CN103214123A - Integrated coagulation-synergism inclined plate oil-removing device - Google Patents
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 52
- 238000005345 coagulation Methods 0.000 claims abstract description 37
- 230000015271 coagulation Effects 0.000 claims abstract description 37
- 238000002156 mixing Methods 0.000 claims abstract description 20
- 230000002195 synergetic effect Effects 0.000 claims abstract description 18
- 239000010865 sewage Substances 0.000 claims abstract description 16
- 239000002245 particle Substances 0.000 claims abstract description 12
- 238000009434 installation Methods 0.000 claims abstract description 11
- 238000005189 flocculation Methods 0.000 claims abstract description 10
- 230000016615 flocculation Effects 0.000 claims abstract description 10
- 238000004062 sedimentation Methods 0.000 claims abstract description 10
- 238000009826 distribution Methods 0.000 claims abstract description 7
- 238000005192 partition Methods 0.000 claims abstract description 7
- 238000005238 degreasing Methods 0.000 claims description 19
- 238000000926 separation method Methods 0.000 claims description 8
- 230000000694 effects Effects 0.000 claims description 6
- 238000001556 precipitation Methods 0.000 claims description 3
- 238000005191 phase separation Methods 0.000 claims description 2
- 239000003921 oil Substances 0.000 claims 21
- 239000002893 slag Substances 0.000 claims 1
- 238000004581 coalescence Methods 0.000 abstract description 4
- 239000013049 sediment Substances 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 11
- 239000002351 wastewater Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000005484 gravity Effects 0.000 description 3
- 239000000701 coagulant Substances 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010170 biological method Methods 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 238000005185 salting out Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
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Abstract
一体化混凝增效斜板除油设备,主要由混凝和去浊除油两部分组成。其中,混凝部分通过混合设备和网格絮凝实现胶态油与乳化油的处理;混凝后的污水经过配水孔板进入去浊除油区,该区设有两种不同形式的斜板,均可起到沉淀除浊和聚结除油的作用,通过改变其安装角度使其分别主要用来实现沉淀颗粒和聚结除油目的;在出水区设置有V型隔板以避免上浮油类进入出水管;油类通过去浊除油区上端的V型槽聚集,经排油管排出;沉淀物在泥斗中聚集,由排泥管排出。本发明与现有技术比较具有处理效率高,出水水质好,投资省,处理成本低等特点,可以最大限度地挖掘现有除油设施的潜力,利用最小投资获取最大的效益。
The integrated coagulation synergistic inclined plate oil removal equipment is mainly composed of two parts: coagulation and turbidity removal. Among them, the coagulation part realizes the treatment of colloidal oil and emulsified oil through mixing equipment and grid flocculation; the coagulated sewage enters the turbidity and oil removal area through the water distribution orifice, and there are two different types of inclined plates in this area. Both can play the role of sedimentation and turbidity removal and coalescence and oil removal. By changing the installation angle, they are mainly used to achieve the purpose of sedimentation particles and coalescence and oil removal respectively; a V-shaped partition is set in the water outlet area to avoid floating oil Into the outlet pipe; the oil is collected through the V-shaped groove at the upper end of the turbidity and oil removal area, and discharged through the oil discharge pipe; the sediment is collected in the mud hopper, and discharged through the mud discharge pipe. Compared with the prior art, the present invention has the characteristics of high treatment efficiency, good effluent quality, low investment and low treatment cost, can maximize the potential of existing oil removal facilities, and obtain maximum benefits with minimum investment.
Description
技术领域:Technical field:
本发明属于水处理设备技术领域,涉及一种污水固液分离及油水分离设备的改进。The invention belongs to the technical field of water treatment equipment and relates to an improvement of sewage solid-liquid separation and oil-water separation equipment.
背景技术:Background technique:
根据含油废水来源和油类在水中的存在形式不同,可分为浮油、分散油、乳化油和溶解油四类:1、浮油,以连续相漂浮于水面,形成油膜或油层,其油滴粒径较大,一般大于100μm;2、分散油,以微小油滴悬浮于水中,经静置一定时间后往往变成浮油,其油滴粒径为10-100μm;3、乳化油,水中含有表面活性剂使油成为稳定的乳化液,油滴粒径一般小于10μm,大部分为0.1-2μm;4、溶解油,是一种以化学方式溶解的微粒分散油,油粒直径比乳化油还要细,有时可小到几纳米。According to the source of oily wastewater and the different forms of oil in water, it can be divided into four categories: slick oil, dispersed oil, emulsified oil and dissolved oil: 1. Slick oil, which floats on the water surface as a continuous phase, forms an oil film or oil layer, and its oil The particle size of the droplet is relatively large, generally greater than 100 μm; 2. Dispersed oil, suspended in water with tiny oil droplets, often becomes oil slick after standing for a certain period of time, and the particle size of the oil droplet is 10-100 μm; 3. Emulsified oil, The water contains surfactants to make the oil a stable emulsion. The particle size of the oil droplets is generally less than 10 μm, and most of them are 0.1-2 μm; 4. Dissolved oil is a kind of dispersed oil that dissolves chemically. The oil is even finer, sometimes as small as a few nanometers.
目前,采油废水的处理按原理可分为物理法(重力沉降、机械分离、离心、粗粒化、过滤、膜分离等),化学法(凝聚、酸化、盐析、电解等),物理化学法(浮选、吸附、离子交换等),生物法(活性污泥、生物滤池、氧化塘等)。由于各油田污水水质差异较大,处理后净化水水质要求也不尽相同,因此各油田根据自身实际情况和注水要求来确定自己油田的污水处理工艺。对油类的去除主要有以下四种方法。At present, the treatment of oil production wastewater can be divided into physical methods (gravity sedimentation, mechanical separation, centrifugation, coarse granulation, filtration, membrane separation, etc.), chemical methods (coagulation, acidification, salting out, electrolysis, etc.), physical and chemical methods. (flotation, adsorption, ion exchange, etc.), biological methods (activated sludge, biological filter, oxidation pond, etc.). Due to the large differences in the quality of sewage in various oilfields, the water quality requirements for purified water after treatment are also different. Therefore, each oilfield determines its own sewage treatment process according to its actual situation and water injection requirements. There are four main methods for oil removal.
自然除油,可以去除废水中的浮油和大部分散油。由于自然除油不投加混凝剂,只靠微小油珠、悬浮颗粒与污水的相对密度差上浮或下沉将水、泥、油分离,因此去除效率低,而且体积大、占地面积大。Natural degreasing can remove slick oil and most of the loose oil in the wastewater. Since natural degreasing does not add coagulant, it only depends on the relative density difference between tiny oil droplets, suspended particles and sewage to float or sink to separate water, mud and oil, so the removal efficiency is low, and the volume is large and the floor area is large. .
斜板除油,它是目前常用的高效除油方法之一,也是利用重力分离技术的除油方法。斜板除油的基本原理是“浅层理论”,简单地说,就是沉淀池越浅,就越能缩短沉淀时间,提高除油效率。Inclined plate degreasing, which is one of the most commonly used efficient degreasing methods, is also a degreasing method using gravity separation technology. The basic principle of inclined plate oil removal is "shallow layer theory". Simply put, the shallower the sedimentation tank, the shorter the sedimentation time and improve the oil removal efficiency.
粗粒化除油,它是指采油污水通过一个装有粗粒化材料(填充物)的设备时,油珠粒径由小变大的过程。粗粒化设备能去除大于20μm的油珠,主要是去除废水中的分散油。Coarse-grained oil removal refers to the process in which the oil droplet size changes from small to large when the oil production sewage passes through a device equipped with coarse-grained materials (fillers). Coarse granulation equipment can remove oil droplets larger than 20μm, mainly to remove dispersed oil in wastewater.
混凝除油,它是通过向废水中加入混凝剂,通过压缩双电层和电中和作用,破坏胶体的稳定性、使胶体凝聚、颗粒不断增大,最后重力沉淀下来,分离去除。混凝除油可以去除废水中的乳化油和胶体颗粒。Coagulation and degreasing, it is by adding coagulant to the wastewater, through the compression of the double layer and the neutralization effect, the stability of the colloid is destroyed, the colloid is agglomerated, the particles continue to grow, and finally the gravity settles down and is separated and removed. Coagulation and oil removal can remove emulsified oil and colloidal particles in wastewater.
含油废水的处理方法虽然较多,但各种方法都有其局限性。如果使用单一的方法,难以达到满意的效果。Although there are many treatment methods for oily wastewater, each method has its limitations. If a single method is used, it is difficult to achieve satisfactory results.
发明内容:Invention content:
为了解决上述问题,本发明提供了一体化混凝增效斜板除油设备,其将斜板除油与混凝除油结合起来,实现高效除油和去浊的作用。其主要由:进水管(1)、混合设备(2)、网格絮凝设备(3)、配水孔板(4)、小角度斜板(5)、大角度斜板(6)、V型隔板(7)、出水管(8)、V型槽(9)、排油管(10)、泥斗(11)、排泥管(12)构成;其主要特征是:设备由混凝和去浊除油两部分组成,其中混凝区由混合设备(2)和网格絮凝设备(3)组成,实现混凝增效处理,随后污水通过配水孔板(4)进入去浊除油区,利用两种不同角度的斜板实现沉淀颗粒和除油的目的,两种斜板上表面均可实现沉淀作用,下表面均可实现聚结除油作用,通过安装角度的变化主要实现的功能不同。沉淀物经排泥装置(11)、(12)排出,浮油类通过去浊除油区上端的V型槽(9)排出,出水区采用V型隔板(7)避免油类进入出水管(8),污水经过这种一体化混凝增效斜板除油设备后,可达到高效的混凝沉淀及除油效果。In order to solve the above problems, the present invention provides an integrated coagulation synergistic inclined plate oil removal equipment, which combines inclined plate oil removal and coagulation oil removal to achieve efficient oil removal and turbidity removal. It is mainly composed of: water inlet pipe (1), mixing equipment (2), grid flocculation equipment (3), water distribution orifice plate (4), small-angle inclined plate (5), large-angle inclined plate (6), V-shaped partition Plate (7), outlet pipe (8), V-shaped groove (9), oil discharge pipe (10), mud bucket (11), mud discharge pipe (12); its main features are: the equipment consists of coagulation and deturbidity Oil removal is composed of two parts, in which the coagulation area is composed of mixing equipment (2) and grid flocculation equipment (3) to achieve coagulation and synergistic treatment, and then the sewage enters the turbidity and oil removal area through the water distribution orifice (4), and utilizes Two kinds of sloping plates with different angles achieve the purpose of sedimentation and degreasing. The upper surface of the two sloping plates can achieve precipitation, and the lower surface can achieve coalescence and degreasing. The main functions achieved by changing the installation angle are different. The sediment is discharged through the mud discharge device (11), (12), the floating oil is discharged through the V-shaped groove (9) at the upper end of the turbidity and oil removal area, and the V-shaped partition (7) is used in the water outlet area to prevent oil from entering the outlet pipe (8) After the sewage passes through this integrated coagulation synergistic inclined plate degreasing equipment, it can achieve high-efficiency coagulation, sedimentation and degreasing effects.
一体化混凝增效斜板除油设备中混凝部分采用两种设备实现高效的混合效果,混合设备(2)安装在池体外部,污水由进水管(1)经过混合设备(2)后,进入设备,再通过网格絮凝设备(3),实现混凝增效目的。一体化设备的去浊除油区安装有两种角度的斜板,下部分是小角度斜板(5),主要用于聚结除油,其安装角度为30°-55°,上部分是大角度斜板(6),主要用于颗粒的沉淀,其安装角度为45°-65°。排油区采用V型槽(9),对于上层的浮油区,V型槽(9)有自动撇油的作用,减少其动力消耗。在出水区设置有V型隔板(7),造成出水区油水的隔断,以避免出水中混杂有油类。The coagulation part of the integrated coagulation synergistic inclined plate degreasing equipment adopts two kinds of equipment to achieve efficient mixing effect. The mixing equipment (2) is installed outside the tank body, and the sewage passes through the mixing equipment (2) through the water inlet pipe (1) , enter the equipment, and then pass through the grid flocculation equipment (3) to achieve the purpose of coagulation and efficiency enhancement. The turbidity and oil removal area of the integrated equipment is equipped with sloping plates with two angles. The lower part is a small-angle sloping plate (5), which is mainly used for coalescence and oil removal. The installation angle is 30°-55°, and the upper part is The large-angle inclined plate (6) is mainly used for the precipitation of particles, and its installation angle is 45°-65°. The oil discharge area adopts a V-shaped groove (9), and for the upper oil slick area, the V-shaped groove (9) has the effect of automatically skimming oil, reducing its power consumption. A V-shaped dividing plate (7) is arranged in the water outlet area, causing the oil and water in the water outlet area to be cut off, so as to avoid mixing oil in the water outlet.
本发明的有益效果:Beneficial effects of the present invention:
(1)混凝、去浊除油处理效率高(1) High efficiency of coagulation, turbidity and oil removal
由于混合迅速,可大大缩短污水在处理设备中的停留时间。同时由于混凝除油和斜板除油的共同使用,两种不同角度斜板的共用,排油区、出水区V型槽的设计,可达到较好的三相分离效率,降低了后续处理设备的负荷。Due to the rapid mixing, the residence time of sewage in the treatment equipment can be greatly shortened. At the same time, due to the common use of coagulation and inclined plate oil removal, the sharing of two inclined plates with different angles, and the design of V-shaped grooves in the oil discharge area and water outlet area, better three-phase separation efficiency can be achieved, and the subsequent treatment is reduced. equipment load.
(2)占地面积小(2) Small footprint
由于设备一体化的设计且设备处理效率高,因此占地面积小。Due to the integrated design of the equipment and the high processing efficiency of the equipment, it occupies a small area.
(3)抗冲击能力强,适用水质广泛(3) Strong impact resistance, suitable for a wide range of water quality
当原水温度、进水流量、投加药量发生一些变化时,不影响出水水质。When the temperature of the raw water, the flow rate of the incoming water, and the dosage of the chemical have some changes, the quality of the effluent water will not be affected.
(4)出水水质好,处理成本低(4) The effluent water quality is good and the treatment cost is low
因设备不需机械部件,没有动力消耗,成本低便于维护,保证出水水质稳定达标。Because the equipment does not require mechanical parts, no power consumption, low cost and easy maintenance, it ensures that the effluent water quality is stable and up to standard.
附图说明:Description of drawings:
图1一体化混凝增效斜板除油设备平面图;Figure 1 Plane view of integrated coagulation synergistic inclined plate degreasing equipment;
图2一体化混凝增效斜板除油设备泥区平面图;Figure 2 Plane view of the mud area of the integrated coagulation synergistic inclined plate degreasing equipment;
图3一体化混凝增效斜板除油设备剖面图。Figure 3 is a sectional view of the integrated coagulation synergistic inclined plate degreasing equipment.
图中标号说明:Explanation of symbols in the figure:
1、进水管 2、混合设备 3、网格絮凝设备1.
4、配水孔板 5、小角度斜板 6、大角度斜板4. Water
7、V型隔板 8、出水管 9、V型槽7. V-shaped
10、排油管 11、泥斗 12、排泥管10.
具体实施方式:Detailed ways:
污水和投加的药剂通过进水管(1)后进入设备外部的混合设备(2),进行初步混合。随后进入设备中的网格絮凝设备(3),强化混合效果。通过配水孔板(4)进入去浊除油区。在去浊除油区污水将经过两道斜板设备,下面一层是小角度斜板(5),主要用于油水分离,使油类聚结,安装角度为30°-55°,上面一层是大角度斜板(6),主要用于泥水分离,使颗粒沉淀,安装角度为45°-65°。在出水区设有V型隔板(7),通过该隔板将油水隔断,保证出水不含油类,出水经出水管(8)排出。上浮的油类经过去浊除油区上端的V型槽(9),通过排油管(10)排走。下沉的颗粒物通过沉淀除油区下部的泥斗(11)聚集,随后有排泥管(12)排出。Sewage and the added chemicals pass through the water inlet pipe (1) and then enter the mixing device (2) outside the equipment for preliminary mixing. Then it enters the mesh flocculation device (3) in the device to strengthen the mixing effect. Enter the turbidity and oil removal area through the water distribution orifice (4). The sewage in the turbidity and oil removal area will pass through two sloping plate equipment. The lower layer is a small-angle sloping plate (5), which is mainly used for oil-water separation to make oil coalesce. The installation angle is 30°-55°, and the upper one is The first layer is a large-angle inclined plate (6), which is mainly used for mud-water separation to make particles settle, and the installation angle is 45°-65°. A V-shaped partition (7) is arranged in the water outlet area, through which the oil and water are cut off to ensure that the outlet water does not contain oil, and the outlet water is discharged through the outlet pipe (8). The floating oil passes through the V-shaped groove (9) at the upper end of the turbidity and oil removal area, and is discharged through the oil discharge pipe (10). The sinking particles are collected through the mud hopper (11) at the lower part of the sedimentation and deoiling area, and then discharged through the mud discharge pipe (12).
实施例:Example:
采用一体化混凝增效斜板除油设备对某油田采油废水进行处理。日进水量为100立方米/天,污水进水水质如表1所示。The integrated coagulation synergistic slant plate oil removal equipment is used to treat oil production wastewater in an oilfield. The daily water inflow is 100 cubic meters per day, and the quality of the sewage influent is shown in Table 1.
表1某油田采油废水水质Table 1 Water quality of oil production wastewater in an oilfield
根据具体情况,按100m3/d进水设计,该一体化设备长1500mm,宽1000mm,高4000mm。混凝区采用高效微涡混合设备和高效微涡网格设备,其中采用高效微涡混合设备的长度为1000mm,设备内部混凝区安装高效微涡网格设备7套。去浊除油区中,小角度斜板设备安装角度为45°,大角度斜板设备安装角度为60°。最终一体化设备对该水质中污染物的去除率如下:COD去除率为84.9%,BOD5去除率为76.3%,SS去除率为95.8%,含油量去除率为89.4%。可见,一体化混凝增效斜板除油设备能实现高效的混凝沉淀及除油作用,可有效降低后续处理设施的处理负荷。According to the specific situation, the integrated equipment is 1500mm long, 1000mm wide and 4000mm high according to the water inlet design of 100m 3 /d. The coagulation area adopts high-efficiency micro-vortex mixing equipment and high-efficiency micro-vortex grid equipment. The length of the high-efficiency micro-vortex mixing equipment is 1000mm, and 7 sets of high-efficiency micro-vortex grid equipment are installed in the coagulation area inside the equipment. In the turbidity and oil removal area, the installation angle of the small-angle inclined plate equipment is 45°, and the installation angle of the large-angle inclined plate equipment is 60°. The removal rate of the final integrated equipment for the pollutants in the water quality is as follows: the removal rate of COD is 84.9%, the removal rate of BOD 5 is 76.3%, the removal rate of SS is 95.8%, and the removal rate of oil content is 89.4%. It can be seen that the integrated coagulation synergistic inclined plate oil removal equipment can achieve efficient coagulation, sedimentation and oil removal, and can effectively reduce the processing load of subsequent treatment facilities.
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CN103787527A (en) * | 2014-01-21 | 2014-05-14 | 碧海舟(北京)石油化工设备有限公司 | Oily sewage air floatation suspension layer filtering device |
CN104003503A (en) * | 2014-06-11 | 2014-08-27 | 中国环境科学研究院 | Integral slurry-water separation device and method for fenton chemical oxidation reaction |
CN105060398A (en) * | 2015-08-19 | 2015-11-18 | 北京神州瑞霖环保科技有限公司 | Coal mine water underground purification treatment method |
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CN109835993A (en) * | 2017-11-24 | 2019-06-04 | 江苏灏逸环保科技有限公司 | A kind of oil-containing sewage treatment system |
CN111170540A (en) * | 2019-12-30 | 2020-05-19 | 霸州嘉明扬科技有限公司 | Oil-water separator for catering |
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