FR2249061A1 - Catalyst for prodn. of aldehydes from olefins - is complex carbonyl of rhodium modified with triphenylphosphine - Google Patents
Catalyst for prodn. of aldehydes from olefins - is complex carbonyl of rhodium modified with triphenylphosphineInfo
- Publication number
- FR2249061A1 FR2249061A1 FR7436098A FR7436098A FR2249061A1 FR 2249061 A1 FR2249061 A1 FR 2249061A1 FR 7436098 A FR7436098 A FR 7436098A FR 7436098 A FR7436098 A FR 7436098A FR 2249061 A1 FR2249061 A1 FR 2249061A1
- Authority
- FR
- France
- Prior art keywords
- catalyst
- triphenylphosphine
- aldehydes
- olefins
- prodn
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Aldehydes are prepd. from a gas from the autothermal cracking of petroleum, contg. 2-4C olefins, CO and H2, using as catalyst a complex carbonyl of rhodium modified by triphenylphosphine, pref. catalyst is used in an amt. corresp. to 50-1000 ppm Rh to reaction mixt., pref. in organic solvent. Pref. the gas is desulphurised before use in process. Process uses the "poor gas" from petroleum cracking after separation of acetylene.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19732354217 DE2354217A1 (en) | 1973-10-30 | 1973-10-30 | METHOD FOR MANUFACTURING ALDEHYDE |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2249061A1 true FR2249061A1 (en) | 1975-05-23 |
Family
ID=5896784
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7436098A Withdrawn FR2249061A1 (en) | 1973-10-30 | 1974-10-29 | Catalyst for prodn. of aldehydes from olefins - is complex carbonyl of rhodium modified with triphenylphosphine |
Country Status (5)
Country | Link |
---|---|
JP (1) | JPS5071611A (en) |
BE (1) | BE821637A (en) |
DE (1) | DE2354217A1 (en) |
FR (1) | FR2249061A1 (en) |
NL (1) | NL7413827A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996022265A1 (en) * | 1995-01-18 | 1996-07-25 | Exxon Chemical Limited | Hydroformylation process |
US6049011A (en) * | 1995-01-18 | 2000-04-11 | Exxon Chemical Patents Inc. | Hydroformylation process |
WO2002002496A1 (en) * | 2000-06-28 | 2002-01-10 | Basf Aktiengesellschaft | Method for producing hydroformylation products of olefins with 2 to 8 carbon atoms |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4262142A (en) * | 1979-12-28 | 1981-04-14 | Union Carbide Corporation | Hydroformylation of ethylene with higher olefins |
JP2001213832A (en) * | 2000-01-31 | 2001-08-07 | Mitsubishi Chemicals Corp | Method for producing aldehyde |
CN103347840B (en) | 2011-01-19 | 2015-11-25 | 埃克森美孚化学专利公司 | The method for transformation of hydrocarbon |
US9676681B2 (en) | 2011-01-19 | 2017-06-13 | Exxonmobil Chemical Patents Inc. | Method and apparatus for managing hydrogen content through the conversion of hydrocarbons into olefins |
US9815751B2 (en) | 2011-01-19 | 2017-11-14 | Exxonmobil Chemical Patents Inc. | Hydrocarbon and oxygenate conversion by high severity pyrolysis to make acetylene and ethylene |
US9868680B2 (en) | 2011-01-19 | 2018-01-16 | Exxonmobil Chemical Patents Inc. | Method and apparatus for converting hydrocarbons into olefins |
US9708232B2 (en) | 2011-01-19 | 2017-07-18 | Exxonmobil Chemical Patents Inc. | Method and apparatus for converting hydrocarbons into olefins |
US9677014B2 (en) | 2011-01-19 | 2017-06-13 | Exxonmobil Chemical Patents Inc. | Process and apparatus for converting hydrocarbons |
WO2012099673A2 (en) | 2011-01-19 | 2012-07-26 | Exxonmobil Chemical Patents Inc. | Hydrocarbon conversion process |
US9708231B2 (en) | 2011-01-19 | 2017-07-18 | Exxonmobil Chemical Patents Inc. | Method and apparatus for converting hydrocarbons into olefins using hydroprocessing and thermal pyrolysis |
US9505680B2 (en) | 2011-01-19 | 2016-11-29 | Exxonmobil Chemical Patents Inc. | Method and apparatus for managing the conversion of hydrocarbons into olefins |
EP2665801A1 (en) | 2011-01-19 | 2013-11-27 | Exxonmobil Chemical Patents Inc. | Method and apparatus for converting hydrocarbons into olefins |
US9856198B1 (en) | 2014-12-10 | 2018-01-02 | Dp&Pl Llc | Processes for making C3 products from ethylene and syngas using hydroformylation strategies |
-
1973
- 1973-10-30 DE DE19732354217 patent/DE2354217A1/en active Pending
-
1974
- 1974-10-22 NL NL7413827A patent/NL7413827A/en unknown
- 1974-10-26 JP JP49123041A patent/JPS5071611A/ja active Pending
- 1974-10-29 FR FR7436098A patent/FR2249061A1/en not_active Withdrawn
- 1974-10-29 BE BE150018A patent/BE821637A/en unknown
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996022265A1 (en) * | 1995-01-18 | 1996-07-25 | Exxon Chemical Limited | Hydroformylation process |
US6049011A (en) * | 1995-01-18 | 2000-04-11 | Exxon Chemical Patents Inc. | Hydroformylation process |
US6090986A (en) * | 1995-01-18 | 2000-07-18 | Exxon Chemical Patents Inc. | Organic compounds and processes for their manufacture |
US6307093B1 (en) | 1995-01-18 | 2001-10-23 | Exxonmobil Chemical Patents Inc. | Organic compounds and processes for their manufacture |
CN1089745C (en) * | 1995-01-18 | 2002-08-28 | 埃克森化学有限公司 | Hydroformylation process |
WO2002002496A1 (en) * | 2000-06-28 | 2002-01-10 | Basf Aktiengesellschaft | Method for producing hydroformylation products of olefins with 2 to 8 carbon atoms |
Also Published As
Publication number | Publication date |
---|---|
DE2354217A1 (en) | 1975-05-15 |
NL7413827A (en) | 1975-05-02 |
JPS5071611A (en) | 1975-06-13 |
BE821637A (en) | 1975-04-29 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
RE | Withdrawal of published application |