CN111440670A - 一种清洁剂配方、清洁剂的制备方法及使用方法 - Google Patents
一种清洁剂配方、清洁剂的制备方法及使用方法 Download PDFInfo
- Publication number
- CN111440670A CN111440670A CN201910040712.9A CN201910040712A CN111440670A CN 111440670 A CN111440670 A CN 111440670A CN 201910040712 A CN201910040712 A CN 201910040712A CN 111440670 A CN111440670 A CN 111440670A
- Authority
- CN
- China
- Prior art keywords
- sodium
- parts
- cleaning agent
- detergent
- imidazoline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims abstract description 10
- 238000002360 preparation method Methods 0.000 title abstract description 7
- 239000003599 detergent Substances 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 18
- 239000004094 surface-active agent Substances 0.000 claims description 14
- 239000002738 chelating agent Substances 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 13
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
- 150000001447 alkali salts Chemical class 0.000 claims description 12
- 239000004115 Sodium Silicate Substances 0.000 claims description 9
- 238000009472 formulation Methods 0.000 claims description 9
- 239000003960 organic solvent Substances 0.000 claims description 9
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 9
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 102000004190 Enzymes Human genes 0.000 claims description 8
- 108090000790 Enzymes Proteins 0.000 claims description 8
- 239000007844 bleaching agent Substances 0.000 claims description 8
- -1 fatty acid salt Chemical class 0.000 claims description 8
- 239000002455 scale inhibitor Substances 0.000 claims description 8
- 239000012190 activator Substances 0.000 claims description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 238000004061 bleaching Methods 0.000 claims description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 6
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 239000004382 Amylase Substances 0.000 claims description 4
- 102000013142 Amylases Human genes 0.000 claims description 4
- 108010065511 Amylases Proteins 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- BQTOJCOSKKLTAB-UHFFFAOYSA-L [Na+].O1P(OC1CO)(=O)OP(=O)([O-])[O-].[Na+] Chemical compound [Na+].O1P(OC1CO)(=O)OP(=O)([O-])[O-].[Na+] BQTOJCOSKKLTAB-UHFFFAOYSA-L 0.000 claims description 4
- FENRSEGZMITUEF-ATTCVCFYSA-E [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].OP(=O)([O-])O[C@@H]1[C@@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H]1OP(=O)([O-])[O-] Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].OP(=O)([O-])O[C@@H]1[C@@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H]1OP(=O)([O-])[O-] FENRSEGZMITUEF-ATTCVCFYSA-E 0.000 claims description 4
- 235000019418 amylase Nutrition 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- 229940083982 sodium phytate Drugs 0.000 claims description 4
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 claims description 4
- 108091005804 Peptidases Proteins 0.000 claims description 3
- 239000004365 Protease Substances 0.000 claims description 3
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 3
- PDIZYYQQWUOPPK-UHFFFAOYSA-N acetic acid;2-(methylamino)acetic acid Chemical compound CC(O)=O.CC(O)=O.CNCC(O)=O PDIZYYQQWUOPPK-UHFFFAOYSA-N 0.000 claims description 3
- 239000013522 chelant Substances 0.000 claims description 3
- 230000007797 corrosion Effects 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- PMYUVOOOQDGQNW-UHFFFAOYSA-N hexasodium;trioxido(trioxidosilyloxy)silane Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] PMYUVOOOQDGQNW-UHFFFAOYSA-N 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical group CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 2
- FENFUOGYJVOCRY-UHFFFAOYSA-N 1-propoxypropan-2-ol Chemical compound CCCOCC(C)O FENFUOGYJVOCRY-UHFFFAOYSA-N 0.000 claims description 2
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 2
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 claims description 2
- QUPKCFBHJFNUEW-UHFFFAOYSA-N 2-ethyl-4,5-dihydro-1h-imidazole Chemical compound CCC1=NCCN1 QUPKCFBHJFNUEW-UHFFFAOYSA-N 0.000 claims description 2
- FDGBQHCDMSYZRC-UHFFFAOYSA-N 2-hydroxy-2-oxo-1,3,2$l^{5}-dioxaphosphinan-4-amine Chemical compound NC1CCOP(O)(=O)O1 FDGBQHCDMSYZRC-UHFFFAOYSA-N 0.000 claims description 2
- VWSLLSXLURJCDF-UHFFFAOYSA-N 2-methyl-4,5-dihydro-1h-imidazole Chemical compound CC1=NCCN1 VWSLLSXLURJCDF-UHFFFAOYSA-N 0.000 claims description 2
- 239000004155 Chlorine dioxide Substances 0.000 claims description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 claims description 2
- 102000004882 Lipase Human genes 0.000 claims description 2
- 239000004367 Lipase Substances 0.000 claims description 2
- 108090001060 Lipase Proteins 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- 239000005708 Sodium hypochlorite Substances 0.000 claims description 2
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 2
- DDAQLPYLBPPPRV-UHFFFAOYSA-N [4-(hydroxymethyl)-2-oxo-1,3,2lambda5-dioxaphosphetan-2-yl] dihydrogen phosphate Chemical compound OCC1OP(=O)(OP(O)(O)=O)O1 DDAQLPYLBPPPRV-UHFFFAOYSA-N 0.000 claims description 2
- 239000003945 anionic surfactant Substances 0.000 claims description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 2
- 239000012964 benzotriazole Substances 0.000 claims description 2
- 229960003237 betaine Drugs 0.000 claims description 2
- 235000019398 chlorine dioxide Nutrition 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical group [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims description 2
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- GXUACSARIHYYTF-UHFFFAOYSA-G heptasodium;[oxido-[oxido-[oxido(phosphonatooxy)phosphoryl]oxyphosphoryl]oxyphosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O GXUACSARIHYYTF-UHFFFAOYSA-G 0.000 claims description 2
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims description 2
- 235000019421 lipase Nutrition 0.000 claims description 2
- 235000002949 phytic acid Nutrition 0.000 claims description 2
- 239000004584 polyacrylic acid Substances 0.000 claims description 2
- 108010064470 polyaspartate Proteins 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 229940080818 propionamide Drugs 0.000 claims description 2
- 235000019419 proteases Nutrition 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 2
- 229960001922 sodium perborate Drugs 0.000 claims description 2
- 229940045872 sodium percarbonate Drugs 0.000 claims description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 2
- NWPMTMCXJZTLSO-UHFFFAOYSA-M sodium;4-acetyloxybenzenesulfonate Chemical compound [Na+].CC(=O)OC1=CC=C(S([O-])(=O)=O)C=C1 NWPMTMCXJZTLSO-UHFFFAOYSA-M 0.000 claims description 2
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 claims description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims description 2
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims description 2
- OHOTVSOGTVKXEL-WJXVXWFNSA-K trisodium;(2s)-2-[bis(carboxylatomethyl)amino]propanoate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)[C@H](C)N(CC([O-])=O)CC([O-])=O OHOTVSOGTVKXEL-WJXVXWFNSA-K 0.000 claims description 2
- GOHZKUSWWGUUNR-UHFFFAOYSA-N 2-(4,5-dihydroimidazol-1-yl)ethanol Chemical compound OCCN1CCN=C1 GOHZKUSWWGUUNR-UHFFFAOYSA-N 0.000 claims 1
- 101710180316 Protease 2 Proteins 0.000 claims 1
- JBFYUZGYRGXSFL-UHFFFAOYSA-N imidazolide Chemical compound C1=C[N-]C=N1 JBFYUZGYRGXSFL-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims 1
- 238000004140 cleaning Methods 0.000 description 13
- 235000013305 food Nutrition 0.000 description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000003344 environmental pollutant Substances 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 231100000719 pollutant Toxicity 0.000 description 3
- 241000251468 Actinopterygii Species 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 241000287828 Gallus gallus Species 0.000 description 2
- 244000017020 Ipomoea batatas Species 0.000 description 2
- 235000002678 Ipomoea batatas Nutrition 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000010411 cooking Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- WGTDLPBPQKAPMN-KTKRTIGZSA-N 2-[2-[(z)-heptadec-8-enyl]-4,5-dihydroimidazol-1-yl]ethanol Chemical compound CCCCCCCC\C=C/CCCCCCCC1=NCCN1CCO WGTDLPBPQKAPMN-KTKRTIGZSA-N 0.000 description 1
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 description 1
- CAAMSDWKXXPUJR-UHFFFAOYSA-N 3,5-dihydro-4H-imidazol-4-one Chemical compound O=C1CNC=N1 CAAMSDWKXXPUJR-UHFFFAOYSA-N 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000002354 daily effect Effects 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 231100000171 higher toxicity Toxicity 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229910052615 phyllosilicate Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/362—Phosphates or phosphites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38609—Protease or amylase in solid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- General Chemical & Material Sciences (AREA)
- Detergent Compositions (AREA)
Abstract
本发明涉及一种清洁剂配方、清洁剂的制备方法及使用方法，其中清洁剂配方包括下述重量组成：
Description
技术领域
本发明涉及到日用化学品领域，尤其涉及一种清洁剂配方及清洁剂的制备方法。
背景技术
蒸箱和烤箱在使用过程中会有食物滴落或飞溅到内胆表面，经高温加热后食物氧化固化，牢牢粘附在内胆表面，给用户清洗带来很大麻烦。现有技术方案是一种包含碱盐、表面活性剂、熬合剂、阻垢剂等成份的清洗剂，或者是用乙二醇醚类、异丙醇等有机溶剂进行清洗，这类溶剂有较大的毒性。含表面活性剂的清洗剂针对此类顽固污垢清洗效果差，清洗不干净。有机溶剂清洗效果相对较好，但也不能完全清洗干净，且有机溶剂易挥发吸入人体，危害人身健康。
CN200510027112.7公开了一种《高固体含量阻垢型机用餐具洗涤剂》，其包括：苛性碱30～50％；耐碱低泡表面活性剂1～5％；有机多元膦酸盐型阻垢剂0.5～5％；螯合剂10～40％；助洗剂5～25％；有机硅消泡剂0.5～3％；含氯杀菌剂0.1～1％；水余量。该申请将高浓度碱、低泡表面活性剂、螯合剂和有机多元膦酸盐复配，既提高去污力又降低表面活性剂和水中的钙、镁等离子同污垢中蛋白质、脂肪酸生成不溶于水的盐在导电电极表面结垢及在被清洗表面残留。无磷螯合剂含氯杀菌剂，具有杀菌作用。但是该洗涤剂对顽固类污垢清除效果不理想。
发明内容
本发明所要解决的技术问题是针对现有技术的现状提供一种能有效清除顽固污垢且环境友好的清洁剂配方。
本发明解决上述技术问题所采用的技术方案为：一种清洁剂配方，其特征在于包括下述重量组成：
所述碱盐选自碳酸钠和/或偏硅酸钠；
所述表面活性剂选自含脂肪酸盐阴离子表面活性剂、脂肪醇聚氧烷基醚非离子表面活性剂和EO-PO型嵌段聚醚非离子表面活性剂中的至少一种；
所述螯合剂选自柠檬酸盐、乙二胺四乙酸四钠、甲基甘氨酸二乙酸三钠、羟基乙叉二磷酸盐、二乙基二胺基五磷酸钠、氨基三亚甲基磷酸盐、聚天冬氨酸盐和植酸盐中的至少一种；
所述漂白剂选自过碳酸钠、过硼酸钠、过硫酸钠、次氯酸钠或二氧化氯；
所述漂白活性剂选自四乙酰基乙二胺、对乙酰氧基苯磺酸钠或三乙酰基乙氰脲酸酯；
所述阻垢剂选自聚丙烯酸、丙烯酸与马来酸酐共聚物、环氧琥珀酸钠和丙烯酸与丙酰胺共聚物中的至少一种；
所述水溶性有机溶剂选自丙二醇甲醚、丙二醇正丁醚、丙二醇正丙醚、二丙二醇正丙醚和三异丙醇胺中的至少一种；
所述缓蚀剂选自苯并三氮唑和咪唑琳复合物中的至少一种；
所述酶选自脂肪酶、淀粉酶和蛋白酶中的至少一种。
优选所述碱盐包括碳酸钠15-30份和偏硅酸钠5-10份。
更优选所述碱盐包括碳酸钠25份和偏硅酸钠10份；所述氢氧化钠用量为0份。
优选所述酶为淀粉酶1份和蛋白酶2份。
较好的，所述螯合剂可以包括羟基乙叉二磷酸钠1-5份、甲基甘氨酸二乙酸三钠5-15份和植酸钠1-5份。
更好地，所述螯合剂包括羟基乙叉二磷酸钠3份、甲基甘氨酸二乙酸三钠5份和植酸钠2份。
上述各方案中，所述咪唑淋复合物优选自2-甲基咪唑啉、2-乙基咪唑啉、油酸基羟乙基咪唑啉、甜菜碱咪唑啉、咪唑啉酰胺和环烷基咪唑啉中的至少一种。
作为优选，所述层状结晶二硅酸钠的用量为10-20份。
更好地，所述层状结晶二硅酸钠的用量为10重量份。
使用上述各方案中清洁剂配方制备清洁剂的方法，其特征在于包括下述步骤：
1)按配方称取各组分
2)将所述碱盐、螯合剂、漂白剂、阻垢剂依次加入到容器中，并搅拌均匀；
3)向容器中加入所述的漂白活性剂和酶，搅拌均匀；
4)向容器中加入所述的有机溶剂以及预先混合好的表面活性剂和改性层状硅酸钠的混合物，搅拌均匀，得到清洁剂混合物；
5)对所述清洁剂混合物研磨成粒度均匀的粉末，即得到清洁剂粉末。
使用所制备的清洁剂的方法，其特征在于将制备得到的清洁剂粉末加5～10倍的水稀释后使用。
本申请中的碱盐能够提供本配方碱性环境，以利于油脂的皂化并协同表面活性剂促乳化；表面活性剂通过渗透、润湿、乳化促使污物脱离基材表面；螯合剂能螯合硬水和污物中的钙镁铁锌等离子，防止表面活性剂因硬水而失效，并使污物中钙镁离子与螯合剂螯合而脱离基材；漂白剂有助于污物因氧化而分解，从而脱离基材表面；漂白活性剂协助漂白剂分解出活性氧；阻垢剂防止污物二次沉淀；水溶性有机溶剂能渗透污物底层，促使污物溶胀溶解；缓蚀剂能保护基材不被腐蚀；酶能分解相应的污物；改性层状二硅酸盐能在配料时吸附表面活性剂，在清洗时能吸附钙镁离子和污物，并可用作擦拭时的研磨剂。
与现有技术相比，本发明所提供的清洁剂配方、清洁剂制备方法以及使用方法能够轻松、有效地清除顽固污渍，且环境友好，符合GB14930.1《食品安全国家标准洗涤剂》标准，尤其适合作为食品容器的清洁剂使用。
具体实施方式
以下结合实施例对本发明作进一步详细描述。
实施例1至实施例5的配方如表1所示。
清洁剂的制备方法如下：
1)按配方称取各组分
2)将所述碱盐、螯合剂、漂白剂、阻垢剂依次加入到容器中，并搅拌均匀；
3)向容器中加入所述的漂白活性剂和酶，搅拌均匀；
4)向容器中加入所述的有机溶剂以及预先混合好的表面活性剂和改性层状硅酸钠的混合物，搅拌均匀，得到清洁剂混合物；
5)对所述清洁剂混合物研磨成粒度均匀的粉末，即得到清洁剂粉末。
表1
注：表1中的四乙酰基乙二胺为漂白活性物。
对上述各实施例制备得到的清洁剂粉末进行检测，各实施例产品均符合GB14930.1《食品安全国家标准洗涤剂》。
洗涤性能测试：
1、标准污染物的制备
蒸箱或烤箱烹饪的食物种类繁多，归纳一下为蛋白质、脂肪、淀粉三大类，我们以这三大类污染物中最难处理的代表食物为标准污染物，分别是鸡翅、鱼和番薯，而且采用蒸烤组合的烹饪工艺，分别将规定数量的鸡翅、鱼和番薯按程序烹饪完毕，以此为一个循环，每天两个循环，以五天后混合残留物为最终的标准污染物。
2、清洗
使用方太ZK55-Z3蒸烤箱，选择清洗程序，清洗温度为60℃-70℃，清洗时间20分钟，清洗过程中对内胆间隔喷300克水蒸汽。将被清洗的内胆底部均匀涂上30克清洗剂粉末，开启清洗程序进行清洗，清洗程序结束后冷却，再用抹布擦拭内胆表面，观察清洁程度。
清洗结果如表2所示：
表2
注：表2中的对比1采用的是米勒内胆清洗剂替换实施例粉末；对比例2采用市售洗碗粉替换实施例粉末。
Claims (10)
1.一种清洁剂配方，其特征在于包括下述重量组成：
所述碱盐选自碳酸钠和/或偏硅酸钠；
所述表面活性剂选自含脂肪酸盐阴离子表面活性剂、脂肪醇聚氧烷基醚非离子表面活性剂和EO-PO型嵌段聚醚非离子表面活性剂中的至少一种；
所述螯合剂选自柠檬酸盐、乙二胺四乙酸四钠、甲基甘氨酸二乙酸三钠、羟基乙叉二磷酸盐、二乙基二胺基五磷酸钠、氨基三亚甲基磷酸盐、聚天冬氨酸盐和植酸盐中的至少一种；
所述漂白剂选自过碳酸钠、过硼酸钠、过硫酸钠、次氯酸钠或二氧化氯；
所述漂白活性剂选自四乙酰基乙二胺、对乙酰氧基苯磺酸钠或三乙酰基乙氰脲酸酯；
所述阻垢剂选自聚丙烯酸、丙烯酸与马来酸酐共聚物、环氧琥珀酸钠和丙烯酸与丙酰胺共聚物中的至少一种；
所述水溶性有机溶剂选自丙二醇甲醚、丙二醇正丁醚、丙二醇正丙醚、二丙二醇正丙醚和三异丙醇胺中的至少一种；
所述缓蚀剂选自苯并三氮唑和咪唑琳复合物中的至少一种；
所述酶选自脂肪酶、淀粉酶和蛋白酶中的至少一种。
2.根据权利要求1所述的清洁剂配方，其特征在于所述碱盐包括碳酸钠15-30份和偏硅酸钠5-10份。
3.根据权利要求2所述的清洁剂配方，其特征在于所述碱盐包括碳酸钠25份和偏硅酸钠10份；所述氢氧化钠用量为0份。
4.根据权利要求1所述的清洁剂配方，其特征在于所述酶为淀粉酶1份和蛋白酶2份。
5.根据权利要求1所述的清洁剂配方，其特征在于所述螯合剂包括羟基乙叉二磷酸钠1-5份、甲基甘氨酸二乙酸三钠5-15份和植酸钠1-5份。
6.根据权利要求5所述的清洁剂配方，其特征在于所述螯合剂包括羟基乙叉二磷酸钠3份、甲基甘氨酸二乙酸三钠5份和植酸钠2份。
7.根据权利要求1所述的清洁剂配方，其特征在于所述咪唑淋复合物选自2-甲基咪唑啉、2-乙基咪唑啉、油酸基羟乙基咪唑啉、甜菜碱咪唑啉、咪唑啉酰胺和环烷基咪唑啉中的至少一种。
8.根据权利要求1至6任一项所述的清洁剂配方，其特征在于所述层状结晶二硅酸钠的用量为10-20份。
9.如权利要求1至8任一项所述的清洁剂配方的制备方法，其特征在于包括下述步骤：
1)按配方称取各组分
2)将所述碱盐、螯合剂、漂白剂、阻垢剂依次加入到容器中，并搅拌均匀；
3)向容器中加入所述的漂白活性剂和酶，搅拌均匀；
4)向容器中加入所述的有机溶剂以及预先混合好的表面活性剂和改性层状硅酸钠的混合物，搅拌均匀，得到清洁剂混合物；
5)对所述清洁剂混合物研磨成粒度均匀的粉末，即得到清洁剂粉末。
10.使用如权利要求9所制备的清洁剂的方法，其特征在于将制备得到的清洁剂粉末加5～10倍的水稀释后使用。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910040712.9A CN111440670A (zh) | 2019-01-16 | 2019-01-16 | 一种清洁剂配方、清洁剂的制备方法及使用方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910040712.9A CN111440670A (zh) | 2019-01-16 | 2019-01-16 | 一种清洁剂配方、清洁剂的制备方法及使用方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111440670A true CN111440670A (zh) | 2020-07-24 |
Family
ID=71626769
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910040712.9A Pending CN111440670A (zh) | 2019-01-16 | 2019-01-16 | 一种清洁剂配方、清洁剂的制备方法及使用方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111440670A (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114540825A (zh) * | 2021-03-15 | 2022-05-27 | 广东多创新材料科技有限公司 | 一种除油除蜡粉及制备方法 |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101223312A (zh) * | 2005-09-23 | 2008-07-16 | 东洋制铁化学株式会社 | 非水液体氧漂白组合物 |
| CN102634422A (zh) * | 2012-03-31 | 2012-08-15 | 湖南洁宇日化新技术股份有限公司 | 含氧洗涤剂的制备方法及由该方法得到的含氧洗涤剂 |
| CN103131542A (zh) * | 2013-03-20 | 2013-06-05 | 广州立白企业集团有限公司 | 一种活氧洗衣机槽清洗剂及其制备方法 |
| CN103923752A (zh) * | 2014-04-08 | 2014-07-16 | 余姚市德派日用品有限公司 | 一种家用洗衣洗碗粉 |
| CN106590949A (zh) * | 2016-12-11 | 2017-04-26 | 深圳市美益洁生物科技有限公司 | 洗衣槽生物酶除菌清洗剂及其制备方法 |
| CN107267303A (zh) * | 2017-06-08 | 2017-10-20 | 湖北大学 | 一种洗碗机专用的餐具洗涤粉剂及其制备方法 |
| CN108795597A (zh) * | 2018-08-09 | 2018-11-13 | 广州立白企业集团有限公司 | 一种低泡型自动洗碗机专用洗涤剂组合物 |
| CN109370802A (zh) * | 2018-11-27 | 2019-02-22 | 微普安全科技（徐州）股份有限公司 | 一种家用经济环保型油烟机清洗剂 |
-
2019
- 2019-01-16 CN CN201910040712.9A patent/CN111440670A/zh active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101223312A (zh) * | 2005-09-23 | 2008-07-16 | 东洋制铁化学株式会社 | 非水液体氧漂白组合物 |
| CN102634422A (zh) * | 2012-03-31 | 2012-08-15 | 湖南洁宇日化新技术股份有限公司 | 含氧洗涤剂的制备方法及由该方法得到的含氧洗涤剂 |
| CN103131542A (zh) * | 2013-03-20 | 2013-06-05 | 广州立白企业集团有限公司 | 一种活氧洗衣机槽清洗剂及其制备方法 |
| CN103923752A (zh) * | 2014-04-08 | 2014-07-16 | 余姚市德派日用品有限公司 | 一种家用洗衣洗碗粉 |
| CN106590949A (zh) * | 2016-12-11 | 2017-04-26 | 深圳市美益洁生物科技有限公司 | 洗衣槽生物酶除菌清洗剂及其制备方法 |
| CN107267303A (zh) * | 2017-06-08 | 2017-10-20 | 湖北大学 | 一种洗碗机专用的餐具洗涤粉剂及其制备方法 |
| CN108795597A (zh) * | 2018-08-09 | 2018-11-13 | 广州立白企业集团有限公司 | 一种低泡型自动洗碗机专用洗涤剂组合物 |
| CN109370802A (zh) * | 2018-11-27 | 2019-02-22 | 微普安全科技（徐州）股份有限公司 | 一种家用经济环保型油烟机清洗剂 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114540825A (zh) * | 2021-03-15 | 2022-05-27 | 广东多创新材料科技有限公司 | 一种除油除蜡粉及制备方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US10774290B2 (en) | Detergent composition in the form of an effervescent tablet | |
| EP2699660B1 (en) | Calcium sequestering composition | |
| CA2803134C (en) | Wash water maintenance for sustainable practices | |
| JP5624127B2 (ja) | ポットおよびパン浸漬用組成物 | |
| JP2013528679A (ja) | 器物洗浄用の高濃縮苛性ブロック | |
| AU2012245236B2 (en) | Calcium sequestering composition | |
| CN112292442B (zh) | 锅盘用酶清洁剂 | |
| US9133424B2 (en) | Stabilization and activation of protease for use at high temperature | |
| CN106590949A (zh) | 洗衣槽生物酶除菌清洗剂及其制备方法 | |
| US20100144576A1 (en) | Dish detergent | |
| WO2004027000A1 (en) | Cleaning solutions for carbon removal on cooking surfaces | |
| JP2004511277A (ja) | 洗剤組成物および器物洗浄方法 | |
| JPH07118689A (ja) | 硬表面洗浄剤組成物 | |
| CN111440670A (zh) | 一种清洁剂配方、清洁剂的制备方法及使用方法 | |
| CN112961734A (zh) | 一种家用自动洗碗机专用洗涤剂及其制备方法 | |
| JPH10130697A (ja) | 漂白洗浄剤組成物 | |
| JP3443500B2 (ja) | 洗濯機槽用洗浄剤組成物 | |
| CN117887526A (zh) | 一种洗碗凝珠组合物及其制备方法 | |
| KR20240143228A (ko) | 발포정 세제 조성물 | |
| JP4012607B2 (ja) | 風呂釜用洗浄剤組成物 | |
| WO2024088608A1 (en) | Builder combination for liquid detergent compositions | |
| JPH108094A (ja) | 食器洗浄機用洗浄剤組成物 | |
| JPH108095A (ja) | 食器洗浄機用洗浄剤組成物 | |
| JP2010280868A (ja) | 茹で麺装置用洗浄剤、及び茹で麺装置の洗浄方法 | |
| JPH108096A (ja) | 食器洗浄機用洗浄剤組成物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200724 |