CN103820035A - Flame retardant adhesive containing modified kaolin - Google Patents
Flame retardant adhesive containing modified kaolin Download PDFInfo
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- CN103820035A CN103820035A CN201410057012.8A CN201410057012A CN103820035A CN 103820035 A CN103820035 A CN 103820035A CN 201410057012 A CN201410057012 A CN 201410057012A CN 103820035 A CN103820035 A CN 103820035A
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Abstract
The invention discloses a flame retardant adhesive containing modified kaolin. The flame retardant adhesive is composed of the following raw materials by weight: 100-150 parts of styrene, 50-80 parts of ethyl methacrylate, 10-15 parts of acrylonitrile, 5-8 parts of a furan resin, 10-15 parts of epoxypropane butyl ether, 10-15 parts of nitrile rubber, 1-3 parts of boron powder, 5-10 parts of a bisphenol A epoxy resin, 5-8 parts of polyvinyl acetate, 15-20 parts of the modified kaolin, 2-4 parts of magnesium hydroxide, 2-3 parts of chlorinated paraffin, 1-3 parts of glass powder, 2-3 parts of magnesium oxide, 15-20 parts of flame retardant polyether polyol, 5-8 parts of lignin, 5-10 parts of bentonite, 3-5 parts of aminated triazine salt, 0.5-0.8 part of dibutyltin dilaurate, 0.3-0.5 part of phosphoric acid, 1-2 parts of an antioxidant 1076, 2-3 parts of an anti-aging agent MB, 1-2 parts of an accelerant CBS, 3-5 parts of a titanate coupling agent and 3-5 parts of modified tree ashes. The adhesive provided by the invention has the advantages of very strong adhesion, flame retardancy, smoke suppression and good storage stability.
Description
Technical field
The present invention relates to sizing agent technical field, relate in particular to a kind of fire-retardant sizing agent that contains modified kaolin.
Background technology
Along with building high stratification, automotive light weight technology, high-newization of electrical equipment, furniture are superior, the development of industrial large-sizedization, sizing agent has obtained application increasingly widely in modern industry field and daily life, but most of sizing agents are more inflammable, exist fire hazard, simultaneously, when sizing agent burning, also can produce smog and poison gas, environment and the person are all impacted.Existing market is in great demand for fire-retardant sizing agent, and for the research in this field or little, sizing agent belongs to macromolecular compound, meets the general condition of superpolymer burning, if without fire-retardant finish, just cannot use some special dimension.Therefore, research and development have fire-retardant, press down cigarette, low toxicity or nontoxic sizing agent has become one of focus direction of development of new sizing agent.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of fire-retardant sizing agent that contains modified kaolin that has very strong adhesiveproperties, flame retardant resistance, presses down cigarette, excellent storage stability is provided.
The present invention adopts following technical scheme to achieve these goals:
A kind of fire-retardant sizing agent that contains modified kaolin, raw material by following weight part forms: vinylbenzene 100-150 part, β-dimethyl-aminoethylmethacrylate 50-80 part, vinyl cyanide 10-15 part, furane resin 5-8 part, epoxy propane butyl ether 10-15 part, paracril 10-15 part, boron powder 1-3 part, bisphenol A epoxide resin 5-10 part, Vinyl Acetate Copolymer 5-8 part, modified kaolin 15-20 part, magnesium hydroxide 2-4 part, clorafin 2-3 part, glass powder 1-3 part, magnesium oxide 2-3 part, flame retardant polyether polyol 15-20 part, xylogen 5-8 part, wilkinite 5-10 part, amination triazine salt 3-5 part, dibutyl tin laurate 0.5-0.8 part, phosphoric acid 0.3-0.5 part, antioxidant 1076 1-2 parts, antioxidant MB 2-3 part, accelerator CBS 1-2 part, titanate coupling agent 3-5 part, modification trees ashes 3-5 part.
Described flame retardant polyether polyol is one or both of halogenated polyether polyvalent alcohol, phenol polyvalent alcohol.
Described modified kaolin is prepared by following methods: kaolin is put into sodium carbonate and potassium permanganate mixing solutions soaks after 4-5h, dry, then add under 1000-1300 rev/min of calcium lignin sulphonate, the aluminum oxide of 0.5-0.8%, 0.3-0.5% dimethyl sulfoxide (DMSO), the 0.2-0.4% gas phase isoprene of the silane coupling agent KH560, the 0.3-0.5% that are equivalent to kaolin weight 0.5-0.8% and stir after 15-20min, mixture is put into sonochemistry reactor, frequency with 15-30KHz is carried out after ultrasonic 1-2h it, filter, grind, obtain modified kaolin.
Described modification trees ashes are prepared by following methods: first use 10-15% salt acid soak trees ashes 3-5h, use deionized water washes clean, soak 3-5h with 10-13% sodium hydroxide solution again, extremely neutral with deionized water wash, dry, add and be equivalent to the wooden sodium sulfonate of trees ashes weight 2-4%, the peregal of 1-3%, the tributyl citrate of 2-4%, high speed 1300-1500 rev/min is stirred 1-3h, pulverizes and grinds to form ultrafine powder.
The preparation method of the described fire-retardant sizing agent that contains modified kaolin, comprises the following steps:
(1) add reactor to be heated to 100-120 ℃ vinylbenzene, β-dimethyl-aminoethylmethacrylate, vinyl cyanide, furane resin, epoxy propane butyl ether, paracril, bisphenol A epoxide resin, Vinyl Acetate Copolymer, magnesium hydroxide, flame retardant polyether polyol, dibutyl tin laurate, phosphoric acid by above-mentioned weight ratio, high-speed stirring 2-3h;
(2) other material is mixed with reactant in step (1), stir 30-50min, be cooled to normal temperature, obtain finished product, packing.
Compared with the prior art, beneficial effect of the present invention is as follows:
The present invention is by adding modified kaolin and flame retardant polyether polyol in sizing agent, adjust formula, significantly improve flame retardant properties, the smoke suppressing of sizing agent, trees ashes are carried out to modification simultaneously, improve the dispersing uniformity of sizing agent component, obviously improve the bonding strength of sizing agent, and obviously improve the package stability of sizing agent.Sizing agent of the present invention have very strong cementability, shock-resistant, fire-retardant, wear-resisting, press down the advantages such as cigarette, excellent storage stability.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
A kind of fire-retardant sizing agent that contains modified kaolin, raw material by following weight part forms: 130 parts of vinylbenzene, 60 parts of β-dimethyl-aminoethylmethacrylates, 12 parts of vinyl cyanide, 6 parts of furane resin, 13 parts of epoxy propane butyl ethers, 13 parts of paracrils, 2 parts, boron powder, 6 parts of bisphenol A epoxide resins, 7 parts of Vinyl Acetate Copolymer, 16 parts of modified kaolins, 3 parts of magnesium hydroxides, 3 parts of clorafins, 2 parts, glass powder, 2 parts, magnesium oxide, 18 parts of halogenated polyether polyvalent alcohols, 7 parts, xylogen, 8 parts of wilkinites, 4 parts of amination triazine salt, 0.6 part of dibutyl tin laurate, 0.4 part of phosphoric acid, 1,076 2 parts of antioxidants, 3 parts of antioxidant MBs, 2 parts of accelerator CBSs, 4 parts of titanate coupling agents, 5 parts, modification trees ashes.
Wherein, modified kaolin is prepared by following methods: kaolin is put into sodium carbonate and potassium permanganate mixing solutions soaks after 4h, dry, then add under 1000 revs/min of silane coupling agent KH560,0.4% calcium lignin sulphonate, 0.6% aluminum oxide, 0.4% dimethyl sulfoxide (DMSO), the 0.3% gas phase isoprene that is equivalent to kaolin weight 0.6% and stir after 15min, mixture is put into sonochemistry reactor, frequency with 30KHz is carried out after ultrasonic 1h it, filter, grind, obtain modified kaolin.
Modification trees ashes are prepared by following methods: first use 15% salt acid soak trees ashes 4h, then use deionized water washes clean, soak 4h with 10% sodium hydroxide solution again, extremely neutral with deionized water wash again, dry, add and be equivalent to the wooden sodium sulfonate of trees ashes weight 3%, 2% peregal, 3% tributyl citrate, 1300 revs/min are stirred 2h at a high speed, pulverize and grind to form ultrafine powder.
The preparation method of the fire-retardant sizing agent that contains modified kaolin, comprises the following steps:
(1) add reactor to be heated to 120 ℃, high-speed stirring 2h vinylbenzene, β-dimethyl-aminoethylmethacrylate, vinyl cyanide, furane resin, epoxy propane butyl ether, paracril, bisphenol A epoxide resin, Vinyl Acetate Copolymer, magnesium hydroxide, flame retardant polyether polyol, dibutyl tin laurate, phosphoric acid by above-mentioned weight ratio;
(2) other material is mixed with reactant in step (1), stir 40min, be cooled to normal temperature, obtain finished product, packing.
Embodiment 2:
A kind of fire-retardant sizing agent that contains modified kaolin, raw material by following weight part forms: 100 parts of vinylbenzene, 50 parts of β-dimethyl-aminoethylmethacrylates, 10 parts of vinyl cyanide, 5 parts of furane resin, 10 parts of epoxy propane butyl ethers, 10 parts of paracrils, 1 part, boron powder, 5 parts of bisphenol A epoxide resins, 5 parts of Vinyl Acetate Copolymer, 17 parts of modified kaolins, 2 parts of magnesium hydroxides, 2 parts of clorafins, 1 part, glass powder, 2 parts, magnesium oxide, 15 parts of phenol polyvalent alcohols, 5 parts, xylogen, 5 parts of wilkinites, 3 parts of amination triazine salt, 0.5 part of dibutyl tin laurate, 0.3 part of phosphoric acid, 1,076 1 parts of antioxidants, 2 parts of antioxidant MBs, 1 part of accelerator CBS, 3 parts of titanate coupling agents, 3 parts, modification trees ashes.
Wherein, modified kaolin is prepared by following methods: kaolin is put into sodium carbonate and potassium permanganate mixing solutions soaks after 4h, dry, then add under 1000 revs/min of silane coupling agent KH560,0.3% calcium lignin sulphonate, 0.5% aluminum oxide, 0.3% dimethyl sulfoxide (DMSO), the 0.2% gas phase isoprene that is equivalent to kaolin weight 0.5% and stir after 20min, mixture is put into sonochemistry reactor, frequency with 30KHz is carried out after ultrasonic 1h it, filter, grind, obtain modified kaolin.
Modification trees ashes are prepared by following methods: first use 15% salt acid soak trees ashes 3h, then use deionized water washes clean, soak 3h with 10% sodium hydroxide solution again, extremely neutral with deionized water wash again, dry, add and be equivalent to the wooden sodium sulfonate of trees ashes weight 2%, 1% peregal, 2% tributyl citrate, 1300 revs/min are stirred 3h at a high speed, pulverize and grind to form ultrafine powder.
The preparation method of the fire-retardant sizing agent that contains modified kaolin, comprises the following steps:
(1) add reactor to be heated to 100 ℃, high-speed stirring 3h vinylbenzene, β-dimethyl-aminoethylmethacrylate, vinyl cyanide, furane resin, epoxy propane butyl ether, paracril, bisphenol A epoxide resin, Vinyl Acetate Copolymer, magnesium hydroxide, flame retardant polyether polyol, dibutyl tin laurate, phosphoric acid by above-mentioned weight ratio;
(2) other material is mixed with reactant in step (1), stir 50min, be cooled to normal temperature, obtain finished product, packing.
Embodiment 3:
A kind of fire-retardant sizing agent that contains modified kaolin, raw material by following weight part forms: 150 parts of vinylbenzene, 80 parts of β-dimethyl-aminoethylmethacrylates, 15 parts of vinyl cyanide, 8 parts of furane resin, 15 parts of epoxy propane butyl ethers, 15 parts of paracrils, 3 parts, boron powder, 10 parts of bisphenol A epoxide resins, 8 parts of Vinyl Acetate Copolymer, 20 parts of modified kaolins, 4 parts of magnesium hydroxides, 3 parts of clorafins, 3 parts, glass powder, 3 parts, magnesium oxide, 20 parts of halogenated polyether polyvalent alcohols, 8 parts, xylogen, 10 parts of wilkinites, 5 parts of amination triazine salt, 0.8 part of dibutyl tin laurate, 0.5 part of phosphoric acid, 1,076 2 parts of antioxidants, 3 parts of antioxidant MBs, 2 parts of accelerator CBSs, 5 parts of titanate coupling agents, 5 parts, modification trees ashes.
Wherein, modified kaolin is prepared by following methods: kaolin is put into sodium carbonate and potassium permanganate mixing solutions soaks after 5h, dry, then add under 1300 revs/min of silane coupling agent KH560,0.5% calcium lignin sulphonate, 0.8% aluminum oxide, 0.5% dimethyl sulfoxide (DMSO), the 0.4% gas phase isoprene that is equivalent to kaolin weight 0.8% and stir after 15min, mixture is put into sonochemistry reactor, frequency with 30KHz is carried out after ultrasonic 2h it, filter, grind, obtain modified kaolin.
Described modification trees ashes are prepared by following methods: first use 15% salt acid soak trees ashes 3h, then use deionized water washes clean, soak 3h with 13% sodium hydroxide solution again, extremely neutral with deionized water wash again, dry, add and be equivalent to the wooden sodium sulfonate of trees ashes weight 4%, 3% peregal, 4% tributyl citrate, 1500 revs/min are stirred 2h at a high speed, pulverize and grind to form ultrafine powder.
The preparation method of the described fire-retardant sizing agent that contains modified kaolin, comprises the following steps:
(1) add reactor to be heated to 120 ℃, high-speed stirring 3h vinylbenzene, β-dimethyl-aminoethylmethacrylate, vinyl cyanide, furane resin, epoxy propane butyl ether, paracril, bisphenol A epoxide resin, Vinyl Acetate Copolymer, magnesium hydroxide, flame retardant polyether polyol, dibutyl tin laurate, phosphoric acid by above-mentioned weight ratio;
(2) other material is mixed with reactant in step (1), stir 30min, be cooled to normal temperature, obtain finished product, packing.
Test example:
After sizing agent in the embodiment of the present invention 1, in embodiment 2 and embodiment 3 solidifies, it is carried out to heat analysis, the temperature that starts decomposition is respectively 289.05 ℃, 278.08 ℃ and 276.07 ℃.
Claims (5)
1. a fire-retardant sizing agent that contains modified kaolin, it is characterized in that: the raw material by following weight part forms: vinylbenzene 100-150 part, β-dimethyl-aminoethylmethacrylate 50-80 part, vinyl cyanide 10-15 part, furane resin 5-8 part, epoxy propane butyl ether 10-15 part, paracril 10-15 part, boron powder 1-3 part, bisphenol A epoxide resin 5-10 part, Vinyl Acetate Copolymer 5-8 part, modified kaolin 15-20 part, magnesium hydroxide 2-4 part, clorafin 2-3 part, glass powder 1-3 part, magnesium oxide 2-3 part, flame retardant polyether polyol 15-20 part, xylogen 5-8 part, wilkinite 5-10 part, amination triazine salt 3-5 part, dibutyl tin laurate 0.5-0.8 part, phosphoric acid 0.3-0.5 part, antioxidant 1076 1-2 parts, antioxidant MB 2-3 part, accelerator CBS 1-2 part, titanate coupling agent 3-5 part, modification trees ashes 3-5 part.
2. the fire-retardant sizing agent that contains modified kaolin according to claim 1, is characterized in that: described flame retardant polyether polyol is one or both of halogenated polyether polyvalent alcohol, phenol polyvalent alcohol.
3. the fire-retardant sizing agent that contains modified kaolin according to claim 1, it is characterized in that: described modified kaolin is prepared by following methods: kaolin is put into sodium carbonate and potassium permanganate mixing solutions soaks after 4-5h, dry, then add the silane coupling agent KH560 that is equivalent to kaolin weight 0.5-0.8%, the calcium lignin sulphonate of 0.3-0.5%, the aluminum oxide of 0.5-0.8%, 0.3-0.5% dimethyl sulfoxide (DMSO), under 1000-1300 rev/min of 0.2-0.4% gas phase isoprene, stir after 15-20min, mixture is put into sonochemistry reactor, frequency with 15-30KHz is carried out after ultrasonic 1-2h it, filter, grind, obtain modified kaolin.
4. the fire-retardant sizing agent that contains modified kaolin according to claim 1, it is characterized in that: described modification trees ashes are prepared by following methods: first use 10-15% salt acid soak trees ashes 3-5h, then use deionized water washes clean, soak 3-5h with 10-13% sodium hydroxide solution again, extremely neutral with deionized water wash, dry, add and be equivalent to the wooden sodium sulfonate of trees ashes weight 2-4%, the peregal of 1-3%, the tributyl citrate of 2-4%, high speed 1300-1500 rev/min is stirred 1-3h, pulverizes and grinds to form ultrafine powder.
5. a preparation method for the fire-retardant sizing agent that contains modified kaolin as claimed in claim 1, is characterized in that: comprise the following steps:
(1) add reactor to be heated to 100-120 ℃ vinylbenzene, β-dimethyl-aminoethylmethacrylate, vinyl cyanide, furane resin, epoxy propane butyl ether, paracril, bisphenol A epoxide resin, Vinyl Acetate Copolymer, magnesium hydroxide, flame retardant polyether polyol, dibutyl tin laurate, phosphoric acid by above-mentioned weight ratio, high-speed stirring 2-3h;
(2) other material is mixed with reactant in step (1), stir 30-50min, be cooled to normal temperature, obtain finished product, packing.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410057012.8A CN103820035B (en) | 2014-02-20 | 2014-02-20 | Flame retardant adhesive containing modified kaolin |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410057012.8A CN103820035B (en) | 2014-02-20 | 2014-02-20 | Flame retardant adhesive containing modified kaolin |
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| CN103820035A true CN103820035A (en) | 2014-05-28 |
| CN103820035B CN103820035B (en) | 2015-04-15 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104017466A (en) * | 2014-06-20 | 2014-09-03 | 合肥长城制冷科技有限公司 | High-temperature-resistant corrosion-resistant coating for aluminum plate |
| CN104059520A (en) * | 2014-06-20 | 2014-09-24 | 合肥长城制冷科技有限公司 | Anti-corrosion treating fluid for treating aluminum plate and preparation method thereof |
| CN105969213A (en) * | 2016-06-29 | 2016-09-28 | 哈尔滨永淇化工有限公司 | Flame-retardant storage battery sealing adhesive based on vinyl toluene and neopentyl glycol dimethacrylate and production method of flame-retardant storage battery sealing adhesive |
| CN106751502A (en) * | 2016-12-06 | 2017-05-31 | 佛山市高明区生产力促进中心 | A kind of neo-epoxy resin composition |
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| CN102504752A (en) * | 2011-11-30 | 2012-06-20 | 山东北方现代化学工业有限公司 | Room-temperature moisture-curable single-component flame-retardant polyurethane sealant |
| CN102965033A (en) * | 2012-11-02 | 2013-03-13 | 铜陵祥云消防科技有限责任公司 | Nano-mica powder modified compound adhesive for packaging |
| CN103214984A (en) * | 2013-04-17 | 2013-07-24 | 安徽金门工贸有限公司 | Holt melt adhesive containing nanometer iron ore tailing powder |
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2014
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102504752A (en) * | 2011-11-30 | 2012-06-20 | 山东北方现代化学工业有限公司 | Room-temperature moisture-curable single-component flame-retardant polyurethane sealant |
| CN102965033A (en) * | 2012-11-02 | 2013-03-13 | 铜陵祥云消防科技有限责任公司 | Nano-mica powder modified compound adhesive for packaging |
| CN103214984A (en) * | 2013-04-17 | 2013-07-24 | 安徽金门工贸有限公司 | Holt melt adhesive containing nanometer iron ore tailing powder |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104017466A (en) * | 2014-06-20 | 2014-09-03 | 合肥长城制冷科技有限公司 | High-temperature-resistant corrosion-resistant coating for aluminum plate |
| CN104059520A (en) * | 2014-06-20 | 2014-09-24 | 合肥长城制冷科技有限公司 | Anti-corrosion treating fluid for treating aluminum plate and preparation method thereof |
| CN104059520B (en) * | 2014-06-20 | 2016-08-17 | 合肥长城制冷科技有限公司 | A kind of for antiseptic wash processing aluminium sheet and preparation method thereof |
| CN105969213A (en) * | 2016-06-29 | 2016-09-28 | 哈尔滨永淇化工有限公司 | Flame-retardant storage battery sealing adhesive based on vinyl toluene and neopentyl glycol dimethacrylate and production method of flame-retardant storage battery sealing adhesive |
| CN106751502A (en) * | 2016-12-06 | 2017-05-31 | 佛山市高明区生产力促进中心 | A kind of neo-epoxy resin composition |
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| CN103820035B (en) | 2015-04-15 |
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Effective date of registration: 20161221 Address after: 542899 Hezhou the Guangxi Zhuang Autonomous Region Electronic Science and technology park is run on the road No. 1 Patentee after: Guangxi Huizhi Productivity Promotion Center Co. Ltd. Address before: 244100 Tongling Jinqiao Industrial Park, Tongling, Anhui Patentee before: Tongling Xiangyun Fire-fighting Technology Co., Ltd. |
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Effective date of registration: 20191204 Address after: 239300 Tianchang copper Town Industrial Park, Anhui, Chuzhou Patentee after: Anhui Huibang paint Co., Ltd Address before: 542899 Hezhou the Guangxi Zhuang Autonomous Region Electronic Science and technology park is run on the road No. 1 Patentee before: Guangxi Huizhi Productivity Promotion Center Co. Ltd. |