EP2008724A1 - Zone de préhension en caoutchouc silicone pour appareils d'écriture, de peinture, de dessin et de sport - Google Patents
Zone de préhension en caoutchouc silicone pour appareils d'écriture, de peinture, de dessin et de sport Download PDFInfo
- Publication number
- EP2008724A1 EP2008724A1 EP07012464A EP07012464A EP2008724A1 EP 2008724 A1 EP2008724 A1 EP 2008724A1 EP 07012464 A EP07012464 A EP 07012464A EP 07012464 A EP07012464 A EP 07012464A EP 2008724 A1 EP2008724 A1 EP 2008724A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- silicone rubber
- structures
- commodity
- commodity according
- crosslinked
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920002379 silicone rubber Polymers 0.000 title claims abstract description 29
- 239000004945 silicone rubber Substances 0.000 title claims abstract description 28
- 238000010422 painting Methods 0.000 title 1
- 238000004132 cross linking Methods 0.000 claims abstract description 8
- 239000006185 dispersion Substances 0.000 claims abstract description 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 5
- BTHCBXJLLCHNMS-UHFFFAOYSA-N acetyloxysilicon Chemical compound CC(=O)O[Si] BTHCBXJLLCHNMS-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 3
- WHIVNJATOVLWBW-PLNGDYQASA-N (nz)-n-butan-2-ylidenehydroxylamine Chemical compound CC\C(C)=N/O WHIVNJATOVLWBW-PLNGDYQASA-N 0.000 claims abstract 2
- -1 polydimethylsiloxane Polymers 0.000 claims description 5
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 2
- 150000002978 peroxides Chemical class 0.000 claims description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 1
- 150000002923 oximes Chemical class 0.000 claims 1
- 229910000077 silane Inorganic materials 0.000 claims 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 abstract 1
- 239000000463 material Substances 0.000 description 15
- 238000004519 manufacturing process Methods 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 238000007650 screen-printing Methods 0.000 description 3
- 238000007669 thermal treatment Methods 0.000 description 3
- 239000004971 Cross linker Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000009969 flowable effect Effects 0.000 description 2
- 238000010327 methods by industry Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920004482 WACKER® Polymers 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000004815 dispersion polymer Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- WHIVNJATOVLWBW-UHFFFAOYSA-N n-butan-2-ylidenehydroxylamine Chemical compound CCC(C)=NO WHIVNJATOVLWBW-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
- B43K—IMPLEMENTS FOR WRITING OR DRAWING
- B43K23/00—Holders or connectors for writing implements; Means for protecting the writing-points
- B43K23/008—Holders comprising finger grips
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B60/00—Details or accessories of golf clubs, bats, rackets or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B25—HAND TOOLS; PORTABLE POWER-DRIVEN TOOLS; MANIPULATORS
- B25G—HANDLES FOR HAND IMPLEMENTS
- B25G1/00—Handle constructions
- B25G1/10—Handle constructions characterised by material or shape
- B25G1/102—Handle constructions characterised by material or shape the shape being specially adapted to facilitate handling or improve grip
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B2102/00—Application of clubs, bats, rackets or the like to the sporting activity ; particular sports involving the use of balls and clubs, bats, rackets, or the like
- A63B2102/02—Tennis
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B2102/00—Application of clubs, bats, rackets or the like to the sporting activity ; particular sports involving the use of balls and clubs, bats, rackets, or the like
- A63B2102/04—Badminton
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B2102/00—Application of clubs, bats, rackets or the like to the sporting activity ; particular sports involving the use of balls and clubs, bats, rackets, or the like
- A63B2102/16—Table tennis
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B60/00—Details or accessories of golf clubs, bats, rackets or the like
- A63B60/06—Handles
- A63B60/14—Coverings specially adapted for handles, e.g. sleeves or ribbons
Definitions
- the invention relates to an article, in particular a pen-shaped writing instrument with a handling zone serving handle, wherein at least on a part of the grip zone individual from the surface of the grip zone projecting structures are present.
- Pen-shaped writing instruments of this kind are for example off EP 1 177 108 known.
- an aqueous polymer dispersion is applied to the pin surface. It is given on a wooden background and special finishes a sufficiently strong adhesion. Due to the aqueous solvent, a firm adhesion of the structures in plastic-tipped pens or writing instruments with plastic shafts is not achievable in many cases.
- the object of the invention is to propose an article of the type mentioned, in which the structures are soft, have a good feel and feel and adhere well to a variety of different materials.
- This object is achieved according to claim 1 by a commodity, in particular by a pen-shaped writing instrument, in which at least on a part of the handle area serving individual from the surface of the grip zone projecting structures of silicone rubber are present.
- Such structures are soft, feel comfortable, offer good slip resistance and grip. They can be applied to a wide variety of materials with good adhesion, which can be used in the production of objects with different materials formed grip zones each on the same application method, for example, applying individual structures forming drops using nozzles, spraying or screen printing.
- the selection of a suitable application method can be independent of the material of the article, so that in particular in the production of writing instruments a universal use of existing silicone rubber structures for any product variants such as sharpened, coated with wood or plastic lead and color and Krosmetikstatte , Pens, ink pens, markers, gel pens and mechanical pencils.
- Common materials for said pens or other commodities are, for example, ABS plastics, polypropylene, polycarbonate, PVC and polystyrene.
- the structures are made of a UV-crosslinked silicone rubber.
- a silicone rubber which can be prepared from a UV-crosslinkable silicone rubber has the advantage that the silicone rubber initially applied in free-flowing form crosslinks at room temperature under UV irradiation. A subsequent drying is not required. It is therefore particularly suitable for writing instruments with temperature-sensitive mines, such as cosmetic mines. In addition, no drying phase is required, which simplifies the process and reduces the production time.
- the UV crosslinking can be radically, e.g. for silicone acrylates, or has ionic, e.g. in the case of epoxy-silicones.
- crosslinking temperatures which normally move in a temperature range of about 100 ° C to 200 ° C, do not matter.
- articles with structures of silicone rubber crosslinked with oxysilane are in particular based on polydimethylsiloxane.
- Acetoxysilane has proven to be particularly advantageous as a crosslinker (Example 1).
- Such a material is available, for example from Wacker Chemie GmbH, D-81737 Ober under the tradename Elastosil ® N10.
- the flowable silicone rubber is applied, for example via nozzles or by screen printing (screen with about 1 mm square mesh size 2 ) in the form of nubs on the grip zone of an object, such as a ballpoint pen with an ABS shaft and by thermal treatment at about 170 ° C networked.
- the thermal treatment can be carried out by means of a short-term infrared irradiation. In such a treatment, the thermal load of the article is reduced, in particular in writing instruments with temperature-sensitive mines is appropriate.
- a silicone rubber with oximosilane, in particular butan-2-onoxime as crosslinker and the abovementioned polydimethylsiloxane has also proved to be particularly advantageous (Example 2).
- a corresponding material is available, for example, from Drawinmaschines GmbH, D-85521 Ottobrunn.
- phenolic paste Cisco Inc.
- the paste is in an agitator at a mild temperature, to max. 40 ° C homogeneously mixed with said silicone rubber.
- the mass obtained is applied by screen printing with wide-mesh sieves in the form of ribs on brush handles and handles of table tennis rackets.
- a short-term thermal treatment is carried out to crosslink the silicone rubber.
- TEGO ® RC 902 65% by weight TEGO ® RC 711 30% by weight TEGO ® A 17 1.5% by weight TEGO ® RC 1772 (Matting agent) 3.5% by weight
- a particularly advantageous variant in terms of process engineering are articles with structures based on at least one silicone rubber dispersion. Both peroxide and addition-crosslinking dispersions are conceivable. In this, as well as in the case of non-dispersion silicone rubber, a catalyst for crosslinking acceleration is useful. In the case of the dispersions mentioned an acceleration can be carried out by small amounts of platinum.
- Fillers, colorants, and optionally additives may be added in all examples given.
- the surfaces of the articles may be improved by corona or plasma treatment or flame treatment to achieve greater adhesion, which may be the case, for example, in highly stressed articles of daily use.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Physical Education & Sports Medicine (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Professional, Industrial, Or Sporting Protective Garments (AREA)
- Fishing Rods (AREA)
- Mechanical Pencils And Projecting And Retracting Systems Therefor, And Multi-System Writing Instruments (AREA)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07012464A EP2008724A1 (fr) | 2007-06-26 | 2007-06-26 | Zone de préhension en caoutchouc silicone pour appareils d'écriture, de peinture, de dessin et de sport |
CNA2008101910973A CN101503040A (zh) | 2007-06-26 | 2008-05-21 | 具有用于操作的握持区的日用品 |
PE2008001081A PE20090542A1 (es) | 2007-06-26 | 2008-06-25 | Objeto de uso con una zona de asido que sirve para su manipuleo |
US12/145,937 US20090003918A1 (en) | 2007-06-26 | 2008-06-25 | Article Having a Grip Zone Which Serves for Handling |
BRPI0803726-4A BRPI0803726A2 (pt) | 2007-06-26 | 2008-06-26 | objeto de uso com uma zona de manuseio que serve para sua manipulação |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07012464A EP2008724A1 (fr) | 2007-06-26 | 2007-06-26 | Zone de préhension en caoutchouc silicone pour appareils d'écriture, de peinture, de dessin et de sport |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2008724A1 true EP2008724A1 (fr) | 2008-12-31 |
Family
ID=38509064
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07012464A Withdrawn EP2008724A1 (fr) | 2007-06-26 | 2007-06-26 | Zone de préhension en caoutchouc silicone pour appareils d'écriture, de peinture, de dessin et de sport |
Country Status (5)
Country | Link |
---|---|
US (1) | US20090003918A1 (fr) |
EP (1) | EP2008724A1 (fr) |
CN (1) | CN101503040A (fr) |
BR (1) | BRPI0803726A2 (fr) |
PE (1) | PE20090542A1 (fr) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
USD914092S1 (en) * | 2019-08-14 | 2021-03-23 | Staedtler Mars Gmbh & Co. Kg | Pencil |
USD914091S1 (en) * | 2019-08-14 | 2021-03-23 | Staedtler Mars Gmbh & Co. Kg | Fountain pen |
USD914093S1 (en) * | 2019-08-14 | 2021-03-23 | Staedtler Mars Gmbh & Co. Kg | Fountain pen |
USD931935S1 (en) * | 2020-01-28 | 2021-09-28 | Staedtler Mars Gmbh & Co. Kg | Writing and drawing instrument |
USD932547S1 (en) * | 2020-01-28 | 2021-10-05 | Staedtler Mars Gmbh & Co. Kg | Writing and drawing instrument |
USD931936S1 (en) * | 2020-01-28 | 2021-09-28 | Staedtler Mars Gmbh & Co. Kg | Writing and drawing instrument |
USD913373S1 (en) * | 2020-02-17 | 2021-03-16 | Pagani Pens Sa | Pen |
USD934342S1 (en) * | 2021-03-08 | 2021-10-26 | elago CO. LTD | Cover for stylus pen |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999048702A1 (fr) * | 1998-03-26 | 1999-09-30 | Bic Corporation | Instrument d'ecriture a dispositif de prehension manuelle |
EP1036671A1 (fr) * | 1999-03-15 | 2000-09-20 | Kotobuki & Co. Ltd. | Manchon d'écriture pour instruments d'écriture |
US6273626B1 (en) * | 1998-10-09 | 2001-08-14 | Zebra Co., Ltd. | Grip for a writing instrument |
US20040190973A1 (en) * | 2003-02-05 | 2004-09-30 | Kyo Nakayama | Writing implement |
EP1526150A1 (fr) * | 2003-10-23 | 2005-04-27 | SigmaKalon Services B.V. | Composition de revêtement antidérapante |
EP1642750A1 (fr) * | 2003-06-26 | 2006-04-05 | Kabushiki Kaisha Pilot Corporation | Instrument d'ecriture |
WO2006037489A1 (fr) * | 2004-09-30 | 2006-04-13 | Wacker Chemie Ag | Revetement d'articles menagers au moyen d'elastomeres thermoplastiques |
EP1700713A1 (fr) * | 2005-03-09 | 2006-09-13 | Faber-Castell AG | Procédé de fabrication de revêtements avec une surface structurée, appliqué particulièrement pour des crayons, et objet avec une surface structurée |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3336135A1 (de) * | 1983-10-05 | 1985-04-25 | Bayer Ag, 5090 Leverkusen | Rtv-siliconpasten |
US5569750A (en) * | 1994-05-24 | 1996-10-29 | Alliedsignal Inc. | RTV silicone compositions using aminohydrocarbyl-substituted ketoximinosilanes |
CZ299958B6 (cs) * | 1999-05-07 | 2009-01-07 | A. W. Faber-Castell Unternehmensverwaltung Gmbh & Co. | Tužka zhotovená ze dreva |
JP2001164111A (ja) * | 1999-12-10 | 2001-06-19 | Dow Corning Toray Silicone Co Ltd | シリコーンゴム組成物、およびキーパッド用シリコーンゴム組成物 |
DE20314274U1 (de) * | 2003-09-12 | 2004-05-27 | Faber-Castell Ag | Holzgefasster Stift für Schreib-, Mal-, Zeichen-, und Kosmetikzwecke |
US20050165138A1 (en) * | 2004-01-23 | 2005-07-28 | Jeannie Holmes | Synthetic cork compound |
US20050234208A1 (en) * | 2004-04-14 | 2005-10-20 | Matthias Koch | Fast curing polydiorganosiloxanes |
US20050288415A1 (en) * | 2004-06-23 | 2005-12-29 | Beers Melvin D | Highly elastomeric and paintable silicone compositions |
-
2007
- 2007-06-26 EP EP07012464A patent/EP2008724A1/fr not_active Withdrawn
-
2008
- 2008-05-21 CN CNA2008101910973A patent/CN101503040A/zh active Pending
- 2008-06-25 PE PE2008001081A patent/PE20090542A1/es not_active Application Discontinuation
- 2008-06-25 US US12/145,937 patent/US20090003918A1/en not_active Abandoned
- 2008-06-26 BR BRPI0803726-4A patent/BRPI0803726A2/pt not_active Application Discontinuation
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999048702A1 (fr) * | 1998-03-26 | 1999-09-30 | Bic Corporation | Instrument d'ecriture a dispositif de prehension manuelle |
US6273626B1 (en) * | 1998-10-09 | 2001-08-14 | Zebra Co., Ltd. | Grip for a writing instrument |
EP1036671A1 (fr) * | 1999-03-15 | 2000-09-20 | Kotobuki & Co. Ltd. | Manchon d'écriture pour instruments d'écriture |
US20040190973A1 (en) * | 2003-02-05 | 2004-09-30 | Kyo Nakayama | Writing implement |
EP1642750A1 (fr) * | 2003-06-26 | 2006-04-05 | Kabushiki Kaisha Pilot Corporation | Instrument d'ecriture |
EP1526150A1 (fr) * | 2003-10-23 | 2005-04-27 | SigmaKalon Services B.V. | Composition de revêtement antidérapante |
WO2006037489A1 (fr) * | 2004-09-30 | 2006-04-13 | Wacker Chemie Ag | Revetement d'articles menagers au moyen d'elastomeres thermoplastiques |
EP1700713A1 (fr) * | 2005-03-09 | 2006-09-13 | Faber-Castell AG | Procédé de fabrication de revêtements avec une surface structurée, appliqué particulièrement pour des crayons, et objet avec une surface structurée |
Also Published As
Publication number | Publication date |
---|---|
PE20090542A1 (es) | 2009-06-04 |
CN101503040A (zh) | 2009-08-12 |
US20090003918A1 (en) | 2009-01-01 |
BRPI0803726A2 (pt) | 2009-03-31 |
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