.5 to 8%, more preferably from 5 to 8% by weight relative to the weight. total of the composition.

The cosmetic composition according to the invention also comprises one or more surfactants which may be chosen from anionic, cationic, nonionic, amphoteric or zwitterionic surfactants and mixtures thereof. The nonionic surfactants that can be used in the compositions of the present invention are well-known compounds per se (see in particular in this connection "Handbook of Surfactants" by MR PORTER, Blackie & Son editions (Glasgow and London), 1991, pp. 116- 178). They are chosen in particular from polyethoxylated, polypropoxylated or polyglycerolated fatty alcohols, polyethoxylated, polypropoxylated or polyglycerolated alpha-diols, polyethoxylated, polypropoxylated or polyglycerolated alkyl (C 1 -C 20) phenols, the fatty chain comprising, for example, from 10 to 20 carbon atoms. carbon, preferably from 16 to 18 carbon atoms, the number of ethylene oxide groups or propylene oxide ranging in particular from 1 to 150 and the number of glycerol groups that can range from 1 to 30. We can also mention the condensates of ethylene oxide and propylene oxide on fatty alcohols; the polyethoxylated fatty amides preferably having from 1 to 100 ethylene oxide units, the polyglycerolated fatty amides comprising on average from 1 to 5 glycerol groups and in particular from 1.5 to 4, the esters of fatty acids and of ethoxylated sorbitan having 1 to 50 ethylene oxide units, sucrose fatty acid esters, polyethylene glycol fatty acid esters, alkylpolyglycosides, polyethoxylated vegetable oils preferably having from 1 to 100 ethylene oxide units; ethylene oxide, N- (C 6-24 alkyl) glucamine derivatives, amine oxides such as (C 1-4 alkyl) amine oxides or N- (C 10-14) acyl aminopropylmorpholine oxides. The alkylpolyglucosides may be chosen, for example, from decylglucoside (Alkyl-C9 / Cl-polyglucoside (1,4)) such as the product sold under the name Mydol 10® by the company Kao Chemicals or the product marketed under the name Plantacare 2000 UP®. by the company Henkel and the product marketed under the name ORAMIX NS 10® by the company SEPPIC; caprylyl / capryl glucoside, such as the product marketed under the name Plantacare KE 3711® by the company Cognis or ORAMIX CG ilo® by the company SEPPIC; laurylglucoside, such as the product marketed under the name Plantacare 1200 UP® by Henkel or Plantaren 1200 N® by Henkel; cocoglucoside, such as the product marketed under the name Plantacare 818 UP® by Henkel; caprylylglucoside, such as the product marketed under the name Plantacare 810 UP® by Cognis; and their mixtures.

The term "anionic surfactant" is understood to mean a surfactant comprising as ionic or ionizable groups only anionic groups. These anionic groups are preferably chosen from the groups CO2H, O2-, SO3H, SO3-, OSO3H, OS03-, -H2PO3, -HPO3-, -P032-, -H2PO2, = HPO2, -HCO2-, = PO2-, = POH, = PO-. Among the anionic surfactants that may be used in the composition according to the invention, mention may be made of alkyl sulphates, alkyl ether sulphates, alkyl amido ether sulphates, alkylaryl polyether sulphates, monoglyceride sulphates, alkyl sulphonates, alkyl amide sulphonates, alkyl aryl sulphonates and alpha olefin sulphonates. paraffinsulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamidesulfosuccinates, alkylsulfoacetates, acylsarcosinates, acylglutamates, alkylethercarboxylates, alkylsulfosuccinamates, acylisethionates and N-acyltaurates; alkyl monoesters and polyglycoside-polycarboxylic acids, acyllactylates, D-galactoside uronic acids, alkyl ether carboxylic acids, alkyl aryl ether carboxylic acids, alkyl amido ether carboxylic acids; as well as the corresponding salified forms of all these compounds; the alkyl and acyl groups of all these compounds having from 6 to 24 carbon atoms and the aryl group denoting a phenyl group. These compounds may be oxyethylenated and then preferably comprise from 1 to 50 ethylene oxide units, more preferably from 1 to 10 ethylene oxide units. The salts of alkyl monoesters of 06-024 and of polyglycoside-polycarboxylic acids may be chosen from among the polyglycoside-citrates of alkyl at 06-024, polyglycoside-tartrates of alkyl at 06-024 and polyglycoside-sulphosuccinates. of alkyl at 06-024. The acyllactylates preferably have an acyl group having from 8 to 20 carbon atoms. When the anionic surfactant is in salt form, it may be chosen from alkali metal salts such as sodium or potassium salt, ammonium salts, amine salts and in particular aminoalcohol salts or salts. alkaline earth metals such as magnesium salt. Mention may be made, as an example of aminoalcohol salts, of the salts of mono-, di- and triethanolamine, the salts of mono-, di- or tri-isopropanolamine, the salts of 2-amino-2-methyl-1-propanol, 2- amino 2-methyl-1,3-propanediol and tris (hydroxymethyl) amino methane.

The alkali metal or alkaline earth metal salts, and in particular the sodium or magnesium salts, are preferably used. The preferred anionic surfactants are chosen from alkyl (C6-24) sulphates, (C6-24) alkyl ether sulphates, acylglutamates and (C6-C24) alkyl ether carboxylates, especially in the form of alkali metal or ammonium salts. , aminoalcohols, or alkaline earth metals, or a mixture of these compounds. In particular, it is preferred to use alkyl (C12-20) sulphates, alkyl (C12-20) ether sulphates comprising from 2 to 20 ethylene oxide units, acylglutamates and (C 12 -C 20) alkyl ether carboxylates, especially in the form of alkali metal, ammonium, aminoalcohol, and alkaline earth metal salts, or a mixture thereof. The amphoteric or zwitterionic surfactants that may be used in the present invention may be in particular derivatives of secondary or tertiary aliphatic amines, optionally quaternized, containing at least one anionic group such as, for example, a carboxylate, sulphonate, sulphate, phosphate or phosphonate, and wherein the aliphatic group or at least one of the aliphatic groups is a linear or branched chain having from 8 to 22 carbon atoms. Mention may in particular be made of (C 8 -C 20) alkyl betaines, sulphobetaines, (C 8 -C 20) alkylamido (C 1 -C 6) alkylbetaines such as cocoamidopropylbetaine and (C 8 -C 20) alkylthioalkyl (C 1 -C 6) alkyls. ) sulfobetaines. Among the optionally quaternized secondary or tertiary aliphatic amine derivatives that may be employed, there may also be mentioned the following products of structures (A1) and (A2): Ra-CON HCH2CH2-N + (Rb) (Rc) (CH2C00 -) (A1) in which: Ra represents a C10-C30 alkyl or alkenyl group derived from a R-COOH acid, preferably present in hydrolyzed coconut oil, a heptyl, nonyl or undecyl group, Rb represents a group beta-hydroxyethyl, and Rc represents a carboxymethyl group; Ra'-CONHCH2CH2-N (B) (B ') (A2) wherein: B represents -CH2CH2OX', X 'represents the group -CH2-000H, CH2-000Z', -CH2CH2-000H, -CH2CH2-COOZ ' , or a hydrogen atom, B 'represents - (CH2) z-Y', with z = 1 or 2, Y 'represents -COOH, -COOZ', the group -CH2-CHOH-SO3H or -CH2-CHOH5 SO3Z ', Z' represents an ion derived from an alkali metal or alkaline earth metal, such as sodium, potassium or magnesium; an ammonium ion; or an ion derived from an organic amine and especially an aminoalcohol, such as mono-, di- and triethanolamine, mono-, di- or tri-isopropanolamine, 2-amino-2-methyl-1-propanol 2-amino-2-methyl-1,3-propanediol and tris (hydroxymethyl) amino methane. Ra 'represents an alkyl or alkenyl group at 010 -030 of an acid Ra'COOH, preferably present in coconut oil or hydrolyzed linseed oil, an alkyl group, in particular at 017 and its iso form, a group in 017 unsaturated. Compounds of formula (A2) are preferred. These compounds are also classified in the CTFA dictionary, 5th edition, 1993, under the names cocoamphodiacétate disodium, lauroamphodiacétate disodium, caprylamphodiacétate disodium, capryloamphodiacétate disodium, cocoamphodipropionate disodium, lauroamphodipropionate disodium, caprylamphodipropionate disodium, capryloamphodipropionate disodium , lauroamphodipropionic acid, cocoamphodipropionic acid. By way of example, mention may be made of cocoamphodiacetate marketed by Rhodia under the trade name MIRANOLO 02M Concentrate. It is also possible to use compounds of formula (A3); Ra "-NH-CH (Y") - (CH2) nC (O) -NH- (CH2) n -N (Rd) (Re) (A3) Formula wherein: Y "represents the group -C (0) OH, -C (O) OZ-, -CH2-CH (OH) -SO3H or the group -CH2-CH (OH) -SO3-Z-; Rd and Re, independently one of the other, represent a C1-C4 alkyl or hydroxyalkyl radical; - represents a cationic counterion derived from an alkaline or alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine; Ra "represents a C 10 -C 30 alkyl or alkenyl group of an acid Ra" -C (O) OH which is preferably present in coconut oil or in hydrolysed linseed oil. n and n ', independently of each other, denote an integer ranging from 1 to 3. Among the compounds of formula (A3), mention may be made of the compound classified in the CTFA dictionary under the name sodium diethylaminopropyl cocoaspartamide and marketed by CHIMEX under the name CHIMEXANE HB. Preferably, the amphoteric or zwitterionic surfactants are chosen from (C 8 -C 20) alkyl betaines, (C 8 -C 20) alkylamidoalkyl (C 1 -C 6) betaines and (C 8 -C 20) alkyl amphodiacetates, the sodium salt of lauryl diethylaminopropyl amino succinamate and mixtures thereof.

Preferably, the amphoteric or zwitterionic surfactants are chosen from, alone or as a mixture, cocoylamidopropylbetaine, cocoylbétaine and cocoamphodiacétate. The cationic surfactant (s) that may be used in the composition according to the invention comprise, for example, primary, secondary or tertiary fatty amine salts, optionally polyoxyalkylenated, quaternary ammonium salts, and mixtures thereof. As quaternary ammonium salts, mention may be made, for example: - those corresponding to the following general formula (I): R 8 / Rio XR (R 11 (I) in which the radicals R 8 to R 11, which may be identical or different, represent a linear or branched aliphatic radical containing from 1 to 30 carbon atoms, or an aromatic radical such as aryl or alkylaryl, at least one of the radicals R8 to R11 comprising from 8 to 30 carbon atoms, preferably from 12 to 24 carbon atoms The aliphatic radicals may comprise heteroatoms such as in particular oxygen, nitrogen, sulfur and halogens, the aliphatic radicals are for example chosen from C1-C30 alkyl radicals and alkoxy radicals. C1-030, polyoxyalkylene (02-06), C1-030 alkylamide, (C12-C22) alkylamido (C2-C6) amidoalkyl, and C1-C30 hydroxyalkyl, X- is an anion selected from the group of halides, phosphates, acetates, lactates, (C1-C4) alkyl sulfates, (C1-C4) alkyl - or kyl (C1-C4) arylsulphonates.

Among the quaternary ammonium salts of formula (I), tetraalkylammonium chlorides, for example dialkyldimethylammonium or alkyltrimethylammonium chlorides in which the alkyl radical contains from about 12 to 22 carbon atoms, are preferred. carbon, in particular behenyltrimethylammonium, distearyldimethylammonium, cetyltrimethylammonium, benzyldimethylstearylammonium dicetyldimethylammonium chlorides or, on the other hand, palmitylamidopropyltrimethylammonium chloride or stearamidopropyldimethyl (myristyl acetate) ammonium chloride sold under the name CERAPHYLO 70 by the company VAN DYK. the quaternary ammonium salts of imidazoline, such as, for example, those of formula (II) below: wherein R 12 represents an alkenyl or alkyl radical comprising from 8 to 30; carbon atoms, for example fatty acid derivatives of tallow, R13 represents a hydrogen atom, a C1-C4 alkyl radical or an alkenyl or alkyl radical containing from 8 to 30 carbon atoms, R14 represents a C1-alkyl radical; -O4, R15 represents a hydrogen atom, a C1-C4 alkyl radical, X- is an anion chosen from the group of halides, phosphates, acetates, lactates, (C1-C4) alkyl sulphates, (C1-C4) alkyls or - (C1-C4) alkylsulphonates. Preferably, R12 and R13 denote a mixture of alkenyl or alkyl radicals containing from 12 to 21 carbon atoms, for example fatty acid derivatives of tallow, R14 denotes a methyl radical, R15 denotes a hydrogen atom. Such a product is for example marketed under the name Varisoft VV 575 PG N by the company Evonik Goldschmidt; the quaternary di- or triammonium salts, in particular of formula (III) below: X R17 R10 R16- (C N -R21 II R15 R20 in which R16 denotes an alkyl radical containing approximately from 16 to 30 carbon atoms, optionally hydroxyl and / or interrupted by one or more oxygen atoms, R17 is chosen from hydrogen or an alkyl radical containing from 1 to 4 carbon atoms or a - (CH2) 3-N + (R16a) (R17a) group (R18a) ), R16a, R17a, R18a, R18, R19, R20 and R21, which are identical or different, are chosen from hydrogen or an alkyl radical containing from 1 to 4 carbon atoms, and X- is an anion chosen from the group of halides, acetates, phosphates, nitrates, (C 1 -C 4) alkyl sulphates, (C 1 -C 4) alkyl or (C 1 -C 4) alkylarylsulfonates, in particular methylsulphate and ethylsulphate, such compounds are, for example, Finquat CT- P proposed by the company lnnospec Active Chemicals (Quaternium 89), the Condicare CT proposed by the company lnnospec Active Chemicals (Q uaternium 75); quaternary ammonium salts containing one or more ester functional groups, such as those of the following formula (IV): ## STR2 ## R24 C- (O-CrHr2 (OH) r1) y (IV) wherein: R22 is selected from C1-6 alkyl radicals and C1-6 hydroxyalkyl or dihydroxyalkyl radicals; R 23 is chosen from: - the radical - linear or branched, saturated or unsaturated C 1 -C 22 hydrocarbon radicals R 2 - hydrogen, R 25 is chosen from: o - radical R 28 -C - radicals R29 hydrocarbon C1-06, linear or branched, saturated or unsaturated, - the hydrogen atom, R24, R26 and R28, identical or different, are selected from hydrocarbon radicals in 07-021, linear or branched, saturated or unsaturated; r, s and t, identical or different, are integers ranging from 2 to 6; r1 and t1 identical or different, equal to 0 or 1 r2 + r1 = 2r and t1 + t2 = 2t y is an integer ranging from 1 to 10; x and z, which are identical or different, are integers ranging from 0 to 10; X- is a simple or complex anion, organic or inorganic; with the proviso that the sum x + y + z is from 1 to 15, that when x is 0 then R23 is R27 and that when z is 0 then R25 is R29. The alkyl radicals R22 may be linear or branched and more particularly linear. Preferably, R 22 denotes a methyl, ethyl, hydroxyethyl or dihydroxypropyl radical, and more particularly a methyl or ethyl radical. Advantageously, the sum x + y + z is from 1 to 10. When R 23 is a hydrocarbon radical R 27, it can be long and have from 12 to 22 carbon atoms, or short and have from 1 to 3 carbon atoms. When R 25 is a hydrocarbon R 29 radical, it preferably has 1 to 3 carbon atoms. Advantageously, R24, R26 and R28, which are identical or different, are chosen from linear or branched, saturated or unsaturated hydrocarbon radicals, and more particularly from linear or branched C1-C12 alkyl and alkenyl radicals. , saturated or unsaturated. Preferably, x and z, identical or different, are 0 or 1. Advantageously, y is equal to 1.

Preferably, r, s and t, which are identical or different, are equal to 2 or 3, and even more particularly are equal to 2. The anion X- is preferably a halide, preferably chloride, bromide or iodide, an alkyl (C1 -C4) sulfate, (C1-C4) alkyl- or (C1-C4) alkyl aryl-sulfonate. However, it is possible to use methanesulphonate, phosphate, nitrate, tosylate, an anion derived from an organic acid such as acetate or lactate or any other anion compatible with ammonium with an ester function. The anion X- is even more particularly chloride, methylsulfate or ethylsulfate. In the composition according to the invention, the ammonium salts of formula (IV) are used more particularly in which: R 22 denotes a methyl or ethyl radical, x and y are equal to 1; z is 0 or 1; r, s and t are equal to 2; - R23 is chosen from: 0 - the radical R26 -C- - methyl, ethyl or hydrocarbon radicals at 014-022, - the hydrogen atom; - R25 is chosen from: o - the radical R28 -C- - the hydrogen atom; - R24, R26 and R28, which are identical or different, are chosen from linear or branched, saturated or unsaturated 013-017 hydrocarbon-based radicals, and preferably from linear or branched, saturated or linear 0-13-017 alkyl and alkenyl radicals; unsaturated. Advantageously, the hydrocarbon radicals are linear. Examples of compounds of the formula include salts, especially diacyloxyethyldimethylammonium chloride, diacyloxyethylhydroxyethylmethylammonium chloride, monoacyloxyethyldihydroxyethylmethylammonium chloride, triacyloxyethylmethylammonium chloride, monoacyloxyethylhydroxyethyldimethylammonium chloride, and mixtures thereof. The acyl radicals preferably have from 14 to 18 carbon atoms and come more particularly from a vegetable oil such as palm oil or sunflower oil. When the compound contains a plurality of acyl radicals, the latter may be the same or different. Distearoylethylhydroxyethylmethylammonium methosulphate, dipalmitoylethylhydroxyethylammonium methosulphate or distearoylethylhydroxyethylammonium methosulphate may be mentioned more particularly. These products are obtained, for example, by direct esterification of triethanolamine, triisopropanolamine, alkyldiethanolamine or alkyldiisopropanolamine, optionally oxyalkylenated, with fatty acids or mixtures of fatty acids of plant or animal origin, or with transesterification of their methyl esters. This esterification is followed by quaternization with an alkylating agent such as alkyl halide, preferably methyl or ethyl, dialkyl sulfate, preferably methyl or ethyl, methanesulfonate methyl, para-toluenesulfonate methyl, chlorohydrin glycol or glycerol. The composition according to the invention may contain, for example, a mixture of quaternary ammonium mono-, di- and triester salts with a majority by weight of diester salts. It is also possible to use the ammonium salts containing at least one ester function described in US-A-4874554 and US-A-4137180. Behenoylhydroxypropyltrimethylammonium chloride proposed by KAO can be used under the name Quartamin BTC 131. Preferably, the ammonium salts containing at least one ester function contain two ester functions. Among the cationic surfactants optionally present in the composition according to the invention, it is more particularly preferred to choose the cetyltrimethylammonium, behenyltrimethylammonium, dipalmitoylethylhydroxyethylmethylammonium salts, and mixtures thereof, and more particularly behenyltrimethylammonium chloride, for example proposed by the Clariant company. under the trade names Gemanin KDMP or Gemanin BTLF or by the company Evonik Goldschmidt under the name Varisoft BT 85, cetyltrimethylammonium chloride, sold for example under the trade name Dehyquart A OR by Cognis or Quartamin 60 2 992 208 25 W25 by Kao or Genamin CTAC 25 by Clariant, dipalmitoylethylhydroxyethylmethylammonium methosulfate such as the commercial product Dehyquart F 30 sold by Cognis, and mixtures thereof. Preferably, the cationic surfactants are chosen from compounds of formulas (I) or (IV). The surfactant (s) of the composition of the invention are preferably chosen from anionic or nonionic surfactants. Even more preferentially, they are chosen from anionic surfactants. The surfactant (s) are present in a content preferably ranging from 0.01 to 2% by weight, more preferably in a content ranging from 0.1 to 1.5% by weight, relative to the total weight of the composition. . The total content by weight of surfactant (s) and insoluble solid particles, ie the sum of the content by weight of surfactant (s) and the content by weight of insoluble solid particles, is less than or equal to 3% by weight. weight, relative to the total weight of the composition. Preferably it may vary from 0.5 to 3%, better still from 1 to 3%, more preferably from 1 to 2.5% and more preferably from 1.5 to 2.5% by weight, relative to the total weight. of the composition. The weight ratio surfactant (s) / insoluble particles is greater than or equal to 1. Preferably it may vary from 1 to 20, more preferably from 1 to 10, more preferably from 1.5 to 5. The composition according to the invention may also include one or more thickeners that can be selected from natural or synthetic polymeric thickeners, associative or not, and non-polymeric thickeners. Polymeric thickeners include, for example, cellulosic thickeners, for example hydroxyethylcellulose, hydroxypropylcellulose and carboxymethylcellulose, guar gum and its derivatives, for example hydroxypropyl guar, marketed by Rhodia under the reference JAGUAR HP 105, gums of microbial origin, such as xanthan gum and scleroglucan gum, carrageenan, for example carrageenan powder marketed by Cargill under the reference 35 Satiagum UTC 30, synthetic polymeric thickeners from radical polymerization reactions or polycondensation reactions such as crosslinked homopolymers of acrylic acid or acrylamidopropanesulphonic acid, for example Carbomer, nonionic, anionic or amphoteric associative polymers, such as the commercially available polymers. under the names PEMULEN TR1 or TR2 by the company GOODRICH, SALCARE SC90 by the company ALLIED COLLOIDS, ACULYN 22, 28, 33, 44 or 46 by the company ROHM & HAAS and ELFACOS T210 and T212 by the company AKZO, or sodium polyacrylate such as the product sold by the company SENSIENT under the trade name Covacryl MV 60. The at least one polymeric thickening agent or agents may be present in a content ranging from 0.1 to 20% by weight, preferably in a content ranging from 0 to 10% by weight, more preferably 0.2 to 5% based on the total weight of the composition. Preferably, the composition comprises water, preferably at a content greater than or equal to 5% by weight relative to the total weight of the composition. The water content preferably varies from 5 to 98%, preferably from 30 to 95%, more preferably from 50 to 90%, more preferably from 70 to 90% by weight relative to the total weight of the composition. The composition may also comprise one or more water-soluble liquid organic solvents preferably selected from monoalcohols such as ethanol or isopropanol; polyols such as propylene glycol, butylene glycol or glycerol; polyol ethers; and their mixtures. The composition according to the invention may comprise a propellant. For example, liquefied gases such as dimethyl ether, 1,1-difluoroethane, or C3-5 alkanes such as propane, isopropane, n-butane, isobutane, pentane, or gases may be mentioned. tablets such as air, nitrogen, carbon dioxide, and mixtures thereof. Preferentially, mention may be made of C 3 -C 5 alkanes and in particular propane, n-butane and isobutane, and mixtures thereof. When it comprises, the composition comprises one or more propellants (s) in an amount ranging from 1 to 60% by weight, more preferably from 2 to 50% by weight, and even more preferably from 4 to 40% by weight. weight relative to the total weight of the composition. The composition for maintaining and / or shaping the hair according to the invention may also contain one or more additives different from the compounds of the invention chosen from the fixing polymers, the non-ionizing conditioning agents and the non-limiting agents. Silicones and in particular cationic polymers, vitamins and pro-vitamins including panthenol, sunscreens, pearlescent and opacifying agents, dyes, sequestering agents, plasticizing agents, solubilizing agents, acidifying agents, agents alkalizing agents, anti-oxidizing agents, anti-foaming agents, moisturizing agents, emollients, hydroxy acids, penetrating agents, perfumes, preservatives and solid charges and particles different from aerogels such as for example inorganic and organic pigments, colored or unstained. These additives may be present in the composition according to the invention in an amount ranging from 0 to 20% by weight relative to the total weight of the composition. Of course, those skilled in the art will take care to choose any additional compounds, and / or their quantity, in such a way that the advantageous properties of the compositions used according to the invention are not, or not substantially, impaired by the addition envisaged. . The composition according to the invention may be present inter alia in the form of more or less thickened liquids, gels, serums, creams, pastes, sprays or foams. In particular the composition of the invention can be applied from an aerosol device. Preferably, the composition according to the invention is in the form of gels, creams or pastes. The cosmetic composition according to the invention can be advantageously used for the cosmetic treatment of the hair. In particular, the composition can be used for styling the hair, for example for shaping and / or maintaining the hairstyle. The present invention also relates to a method for the cosmetic treatment of hair, for example a method of shaping and / or maintaining the hairstyle, which consists in applying to the hair an effective quantity of a composition according to the invention such that described above, then to carry out a possible rinsing after a possible exposure time. Preferably, the composition according to the invention is not rinsed. The method of the invention can be carried out at room temperature (25 ° C) or under heat at a temperature ranging from 40 to 250 ° C using any heating device: helmet, hair dryer, iron. The invention is further illustrated in the following examples which are presented by way of illustration and not limitation of the invention.

EXAMPLES Hair styling creams were prepared from the ingredients indicated in percent by weight of product as such in the following tables: Chemical Name Ex 1 Ex 2 Ex 3 Comparative (Invention) (Invention) (Invention) Wax bee (1) 7.5 5 7.5 7.5 Polymethyl methacrylate (2) 0.5 - - 0.5 Trimethylated silica (3) - 0.5 0.5 - Carrageenan (4) 4 4 4 4 Sodium cetearyl sulfate (5) 1,2 1,2 1,2 - Phenoxy-2 ethanol 0.7 0.7 0.7 0.7 Isothiazoline 0.1 0.1 0.1 0.1 Water QSP 100 QSP 100 QSP 100 QSP 100 (1) CERABEIL LOR marketed by the company BAERLOCHER (2) MICROPEARL M 310 marketed by the company MATSUMOTO YUSHI-SEIYAKU (3) VM-2270 AEROGEL FINE PARTICLES marketed by the company Dow Corning (4) SATIAGUM UTC 30 marketed by the company CARGILL (5) LANETTE E GRANULES sold by the company COGNIS The creams of Examples 1 to 3 according to the invention and the cream of the comparative dry hair were applied. The cream of Example 1 has a less pasty texture than that of the comparative, with a less greasy effect on the hands. The cream of Example 1 is more easily removed with water than that of the comparative. In addition, there is less dusting (residues after elimination) on the hair on which the cream of Example 1 was applied than on the hair on which the cream of the comparison was applied.

Claims (19)

REVENDICATIONS1. Cosmetic composition comprising at least one non-liquid fatty substance, at least one surfactant, solid particles that are insoluble in water, the weight ratio of surfactant (s) / insoluble solid particles being greater than or equal to 1, the total content by weight of surfactant (s) and insoluble particles being less than or equal to 3% relative to the total weight of the composition. 2. - Composition according to revendfication 1, wherein the insoluble solid particles are selected from particles of one or more polymeric organic compounds and / or particles of one or more inorganic compounds. 3. - Composition according to any one of the preceding claims, wherein the insoluble solid particles are chosen from polyamide powders, crosslinked sodium polyacrylate powders and polyethylene powders, polymethyl methacrylate powders, preferably from powders. of polymethyl methacrylate. 4. - Composition according to any one of claims 1 or 2 wherein the insoluble solid particles are selected from metal particles, oxides, inorganic salts, carbides, nitrides, sulfides and hydroxides, especially from clays. silicates, alumina, silica, kaolin and hydroxyapatite, preferably from silica particles, and especially from hydrophobic silica airgel particles. 5. - Composition according to the preceding claim, wherein the hydrophobic silica airgel particles have a specific surface per unit mass (SM) ranging from 500 to 1500 m 2 / g, preferably from 600 to 1200 m 2 / g and better from 600 to 800 m2 / g, and a size expressed in average diameter (D [0.5]) ranging from 1 to 30 pm and / or an oil absorption capacity measured at VVET POINT ranging from 5 to 18 ml g / g of particles, preferably 6 to 15 ml / g and more preferably 8 to 12 ml / g. 6. - Composition according to any one of claims 4 or 5, wherein the hydrophobic silica airgel particles are hydrophobic silica particles surface-modified with trimethylsilyl groups. 7. - Composition according to any one of claims 4 to 6, characterized in that the hydrophobic silica airgel particles have a specific surface area per volume unit SV ranging from 5 to 60 m2 / cm3, preferably from 10 to 50 m2 / cm3 and better from 15 to 40 m2 / cm3. 8. - Composition according to any one of the preceding claims, wherein the insoluble solid particles are present in the composition in concentrations ranging from 0.01 to 1% by weight, preferably from 0.1 to 0.7%, and still more preferably from 0.2 to 0.5% by weight relative to the total weight of the composition. 9. - Composition according to any one of the preceding claims wherein the non-liquid fatty substance or fats are chosen from fatty alcohols, esters of fatty acid and / or fatty alcohol, waxes of animal origin, vegetable , mineral or synthetic, silicone resins or gums, fatty ethers, non-liquid and preferably solid. 10. - Composition according to any one of the preceding claims wherein the non-liquid fatty substance or fats are chosen from waxes, preferably from waxes of animal origin such as beeswax, or beeswax. changed. 11. Composition according to any one of the preceding claims, in which the non-liquid fatty substance or fats are present in the composition in concentrations ranging from 0.01 to 10%, preferably from 1 to 9%, better still from 2 to , 5 to 8%, more preferably 5 to 8% by weight relative to the total weight of the composition. 12. - Composition according to any one of the preceding claims, wherein the surfactant or surfactants are chosen from anionic, cationic, nonionic, amphoteric or zwitterionic surfactants and mixtures thereof, preferably from anionic or nonionic surfactants. 13. - Composition according to any one of the preceding claims, wherein the surfactant or surfactants are present in the composition in concentrations ranging from 0.01 to 2% by weight, preferably from 0.1 to 1.5% by weight. weight relative to the total weight of the composition. 2,992,208 31 14. - Composition according to any one of the preceding claims, wherein the weight ratio surfactant (s) / insoluble solid particles ranges from 1 to 20, better from 1 to 10, more preferably from 1.5 to 5. 5 15. Composition according to any one of the preceding claims, in which the total content by weight of surfactant (s) and of insoluble solid particles varies from 0.5 to 3%, better still from 1 to 3%, and still more preferably from 1 to 3%. at 2.5 and more preferably from 1.5 to 2.5% by weight, based on the total weight of the composition. 16. The composition as claimed in any one of the preceding claims, which comprises at least one thickening agent that may be chosen from natural or synthetic, associative or non-associative polymeric thickeners and non-polymeric thickeners. 17. - Composition according to any one of the preceding claims, which comprises water, preferably in a content ranging from 5 to 98%, preferably from 30 to 95%, more preferably from 50 to 90%, more preferably from 70 to 90% by weight relative to the total weight of the composition. 18. Process for the cosmetic treatment of keratinous fibers, in particular human keratinous fibers such as the hair, characterized in that it consists in applying to said fibers an effective amount of a composition as defined according to any one of the following: Claims 1 to 17. 19. - Use of a composition according to any one of claims 1 to 17 for the hair treatment, in particular for the treatment of keratin fibers and in particular for maintaining / shaping the hair. 30