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AR088124A1 - Proceso para la preparacion de esteres de acido alcanoico en un proceso de carbonilacion utilizando ligandos de bifosfato bidentados de paladio - Google Patents

Proceso para la preparacion de esteres de acido alcanoico en un proceso de carbonilacion utilizando ligandos de bifosfato bidentados de paladio

Info

Publication number
AR088124A1
AR088124A1 ARP120101033A ARP120101033A AR088124A1 AR 088124 A1 AR088124 A1 AR 088124A1 AR P120101033 A ARP120101033 A AR P120101033A AR P120101033 A ARP120101033 A AR P120101033A AR 088124 A1 AR088124 A1 AR 088124A1
Authority
AR
Argentina
Prior art keywords
optionally substituted
preparation
waste
bifosphate
bidented
Prior art date
Application number
ARP120101033A
Other languages
English (en)
Inventor
Gerardus De Vries Johannes
Sereinig Natascha
Catherine Christianne Janssen Michele
Wilhelmina Maria Van De Vondervoort Elisabeth
Original Assignee
Dsm Ip Assets Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dsm Ip Assets Bv filed Critical Dsm Ip Assets Bv
Publication of AR088124A1 publication Critical patent/AR088124A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
    • C07C209/48—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of nitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D307/30—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/32—Oxygen atoms
    • C07D307/33—Oxygen atoms in position 2, the oxygen atom being in its keto or unsubstituted enol form

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Proceso de carbonilación para la preparación de un éster de ácido alcanoico que comprende hacer reaccionar: (a) un alqueno; (b) una fuente de Pd; (c) un ligando de fosfino bidentado de la fórmula (1): R¹R²P-R³-R-R⁴-PR⁵R⁶ (1) en donde P representa un átomo de fósforo; R¹, R², R⁵ y R⁶ pueden representar independientemente los mismos grupos o diferentes grupos orgánicos opcionalmente sustituidos que contienen un átomo de carbono terciario a través del cual el grupo se liga al átomo de fósforo; R³ y R⁴ representan independientemente grupos alquileno inferiores opcionalmente sustituidos y R representa un grupo aromático opcionalmente sustituido; (d) una fuente de aniones derivados de un ácido con un pKa < 3; (e) monóxido de carbono; y (f) un alcanol; caracterizado porque el proceso se realiza en la presencia de entre 0.1 y 3% en peso de agua. El proceso tiene ventajosamente un alto índice de conversión y es adecuado para la producción de dimetil adipato, adipato y hexametileno diamina y productos derivados de los mismos tales como nylon 6,6 de fuentes renovables tales como desperdicio de planta, desperdicio de aguas residuales en lugar de utilizar fuentes fósiles.
ARP120101033A 2011-04-01 2012-03-27 Proceso para la preparacion de esteres de acido alcanoico en un proceso de carbonilacion utilizando ligandos de bifosfato bidentados de paladio AR088124A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161470673P 2011-04-01 2011-04-01
EP11160912 2011-04-01

Publications (1)

Publication Number Publication Date
AR088124A1 true AR088124A1 (es) 2014-05-14

Family

ID=44140819

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP120101033A AR088124A1 (es) 2011-04-01 2012-03-27 Proceso para la preparacion de esteres de acido alcanoico en un proceso de carbonilacion utilizando ligandos de bifosfato bidentados de paladio

Country Status (5)

Country Link
US (1) US20140128631A1 (es)
EP (1) EP2694467A1 (es)
CN (1) CN103619801A (es)
AR (1) AR088124A1 (es)
WO (1) WO2012131027A1 (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017135897A1 (en) * 2016-02-02 2017-08-10 Agency For Science, Technology And Research A catalyst for the carbonylation of alkenes
EP3272728B1 (de) 2016-07-19 2019-06-19 Evonik Degussa GmbH Verfahren zur alkoxycarbonylierung von alkoholen
DE102018114441A1 (de) 2018-06-15 2019-08-01 Leibniz-Institut Für Katalyse E.V. An Der Universität Rostock Verfahren zur Herstellung von endständig ungesättigtem Alkencarbonsäureester aus Lactonen

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2368366A (en) 1942-08-21 1945-01-30 Monsanto Chemicals Process for the production of lactones
US3065263A (en) 1959-11-17 1962-11-20 Rayonier Inc Process for the manufacture of levulinic acid
DE3609138A1 (de) * 1986-03-19 1987-09-24 Basf Ag Verfahren zur herstellung von alkencarbonsaeureestern
DE3609139A1 (de) 1986-03-19 1987-09-24 Basf Ag Verfahren zur herstellung von 4-pentensaeureestern
US4897497A (en) 1988-04-26 1990-01-30 Biofine Incorporated Lignocellulose degradation to furfural and levulinic acid
US5608105A (en) 1995-06-07 1997-03-04 Biofine Incorporated Production of levulinic acid from carbohydrate-containing materials
MY127358A (en) * 2000-03-14 2006-11-30 Shell Int Research Process for the carbonylation of ethylenically unsaturated compounds
US6835849B2 (en) 2002-07-15 2004-12-28 E. I. Du Pont De Nemours And Company Synthesis of alkenoate esters from lactones and alcohols
JP2007514713A (ja) 2003-12-19 2007-06-07 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ アルケン酸アルキルの製造方法
GB0516556D0 (en) * 2005-08-12 2005-09-21 Lucite Int Uk Ltd Improved catalyst system
GB0713624D0 (en) * 2007-07-13 2007-08-22 Lucite Int Uk Ltd Improved solvent for catalyst system
US8148553B2 (en) * 2009-06-23 2012-04-03 Wisconsin Alumni Research Foundation Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities
GB0921876D0 (en) * 2009-12-15 2010-01-27 Lucite Int Uk Ltd Improved carbonylation process
EP2537840B1 (en) * 2011-06-21 2013-07-24 DSM IP Assets B.V. Process to produce valerolactone from levulinic acid

Also Published As

Publication number Publication date
WO2012131027A1 (en) 2012-10-04
US20140128631A1 (en) 2014-05-08
CN103619801A (zh) 2014-03-05
EP2694467A1 (en) 2014-02-12

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