CN113573692A - Hair wax composition - Google Patents
Hair wax composition Download PDFInfo
- Publication number
- CN113573692A CN113573692A CN202080021759.1A CN202080021759A CN113573692A CN 113573692 A CN113573692 A CN 113573692A CN 202080021759 A CN202080021759 A CN 202080021759A CN 113573692 A CN113573692 A CN 113573692A
- Authority
- CN
- China
- Prior art keywords
- polyethylene glycol
- ether
- peg
- weight
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000203 mixture Substances 0.000 title claims abstract description 119
- 210000004209 hair Anatomy 0.000 title claims abstract description 65
- 239000001993 wax Substances 0.000 claims abstract description 99
- 239000003921 oil Substances 0.000 claims abstract description 37
- 239000002202 Polyethylene glycol Substances 0.000 claims description 101
- 229920001223 polyethylene glycol Polymers 0.000 claims description 101
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 72
- -1 polydimethylsiloxanes Polymers 0.000 claims description 31
- 239000003995 emulsifying agent Substances 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 20
- LQXBZWFNAKZUNM-UHFFFAOYSA-N 16-methyl-1-(16-methylheptadecoxy)heptadecane Chemical compound CC(C)CCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC(C)C LQXBZWFNAKZUNM-UHFFFAOYSA-N 0.000 claims description 18
- 229920000642 polymer Polymers 0.000 claims description 17
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 claims description 16
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 claims description 16
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 15
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 14
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 14
- 239000000194 fatty acid Substances 0.000 claims description 14
- 229930195729 fatty acid Natural products 0.000 claims description 14
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- 229920006395 saturated elastomer Polymers 0.000 claims description 13
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 10
- 239000002562 thickening agent Substances 0.000 claims description 10
- 229920001519 homopolymer Polymers 0.000 claims description 9
- 239000003906 humectant Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 claims description 8
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 claims description 8
- 235000013871 bee wax Nutrition 0.000 claims description 8
- 239000012166 beeswax Substances 0.000 claims description 8
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 8
- 229940100460 peg-100 stearate Drugs 0.000 claims description 8
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 8
- 150000007513 acids Chemical class 0.000 claims description 7
- 229940073669 ceteareth 20 Drugs 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 7
- 229940075529 glyceryl stearate Drugs 0.000 claims description 7
- 239000012071 phase Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- 150000002191 fatty alcohols Chemical class 0.000 claims description 6
- 229920002545 silicone oil Polymers 0.000 claims description 6
- 229920001908 Hydrogenated starch hydrolysate Polymers 0.000 claims description 5
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 5
- 150000001298 alcohols Chemical class 0.000 claims description 5
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 5
- 239000004203 carnauba wax Substances 0.000 claims description 5
- 235000013869 carnauba wax Nutrition 0.000 claims description 5
- DLAHAXOYRFRPFQ-UHFFFAOYSA-N dodecyl benzoate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1 DLAHAXOYRFRPFQ-UHFFFAOYSA-N 0.000 claims description 5
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical class CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 5
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 5
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 claims description 4
- 241000196324 Embryophyta Species 0.000 claims description 4
- DLRVVLDZNNYCBX-UHFFFAOYSA-N Polydextrose Polymers OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(O)O1 DLRVVLDZNNYCBX-UHFFFAOYSA-N 0.000 claims description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
- 239000012530 fluid Substances 0.000 claims description 4
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 claims description 4
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 4
- 229920001897 terpolymer Polymers 0.000 claims description 4
- 150000003626 triacylglycerols Chemical class 0.000 claims description 4
- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical compound CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 claims description 4
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- ZITBHNVGLSVXEF-UHFFFAOYSA-N 2-[2-(16-methylheptadecoxy)ethoxy]ethanol Chemical compound CC(C)CCCCCCCCCCCCCCCOCCOCCO ZITBHNVGLSVXEF-UHFFFAOYSA-N 0.000 claims description 3
- NLMKTBGFQGKQEV-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-hexadecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO NLMKTBGFQGKQEV-UHFFFAOYSA-N 0.000 claims description 3
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
- 241000238631 Hexapoda Species 0.000 claims description 3
- 108010009736 Protein Hydrolysates Proteins 0.000 claims description 3
- 239000008346 aqueous phase Substances 0.000 claims description 3
- 229920006037 cross link polymer Polymers 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 229940049964 oleate Drugs 0.000 claims description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 3
- 229940032067 peg-20 stearate Drugs 0.000 claims description 3
- 229940114926 stearate Drugs 0.000 claims description 3
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 claims description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 2
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical group OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 claims description 2
- AOWCOHYBGYRYGE-UHFFFAOYSA-N 1-[2,3-bis(2-oxopropoxy)propoxy]propan-2-one Chemical compound CC(=O)COCC(OCC(C)=O)COCC(C)=O AOWCOHYBGYRYGE-UHFFFAOYSA-N 0.000 claims description 2
- JWYVGKFDLWWQJX-UHFFFAOYSA-N 1-ethenylazepan-2-one Chemical compound C=CN1CCCCCC1=O JWYVGKFDLWWQJX-UHFFFAOYSA-N 0.000 claims description 2
- XYTHHAXRVHHXKO-JIUYZRCGSA-N 18-[(2r,3s,4r,5r)-4,5-dihydroxy-2-(hydroxymethyl)-6-methoxyoxan-3-yl]oxyoctadecanoic acid;ethanol Chemical compound CCO.COC1O[C@H](CO)[C@@H](OCCCCCCCCCCCCCCCCCC(O)=O)[C@H](O)[C@H]1O XYTHHAXRVHHXKO-JIUYZRCGSA-N 0.000 claims description 2
- OEZPKXDBWNXBRE-UHFFFAOYSA-N 2,3-bis(2-hydroxyethoxy)propyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(OCCO)COCCO OEZPKXDBWNXBRE-UHFFFAOYSA-N 0.000 claims description 2
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims description 2
- WMPGRAUYWYBJKX-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-dodecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO WMPGRAUYWYBJKX-UHFFFAOYSA-N 0.000 claims description 2
- OIALAIQRYISUEV-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]e Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO OIALAIQRYISUEV-UHFFFAOYSA-N 0.000 claims description 2
- DNXDAPMZRQRFSL-UHFFFAOYSA-N 2-hydroxy-2-(2-octadecoxy-2-oxoethyl)butanedioic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.CCCCCCCCCCCCCCCCCCOC(=O)CC(O)(C(O)=O)CC(O)=O DNXDAPMZRQRFSL-UHFFFAOYSA-N 0.000 claims description 2
- ICIDSZQHPUZUHC-UHFFFAOYSA-N 2-octadecoxyethanol Chemical compound CCCCCCCCCCCCCCCCCCOCCO ICIDSZQHPUZUHC-UHFFFAOYSA-N 0.000 claims description 2
- MXRGSJAOLKBZLU-UHFFFAOYSA-N 3-ethenylazepan-2-one Chemical compound C=CC1CCCCNC1=O MXRGSJAOLKBZLU-UHFFFAOYSA-N 0.000 claims description 2
- ONAIRGOTKJCYEY-XXDXYRHBSA-N CCCCCCCCCCCCCCCCCC(O)=O.O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 Chemical compound CCCCCCCCCCCCCCCCCC(O)=O.O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 ONAIRGOTKJCYEY-XXDXYRHBSA-N 0.000 claims description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 2
- HDIFHQMREAYYJW-XGXNLDPDSA-N Glyceryl Ricinoleate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(=O)OCC(O)CO HDIFHQMREAYYJW-XGXNLDPDSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- 229920001100 Polydextrose Polymers 0.000 claims description 2
- 229920002701 Polyoxyl 40 Stearate Polymers 0.000 claims description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 2
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 claims description 2
- PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 claims description 2
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 claims description 2
- 229940061720 alpha hydroxy acid Drugs 0.000 claims description 2
- 150000001280 alpha hydroxy acids Chemical class 0.000 claims description 2
- 239000004204 candelilla wax Substances 0.000 claims description 2
- 235000013868 candelilla wax Nutrition 0.000 claims description 2
- 229940073532 candelilla wax Drugs 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 2
- 229940073638 ceteareth-15 Drugs 0.000 claims description 2
- 229940056318 ceteth-20 Drugs 0.000 claims description 2
- OWMBTIRJFMGPAC-UHFFFAOYSA-N dimethylamino 2-methylprop-2-enoate Chemical compound CN(C)OC(=O)C(C)=C OWMBTIRJFMGPAC-UHFFFAOYSA-N 0.000 claims description 2
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 claims description 2
- 238000007046 ethoxylation reaction Methods 0.000 claims description 2
- 229960005150 glycerol Drugs 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 229940074052 glyceryl isostearate Drugs 0.000 claims description 2
- 229940074046 glyceryl laurate Drugs 0.000 claims description 2
- 229940116338 glyceryl ricinoleate Drugs 0.000 claims description 2
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 claims description 2
- 235000012907 honey Nutrition 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 150000007529 inorganic bases Chemical class 0.000 claims description 2
- 239000004310 lactic acid Substances 0.000 claims description 2
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- 239000000845 maltitol Substances 0.000 claims description 2
- 235000010449 maltitol Nutrition 0.000 claims description 2
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 claims description 2
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- 238000004519 manufacturing process Methods 0.000 claims description 2
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
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- YZUUTMGDONTGTN-UHFFFAOYSA-N nonaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCOCCOCCOCCO YZUUTMGDONTGTN-UHFFFAOYSA-N 0.000 claims description 2
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- ARIWANIATODDMH-UHFFFAOYSA-N rac-1-monolauroylglycerol Chemical compound CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 claims description 2
- DCBSHORRWZKAKO-UHFFFAOYSA-N rac-1-monomyristoylglycerol Chemical compound CCCCCCCCCCCCCC(=O)OCC(O)CO DCBSHORRWZKAKO-UHFFFAOYSA-N 0.000 claims description 2
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- 239000001788 mono and diglycerides of fatty acids Substances 0.000 claims 2
- 239000000263 2,3-dihydroxypropyl (Z)-octadec-9-enoate Substances 0.000 claims 1
- RZRNAYUHWVFMIP-GDCKJWNLSA-N 3-oleoyl-sn-glycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-GDCKJWNLSA-N 0.000 claims 1
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- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 210000004919 hair shaft Anatomy 0.000 description 4
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 4
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- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
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- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
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- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 1
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- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 235000011929 mousse Nutrition 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
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- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 1
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- 239000000312 peanut oil Substances 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
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- 235000010987 pectin Nutrition 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
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- 239000004033 plastic Substances 0.000 description 1
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- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000012177 spermaceti Substances 0.000 description 1
- 229940084106 spermaceti Drugs 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
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- 239000010496 thistle oil Substances 0.000 description 1
- 235000010487 tragacanth Nutrition 0.000 description 1
- 239000000196 tragacanth Substances 0.000 description 1
- 229940116362 tragacanth Drugs 0.000 description 1
- KMEHEQFDWWYZIO-UHFFFAOYSA-N triacontyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC KMEHEQFDWWYZIO-UHFFFAOYSA-N 0.000 description 1
- 239000012178 vegetable wax Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention belongs to the field of cosmetics and discloses a hair styling composition, in particular a hair wax composition which does not contain fossil-source oil and wax. By using alternative oils and waxes, compositions with good hair styling properties are provided.
Description
Technical Field
The present invention relates to a cosmetic preparation, in particular a hair styling composition, more particularly a hair wax composition. The composition is free of oils and waxes from fossil origin. By using alternative oils and waxes, it is possible to obtain a very desirable product for proper styling of the hair.
Background
The entire body, except for the lips, palms and soles, is covered with hair, although most are barely visible. Since the hair root has many nerve endings, the hair is sensitive to external influences such as wind or touch and is therefore part of the sense of touch that should not be underestimated. Today, however, the most important function of human hair is to help sculpt the appearance of the human in a characteristic way. Like skin, it fulfills a social function because it contributes considerably to the individual's personal relationships and self-esteem through its appearance.
Hair consists of hair shafts and hair roots. The hair shaft protrudes freely from the skin and is the keratinized (dead) part of the hair. The hair shaft represents the actual visible part of the hair and is constantly renewed. The hair roots buried in the skin are the living parts of the hair. The hair shaft is composed of three layers: the central part, called the hair marrow (medulla), degenerates in humans, often disappearing completely; then the marrow, also called cortex; and epidermis, which is the outermost layer, containing up to ten stratum corneum layers.
The condition of the human hair in the new growth state is hardly improved. The hair parts near the scalp accordingly have an almost closed cuticle.
In particular, the stratum corneum, which is the outer sheath of hair, and the inner area under the epidermis are subjected to specific stresses of environmental influence.
In many cases, natural growth does not have sufficient mass, and in most cases, natural growth does not have a personally preferred hairstyle. Therefore, there is a strong need for styling products that provide volume and individualized styling to the hair. There are several product formats on the market that serve the different preferences of consumers. There are products applied to wet hair, such as mousses and lotions. After drying, the hair is styled and styled primarily by the fixing/styling polymers contained in the product. Different styling product forms are those intended for dry hair. A conventional product is hair spray, which is used to hold already styled hair.
Another type of product that is commonly applied to dry hair is hair wax. Typically, these products are primarily wax-based, containing no water or only a small amount of water. Due to the wax relationship, the product is solid or semi-solid and sold in cans. When a small amount of product is removed from the container, it is dispensed into the hand, and the temperature is raised to melt the wax. The product is applied to the hair, and can be used for styling. The product cools again, resulting in a fixed hairstyle. To improve the elution of the hair wax, an emulsifier is included.
In order to further improve the elution of the hair wax, polyethylene glycol or a component containing a considerable amount of ethylene glycol residues is contained in the hair wax. When such a component is used, it is not necessary to include an emulsifier.
Hair waxes often contain components that impart shine to the hair. Typically, these components are oils, which may be of natural or synthetic origin. Examples of natural oils are macadamia nut oil or almond oil; an example of a synthetic oil is silicone oil.
Pomades are known and available as aerosol sprays. The hair wax also contains a volatile hydrocarbon, such as isodecane and a gaseous propellant.
The aforementioned products are also described in the prior art. EP 1792607 a1 describes hair waxes having a pleasant white appearance. To achieve this, a disaccharide polyester or polysaccharide polyester is contained.
US 2005/0163738 a1 discloses hair waxes comprising a silicone-free wax, a liquid oil and a silicone wax.
US 2004/0052744 a1 describes a hair wax product comprising, in addition to wax, at least 40% of an aqueous or alcoholic carrier and an emulsifier.
US 2004/0115152 a1 discloses hair wax compositions containing polyethylene glycol in addition to wax.
JP 2005314365 a1 describes a spray type hair wax comprising a film forming resin, a liquid ester oil, a semi-solid oil and being substantially free of water.
Generally, hair wax products are characterized by the fact that they contain wax. The term "wax" or "waxy" as used herein corresponds to the definition of wax given in Roempp (online version; Roempp. Thieme. de/Roempp4.0, month 12 in 2007 for the last renewal of the wax). By this definition, wax substances are plastic, strong to brittle, coarse to fine crystalline, transparent to opaque, but not glassy at 20 ℃ and melt above 40 ℃ but do not decompose. They have a relatively low viscosity above the melting point, have a consistency and solubility that is highly temperature dependent, and are polishable under mild pressure.
Waxes can be classified into
Natural waxes (e.g. insect waxes, animal waxes and vegetable waxes),
paraffin waxes (e.g. mineral oil waxes or ozokerite),
-a mineral wax,
synthetic waxes (e.g. Fischer-Tropsch waxes, polyolefin waxes such as polyethylene or polybutylene waxes, amide waxes) and
-a partially synthetic wax,
-a microcrystalline wax, the microcrystalline wax being,
-a coarse-grained wax,
hydrocarbon waxes, especially solid high-melting paraffin waxes, petrolatum,
-a montan wax,
acid-functionalized hydrocarbon waxes (obtained, for example, by oxidation of hydrocarbon materials such as polyolefins or paraffins, or by copolymerization of ethylene with acid-containing comonomers such as acrylic acid or vinyl acetate),
-polyethylene glycol waxes and
-silicone wax.
Many of these waxes are derived from mineral oil or other fossil sources. The wax is composed primarily of hydrogenated long carbon chains. In addition, highly alkylated cyclic hydrocarbons are also contained. This fraction may be referred to as MOSH. The second term used in connection with components derived from fossil origin is the term MOAH. Monocyclic or polycyclic aromatic components, sometimes highly alkylated, are referred to in this term. In a few cases, traces of MOAH can be found in cosmetic raw materials derived from fossil sources. It cannot be excluded that a component classified as MOAH may be associated with cancer production.
While all waxes that are allowed to be used are evaluated as safe ingredients for cosmetic compositions according to eu cosmetic product regulations, consumers are increasingly aware of MOSH and MOAH expressions and prefer products that do not contain the raw materials associated with the terms MOSH and MOAH.
Disclosure of Invention
In view of the above-mentioned drawbacks, there is a need to make available hair care compositions, in particular hair waxes, which are free of waxes and/or oils from fossil origin and at the same time provide styling properties which are at least as good, preferably better, than those of conventional hair wax compositions containing waxes from fossil origin.
Surprisingly, it has been found that a hair styling composition, in particular a hair wax composition, containing a composition comprising
-at least one synthetic wax,
-at least one oil, at least one of which,
-at least one emulsifier.
According to the invention, the hair wax composition is an aqueous composition containing from 50 to 80% by weight, preferably from 60 to 75% by weight, of water relative to the total weight of the composition.
According to the invention, it is preferred that the hair wax composition is free of waxes and/or oils derived from fossil origin. In the meaning of the present invention, the term "free" means containing 0.1% by weight or less, preferably 0.001% by weight or less and most preferably 0% by weight of the corresponding substances.
The at least one synthetic wax used in the present invention is preferably produced by a process known as fischer-tropsch synthesis. By this process, the starting materials are carbon monoxide and hydrogen, which are converted into a mixture of paraffins and olefins and water. By using the waxes produced in this way, no aromatic mono-or polycyclic components are contained.
For example, a suitable synthetic wax is available from Sasaol under the trade name TITANEL.
According to the invention, in the hair wax composition, the total content of the at least one synthetic wax is from 1.0 to 15.0% by weight, preferably from 3.0 to 12.0% by weight, relative to the total weight of the composition.
Natural waxes are derived from natural sources, in particular from plants or insects. One well-known wax is beeswax, which is produced by bees. It contains a mixture of components, of which palmitate, palmitoleate and oleate of long-chain fatty alcohols (30 to 32 carbon atoms) are the main components, of the formula CH3(CH2)29O-CO-(CH2)14CH3Triacontyl palmitate of the formula with CH3(CH2)24The wax acid ratio of COOH was 6:1, both of which are the two main components of beeswax. Beeswax useful in the cosmetic composition may be purchased from Koster Keunen as Permulgin 1550BDF and/or from Kahl as Kahlwax 2956.
Another source of natural waxes is plants. It is advantageous if the wax is extracted from the leaves of the carnauba tree (copernica cerifera) or from the leaves of the candelilla (Euphorbia cerifera) and/or Euphorbia cerifera (Euphorbia antayphyllitica). Waxes from these plants are called carnauba wax and candelilla wax, respectively. For example, carnauba wax is available from Kahl as Kahlwax 2442L.
Preferably, in addition to the synthetic waxes, one or more waxes derived from natural sources, preferably beeswax and/or carnauba wax, are also contained in the compositions of the invention.
In addition, cetyl esters may be included. Cetyl esters are blends of the reaction products of myristyl, cetyl and palmitic alcohols with myristic and palmitic acids, the main component of cetyl esters being cetyl palmitate. Sometimes, cetyl esters are also referred to as "synthetic waxes". They were introduced as a replacement for spermaceti. However, in the meaning of the present invention, cetyl esters will only be named cetyl esters. Because they are chemically different from the synthetic waxes described above, a precise distinction will be made between synthetic waxes and cetyl esters throughout the present invention.
In addition, the compositions of the present invention may contain synthetic beeswax. Synthetic beeswax is a manufactured wax that is a blend of fatty esters (C32-C62), fatty acids (C16-C36), fatty alcohols (C16-C36), and high molecular weight hydrocarbons (C21-C34). The highest ester content is followed by hydrocarbons, acids and alcohols.
To produce the comparative examples, waxes derived from fossil sources, such as paraffin wax, microcrystalline wax and ozokerite, were used.
The total amount of the one or more waxes contained in the composition of the invention is from 1.0 to 20.0% by weight, preferably from 3.0 to 15.0% by weight, relative to the total weight of the composition.
According to the invention, the hair wax composition contains at least one oil.
To distinguish between oil and wax, oil is fluid at room temperature.
According to the invention, the at least one oil may be chosen from lecithin and fatty acid triglycerides, i.e. triglycerides of saturated and/or unsaturated, branched and/or unbranched alkanecarboxylic acids having a chain length of 8 to 24, in particular 12 to 18, carbon atoms, with the proviso that the triglycerides are fluid at room temperature. For example, the fatty acid triglycerides may advantageously be selected from synthetic or semi-synthetic and natural oils, such as caprylic/capric triglyceride, cocoglyceride, olive oil, sunflower oil, soybean oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, castor oil, wheat germ oil, grape seed oil, thistle oil, evening primrose oil, macadamia nut oil and the like. Preferably, caprylic/capric triglyceride is included in the compositions of the invention.
According to the invention, the at least one oil may be chosen from linear silicone oils.
Silicone oil is a synthetic polymeric compound in which silicon atoms are linked in a chain and/or network-like manner through oxygen atoms, and the remaining valencies of the silicon are saturated with hydrocarbon groups (in most cases methyl, less commonly ethyl, propyl, phenyl groups, etc.). Systematically, silicone oils are known as polyorganosiloxanes. Methyl-substituted polyorganosiloxanes are the most important compounds of this group in terms of amount and are characterized by the following formula:
wherein n is 2 to about 2000.
Methyl-substituted polyorganosiloxanes are also known as polydimethylsiloxanes or dimethylpolysiloxanes (INCI). Polydimethylsiloxanes have various chain lengths and various molecular weights. For example, suitable polydimethylsiloxanes are available from KCC as SF1000N-350 cst.
According to the invention, the at least one oil may be chosen from esters of saturated and/or unsaturated, branched and/or unbranched alkane carboxylic acids with a chain length of 3 to 30 carbon atoms and saturated and/or unsaturated, branched and/or unbranched alcohols with a chain length of 3 to 30 carbon atoms, and from esters of aromatic carboxylic acids with saturated and/or unsaturated, branched and/or unbranched alcohols with a chain length of 3 to 30 carbon atoms, with the proviso that the esters are fluid at room temperature. Examples of such ester oils may be octyl palmitate, isopropyl myristate, isopropyl palmitate and/or C12-15 alkyl benzoate. Preferably, the compositions of the present invention contain C12-15 alkyl benzoate.
To produce the comparative examples, oils derived from fossil sources, such as liquid paraffin, were used.
According to the invention, one of the oils is preferably chosen from linear silicone oils, and it is particularly preferred that one of the oils is a polydimethylsiloxane. It is further preferred that one of the oils is selected from fatty acid triglycerides, especially caprylic/capric triglyceride. It is also further preferred that the compositions of the present invention contain C12-15 alkyl benzoate. More preferably, the compositions of the present invention comprise one or more polydimethylsiloxanes and caprylic/capric triglycerides and/or C12-15 alkyl benzoates.
According to the invention, the total content of said at least one oil is from 1.0 to 15.0% by weight, preferably from 2.0 to 8.0% by weight, relative to the total weight of the composition.
According to the invention, at least one emulsifier is contained in the composition according to the invention. The emulsifier stabilizes the emulsion. In general, an emulsion is understood to mean a heterogeneous system consisting of at least two liquids which are immiscible or have only a limited miscibility with each other and are generally referred to as phases. In an emulsion, one of the two liquids (water or oil) is dispersed in the other liquid (water or oil, respectively) in the form of very fine droplets. The liquids (pure or as solutions) are present in the emulsion in a more or less fine distribution, usually with only limited stability.
Emulsifiers help to combine two immiscible liquids in some way (e.g., oil-in-water), resulting in a stable formulation, i.e., an emulsion. For this purpose, the emulsifier must have amphiphilic properties, the hydrophobic part interacting with the oil or lipid phase and the hydrophilic part with the aqueous phase. By stirring or homogenizing, the resulting droplets are dispersed in the respective environment, i.e. aqueous droplets in a lipid environment or lipid droplets in an aqueous environment. First, the emulsifier does not have detersive surfactant properties. The emulsifier reduces the interfacial tension between the two phases and at the same time reduces the interfacial work and also stabilizes the emulsion formed. They stabilize the formed emulsion by the interfacial film and by forming a spatial or electrical barrier, thereby preventing coalescence (coalescence) of the emulsified particles.
The HLB value is suitable for characterizing an emulsifier, which value indicates the hydrophilicity of a given emulsifier. The HLB value can be determined by the following formula:
HLB＝20×(1-Mlipophilic nature/M)，
Wherein M isLipophilic natureDenotes the molar mass of the lipophilic part of a given emulsifier, and M denotes the molar mass of the total emulsifier.
Generally, emulsifiers having HLB values up to about 8 are considered W/O emulsifiers. In contrast, the HLB value of O/W emulsifiers is greater than 8 to 15. Substances with HLB values greater than 15 are often referred to as solubilizers.
Emulsifiers can be further classified as anionic, amphoteric and nonionic emulsifiers. According to the invention, nonionic emulsifiers are preferably present. Examples of nonionic emulsifiers are:
partial fatty acid esters and fatty acid esters of polyhydric alcohols and ethoxylated derivatives thereof (e.g. glycerol monostearate, sorbitan stearate, glycerol stearyl citrate, sucrose stearate), and
ethoxylated fatty alcohols and fatty acids.
The partial fatty acid esters may be monoglycerides of saturated and/or unsaturated, branched and/or unbranched alkanecarboxylic acids having a chain length of 8 to 24, in particular 12 to 18, carbon atoms, diglycerides of saturated and/or unsaturated, branched and/or unbranched alkanecarboxylic acids having a chain length of 8 to 24, in particular 12 to 18, carbon atoms. More preferably according to the invention, the emulsifier is a monoglyceride of a saturated and/or unsaturated, branched and/or unbranched alkanecarboxylic acid having a chain length of 8 to 24, in particular 12 to 18 carbon atoms, especially selected from the group consisting of glycerol monostearate, glycerol monoisostearate, glycerol monomyristate, glycerol monooleate, most preferably glycerol monostearate, commercially available from BASF as Cutina GMS V.
The ethoxylated derivative may be a polyethoxylated fatty acid ester having a chain length of 10 to 40 carbon atoms and a degree of ethoxylation of 5 to 200. More preferably, according to the present invention, the emulsifier is selected from the group consisting of PEG-9 stearate, PEG-8 distearate, PEG-20 stearate, PEG-8 oleate, PEG-25 glyceryl trioleate, PEG-40 sorbitan lanolate, PEG-15 glyceryl ricinoleate, PEG-20 glyceryl stearate, PEG-20 glyceryl isostearate, PEG-20 glyceryl oleate, PEG-20 methyl glucose sesquistearate, PEG-30 glyceryl isostearate, PEG-20 glyceryl laurate, PEG-30 stearate, PEG-30 glyceryl stearate, PEG-40 stearate, PEG-30 glyceryl laurate, PEG-50 stearate, PEG-100 stearate, and PEG-150 laurate. Most preferably, the compositions of the present invention comprise PEG-100 stearate. For example, PEG-100 stearate is commercially available from Croda as SP MYRJ S100 MBAL-PA- (SG) ET 80149.
The ethoxylated fatty alcohol may be chosen from ethoxylated stearyl alcohol, cetyl alcohol, cetostearyl alcohol (cetostearyl alcohol), examples of which can be found in the following list: polyethylene glycol (13) stearyl ether (steareth-13), polyethylene glycol (14) stearyl ether (steareth-14), polyethylene glycol (15) stearyl ether (steareth-15), polyethylene glycol (16) stearyl ether (steareth-16), polyethylene glycol (17) stearyl ether (steareth-17), polyethylene glycol (18) stearyl ether (steareth-18), polyethylene glycol (19) stearyl ether (steareth-19), polyethylene glycol (20) stearyl ether (steareth-20), polyethylene glycol (12) isostearyl ether (isosteareth-12), polyethylene glycol (13) isostearyl ether (isosteareth-13), polyethylene glycol (14) isostearyl ether (isosteareth-14), polyethylene glycol (15) isostearyl ether (isosteareth-15), polyethylene glycol (16) isostearyl ether (isosteareth-16), polyethylene glycol (17) isostearyl ether (isosteareth-17), polyethylene glycol (18) isostearyl ether (isosteareth-18), polyethylene glycol (19) isostearyl ether (isosteareth-19), polyethylene glycol (20) isostearyl ether (isosteareth-20), polyethylene glycol (13) cetyl ether (cetearyl-13), polyethylene glycol (14) cetyl ether (cetearyl-14), polyethylene glycol (15) cetyl ether (cetearyl-15), polyethylene glycol (16) cetyl ether (cetearyl-16), polyethylene glycol (17) cetyl ether (cetearyl-17), polyethylene glycol (18) cetyl ether (cetearyl-18), polyethylene glycol (19) cetyl ether (cetearyl-19), polyethylene glycol (20) cetyl ether (ceteth-20), polyethylene glycol (13) isocetyl ether (isocetyl-13), polyethylene glycol (14) isocetyl ether (isocetyl-14), polyethylene glycol (15) isocetyl ether (isocetyl-15), polyethylene glycol (16) isocetyl ether (isocetyl-16), polyethylene glycol (17) isocetyl ether (isocetyl-17), polyethylene glycol (18) isocetyl ether (isocetyl-18), polyethylene glycol (19) isocetyl ether (isocetyl-19), polyethylene glycol (20) isocetyl ether (isocetyl-20), polyethylene glycol (12) oleyl ether (oleyl-12), polyethylene glycol (13) oleyl ether (oleyl-13), polyethylene glycol (14) oleyl ether (oleyl-14), polyethylene glycol (15) oleyl ether (oleyl-ether-15), polyethylene glycol (12) lauryl ether (laureth-12), polyethylene glycol (12) lauryl ether (isolaureth-12), polyethylene glycol (13) cetearyl ether (ceteareth-13), polyethylene glycol (14) cetearyl ether (ceteareth-14), polyethylene glycol (15) cetearyl ether (ceteareth-15), polyethylene glycol (16) cetearyl ether (ceteareth-16), polyethylene glycol (17) cetearyl ether (ceteareth-17), polyethylene glycol (18) cetearyl ether (ceteareth-18), polyethylene glycol (19) cetearyl ether (ceteareth-19), polyethylene glycol (20) cetearyl ether (ceteareth-20). According to the invention, it is preferred to include polyethylene glycol (20) cetearyl ether (ceteareth-20) in the compositions of the invention.
According to the invention, it is advantageous if two emulsifiers having different HLB values, in particular three emulsifiers having different HLB values, are present. In a very advantageous embodiment, the composition according to the invention comprises glyceryl stearate, PEG-100 stearate and polyethylene glycol (20) cetearyl ether (ceteareth-20). It is furthermore advantageous if the weight ratio of glyceryl stearate to PEG-100 stearate to polyethylene glycol (20) cetearyl ether (ceteareth-20) is from 2.5:1.5:0.45 to 1.5:1.5: 0.45.
According to the invention, the total content of said at least one emulsifier is from 1.0 to 10.0% by weight, preferably from 2.0 to 5.0% by weight, relative to the total weight of the composition.
Advantageously, according to the invention, the composition according to the invention additionally comprises at least one styling polymer. Styling polymers can create very small bridges between individual hairs or strands of hair, thereby securing the hair. Modeling polymers are known in the art. They can be classified into anionic polymers, nonionic polymers and cationic polymers.
According to the invention, it is preferred to include at least one nonionic structuring polymer in the compositions of the invention. The nonionic styling polymer may be a homopolymer of vinylpyrrolidone, a homopolymer of N-vinylformamide, or a homopolymer of N-vinylcaprolactam. Also suitable are copolymers of vinylpyrrolidone and vinyl acetate or copolymers of vinylpyrrolidone and dimethylaminoethyl methacrylate, terpolymers of vinylpyrrolidone, vinyl acetate and propionate or terpolymers of vinylcaprolactam, vinylpyrrolidone and dimethylamino methacrylate. According to the invention, preference is given to compositions according to the invention which comprise homopolymers of vinylpyrrolidone. Homopolymers of vinyl pyrrolidone are available from BASF as Luviskol K90 AT 1 lsg.20%.
If at least one styling polymer is present in the composition according to the invention, the at least one styling polymer is preferably present in a total amount of from 0.1 to 3.0% by weight, more preferably from 0.5 to 2.0% by weight, relative to the total weight of the composition. The values refer to the active content of the styling polymer.
Advantageously, according to the invention, the composition of the invention additionally comprises at least one humectant. Humectants are hygroscopic substances that bind water and thereby provide moisture. This hygroscopic quality is due to the hydrophilic substituents of the molecule, in many cases hydroxyl groups, but other functional groups such as amine or carboxyl groups can fulfil the same function. Examples of humectants are propylene glycol, butylene glycol, glycerol, sorbitol, xylitol, maltitol, polydextrose, hydrogenated starch hydrolysates, urea, alpha-hydroxy acids such as lactic acid, and/or honey. Preferred humectants are hydrogenated starch hydrolysates and/or propylene glycol.
If at least one humectant is present in the composition of the present invention, the at least one humectant is preferably present in a total amount of from 1.0 to 20.0 wt%, more preferably from 5.0 to 15.0 wt%, relative to the total weight of the composition.
Advantageously, according to the invention, the composition of the invention additionally comprises at least one thickener. Thickeners are macromolecules having a predominantly linear configuration and also having varying degrees of intermolecular interaction forces that allow for secondary and primary valencies between the various residues of the molecule, thereby forming a network. Thickeners may be water soluble natural or synthetic polymers which form gels or viscous solutions in aqueous systems. They increase the viscosity of water by binding water molecules (hydration) or by absorbing and entrapping water in their macromolecules, which may be interlaced with each other; both effects result in limiting the mobility of water. Such water-soluble polymers represent a large group of chemically very different natural and synthetic polymers, which have in common the characteristic of their solubility in water or aqueous media. A prerequisite for water solubility is a sufficient number of hydrophilic groups to ensure water solubility and limited crosslinking. The hydrophilic group may be a nonionic group, an anionic group, or a cationic group.
Cosmetically relevant thickeners can be classified as follows:
organic, natural compounds, such as agar-agar, carrageenan, tragacanth, acacia, alginates, pectins, polysaccharides, guar flour, carob flour, starch, dextrin, gelatin, casein,
organic, modified natural substances, such as carboxymethylcellulose and other cellulose ethers, hydroxyethylcellulose and hydroxypropylcellulose, and the like,
organic, fully synthetic compounds, such as polyacrylic and polymethacrylic compounds, vinyl polymers, polycarboxylic acids, polyethers, polyimines, polyamides,
inorganic compounds, for example polysilicic acids, clay minerals such as montmorillonite, zeolites, silicas.
According to the invention, preference is given to the compositions according to the invention containing polyacrylates. More preferably a copolymer comprising one or more monomers of acrylic acid, methacrylic acid or esters thereof and a C10-30 alkyl acrylate. More preferably, a copolymer having the INCI name "acrylate/C10-30 alkyl acrylate crosspolymer" is selected. Such polymers are available, for example, from Lubrizol Advanced Materials under the trade name Carbopol Ultrez 21.
If at least one thickener is present in the composition according to the invention, the at least one thickener is preferably present in a total amount of from 0.05 to 1.0% by weight, more preferably from 0.1 to 0.5% by weight, relative to the total weight of the composition. The values refer to the active content of the thickener.
Advantageously, according to the invention, the composition of the invention additionally comprises at least one preservative. All preservatives permitted and suitable for use in cosmetic preparations may be present. However, methyl paraben, ethyl paraben and phenoxyethanol, or mixtures thereof, are preferred. Other preservatives, such as benzyl alcohol, methylisothiazolinone, methylchloroisothiazolinone and/or DMDM hydantoin, may also be used. These preservatives can be used alone or in combination with the preferred preservatives described above.
If at least one preservative is present in the composition of the invention, the at least one preservative is preferably present in a total amount of 0.01 to 2.0 wt.%, more preferably 0.05 to 1.0 wt.%, relative to the total weight of the composition. The values refer to the active content of the preservative.
The pH of the composition of the invention can be adjusted in all ways suitable for cosmetic compositions. However, it is preferred to contain an appropriate amount of an inorganic or organic base, especially sodium hydroxide and/or potassium hydroxide, to adjust the pH. Advantageously, the pH of the composition of the invention is in the range of 5.5 to 8.5, preferably 6.5 to 7.5.
Detailed Description
The following examples are intended to illustrate the invention without limiting it. The values in the examples are given as weight percent based on the total weight of the particular formulation, in active content.
Preparation method
The compositions of the present invention may be prepared by any known or effective technique for preparing hair wax compositions. Methods of preparing the compositions of the present invention include conventional formulation and mixing techniques.
Specifically, the compositions of the present invention and comparative compositions are preferably produced using the following procedure (table 1 shows the detailed composition of the examples, table 3 shows the corresponding trade names and INCI names of the components):
heating the oily phase (for example C12-15 alkyl benzoate, dimethicone, glyceryl stearate, ceteareth-20, PEG-100 stearate, synthetic wax, carnauba wax (Copernicia Cerifera), beeswax, methylparaben and phenoxyethanol) to 90 ℃,
heating the aqueous phase (e.g. water, PEG-32, propylene glycol, hydrogenated starch hydrolysate, acrylate/C10-30 alkyl acrylate crosspolymer, trisodium EDTA) to 90 ℃,
-combining the two phases while stirring, then homogenizing the batch until homogeneous in appearance,
-adding sodium hydroxide and water, continuously stirring and homogenizing,
-cooling to 45 deg.C,
addition of styling polymers (e.g. PVP) and perfumes,
continuous stirring and cooling to room temperature.
Test method
In order to demonstrate that the hair wax composition without the fossil-derived wax or oil has comparable properties in terms of styling, holding and spreadability to hair wax compositions containing raw materials derived from fossil sources, a hair tress test was performed. The test was performed by the following procedure:
the compositions according to the invention (examples 1.1, 2 to 5) and the comparative compositions (examples 1, 6 to 11) were prepared, the compositions according to the invention being free of waxes of fossil origin and free of oils of fossil origin, while the comparative examples contain waxes and/or oils of fossil origin.
The 3-D hair tresses were washed using a standard shampoo and then rinsed until no shampoo and other residue remained. The hair tresses were allowed to dry at room temperature. 1.0g of the styling composition was evenly spread over 8g of dry hair tresses. Ten trained panelists evaluated the spreadability by giving a score on how easy the respective composition was to be applied to the hair. The easier the application, the higher the score obtained for the corresponding composition. The styling effect was evaluated by giving a score of how easily it was to erect the hair (from the horizontal position to the upright position). The easier it is to erect the hair, the higher the score obtained for the corresponding composition. The hold effect was evaluated by determining how long the pattern of the hair strand lasted. The longer the time, the higher the score obtained for the corresponding composition.
Each parameter is rated with a score between 1 and 10, where 1 means "poor" and 10 is equivalent to very good.
Table 3: trade name and INCI of compound:
observing the overall evaluation, it is clear that on average the hair wax compositions containing synthetic waxes produced by the fischer-tropsch synthesis (referred to as synthetic waxes) (examples 1.1, 2 to 5) are slightly better than the compositions containing raw materials of fossil origin (examples 1, 6 to 11). It is thus shown that the compositions of the invention do have properties at least at the same level or even better than those containing waxes and oils of fossil origin.
Observing the evaluations in more detail, it is clear that the compositions having a good evaluation in terms of spreadability mostly have a poor evaluation with respect to styling and holding effects (examples 2, 8, 9 and 10). The same is true for the opposite case, the example compositions having a good evaluation in terms of build and hold effect have a poor evaluation with respect to spreadability (examples 3, 4 and 5). Neither spreadability nor styling and holding effects should be too poor in order to provide a consumer acceptable product. Therefore, compositions that are not poorly rated with respect to spreadability and styling and hold effects are best suited to meet the desires of the consumer. Thus, the composition of example 1.1 can be considered as the optimal composition, and was not evaluated as poor in both categories. It is therefore clear that great care must be taken to maintain a delicate balance between good spreadability and good styling and holding effect.
Claims (22)
1. A hair wax composition comprises
-at least one synthetic wax,
-at least one oil, and
-at least one emulsifier, wherein the composition is free of waxes and/or oils derived from fossil origin.
2. Composition according to claim 1, characterized in that it contains from 50 to 80% by weight, preferably from 60 to 75% by weight, of water relative to the total weight of the composition.
3. Composition according to claim 1 or 2, characterized in that the at least one synthetic wax is produced from carbon monoxide and hydrogen by the fischer-tropsch process.
4. Composition according to any one of the preceding claims, characterized in that the total content of said at least one synthetic wax is from 1.0 to 15.0% by weight, preferably from 3.0 to 12.0% by weight, relative to the total weight of the composition.
5. Composition according to any one of the preceding claims, characterized in that it additionally contains at least one wax derived from natural sources, in particular from plants and insects.
6. Composition according to claim 5, characterized in that the at least one wax derived from natural sources is chosen from beeswax, carnauba wax and/or candelilla wax.
7. Composition according to claim 5 or 6, characterized in that the total amount of wax ranges from 1.0 to 20.0% by weight, preferably from 3.0 to 15.0% by weight, relative to the total weight of the composition.
8. Composition according to any one of the preceding claims, characterized in that the at least one oil is chosen from
Triglycerides of saturated and/or unsaturated, branched and/or unbranched alkanecarboxylic acids having a chain length of 8 to 24, in particular caprylic/capric triglyceride;
-linear silicone oils, in particular polydimethylsiloxanes;
-esters of saturated and/or unsaturated, branched and/or unbranched alkane carboxylic acids with a chain length of 3 to 30 carbon atoms with saturated and/or unsaturated, branched and/or unbranched alcohols with a chain length of 3 to 30 carbon atoms, and esters selected from aromatic carboxylic acids with saturated and/or unsaturated, branched and/or unbranched alcohols with a chain length of 3 to 30 carbon atoms, with the proviso that the esters are fluid at room temperature, preferably C12-15 alkyl benzoate.
9. Composition according to any one of the preceding claims, characterized in that the total content of said at least one oil is from 1.0 to 15.0% by weight, preferably from 2.0 to 8.0% by weight, relative to the total weight of the composition.
10. Composition according to any one of the preceding claims, characterized in that the at least one emulsifier is a non-ionic emulsifier, preferably selected from
Partial fatty acid esters and fatty acid esters of polyhydric alcohols and ethoxylated derivatives thereof (e.g. glycerol monostearate, sorbitan stearate, glycerol stearyl citrate, sucrose stearate), and
ethoxylated fatty alcohols and fatty acids.
11. Composition according to claim 10, characterized in that the partial fatty acid ester is a monoglyceride of a saturated and/or unsaturated, branched and/or unbranched alkane carboxylic acid having a chain length of 8 to 24, preferably selected from the group consisting of glyceryl monostearate, glyceryl monoisostearate, glyceryl monomyristate, glyceryl monooleate, more preferably glyceryl monostearate.
12. Composition according to claim 10, characterized in that the ethoxylated derivative is a polyethoxylated fatty acid ester with a chain length of 10 to 40 carbon atoms and a degree of ethoxylation of 5 to 200, preferably selected from the group consisting of PEG-9 stearate, PEG-8 distearate, PEG-20 stearate, PEG-8 oleate, PEG-25 glyceryl trioleate, PEG-40 sorbitan lanolate, PEG-15 glyceryl ricinoleate, PEG-20 glyceryl stearate, PEG-20 glyceryl isostearate, PEG-20 glyceryl oleate, PEG-20 stearate, PEG-20 methyl glucose sesquistearate, PEG-30 glyceryl isostearate, PEG-20 glyceryl laurate, PEG-30 stearate, PEG-30 glyceryl stearate, PEG-40 stearate, PEG-30 glyceryl laurate, PEG-50 stearate, PEG-100 stearate, PEG-150 laurate, more preferably PEG-100 stearate.
13. Composition according to claim 10, characterized in that the ethoxylated fatty alcohol is chosen from ethoxylated stearyl alcohol, cetyl stearyl alcohol (cetearyl alcohol), preferably polyethylene glycol (13) stearyl ether (steareth-13), polyethylene glycol (14) stearyl ether (steareth-14), polyethylene glycol (15) stearyl ether (steareth-15), polyethylene glycol (16) stearyl ether (steareth-16), polyethylene glycol (17) stearyl ether (steareth-17), polyethylene glycol (18) stearyl ether (steareth-18), polyethylene glycol (19) stearyl ether (steareth-19), polyethylene glycol (20) stearyl ether (steareth-20), polyethylene glycol (12) isostearyl ether (isostearyl-12), Polyethylene glycol (13) isostearyl ether (isosteareth-13), polyethylene glycol (14) isostearyl ether (isosteareth-14), polyethylene glycol (15) isostearyl ether (isosteareth-15), polyethylene glycol (16) isostearyl ether (isosteareth-16), polyethylene glycol (17) isostearyl ether (isosteareth-17), polyethylene glycol (18) isostearyl ether (isosteareth-18), polyethylene glycol (19) isostearyl ether (isosteareth-19), polyethylene glycol (20) isostearyl ether (isosteareth-20), polyethylene glycol (13) cetyl ether (cetyl polyether-13), polyethylene glycol (14) cetyl ether (cetyl polyether-14), polyethylene glycol (15) cetyl ether (cetyl polyether-15), Polyethylene glycol (16) cetyl ether (ceteth-16), polyethylene glycol (17) cetyl ether (ceteth-17), polyethylene glycol (18) cetyl ether (ceteth-18), polyethylene glycol (19) cetyl ether (ceteth-19), polyethylene glycol (20) cetyl ether (ceteth-20), polyethylene glycol (13) isocetyl ether (isocetyl-13), polyethylene glycol (14) isocetyl ether (isocetyl-14), polyethylene glycol (15) isocetyl ether (isocetyl-15), polyethylene glycol (16) isocetyl ether (isocetyl-16), polyethylene glycol (17) isocetyl ether (isocetyl-17), polyethylene glycol (18) isocetyl ether (isocetyl-18), polyethylene glycol (19) isocetyl ether (isocetyl-19), Polyethylene glycol (20) isocetyl ether (isocetyl polyether-20), polyethylene glycol (12) oleyl ether (oleyl-12), polyethylene glycol (13) oleyl ether (oleyl-13), polyethylene glycol (14) oleyl ether (oleyl-14), polyethylene glycol (15) oleyl ether (oleyl-15), polyethylene glycol (12) lauryl ether (laureth-12), polyethylene glycol (12) lauryl ether (isolaureth-12), polyethylene glycol (13) cetearyl ether (ceteareth-13), polyethylene glycol (14) cetearyl ether (ceteareth-14), polyethylene glycol (15) cetearyl ether (ceteareth-15), polyethylene glycol (16) cetearyl ether (ceteareth-16), polyethylene glycol (17) cetearyl ether (cetearyl-17), Polyethylene glycol (18) cetearyl ether (ceteareth-18), polyethylene glycol (19) cetearyl ether (ceteareth-19), polyethylene glycol (20) cetearyl ether (ceteareth-20), most preferably polyethylene glycol (20) cetearyl ether (ceteareth-20).
14. Composition according to any one of the preceding claims, characterized in that the total content of said at least one emulsifier is from 1.0 to 10.0% by weight, preferably from 2.0 to 5.0% by weight, relative to the total weight of the composition.
15. Composition according to any one of the preceding claims, characterized in that it additionally contains at least one structuring polymer, preferably chosen from nonionic structuring polymers, more preferably homopolymers of vinylpyrrolidone, homopolymers of N-vinylformamide or homopolymers of N-vinylcaprolactam, or copolymers of vinylpyrrolidone and vinyl acetate or copolymers of vinylpyrrolidone and dimethylaminoethyl methacrylate, terpolymers of vinylpyrrolidone, vinyl acetate and propionate or terpolymers of vinylcaprolactam, vinylpyrrolidone and dimethylaminomethacrylate, most preferably homopolymers of vinylpyrrolidone.
16. Composition according to claim 15, characterized in that the total content of said at least one structuring polymer is from 0.1 to 3.0% by weight, more preferably from 0.5 to 2.0% by weight, relative to the total weight of the composition and relative to the active content of the structuring polymer.
17. Composition according to any one of the preceding claims, characterized in that it additionally contains at least one humectant, preferably chosen from propylene glycol, butylene glycol, glycerol, sorbitol, xylitol, maltitol, polydextrose, hydrogenated starch hydrolysates, urea, alpha-hydroxy acids such as lactic acid, and/or honey, more preferably chosen from hydrogenated starch hydrolysates and/or propylene glycol.
18. Composition according to claim 17, characterized in that the total content of said at least one humectant is from 1.0 to 20.0% by weight, more preferably from 5.0 to 15.0% by weight, relative to the total weight of the composition.
19. Composition according to any one of the preceding claims, characterized in that it additionally contains at least one thickener, preferably chosen from polyacrylates, more preferably from copolymers of one or more monomers chosen from acrylic acid, methacrylic acid or esters thereof with C10-30 alkyl acrylates, most preferably acrylate/C10-30 alkyl acrylate crosspolymers.
20. Composition according to claim 19, characterized in that the total content of said at least one thickening agent is from 0.05 to 1.0% by weight, more preferably from 0.1 to 0.5% by weight, relative to the total weight of the composition and relative to the active content.
21. A method of making the composition of any of the preceding claims, the method comprising the steps of:
heating the oil phase (comprising wax, oil and emulsifier),
heating the aqueous phase (including water, optional humectant and thickener),
the two phases were combined while stirring, and then the batch was homogenized until the appearance was uniform,
adding an inorganic or organic base and water to adjust the pH in the range of 5.5 to 8.5, preferably 6.5 to 7.5, continuously stirring and homogenizing,
the mixture is cooled down and then is cooled down,
optionally adding a styling polymer and perfume, and
continue stirring and cool to room temperature.
22. Use of a composition according to any one of claims 1 to 20 in hair styling.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2019/084465 WO2020215300A1 (en) | 2019-04-26 | 2019-04-26 | A Hair Wax Composition |
| CNPCT/CN2019/084465 | 2019-04-26 | ||
| PCT/EP2020/060369 WO2020216641A1 (en) | 2019-04-26 | 2020-04-14 | A hair wax composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113573692A true CN113573692A (en) | 2021-10-29 |
Family
ID=70292955
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202080021759.1A Pending CN113573692A (en) | 2019-04-26 | 2020-04-14 | Hair wax composition |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN113573692A (en) |
| WO (2) | WO2020215300A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4014959A1 (en) * | 2020-12-17 | 2022-06-22 | Kao Corporation | Solid hair styling composition |
| CN116270309A (en) * | 2022-11-15 | 2023-06-23 | 许华群 | Water-soluble hair oil capable of shaping and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040052744A1 (en) * | 2002-07-31 | 2004-03-18 | Sarah Maillefer | Hair wax products with a liquid or creamy consistency |
| US20050163738A1 (en) * | 2004-01-28 | 2005-07-28 | Marina Loifenfeld | Hair wax products containing silicone wax, silicone-free wax and oils |
| CN101203275A (en) * | 2005-06-20 | 2008-06-18 | 宝洁公司 | A product release system to atomize compositions containing hair-conditioning ingredients |
| WO2018098542A1 (en) * | 2016-12-02 | 2018-06-07 | L'oreal | Hair care composition and methods of use |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3917352B2 (en) * | 2000-02-25 | 2007-05-23 | 株式会社資生堂 | Hairdressing fee |
| JP4137766B2 (en) | 2002-11-09 | 2008-08-20 | ウエラ アクチェンゲゼルシャフト | Hair wax products containing polyethylene glycol wax and hydrophobic substances |
| JP2005314365A (en) | 2004-03-29 | 2005-11-10 | Kose Corp | Spray-type hair wax |
| DE602005010101D1 (en) | 2005-12-01 | 2008-11-13 | Wella Ag | Use of di- or oligosaccharide polyesters in hairstyling products |
| CN101433507A (en) * | 2007-11-14 | 2009-05-20 | 冷博 | Hair care product for preventing hair winding |
| CN103189404A (en) * | 2010-10-29 | 2013-07-03 | 三菱化学株式会社 | Copolymer and cosmetic material composition |
| CN105616197A (en) * | 2014-10-29 | 2016-06-01 | 胡粉玉 | Petrolatum hair wax |
| CN108653055A (en) * | 2018-07-13 | 2018-10-16 | 跨越生物科技（滁州）有限公司 | A kind of aqueous emulsus pomade |
-
2019
- 2019-04-26 WO PCT/CN2019/084465 patent/WO2020215300A1/en active Application Filing
-
2020
- 2020-04-14 WO PCT/EP2020/060369 patent/WO2020216641A1/en active Application Filing
- 2020-04-14 CN CN202080021759.1A patent/CN113573692A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040052744A1 (en) * | 2002-07-31 | 2004-03-18 | Sarah Maillefer | Hair wax products with a liquid or creamy consistency |
| US20050163738A1 (en) * | 2004-01-28 | 2005-07-28 | Marina Loifenfeld | Hair wax products containing silicone wax, silicone-free wax and oils |
| CN101203275A (en) * | 2005-06-20 | 2008-06-18 | 宝洁公司 | A product release system to atomize compositions containing hair-conditioning ingredients |
| WO2018098542A1 (en) * | 2016-12-02 | 2018-06-07 | L'oreal | Hair care composition and methods of use |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2020216641A1 (en) | 2020-10-29 |
| WO2020215300A1 (en) | 2020-10-29 |
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