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EA201290514A1 - Улучшенный способ карбонилирования - Google Patents

Улучшенный способ карбонилирования

Info

Publication number
EA201290514A1
EA201290514A1 EA201290514A EA201290514A EA201290514A1 EA 201290514 A1 EA201290514 A1 EA 201290514A1 EA 201290514 A EA201290514 A EA 201290514A EA 201290514 A EA201290514 A EA 201290514A EA 201290514 A1 EA201290514 A1 EA 201290514A1
Authority
EA
Eurasian Patent Office
Prior art keywords
atoms
source
catalyst system
groups
carbonylate
Prior art date
Application number
EA201290514A
Other languages
English (en)
Other versions
EA024236B1 (ru
Inventor
Грэхам Рональд Истхэм
Филип Ян Ричардс
Original Assignee
ЛУСАЙТ ИНТЕРНЭШНЛ ЮКей ЛИМИТЕД
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ЛУСАЙТ ИНТЕРНЭШНЛ ЮКей ЛИМИТЕД filed Critical ЛУСАЙТ ИНТЕРНЭШНЛ ЮКей ЛИМИТЕД
Publication of EA201290514A1 publication Critical patent/EA201290514A1/ru
Publication of EA024236B1 publication Critical patent/EA024236B1/ru

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
    • C07C69/24—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Описывается способ увеличения значения TON системы катализатора монокарбонилирования этиленненасыщенных соединений при использовании монооксида углерода в присутствии сореагента, отличного от воды или ее источника и содержащего подвижный атом водорода. Система катализатора может быть получена в результате объединения: (а) металла из групп (8), (9) или (10) или его подходящего для использования соединения; (b) лиганда, описывающегося общей формулой (I), где группы Xи Xнезависимо представляют собой одновалентные радикалы, содержащие до 30 атомов, или Xи Xсовместно образуют двухвалентный радикал, содержащий до 40 атомов, а Xсодержит до 400 атомов; Qпредставляет собой атом фосфора, мышьяка или сурьмы; и с) необязательно источника анионов. Способ включает стадию добавления к системе катализатора воды или ее источника. Способ предпочтительно реализуют в присутствии электроположительного металла.
EA201290514A 2009-12-15 2010-12-15 Улучшенный способ карбонилирования EA024236B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB0921876.9A GB0921876D0 (en) 2009-12-15 2009-12-15 Improved carbonylation process
PCT/GB2010/052093 WO2011073653A1 (en) 2009-12-15 2010-12-15 Improved carbonylation process

Publications (2)

Publication Number Publication Date
EA201290514A1 true EA201290514A1 (ru) 2013-01-30
EA024236B1 EA024236B1 (ru) 2016-08-31

Family

ID=41667109

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201290514A EA024236B1 (ru) 2009-12-15 2010-12-15 Улучшенный способ карбонилирования

Country Status (15)

Country Link
US (1) US20120309613A1 (ru)
EP (1) EP2512670A1 (ru)
JP (2) JP2013513653A (ru)
KR (1) KR20120106974A (ru)
CN (1) CN102740972B (ru)
AU (1) AU2010332501B2 (ru)
BR (1) BR112012014500A2 (ru)
CA (1) CA2783586A1 (ru)
EA (1) EA024236B1 (ru)
GB (1) GB0921876D0 (ru)
MX (1) MX2012006967A (ru)
SG (1) SG181699A1 (ru)
TW (1) TWI508780B (ru)
WO (1) WO2011073653A1 (ru)
ZA (1) ZA201204316B (ru)

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GB0921876D0 (en) * 2009-12-15 2010-01-27 Lucite Int Uk Ltd Improved carbonylation process
AR088124A1 (es) * 2011-04-01 2014-05-14 Dsm Ip Assets Bv Proceso para la preparacion de esteres de acido alcanoico en un proceso de carbonilacion utilizando ligandos de bifosfato bidentados de paladio
GB201122054D0 (en) * 2011-12-21 2012-02-01 Lucite Int Uk Ltd A continuous process for the carbonylation of ethylene
WO2013107902A1 (en) 2012-01-20 2013-07-25 Dsm Ip Assets B.V. Process for the separation of a dissolved catalyst system from an alkoxycarbonylation reaction mixture
CN114409541A (zh) * 2020-10-28 2022-04-29 上海浦景化工技术股份有限公司 一种乙烯羰基化制丙酸酯类的系统
CN112480170B (zh) * 2020-12-02 2023-03-14 中国海洋石油集团有限公司 一种双膦化合物、包含其的催化剂体系及其应用

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Also Published As

Publication number Publication date
AU2010332501A2 (en) 2012-08-02
US20120309613A1 (en) 2012-12-06
JP2013513653A (ja) 2013-04-22
BR112012014500A2 (pt) 2016-08-16
WO2011073653A1 (en) 2011-06-23
KR20120106974A (ko) 2012-09-27
AU2010332501A1 (en) 2012-07-26
JP2015214551A (ja) 2015-12-03
AU2010332501B2 (en) 2014-10-30
CN102740972B (zh) 2015-02-11
SG181699A1 (en) 2012-07-30
EP2512670A1 (en) 2012-10-24
MX2012006967A (es) 2012-07-17
TWI508780B (zh) 2015-11-21
CA2783586A1 (en) 2011-06-23
CN102740972A (zh) 2012-10-17
EA024236B1 (ru) 2016-08-31
TW201143889A (en) 2011-12-16
ZA201204316B (en) 2013-02-27
GB0921876D0 (en) 2010-01-27

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Legal Events

Date Code Title Description
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KZ KG MD TJ TM RU