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ES2132378T3 - Procedimiento para la preparacion de copolimeros de cicloolefinas con baja viscosidad de masa fundida y baja amortiguacion optica. - Google Patents

Procedimiento para la preparacion de copolimeros de cicloolefinas con baja viscosidad de masa fundida y baja amortiguacion optica.

Info

Publication number
ES2132378T3
ES2132378T3 ES94905734T ES94905734T ES2132378T3 ES 2132378 T3 ES2132378 T3 ES 2132378T3 ES 94905734 T ES94905734 T ES 94905734T ES 94905734 T ES94905734 T ES 94905734T ES 2132378 T3 ES2132378 T3 ES 2132378T3
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ES
Spain
Prior art keywords
sub
sup
group
formula
atom
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94905734T
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English (en)
Inventor
Michael-Joachim Brekner
Hellmuth Deckers
Frank Osan
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Ticona GmbH
Original Assignee
Ticona GmbH
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Application granted granted Critical
Publication of ES2132378T3 publication Critical patent/ES2132378T3/es
Anticipated expiration legal-status Critical
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F232/00—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C08F232/08—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having condensed rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G02B1/045—Light guides
    • G02B1/046—Light guides characterised by the core material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2964—Artificial fiber or filament
    • Y10T428/2967—Synthetic resin or polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y10T428/31913—Monoolefin polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)

Abstract

LA INVENCION SE REFIERE A UN PROCESO PARA LA ELABORACION DE COPOLIMEROS (COC) CICLOOLEFINA CON UNA BAJA VISCOSIDAD DE FUSION MEDIANTE LA COPOLIMERIZACION DE 0,1 HASTA 99,9 % EN PESO, EN RELACION A LA CANTIDAD TOTAL DE MONOMEROS, DE AL MENOS UN MONOMERO EN DONDE R{SUP.1}, R{SUP.2}, R{SUP.3}, R{SUP.4}, R{SUP.5}, R{SUP.6}, R{SUP.7} Y R{SUP.8} SON IGUALES O DIFERENTES Y REPRESENTAN UN ATOMO DE HIDROGENO O UN RADICAL C{SUB.1} C{SUB.8} ALQUIL O RADICAL ARIL, DONDE LOS RADICALES IDENTICOS PUEDEN TENER UN SIGNIFICADO DIFERENTE EN VARIAS FORMULAS, 0 HASTA 99,9 % EN PESO EN RELACION A LA CANTIDAD TOTAL DE MONOMEROS, DE UNA CICLOOLEFINA DE LA FORMULA (V) EN DONDE N ES UN NUMERO DESDE 0 HASTA 10 Y 0,1 HASTA 99,9 % EN PESO, EN RELACION A LA CANTIDAD TOTAL DE MONOMEROS, DE AL MENOS UNA 1 - OLEFINA ACICLICA DE LA FORMULA (VI), EN DONDE R{SUP.9}, R{SUP.10}, R{SUP.11} Y R{SUP.12} SON IGUALES O DIFERENTES Y SIGNIFICAN UN ATOMO DE HIDROGENO O UN RADICAL C{SUB.1} - C{SUB.8} ALQUIL, EN SOLUCION, EN SUSPENSION,EN EL MONOMERO LIQUIDO CICLOOLEFINA O MEZCLA DE MONOMERO CICLOOLEFINA O EN FASE GASEOSA A UNA TEMPERATURA DE -78 HASTA 150 IA DE UN CATALIZADOR, QUE CONSISTE EN UN METALOCENO COMO COMPONENTE DE METAL DE TRANSICION Y UN ALUMINOXANO DE LA FORMULA (VII) PARA EL TIPO LINEAL Y/O FORMULA (VIII) DEL TIPO CICLICO. EN LAS FORMULA (VII) Y (VIII), R{SUP.13} ES UN GRUPO C{SUB.1} C{SUB.6} ALQUIL O FENIL O BENCIL Y N ES UN NUMERO COMPLETO DESDE 2 HASTA 50. LA POLIMERIZACION SE DIRIGE EN PRESENCIA DE UN CATALIZADOR CON COMPONENTE DE METAL DE TRANSICION, DE DONDE AL MENOS UNO DE LOS COMPONENTES ES DE LA FORMULA (IX), EN DONDE: M{SUP.1} ES TITANIO, ZIRCONIO, HAFNIO, VANADIO, NIOBIO O TANTALIO; R{SUP.14} Y R{SUP.15} SON IGUALES O DIFERENTES Y SIGNIFICAN UN ATOMO DE HIDROGENO, UNA ATOMO DE HALOGENO, UN GRUPO C{SUB.1} - C{SUB.10} ALQUIL, UN GRUPO C{SUB.1} - C{SUB.10} ALCOXI, UN GRUPO C{SUB.6} C{SUB.10} ARIL, UN GRUPO C{SUB.6} - C{SUB.10} ARILOXI, UN GRUPO C{SUB.2} - C{SUB.10} ALQUENIL, UN GRUPO C{SUB.7} - C{SUB.40} ARILALQUIL, UN GRUPO C{SUB.7} - C{SUB.40} ALQUILARIL O UN GRUPO C{SUB.8} - C{SUB.40} ARILALQUENIL Y M PUEDE SER 1 O 2 DEPENDIENDO DE LA VALENCIA DEL ATOMO CENTRAL M{SUP.1}. R{SUP.18} ES = BR{SUP.19} = AIR{SUP.19, -CE -, - SN -, - O -, - S -, = SO, = SO{SUB.2} = NR{SUP.19}, = CO, = PR{SUP.19} O = P(O)R{SUP.19}, DONDE R{SUP.19}, R{SUP.20} Y R{SUP.21} SON IGUALES O DIFERENTES Y SIGNIFICAN UN ATOMO DE HIDROGENO, UN ATOMO DE HALOGENO, UN GRUPO C{SUB.1} - C{SUB.10} ALQUIL, UN GRUPO C{SUB.1} - C{SUB.10} FLUORALQUIL, UN GRUPO C{SUB.6} - C {SUB.10} FLUORARIL, UN GRUPO C{SUB,6} - C{SUB.10} ARIL, UN GRUPO C{SUB.1} - C{SUB.10} ALCOXI, UN GRUPO C{SUB.2} - C {SUB.10} ALQUENIL, UN GRUPO C{SUB.7} C{SUB.40} ARILALQUIL, UN GRUPO C{SUB.8} C{SUB.40} ARILALQUENIL O UN GRUPO C{SUB.7} -C{SUB.40} ALQUILARIL, O R{SUP.19} Y R{SUP.20} O R{SUP.19} Y R{SUP.21} FORMAN UN ANILLO CON LOS ATOMOS UNIDOS, M{SUP.2} ES SILICIO, GERMANIO O ESTAÑO, R{SUP.16} Y R{SUP.17} SON DIFERENTES Y SIGNIFICAN UN RADICAL DE HIDROCARBURO MONO O MULTINUCLEAR QUE PUEDE FORMAR UNA ESTRUCTURA SANDWICH CON EL ATOMO M{SUP.1} CENTRAL. EL METALOCENO DE LA FORMULA (IX) MUESTRA SIMETRIA C{SUB.S} EN RELACION A LAS LIGANDURAS R{SUP.16} Y R{SUP.17} Y A LOS ENLACES DEL ATOMO CENTRAL M{SUP.1}.
ES94905734T 1993-02-12 1994-01-31 Procedimiento para la preparacion de copolimeros de cicloolefinas con baja viscosidad de masa fundida y baja amortiguacion optica. Expired - Lifetime ES2132378T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4304291A DE4304291A1 (de) 1993-02-12 1993-02-12 Cycloolefincopolymere mit niedriger Schmelzeviskosität und niedriger optischer Dämpfung

Publications (1)

Publication Number Publication Date
ES2132378T3 true ES2132378T3 (es) 1999-08-16

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ID=6480340

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ES94905734T Expired - Lifetime ES2132378T3 (es) 1993-02-12 1994-01-31 Procedimiento para la preparacion de copolimeros de cicloolefinas con baja viscosidad de masa fundida y baja amortiguacion optica.

Country Status (11)

Country Link
US (1) US5637400A (es)
EP (1) EP0683797B1 (es)
JP (1) JP3361808B2 (es)
KR (1) KR100306351B1 (es)
CN (1) CN1117737A (es)
AU (1) AU693083B2 (es)
BR (1) BR9405831A (es)
CA (1) CA2155936C (es)
DE (2) DE4304291A1 (es)
ES (1) ES2132378T3 (es)
WO (1) WO1994018251A1 (es)

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CA2155936C (en) 2006-05-30
WO1994018251A1 (de) 1994-08-18
AU5972494A (en) 1994-08-29
KR100306351B1 (ko) 2001-11-30
EP0683797A1 (de) 1995-11-29
DE59408117D1 (de) 1999-05-20
US5637400A (en) 1997-06-10
EP0683797B1 (de) 1999-04-14
JPH08507800A (ja) 1996-08-20
JP3361808B2 (ja) 2003-01-07
BR9405831A (pt) 1995-12-26
CN1117737A (zh) 1996-02-28
AU693083B2 (en) 1998-06-25
DE4304291A1 (de) 1994-08-18
KR960701111A (ko) 1996-02-24
CA2155936A1 (en) 1994-08-18

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