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FR2429201A1 - Sulfoxydes utilisables comme agents initiateurs de photopolymerisation - Google Patents

Sulfoxydes utilisables comme agents initiateurs de photopolymerisation

Info

Publication number
FR2429201A1
FR2429201A1 FR7915667A FR7915667A FR2429201A1 FR 2429201 A1 FR2429201 A1 FR 2429201A1 FR 7915667 A FR7915667 A FR 7915667A FR 7915667 A FR7915667 A FR 7915667A FR 2429201 A1 FR2429201 A1 FR 2429201A1
Authority
FR
France
Prior art keywords
sulfoxides
initiating agents
photopolymerization initiating
photopolymerization
agents
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7915667A
Other languages
English (en)
Other versions
FR2429201B1 (fr
Inventor
Lajos Avar
Hans-Werner Finck
Evelyne Kalt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sandoz AG
Original Assignee
Sandoz AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CH687678A external-priority patent/CH635352A5/de
Priority claimed from CH1069278A external-priority patent/CH643538A5/de
Application filed by Sandoz AG filed Critical Sandoz AG
Publication of FR2429201A1 publication Critical patent/FR2429201A1/fr
Application granted granted Critical
Publication of FR2429201B1 publication Critical patent/FR2429201B1/fr
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D333/00Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/50Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
    • C07D333/52Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes
    • C07D333/62Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00Sulfones; Sulfoxides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40Radicals substituted by oxygen atoms
    • C07D307/46Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D311/00Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
    • C07D311/02Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D311/78Ring systems having three or more relevant rings
    • C07D311/80Dibenzopyrans; Hydrogenated dibenzopyrans
    • C07D311/82Xanthenes
    • C07D311/84Xanthenes with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 9
    • C07D311/86Oxygen atoms, e.g. xanthones
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D333/00Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/06Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
    • C07D333/22Radicals substituted by doubly bound hetero atoms, or by two hetero atoms other than halogen singly bound to the same carbon atom
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D335/00Heterocyclic compounds containing six-membered rings having one sulfur atom as the only ring hetero atom
    • C07D335/04Heterocyclic compounds containing six-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
    • C07D335/10Dibenzothiopyrans; Hydrogenated dibenzothiopyrans
    • C07D335/12Thioxanthenes
    • C07D335/14Thioxanthenes with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 9
    • C07D335/16Oxygen atoms, e.g. thioxanthones
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/46Polymerisation initiated by wave energy or particle radiation
    • C08F2/48Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41Compounds containing sulfur bound to oxygen
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/101Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/027Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/028Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
    • G03F7/031Organic compounds not covered by group G03F7/029

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • Polymerisation Methods In General (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention comprend l'application de sulfoxydes comme agents initiateurs de photopolymérisation. Ces sulfoxydes répondent à la formule :
FR7915667A 1978-06-23 1979-06-19 Sulfoxydes utilisables comme agents initiateurs de photopolymerisation Granted FR2429201A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH687678A CH635352A5 (en) 1978-06-23 1978-06-23 Use of substituted alkyl phenyl sulphoxides and/or substituted phenyl phenyl sulphoxides as photoinitiators
CH1069278A CH643538A5 (en) 1978-10-16 1978-10-16 Sulphoxides

Publications (2)

Publication Number Publication Date
FR2429201A1 true FR2429201A1 (fr) 1980-01-18
FR2429201B1 FR2429201B1 (fr) 1984-05-11

Family

ID=25700316

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7915667A Granted FR2429201A1 (fr) 1978-06-23 1979-06-19 Sulfoxydes utilisables comme agents initiateurs de photopolymerisation

Country Status (7)

Country Link
US (1) US4324628A (fr)
DE (1) DE2923602A1 (fr)
ES (1) ES481839A1 (fr)
FR (1) FR2429201A1 (fr)
GB (1) GB2025991B (fr)
IT (1) IT1117247B (fr)
NL (1) NL7904770A (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA839398B (en) * 1982-12-27 1985-08-28 Lilly Co Eli Substituted imidazopyrimidines-pyrazines,and-triazines
US4537889A (en) * 1982-12-27 1985-08-27 Eli Lilly And Company Inotropic agents
US4636502A (en) * 1982-12-27 1987-01-13 Eli Lilly And Company Methods of producing a positive inotropic effect or vasodilation by administration of 2-phenyl imidazo pyrimidines and pyrazines
IT1208494B (it) * 1985-01-28 1989-07-10 Lamberti Flli Spa Polimerizzazione. derivati solforati di chetoni aromatico-alifatici e alifatici come fotoiniziatori di
IT1187703B (it) * 1985-07-23 1987-12-23 Lamberti Fratelli Spa Benzofenoni sostituiti e loro miscele liquide,atti all'impiego come iniziatori di fotopolimerizzazione
AU625123B2 (en) * 1989-04-24 1992-07-02 Otsuka Pharmaceutical Factory, Inc. 3-halogeno-2,3-diphenylacrylaldehyde derivative, method of production thereof and curing agent for hyperlipidemia
GB9620202D0 (en) * 1996-09-27 1996-11-13 Rhone Poulenc Agriculture New herbicides
JP2002534488A (ja) 1999-01-12 2002-10-15 クラリアント・インターナシヨナル・リミテツド ベンゾフェノンおよび光重合開始剤としてのその使用
JP5717959B2 (ja) 2009-11-17 2015-05-13 株式会社Adeka 芳香族スルホニウム塩化合物

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3949084A (en) * 1972-03-03 1976-04-06 Syntex (U.S.A.) Inc. Novel substituted xanthone carboxylic acid compounds
US4054682A (en) * 1976-01-23 1977-10-18 Basf Aktiengesellschaft Photopolymerizable composition containing a thioether sensitizer

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2769777A (en) * 1954-01-04 1956-11-06 Monsanto Chemicals Initiation of photopolymerization
AU451354B2 (en) * 1971-01-06 1974-08-08 Inmont Corp. "actinic radiation curing compositions and method of coating and printing using same"
CH570965A5 (fr) * 1972-07-14 1975-12-31 Sandoz Ag
US3903322A (en) * 1974-03-07 1975-09-02 Continental Can Co Photopolymerizable ethylenically unsaturated compounds photoinitiated with benzoyl derivatives of diphenyl sulfide and an organic amine compound
CH594705A5 (fr) 1974-09-19 1978-01-31 Sandoz Ag
US4165267A (en) * 1974-09-19 1979-08-21 Sandoz Ltd. Photo-polymerizable systems containing 2-haloacetophenone derivatives as photosensitizing agents
US4111692A (en) * 1976-06-04 1978-09-05 Toyo Boseki Kabushiki Kaisha Electrostatic printing plate
JPS6032175B2 (ja) * 1977-05-18 1985-07-26 バスフ アクチェン ゲゼルシャフト 版木及びレリ−フ版木を製造するために改良された光重合可能な物質
US4186108A (en) * 1978-02-08 1980-01-29 Minnesota Mining And Manufacturing Company Liquid compositions containing triarylsulfonium complex salts and oxyethylene material
US4339567A (en) * 1980-03-07 1982-07-13 Ciba-Geigy Corporation Photopolymerization by means of sulphoxonium salts

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3949084A (en) * 1972-03-03 1976-04-06 Syntex (U.S.A.) Inc. Novel substituted xanthone carboxylic acid compounds
US4054682A (en) * 1976-01-23 1977-10-18 Basf Aktiengesellschaft Photopolymerizable composition containing a thioether sensitizer

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CA1974 *
EXBK/71 *

Also Published As

Publication number Publication date
IT7949459A0 (it) 1979-06-19
GB2025991A (en) 1980-01-30
FR2429201B1 (fr) 1984-05-11
NL7904770A (nl) 1979-12-28
US4324628A (en) 1982-04-13
ES481839A1 (es) 1980-07-01
IT1117247B (it) 1986-02-17
DE2923602A1 (de) 1980-01-10
GB2025991B (en) 1982-11-10

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Legal Events

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TP Transmission of property
ST Notification of lapse