CN103865592B - Methanol gasoline - Google Patents
Methanol gasoline Download PDFInfo
- Publication number
- CN103865592B CN103865592B CN201410099931.1A CN201410099931A CN103865592B CN 103865592 B CN103865592 B CN 103865592B CN 201410099931 A CN201410099931 A CN 201410099931A CN 103865592 B CN103865592 B CN 103865592B
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- Prior art keywords
- methanol gasoline
- low
- stablizer
- antioxidant
- lubricant
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 114
- 239000003502 gasoline Substances 0.000 title claims abstract description 23
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 33
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 18
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 18
- 230000007797 corrosion Effects 0.000 claims abstract description 16
- 238000005260 corrosion Methods 0.000 claims abstract description 16
- 239000000654 additive Substances 0.000 claims abstract description 15
- 239000003112 inhibitor Substances 0.000 claims abstract description 15
- 239000000314 lubricant Substances 0.000 claims abstract description 15
- 230000000996 additive effect Effects 0.000 claims abstract description 14
- 239000003208 petroleum Substances 0.000 claims abstract description 12
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 claims abstract description 10
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims abstract description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 19
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 14
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 7
- 239000012964 benzotriazole Substances 0.000 claims description 7
- CAAMSDWKXXPUJR-UHFFFAOYSA-N 3,5-dihydro-4H-imidazol-4-one Chemical compound O=C1CNC=N1 CAAMSDWKXXPUJR-UHFFFAOYSA-N 0.000 claims description 6
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 6
- 235000006708 antioxidants Nutrition 0.000 abstract description 14
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract description 9
- 239000000446 fuel Substances 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000012360 testing method Methods 0.000 abstract description 5
- 230000002633 protecting effect Effects 0.000 abstract description 4
- 230000009286 beneficial effect Effects 0.000 abstract description 3
- 238000012795 verification Methods 0.000 abstract description 3
- 238000002485 combustion reaction Methods 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract description 2
- 239000007858 starting material Substances 0.000 abstract description 2
- 239000002699 waste material Substances 0.000 abstract 1
- 238000011161 development Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000002154 agricultural waste Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
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- Lubricants (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention discloses a kind of methanol gasoline, be made up of the component of following mass percent: methyl alcohol 73-75%, sodium hydroxide 0.004-0.006%, corrosion inhibitor 0.3-0.5%, antioxidant 0.2-0.4%, lubricant 0.5-0.7%, methyl tertiary butyl ether 3-4%, sherwood oil 3-5%, hexahydroaniline 0.4-0.6%, petroleum naphtha 7-9%, carbon five 4-6%, stablizer 2-2.5%.The present invention has following beneficial effect: the starting material that (1) additive all adopts abundance, stable performance, post combustion emission to clean, and Blending is simple, low production cost, production process three-waste free discharge; (2) can available protecting environment, reduce fuel cost, save petroleum resources; (3) the present invention has better protecting effect to the power system of vehicle and oil supply system, and its dynamic performance, oilness, anticorrosive, anti-oxidant, low-temperature ignition after actual test verification, oil consumption etc. are all better than 97# state 5 normal benzene.
Description
Technical field
The present invention relates to a kind of fuel of power-equipment, be specifically related to a kind of methanol gasoline.
Background technology
Along with the development of world economy, the demand for fuel grows with each passing day, and the resources such as traditional diesel oil, gasoline, Sweet natural gas are all the more deficient.According to world oil summit statistic data, world oil commercial use can exploit 32 years, so development of new abrasive substitute energy becomes the Main way of future source of energy field development; For the renewable energy resources exploitation brought up to unprecedented height, rubbish, agricultural waste, coal, timber, stalk etc. can through gasification synthesis manufacture methyl alcohol, so Methanol fuel worldwide spread use.
Summary of the invention
Instant invention overcomes the deficiencies in the prior art, a kind of with low cost, high comprehensive performance is provided and is beneficial to the methanol gasoline of environment protection.
Consider the problems referred to above of prior art, according to an aspect disclosed by the invention, the present invention by the following technical solutions:
A kind of methanol gasoline, comprises following composition, is by mass percentage:
Methyl alcohol 73-75%, sodium hydroxide 0.004-0.006%, corrosion inhibitor 0.3-0.5%, antioxidant 0.2-0.4%, lubricant 0.5-0.7%, methyl tertiary butyl ether 3-4%, sherwood oil 3-5%, hexahydroaniline 0.4-0.6%, petroleum naphtha 7-9%, low-temperature ignition additive 4-6%, stablizer 2-2.5%.
In order to realize the present invention better, further technical scheme is:
According to one embodiment of the invention, described methyl alcohol 73-75%, sodium hydroxide 0.005%, corrosion inhibitor 0.4%, antioxidant 0.3%, lubricant 0.5-0.7%, methyl tertiary butyl ether 3-4%, sherwood oil 3-5%, hexahydroaniline 0.5%, petroleum naphtha 7-9%, low-temperature ignition additive 5%, stablizer 2-2.5%.
According to one embodiment of the invention, described methyl alcohol 74%, sodium hydroxide 0.005%, corrosion inhibitor 0.4%, antioxidant 0.3%, lubricant 0.7%, methyl tertiary butyl ether 4%, sherwood oil 4%, hexahydroaniline 0.5%, petroleum naphtha 8.995%, low-temperature ignition additive 5%, stablizer 2.1%.
According to one embodiment of the invention, described corrosion inhibitor comprises benzotriazole and oleic imidazolinone, and described benzotriazole and oleic imidazolinone quality proportioning are 2:3.
According to one embodiment of the invention, described antioxidant is BHT501.
According to one embodiment of the invention, described lubricant is whiteruss.
According to one embodiment of the invention, described stablizer comprises butanone and glycerol, and the mass ratio of described butanone and glycerol is 2:3.
The present invention can also be:
According to one embodiment of the invention, described low-temperature ignition additive is carbon five.
Compared with prior art, one of beneficial effect of the present invention is:
A kind of methanol gasoline of the present invention, the starting material that (1) all additives all adopt abundance, stable performance, renewable, post combustion emission clean, Blending is simple, low production cost, and production process is discharged without waste water,waste gas and industrial residue; (2) popularization of the present invention can available protecting environment, reduce fuel cost, save petroleum resources; (3) the present invention has better protecting effect to the power system of vehicle and oil supply system; its dynamic performance, oilness, anticorrosive, anti-oxidant, low-temperature ignition after actual test verification, oil consumption, micro-metal discharge, sulphur emissions, mutual solubility, vapour lock etc. are all better than 97# state 5 normal benzene.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, but embodiments of the present invention are not limited thereto.
A kind of methanol gasoline, comprises following composition, is by mass percentage:
Methyl alcohol 73-75%, sodium hydroxide 0.004-0.006%, corrosion inhibitor 0.3-0.5%, antioxidant 0.2-0.4%, lubricant 0.5-0.7%, methyl tertiary butyl ether 3-4%, sherwood oil 3-5%, hexahydroaniline 0.4-0.6%, petroleum naphtha 7-9%, low-temperature ignition additive 4-6%, stablizer 2-2.5%.
In one preferred embodiment, described methyl alcohol 73-75%, sodium hydroxide 0.005%, corrosion inhibitor 0.4%, antioxidant 0.3%, lubricant 0.5-0.7%, methyl tertiary butyl ether 3-4%, sherwood oil 3-5%, hexahydroaniline 0.5%, petroleum naphtha 7-9%, low-temperature ignition additive 5%, stablizer 2-2.5%.
In another preferred embodiment, described methyl alcohol 74%, sodium hydroxide 0.005%, corrosion inhibitor 0.4%, antioxidant 0.3%, lubricant 0.7%, methyl tertiary butyl ether 4%, sherwood oil 4%, hexahydroaniline 0.5%, petroleum naphtha 8.995%, low-temperature ignition additive 5%, stablizer 2.1%.
Described corrosion inhibitor comprises benzotriazole and oleic imidazolinone, and described benzotriazole and oleic imidazolinone quality proportioning are 2:3.
Described antioxidant can be BHT501.
Described lubricant can be whiteruss.
Described stablizer can comprise butanone and glycerol, and the mass ratio of described butanone and glycerol is 2:3.
Described low-temperature ignition additive can select carbon five, can ensure that subzero 40 DEG C of methanol gasoline normally starts by carbon five.
Further illustrate below by the component situation of table 1 to different embodiment methanol gasoline:
The component situation of the different embodiment methanol gasoline of table 1
Above-mentioned component at normal temperatures and pressures circulation stirring methanol gasoline of the present invention, the mode of circulation stirring is varied, does not repeat them here.
Wherein, described sodium hydroxide, in and organic acid in methyl alcohol, regulate the pH value of methanol gasoline; Described corrosion inhibitor is that benzotriazole and oleic imidazolinone form with quality proportioning 2:3, effectively can form protective membrane on surfaces such as container, pipeline, engines, thus solve the corrosion problems of methyl alcohol; Described antioxidant is BHT501, effectively can solve the problem of oxidation of methyl alcohol to metal.Described lubricant is whiteruss, effectively can improve the lubricity of methyl alcohol.Described stablizer is that butanone and glycerol form with mass ratio 2:3, effectively can improve the mixed stability of various additive.Described corrosion inhibitor, antioxidant, lubricant and stablizer also can select the component that other play phase same-action as known in the art to substitute.
Through checking methanol gasoline performance data parameter of the present invention following (table 2):
The detection case of the different embodiment methanol gasoline of table 2
Test set adopts ASTM, GB standard equipment.
As can be seen from Table 2, each test item of methanol gasoline of the present invention all detect qualified.After actual test verification, its dynamic performance, oilness, anticorrosive, anti-oxidant, low-temperature ignition, oil consumption, micro-metal discharge, sulphur emissions, mutual solubility, vapour lock etc. are all better than 97# state 5 normal benzene.
In this specification sheets, each embodiment adopts the mode of going forward one by one to describe, and what each embodiment stressed is the difference with other embodiment, identical similar portion cross-reference between each embodiment.
Spoken of in this manual " embodiment ", " another embodiment ", " embodiment ", etc., refer to the specific features, structure or the feature that describe in conjunction with this embodiment and be included at least one embodiment of the application's generality description.Multiple place occurs that statement of the same race is not necessarily refer to same embodiment in the description.Furthermore, when describing specific features, structure or a feature in conjunction with any embodiment, what advocate is also fall within the scope of the invention to realize this feature, structure or feature in conjunction with other embodiments.
Although with reference to multiple explanatory embodiment of the present invention, invention has been described here, but, should be appreciated that, those skilled in the art can design a lot of other amendment and embodiment, these amendments and embodiment will drop within spirit disclosed in the present application and spirit.More particularly, in the scope of and claim open in the application, multiple modification and improvement can be carried out to the building block of subject combination layout and/or layout.Except the modification of carrying out building block and/or layout is with except improvement, to those skilled in the art, other purposes also will be obvious.
Claims (6)
1. a methanol gasoline, is characterized in that, comprises following composition, is by mass percentage:
Methyl alcohol 73-75%, sodium hydroxide 0.004-0.006%, corrosion inhibitor 0.3-0.5%, antioxidant 0.2-0.4%, lubricant 0.5-0.7%, methyl tertiary butyl ether 3-4%, sherwood oil 3-5%, hexahydroaniline 0.4-0.6%, petroleum naphtha 7-9%, low-temperature ignition additive 4-6%, stablizer 2-2.5%, described stablizer comprises butanone and glycerol, the mass ratio of described butanone and glycerol is 2:3, described corrosion inhibitor comprises benzotriazole and oleic imidazolinone, and described benzotriazole and oleic imidazolinone quality proportioning are 2:3.
2. methanol gasoline according to claim 1, it is characterized in that, described methyl alcohol 73-75%, sodium hydroxide 0.005%, corrosion inhibitor 0.4%, antioxidant 0.3%, lubricant 0.5-0.7%, methyl tertiary butyl ether 3-4%, sherwood oil 3-5%, hexahydroaniline 0.5%, petroleum naphtha 7-9%, low-temperature ignition additive 5%, stablizer 2-2.5%.
3. methanol gasoline according to claim 2, it is characterized in that, described methyl alcohol 74%, sodium hydroxide 0.005%, corrosion inhibitor 0.4%, antioxidant 0.3%, lubricant 0.7%, methyl tertiary butyl ether 4%, sherwood oil 4%, hexahydroaniline 0.5%, petroleum naphtha 8.995%, low-temperature ignition additive 5%, stablizer 2.1%.
4. the methanol gasoline according to claims 1 to 3 any one, is characterized in that, described antioxidant is BHT501.
5. the methanol gasoline according to claims 1 to 3 any one, is characterized in that, described lubricant is whiteruss.
6. the methanol gasoline according to claims 1 to 3 any one, is characterized in that, described low-temperature ignition additive is carbon five.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410099931.1A CN103865592B (en) | 2014-03-19 | 2014-03-19 | Methanol gasoline |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410099931.1A CN103865592B (en) | 2014-03-19 | 2014-03-19 | Methanol gasoline |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103865592A CN103865592A (en) | 2014-06-18 |
| CN103865592B true CN103865592B (en) | 2015-12-30 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410099931.1A Expired - Fee Related CN103865592B (en) | 2014-03-19 | 2014-03-19 | Methanol gasoline |
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Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104498112B (en) * | 2014-12-25 | 2016-07-06 | 山西华顿实业有限公司 | M85 compound additive for methanol gasoline |
| CN104611075A (en) * | 2015-01-20 | 2015-05-13 | 刘敏 | Blended gasoline and preparation method thereof |
| CN105255526A (en) * | 2015-10-30 | 2016-01-20 | 汉阴县富源清洁能源科技开发有限责任公司 | Synthesized environment-friendly automobile gasoline and preparation method thereof |
| CN108251168B (en) * | 2018-02-11 | 2020-08-11 | 陕西延长石油能源科技有限公司 | Ethanol gasoline composite additive for vehicles and preparation method and application thereof |
| CN110272768A (en) * | 2018-03-16 | 2019-09-24 | 孙高杰 | A kind of low-carbon gasoline and preparation method thereof |
| CN108219872A (en) * | 2018-03-27 | 2018-06-29 | 广东九宇同创网络科技有限公司 | A kind of automobile exhaust detergent and preparation method thereof |
| CN108753374A (en) * | 2018-04-04 | 2018-11-06 | 四川茂丛岭网络科技有限公司 | A kind of environment-protecting clean methanol fuel and preparation method thereof |
| CN108531226A (en) * | 2018-04-09 | 2018-09-14 | 国通达新能源股份有限公司 | A kind of alcohol liquid fuel |
| CN108342234A (en) * | 2018-04-09 | 2018-07-31 | 国通达新能源股份有限公司 | Alcohol liquid fuel |
| CN108359503A (en) * | 2018-04-20 | 2018-08-03 | 北京安途行科技有限公司 | A kind of automobile exhaust detergent manufacture craft |
| CN108546573A (en) * | 2018-05-07 | 2018-09-18 | 国通达新能源股份有限公司 | A kind of automobile-used alcohol liquid fuel |
| CN108728180A (en) * | 2018-05-28 | 2018-11-02 | 国通达新能源股份有限公司 | A kind of automobile-used alcohol liquid fuel formulation |
| CN108949254A (en) * | 2018-07-17 | 2018-12-07 | 湖南绿盛源能源科技有限公司 | A kind of methanol gasoline with protecting effect |
| CN110016371A (en) * | 2019-05-05 | 2019-07-16 | 中易华恒石油化工有限责任公司 | A kind of methanol gasoline and preparation method thereof |
| CN110331011A (en) * | 2019-05-09 | 2019-10-15 | 杨龙 | It is a kind of for removing the fuel assistants of automobile carbon deposition |
| CN110408439A (en) * | 2019-06-27 | 2019-11-05 | 河南佰扬新能源有限公司 | A kind of carbinol-modified fuel reducing vehicle exhaust |
| FR3137104A1 (en) | 2022-06-23 | 2023-12-29 | Veryone | Methanol-based motor fuel containing a combustion improvement additive. |
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| CN102161919A (en) * | 2011-03-25 | 2011-08-24 | 山西丰喜新能源开发有限公司 | Vehicle high-methanol content gasoline |
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| CN102796574A (en) * | 2012-08-25 | 2012-11-28 | 张伯义 | Methanol gasoline |
| CN103275769A (en) * | 2013-05-28 | 2013-09-04 | 鲁家政 | High-cleanness environment-friendly alcohol ether fuel for car |
-
2014
- 2014-03-19 CN CN201410099931.1A patent/CN103865592B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102161919A (en) * | 2011-03-25 | 2011-08-24 | 山西丰喜新能源开发有限公司 | Vehicle high-methanol content gasoline |
| CN102634384A (en) * | 2012-04-17 | 2012-08-15 | 罗浩南 | Novel vehicle alcohols environment-friendly fuel |
| CN102796574A (en) * | 2012-08-25 | 2012-11-28 | 张伯义 | Methanol gasoline |
| CN103275769A (en) * | 2013-05-28 | 2013-09-04 | 鲁家政 | High-cleanness environment-friendly alcohol ether fuel for car |
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| Publication number | Publication date |
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| CN103865592A (en) | 2014-06-18 |
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