CN103170082A - Fire-extinguishing composition containing amino acid compounds - Google Patents
Fire-extinguishing composition containing amino acid compounds Download PDFInfo
- Publication number
- CN103170082A CN103170082A CN2011104514617A CN201110451461A CN103170082A CN 103170082 A CN103170082 A CN 103170082A CN 2011104514617 A CN2011104514617 A CN 2011104514617A CN 201110451461 A CN201110451461 A CN 201110451461A CN 103170082 A CN103170082 A CN 103170082A
- Authority
- CN
- China
- Prior art keywords
- fire
- acid
- extinguishing
- extinguishing composite
- amino acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/06—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires containing gas-producing, chemically-reactive components
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Fireproofing Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a fire-extinguishing composition containing amino acid compounds. The fire-extinguishing composition comprises the following components in percentage by mass: 10-70% of amino acid and 30-90% of fire retardant; and in the fire-extinguishing composition, fireworks drug is used as heat source and power source, and the fire-extinguishing composition is driven by setting fire to the fireworks drug to react to generate a large amount of fire-extinguishing substances which are sprayed out together with the fireworks drug to extinguish fire. By adopting the amino acid compounds and through using the characteristic of low toxicity of amino acid, the fire-extinguishing composition has no harm to people and livestock; and in addition, the amino acid compounds decompose and generate various aerosol fire-extinguishing substances which are excellent in fire-extinguishing effect, therefore, the fire-extinguishing efficiency of the fire-extinguishing composition is improved.
Description
Technical field
The present invention relates to a kind of fire-extinguishing composite, particularly a kind of take the fire-extinguishing composite of firework medicament as heating power source and power source.
Background technology
Existing aerosol extinguishing agent mainly contains S type and K type extinguishing chemical, by its performance characteristics of analysis-by-synthesis, its weak point mainly contains: aerosol extinguishing agent is all to utilize extinguishing chemical generation redox reaction to discharge a large amount of gases, active particle, chain-breaking reaction by active particle, the covering of a large amount of gases suffocates, and realizes the fire extinguishing purpose that chemistry combines with physics.Aerogel generating agent is when the generation combustion reaction discharges extinguishing material, discharge a large amount of heat, for effectively reducing device and aerocolloidal temperature, avoid occuring spot fire, need to increase cooling system, but increased cooling system and will cause device complex structure heaviness on the whole, technological process is complicated, cost up, and due to the existence of cooling system, a large amount of active particles are lost activity, cause extinguishing property greatly to reduce.In addition, its material that decomposes generation of common extinguishing chemical is toxic to human body, and it is released in air can cause certain injury to people and animals.
Summary of the invention
The fire extinguishing effectiveness that exists based on extinguishing medium of the prior art is not high, and the problem that effective rate of utilization is low the invention provides the Novel fire extinguishing composition that a kind of fire extinguishing effectiveness is high, security performance good and utilization rate is higher.
The technical scheme of technical solution problem of the present invention is:
A kind of fire-extinguishing composite that contains amino acids comprises amino acid and fire retardant; Its mass percent is respectively:
Amino acid: 10%～70%;
Fire retardant: 30%～90%;
Described fire-extinguishing composite is take pyrotechnics class medicament as heating power source and power source, emits heat and makes a large amount of extinguishing materials of its output that reacts by lighting pyrotechnics class medicament burning, sprays together and puts out a fire with pyrotechnics class medicament.
Further, described amino acid is amino carboxylic acid compounds and derivative, sulfamic acid compounds and derivative thereof, phosphoramidic acid compounds and derivative thereof or its combination.
Further, described amino carboxylic acid compounds and derivative thereof are one or more in glycine, alanine, valine, leucine, isoleucine, phenylalanine, proline, tryptophan, serine, tyrosine, cysteine, methionine, threonine, aspartic acid, glutamic acid, lysine, arginine, histidine, asparagine, glutamine or cupric glycinate.
Further, described sulfamic acid compounds and derivative thereof are one or more in sulfamic acid, taurine, sulfanilic acid, phenalgin sulfonamide, sulfacetamide, toluene sulfonyl hydrazide or zinc sulfanilate.
Further, described phosphoramidic acid compounds and derivative thereof are one or more in amino trimethylene methyl acid phosphate, ATMP sodium, ATMP potassium, diethylene triamine pentamethylene phosphonic sodium, ethylene diamine tetra methylene phosphonic acid, ethylene diamine tetra methylene phosphonic acid sodium or polyamino polyether base methylenephosphonic acid.
Fire retardant of the present invention is bromide fire retardant, chlorine-based flame retardant, organic phosphorus flame retardant, phosphorus-halogenated flame retardant, nitrogen system and phosphorus-nitrogenated flame retardant, other based flame retardants or its combination.
further, described bromide fire retardant is tetrabromobisphenol A, tetra bromobisphenol A ether, 1, two (tribromophenoxy) ethane of 2-, tetrabromophthalic anhydride, 1, two (tetrabromo phthalimide) ethane of 2-, deca-BDE, ten tetrabromo two (phenoxy group) benzene, 1, two (penta-bromophenyl) ethane of 2-, bromo trimethylphenyl hydrogenation indenes, acrylic acid pentabromo-benzyl ester, HBB, pentabromotoluene, HBCD, N, N '-1, two (the dibromo norborny two carbimides) ethane of 2-, the bromostyrene copolymer, the tetrabromobisphenol A carbonic ester oligomer, polyacrylic acid pentabromo-benzyl ester, poly-dibromo phenylene ether or its combination.
Further, described chlorine-based flame retardant is DCRP, extra large special acid anhydrides, mirex, tetrachlorobisphenol A, chlorinated polypropylene, the poly-rate ethene of chlorination, vinyl chloride-vinylidene chloride copolymer, chlorinated polyether or its combination.
Further, described organic phosphorus flame retardant is 1-oxo-4-methylol-2,6,7-trioxa-1-phospha dicyclo [2,2,2] octane, 2,2-dimethyl-1, ammediol-two (neopentyl glycol) biphosphonate, 9, the 10-dihydro-9-oxy is assorted-10-phospho hetero phenanthrene-10 oxide (DOPO), two (4-carboxy phenyl) phenyl phosphorous oxide, two (4-hydroxyphenyl) phenyl phosphorous oxide, phosphoric acid phenyl diphenyl sulphone (DPS) ester oligomer or its combination.
further, described phosphorus-halogenated flame retardant is three (2, 2-two (bromomethyl)-3-bromopropyl) phosphate, three (dibromo phenyl) phosphate, 3, two (tribromophenoxy)-2 of 9-, 4, 8, 10,-four oxa-s-3, 9-two phospha volutions [5, 5]-3, 9-dioxy hendecane, 3, two (the pentabromo-phenoxy groups)-2 of 9-, 4, 8, 10,-four oxa-s-3, 9-two phospha volutions [5, 5]-3, 9-dioxy hendecane, 1-oxo-4-tribromo carbobenzoxy-2, 6, 7-trioxa-1-phospha dicyclo [2, 2, 2] octane, to phenylene four (2, 4, 6-tribromo phenyl) biphosphonate, 2, 2-two (chloromethyl)-1, ammediol-two (neopentyl glycol) biphosphonate or 3, 9-two (tribromo neopentyl oxygen)-2, 4, 8, 10-four oxa-s-3, 9-two phospha volutions [5.5]-3, 9-dioxy hendecane or its combination.
further, described nitrogen system and phosphorus-nitrogen combustion inhibitor are melamine cyanurate, the orthophosphoric acid melamine, orthophosphoric acid two melamines, polyphosphoric acid melamine, the boric acid melamine, eight molybdic acid melamines, trihydroxyethyl isocyanuric ester, 2,4-diaminourea-6-(3,3,3-, three chloropropyls)-1,3,5-triazines, 2,4-two (the N-methylol is amino)-6-(3,3,3-, three chloropropyls-1,3,5-triazines), phosphoric acid hydrogen two guanidines, the biphosphate guanidine, phosphoguanidine, guanidine carbonate, Guanidine Sulfamate 99, urea, the biphosphate urea, dicyandiamide, melamine, two (2,6,7-trioxa-1-phospha-dicyclo [2.2.2] octane-1-oxygen-4-methyl) hydroxyl phosphate melamine, 3,9-dihydroxy-3,9-dioxy-2,4,8,10-four oxa-s-3,9-two phospha volution [5.5] hendecanes-3,9-two melamines, 1,2-two (3-dioxa-2-phosphorus heterocycle cyclohexyl-2-is amino for 2-oxygen-5,5-dimethyl-1) ethane, N, N '-two (3-dioxa-2-phospha changes hexyl for 2-oxygen-5,5-dimethyl-1)-2,2 '-m-phenylene diamine (MPD), three (2-oxygen-5,5-dimethyl-1,3-dioxa-2-piperidyl-2-methyl) amine, hexachlorocyclotriph,sphazene or its combination.
further, described other based flame retardants are APP, diammonium hydrogen phosphate, ammonium dihydrogen phosphate (ADP), trbasic zinc phosphate, aluminum phosphate, boron phosphate, antimony oxide, aluminium hydroxide, magnesium hydroxide, basic magnesite, alkalescence oxalic acid aluminium, Firebrake ZB, barium metaborate, zinc oxide, zinc sulphide, white vitriol, aluminium borate whisker, ammonium octamolybdate, ammonium heptamolybdate, zinc stannate, tin monoxide, ferrocene, acetone iron, di-iron trioxide, tri-iron tetroxide, sodium tungstate, the hexafluoro potassium titanate, Potassium Zirconium Fluoride, titanium dioxide, potassium citrate, manganese carbonate, strontium carbonate, calcium carbonate, barium sulfate or its combination.
Fire-extinguishing composite of the present invention also comprises performance additive, and its mass percent is 0%～10%.
Further, described performance additive is one or more in stearate, HPMC, ethyl cellulose, polyvinyl alcohol, graphite, waterglass, phenolic resins, shellac or starch.
Each component and the mass percent thereof of fire-extinguishing composite of the present invention are:
Amino acid: 10%～60%
Fire retardant: 35%～90%
Performance additive: 0%～10%.
Each component and the mass percent thereof of fire-extinguishing composite of the present invention are:
Amino acid: 15%～55%
Fire retardant: 40%～80%
Additive: 0%～10%.
Each component and the mass percent thereof of fire-extinguishing composite of the present invention are:
Amino acid 20%～50%
Fire retardant 45%～80%
Additive 0%～10%.
The fire-fighting principle of fire-extinguishing composite of the present invention is:
amino acids of the present invention is take pyrotechnics class medicament as heating power source and power source, emit heat and make its at high temperature endothermic decomposition by lighting pyrotechnics class medicament burning, discharge extinguishing material, this extinguishing material can be by free radical and the necessary O of looping combustion reaction, OH, one or more in the H free radical are reacted, thereby cut off the looping combustion reaction, also can reduce oxygen partial pressure by physical action and suppress flame, or physics occurs simultaneously and organoselenocyanate is realized the effect of putting out a fire jointly, meanwhile, itself and firework medicament produce synergistic function, further improved the fire extinguishing effectiveness of extinguishing chemical, greatly shortened effective attack time.
It has the following advantages the fire-extinguishing composite that contains amino acids of the present invention:
1, fire-extinguishing composite of the present invention adopts amino acids, and it has utilized the little characteristic of amino acid whose toxicity, and it can not damage people and animals.
2, the amino acids in fire-extinguishing composite of the present invention, its aerosol fire-extinguishing substance classes that decompose to produce is many, and good extinguishing effect has improved the fire extinguishing effectiveness of fire-extinguishing composite.
3, endothermic decomposition in the situation of being heated, can occur rapidly in fire-extinguishing composite of the present invention, effectively reduces rapidly the heat that the firework medicament burning discharges, and the temperature that greatly reduces the extinguishing device spout and spurt material is safer.
4, fire-extinguishing composite of the present invention is that the employing firework medicament is the heating power source, and its use is more convenient.
5, add fire retardant, additive in fire-extinguishing composite of the present invention, further improved extinguishing property and processing characteristics that main extinguish material is amino acids, make its stable performance and be easy to long-term storage.
The specific embodiment
Now in conjunction with the embodiments the fire-extinguishing composite that contains amino acids of the present invention is further illustrated:
Fire-extinguishing composite of the present invention carries out following test, and it is compared in the identical experiment condition of same device with existing fire-extinguishing composite, and result is as follows:
The sheet fire-extinguishing composite 50g that makes is added respectively in the extinguishing device that 50gK type hot aerosol propellant is housed, carry out fire-extinguishing test according to GA86-2009 6.3.2 money respectively, extinguishing grade is selected 8B; Comparative Examples is chosen as the commercially available K type of 50g hot aerosol propellant, is also to test according to identical method.Its experimental test the results are shown in Table 1.
The various component comparison of ingredients of table 1 and comparison of test results
Can clearly be seen that by table 1, the fire-extinguishing composite that contains amino acids of embodiments of the invention 1-18 is better than the situation of Comparative Examples on fire-fighting efficiency, also is being starkly lower than Comparative Examples on attack time and on apart from spout 10cm place temperature.
Claims (17)
1. fire-extinguishing composite that contains amino acids, it is characterized in that: described fire-extinguishing composite comprises amino acid and fire retardant; Its mass percent is respectively:
Amino acid: 10%～70%
Fire retardant: 30%～90%
Described fire-extinguishing composite is take pyrotechnics class medicament as heating power source and power source, emits heat and makes a large amount of extinguishing materials of its output that reacts by lighting pyrotechnics class medicament burning, sprays together and puts out a fire with pyrotechnics class medicament.
2. fire-extinguishing composite according to claim 1, it is characterized in that: described amino acid is amino carboxylic acid compounds and derivative, sulfamic acid compounds and derivative thereof, phosphoramidic acid compounds and derivative thereof or its combination.
3. fire-extinguishing composite according to claim 2, it is characterized in that: described amino carboxylic acid compounds and derivative thereof are one or more in glycine, alanine, valine, leucine, isoleucine, phenylalanine, proline, tryptophan, serine, tyrosine, cysteine, methionine, threonine, aspartic acid, glutamic acid, lysine, arginine, histidine, asparagine, glutamine or cupric glycinate.
4. fire-extinguishing composite according to claim 2, it is characterized in that: described sulfamic acid compounds and derivative thereof are one or more in sulfamic acid, taurine, sulfanilic acid, phenalgin sulfonamide, sulfacetamide, toluene sulfonyl hydrazide or zinc sulfanilate.
5. fire-extinguishing composite according to claim 2, it is characterized in that: described phosphoramidic acid compounds and derivative thereof are one or more in amino trimethylene methyl acid phosphate, ATMP sodium, ATMP potassium, diethylene triamine pentamethylene phosphonic sodium, ethylene diamine tetra methylene phosphonic acid, ethylene diamine tetra methylene phosphonic acid sodium or polyamino polyether base methylenephosphonic acid.
6. fire-extinguishing composite described according to claims 1 is characterized in that: described fire retardant is bromide fire retardant, chlorine-based flame retardant, organic phosphorus flame retardant, phosphorus-halogenated flame retardant, nitrogen system and phosphorus-nitrogenated flame retardant, other based flame retardants or its combination.
7. fire-extinguishing composite described according to claims 6, it is characterized in that: described bromide fire retardant is tetrabromobisphenol A, tetra bromobisphenol A ether, 1, two (tribromophenoxy) ethane of 2-, tetrabromophthalic anhydride, 1, two (tetrabromo phthalimide) ethane of 2-, deca-BDE, ten tetrabromo two (phenoxy group) benzene, 1, two (penta-bromophenyl) ethane of 2-, bromo trimethylphenyl hydrogenation indenes, acrylic acid pentabromo-benzyl ester, HBB, pentabromotoluene, HBCD, N, N '-1, two (the dibromo norborny two carbimides) ethane of 2-, the bromostyrene copolymer, the tetrabromobisphenol A carbonic ester oligomer, polyacrylic acid pentabromo-benzyl ester, poly-dibromo phenylene ether or its combination.
8. fire-extinguishing composite described according to claims 6 is characterized in that: described chlorine-based flame retardant is DCRP, extra large special acid anhydrides, mirex, tetrachlorobisphenol A, chlorinated polypropylene, the poly-rate ethene of chlorination, vinyl chloride-vinylidene chloride copolymer, chlorinated polyether or its combination.
9. fire-extinguishing composite described according to claims 6, it is characterized in that: described organic phosphorus flame retardant is 1-oxo-4-methylol-2,6,7-trioxa-1-phospha dicyclo [2,2,2] octane, 2,2-dimethyl-1, ammediol-two (neopentyl glycol) biphosphonate, 9, the 10-dihydro-9-oxy is assorted-10-phospho hetero phenanthrene-10 oxide (DOPO), two (4-carboxy phenyl) phenyl phosphorous oxide, two (4-hydroxyphenyl) phenyl phosphorous oxide, phosphoric acid phenyl diphenyl sulphone (DPS) ester oligomer or its combination.
10. fire-extinguishing composite described according to claims 6, it is characterized in that: described phosphorus-halogenated flame retardant is three (2, 2-two (bromomethyl)-3-bromopropyl) phosphate, three (dibromo phenyl) phosphate, 3, two (tribromophenoxy)-2 of 9-, 4, 8, 10,-four oxa-s-3, 9-two phospha volutions [5, 5]-3, 9-dioxy hendecane, 3, two (the pentabromo-phenoxy groups)-2 of 9-, 4, 8, 10,-four oxa-s-3, 9-two phospha volutions [5, 5]-3, 9-dioxy hendecane, 1-oxo-4-tribromo carbobenzoxy-2, 6, 7-trioxa-1-phospha dicyclo [2, 2, 2] octane, to phenylene four (2, 4, 6-tribromo phenyl) biphosphonate, 2, 2-two (chloromethyl)-1, ammediol-two (neopentyl glycol) biphosphonate or 3, 9-two (tribromo neopentyl oxygen)-2, 4, 8, 10-four oxa-s-3, 9-two phospha volutions [5.5]-3, 9-dioxy hendecane or its combination.
11. fire-extinguishing composite described according to claims 6 is characterized in that: described nitrogen system and phosphorus-nitrogen combustion inhibitor are melamine cyanurate, the orthophosphoric acid melamine, orthophosphoric acid two melamines, polyphosphoric acid melamine, the boric acid melamine, eight molybdic acid melamines, trihydroxyethyl isocyanuric ester, 2,4-diaminourea-6-(3,3,3-, three chloropropyls)-1,3,5-triazines, 2,4-two (the N-methylol is amino)-6-(3,3,3-, three chloropropyls-1,3,5-triazines), phosphoric acid hydrogen two guanidines, the biphosphate guanidine, phosphoguanidine, guanidine carbonate, Guanidine Sulfamate 99, urea, the biphosphate urea, dicyandiamide, melamine, two (2,6,7-trioxa-1-phospha-dicyclo [2.2.2] octane-1-oxygen-4-methyl) hydroxyl phosphate melamine, 3,9-dihydroxy-3,9-dioxy-2,4,8,10-four oxa-s-3,9-two phospha volution [5.5] hendecanes-3,9-two melamines, 1,2-two (3-dioxa-2-phosphorus heterocycle cyclohexyl-2-is amino for 2-oxygen-5,5-dimethyl-1) ethane, N, N '-two (3-dioxa-2-phospha changes hexyl for 2-oxygen-5,5-dimethyl-1)-2,2 '-m-phenylene diamine (MPD), three (2-oxygen-5,5-dimethyl-1,3-dioxa-2-piperidyl-2-methyl) amine, hexachlorocyclotriph,sphazene or its combination.
12. fire-extinguishing composite described according to claims 6, it is characterized in that: described other based flame retardants are APP, diammonium hydrogen phosphate, ammonium dihydrogen phosphate (ADP), trbasic zinc phosphate, aluminum phosphate, boron phosphate, antimony oxide, aluminium hydroxide, magnesium hydroxide, basic magnesite, alkalescence oxalic acid aluminium, Firebrake ZB, barium metaborate, zinc oxide, zinc sulphide, white vitriol, aluminium borate whisker, ammonium octamolybdate, ammonium heptamolybdate, zinc stannate, tin monoxide, ferrocene, acetone iron, di-iron trioxide, tri-iron tetroxide, sodium tungstate, the hexafluoro potassium titanate, Potassium Zirconium Fluoride, titanium dioxide, potassium citrate, manganese carbonate, strontium carbonate, calcium carbonate, barium sulfate or its combination.
13. the described fire-extinguishing composite of any one claim according to claim 1 to 12, it is characterized in that: described fire-extinguishing composite also comprises performance additive, and its mass percent is approximately 0%～10%.
14. fire-extinguishing composite according to claim 13 is characterized in that: described performance additive is one or more in stearate, HPMC, ethyl cellulose, polyvinyl alcohol, graphite, waterglass, phenolic resins, shellac or starch.
15. according to the described fire-extinguishing composite of claim 14, it is characterized in that: each component and the mass percent thereof of described fire-extinguishing composite are:
Amino acid: 10%～60%
Fire retardant: 35%～90%
Performance additive: 0%～10%.
16. according to the described fire-extinguishing composite of claim 15, it is characterized in that: each component and the mass percent thereof of described fire-extinguishing composite are:
Amino acid: 15%～55%
Fire retardant: 40%～80%
Performance additive: 0%～10%.
17. according to the described fire-extinguishing composite of claim 16, it is characterized in that: each component and the mass percent thereof of described fire-extinguishing composite are:
Amino acid 20%～50%
Fire retardant 45%～80%
Performance additive 0%～10%.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104514617A CN103170082A (en) | 2011-12-20 | 2011-12-20 | Fire-extinguishing composition containing amino acid compounds |
| PCT/CN2012/080086 WO2013091385A1 (en) | 2011-12-20 | 2012-08-14 | Fire extinguishing composition containing amino acid compounds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104514617A CN103170082A (en) | 2011-12-20 | 2011-12-20 | Fire-extinguishing composition containing amino acid compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103170082A true CN103170082A (en) | 2013-06-26 |
Family
ID=48630547
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011104514617A Pending CN103170082A (en) | 2011-12-20 | 2011-12-20 | Fire-extinguishing composition containing amino acid compounds |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN103170082A (en) |
| WO (1) | WO2013091385A1 (en) |
Cited By (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103741461A (en) * | 2013-12-31 | 2014-04-23 | 苏州市轩德纺织科技有限公司 | Acrylic fabric finishing agent and preparation method thereof |
| CN103736238A (en) * | 2014-01-13 | 2014-04-23 | 西安坚瑞安全应急设备有限责任公司 | Fire extinguishing composition containing sulfur-containing organic compound |
| CN103736240A (en) * | 2014-01-13 | 2014-04-23 | 西安坚瑞安全应急设备有限责任公司 | Fire extinguishing composition containing saturated hydrocarbon compound and derivatives of saturated hydrocarbon compound |
| CN103751943A (en) * | 2014-01-13 | 2014-04-30 | 西安坚瑞安全应急设备有限责任公司 | Fire extinguishing composition containing nitrogenous organic compound |
| CN103768754A (en) * | 2014-01-13 | 2014-05-07 | 西安坚瑞安全应急设备有限责任公司 | Fire-extinguishment composition containing unsaturated hydrocarbon compounds and derivatives thereof |
| WO2015104004A1 (en) * | 2014-01-13 | 2015-07-16 | 西安坚瑞安全应急设备有限责任公司 | Fire extinguishing composition comprising carboxylic acid derivative |
| CN104874145A (en) * | 2015-06-16 | 2015-09-02 | 公安部四川消防研究所 | Slurry fire extinguishing agent for extinguishing stacking fire |
| CN104922844A (en) * | 2015-06-04 | 2015-09-23 | 公安部四川消防研究所 | Fire extinguishing agent for extinguishing cotton textile stack fire |
| CN105288925A (en) * | 2015-12-01 | 2016-02-03 | 西安坚瑞安全应急设备有限责任公司 | Fire extinguishing composition |
| CN105592893A (en) * | 2013-10-02 | 2016-05-18 | 英派尔科技开发有限公司 | Bromine-free fire retardant (FR) agents capable of using cyclization mechanism |
| CN106632468A (en) * | 2016-11-22 | 2017-05-10 | 同济大学 | A preparing method of an aminotris(methylenephosphonic acid) metal salt flame retardant |
| CN107019861A (en) * | 2016-01-29 | 2017-08-08 | 天津鹏安数讯消防设备工程有限公司 | Fire extinguishing sheet |
| CN107854800A (en) * | 2017-11-24 | 2018-03-30 | 西安威西特消防科技有限责任公司 | A kind of self-extinguishing composition |
| CN108252088A (en) * | 2017-12-12 | 2018-07-06 | 江苏新瑞贝科技股份有限公司 | A kind of textile flame-retardant finishing agent and preparation method thereof |
| US10035033B2 (en) | 2014-01-13 | 2018-07-31 | Xi'an Westpeace Fire Technology Co., Ltd. | Fire extinguishing composition comprising alcohol phenol compound and derivative thereof |
| US10092786B2 (en) | 2014-01-13 | 2018-10-09 | Xi'an Westpeace Fire Technology Co., Ltd. | Fire extinguishing composition comprising aldoketones compound |
| CN108853861A (en) * | 2018-08-20 | 2018-11-23 | 常州扬鹏科技有限公司 | From temperature sensitive type fire-extinguishing composite and preparation method thereof |
| CN110066293A (en) * | 2018-01-24 | 2019-07-30 | 金发科技股份有限公司 | A kind of aminotrimethylenephosphonic acid aluminium and its preparation method and application |
| CN111408095A (en) * | 2020-03-27 | 2020-07-14 | 浙江蓝盾电工新材料科技有限公司 | Lithium battery foam extinguishing agent |
| CN112175294A (en) * | 2020-10-26 | 2021-01-05 | 江苏昊晟塑业科技有限公司 | Flame-retardant foamed polypropylene and preparation method thereof |
| CN113679996A (en) * | 2021-08-17 | 2021-11-23 | 湖南神州防务科技有限公司 | High-ammonium-polyphosphate-based forest dry powder extinguishing agent and preparation method thereof |
| CN115197475A (en) * | 2022-07-18 | 2022-10-18 | 福州大学 | DOPO/ATMP modified chitosan loaded aluminum-based single-component intumescent flame retardant, and preparation method and application thereof |
| CN115340711A (en) * | 2022-05-26 | 2022-11-15 | 浙江农林大学 | Efficient preparation and application of nitrogen-phosphorus grafted bamboo charcoal-based flame retardant |
| CN115850849A (en) * | 2023-02-17 | 2023-03-28 | 广东南洋电缆股份有限公司 | Freely-bendable wear-resistant weather-resistant halogen-free low-smoke cable material, preparation method thereof and application thereof in robot |
| CN117046026A (en) * | 2023-06-27 | 2023-11-14 | 湖北及安盾消防科技有限公司 | Chemical coolant and application thereof in aerosol fire extinguishment |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109674683A (en) * | 2019-02-01 | 2019-04-26 | 陈学龙 | A kind of polypeptide skin care compositions without preservative |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4382884A (en) * | 1980-06-30 | 1983-05-10 | Ciba-Geigy Corporation | Fire-retardant, intumescent composition and its use for the flameproofing of substrates, and as a fire-extinguishing agent comprising an ammonium salt, a water-soluble nitrogen compound as a blowing agent and dextrin |
| JPH01155874A (en) * | 1987-12-14 | 1989-06-19 | Nippon Dry Chem Co Ltd | Fire extinguishing liquid |
| CN1275088A (en) * | 1998-08-14 | 2000-11-29 | 株式会社Gtl | Water-based foam fire extinguisher |
| CN102151515A (en) * | 2011-03-11 | 2011-08-17 | 上海瀛正科技有限公司 | Amino acid type fluorocarbon surfactant, synthesis method and application |
| CN102179026A (en) * | 2010-09-16 | 2011-09-14 | 陕西坚瑞消防股份有限公司 | Fire extinguishing composition generating extinguishant by pyrolysis |
| CN102179027A (en) * | 2010-09-16 | 2011-09-14 | 陕西坚瑞消防股份有限公司 | Ferrocene extinguishing composition |
-
2011
- 2011-12-20 CN CN2011104514617A patent/CN103170082A/en active Pending
-
2012
- 2012-08-14 WO PCT/CN2012/080086 patent/WO2013091385A1/en active Application Filing
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4382884A (en) * | 1980-06-30 | 1983-05-10 | Ciba-Geigy Corporation | Fire-retardant, intumescent composition and its use for the flameproofing of substrates, and as a fire-extinguishing agent comprising an ammonium salt, a water-soluble nitrogen compound as a blowing agent and dextrin |
| JPH01155874A (en) * | 1987-12-14 | 1989-06-19 | Nippon Dry Chem Co Ltd | Fire extinguishing liquid |
| CN1275088A (en) * | 1998-08-14 | 2000-11-29 | 株式会社Gtl | Water-based foam fire extinguisher |
| CN102179026A (en) * | 2010-09-16 | 2011-09-14 | 陕西坚瑞消防股份有限公司 | Fire extinguishing composition generating extinguishant by pyrolysis |
| CN102179027A (en) * | 2010-09-16 | 2011-09-14 | 陕西坚瑞消防股份有限公司 | Ferrocene extinguishing composition |
| CN102151515A (en) * | 2011-03-11 | 2011-08-17 | 上海瀛正科技有限公司 | Amino acid type fluorocarbon surfactant, synthesis method and application |
Cited By (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105592893A (en) * | 2013-10-02 | 2016-05-18 | 英派尔科技开发有限公司 | Bromine-free fire retardant (FR) agents capable of using cyclization mechanism |
| CN103741461A (en) * | 2013-12-31 | 2014-04-23 | 苏州市轩德纺织科技有限公司 | Acrylic fabric finishing agent and preparation method thereof |
| CN103741461B (en) * | 2013-12-31 | 2016-06-15 | 苏州市轩德纺织科技有限公司 | A kind of acrylic fibers material treatment agent and its preparation method |
| US10035033B2 (en) | 2014-01-13 | 2018-07-31 | Xi'an Westpeace Fire Technology Co., Ltd. | Fire extinguishing composition comprising alcohol phenol compound and derivative thereof |
| CN103751943B (en) * | 2014-01-13 | 2020-10-13 | 湖北及安盾消防科技有限公司 | Fire extinguishing composition containing nitrogen-containing organic compound |
| WO2015104004A1 (en) * | 2014-01-13 | 2015-07-16 | 西安坚瑞安全应急设备有限责任公司 | Fire extinguishing composition comprising carboxylic acid derivative |
| CN103768754A (en) * | 2014-01-13 | 2014-05-07 | 西安坚瑞安全应急设备有限责任公司 | Fire-extinguishment composition containing unsaturated hydrocarbon compounds and derivatives thereof |
| CN103736238B (en) * | 2014-01-13 | 2020-10-13 | 湖北及安盾消防科技有限公司 | Fire extinguishing composition containing sulfur-containing organic compound |
| CN103736240A (en) * | 2014-01-13 | 2014-04-23 | 西安坚瑞安全应急设备有限责任公司 | Fire extinguishing composition containing saturated hydrocarbon compound and derivatives of saturated hydrocarbon compound |
| CN103751943A (en) * | 2014-01-13 | 2014-04-30 | 西安坚瑞安全应急设备有限责任公司 | Fire extinguishing composition containing nitrogenous organic compound |
| US10092786B2 (en) | 2014-01-13 | 2018-10-09 | Xi'an Westpeace Fire Technology Co., Ltd. | Fire extinguishing composition comprising aldoketones compound |
| GB2538650A (en) * | 2014-01-13 | 2016-11-23 | Xi'an J&R Fire Fighting Equipment Co Ltd | Fire extinguishing composition comprising Carboxylic acid derivative |
| CN103736238A (en) * | 2014-01-13 | 2014-04-23 | 西安坚瑞安全应急设备有限责任公司 | Fire extinguishing composition containing sulfur-containing organic compound |
| US9974992B2 (en) | 2014-01-13 | 2018-05-22 | Xi'an Westpeace Fire Technology Co., Ltd. | Fire extinguishing composition comprising carboxylic acid derivative |
| CN104922844B (en) * | 2015-06-04 | 2018-08-21 | 公安部四川消防研究所 | A kind of extinguishing chemical for putting out cotton spinning stacking fire |
| CN104922844A (en) * | 2015-06-04 | 2015-09-23 | 公安部四川消防研究所 | Fire extinguishing agent for extinguishing cotton textile stack fire |
| CN104874145B (en) * | 2015-06-16 | 2018-11-20 | 公安部四川消防研究所 | It is a kind of for putting out the mud extinguishing chemical of stacking fire |
| CN104874145A (en) * | 2015-06-16 | 2015-09-02 | 公安部四川消防研究所 | Slurry fire extinguishing agent for extinguishing stacking fire |
| WO2017092658A1 (en) * | 2015-12-01 | 2017-06-08 | 西安威西特消防科技有限责任公司 | Fire-extinguishing composition |
| CN105288925A (en) * | 2015-12-01 | 2016-02-03 | 西安坚瑞安全应急设备有限责任公司 | Fire extinguishing composition |
| CN107019861A (en) * | 2016-01-29 | 2017-08-08 | 天津鹏安数讯消防设备工程有限公司 | Fire extinguishing sheet |
| CN106632468A (en) * | 2016-11-22 | 2017-05-10 | 同济大学 | A preparing method of an aminotris(methylenephosphonic acid) metal salt flame retardant |
| CN106632468B (en) * | 2016-11-22 | 2019-08-06 | 同济大学 | The preparation method of aminotrimethylenephosphonic acid metal salt fire retardant |
| CN107854800A (en) * | 2017-11-24 | 2018-03-30 | 西安威西特消防科技有限责任公司 | A kind of self-extinguishing composition |
| CN108252088A (en) * | 2017-12-12 | 2018-07-06 | 江苏新瑞贝科技股份有限公司 | A kind of textile flame-retardant finishing agent and preparation method thereof |
| WO2019144331A1 (en) * | 2018-01-24 | 2019-08-01 | 金发科技股份有限公司 | Aluminum amino trimethylene phosphonate, preparation method therefor and use thereof |
| CN110066293A (en) * | 2018-01-24 | 2019-07-30 | 金发科技股份有限公司 | A kind of aminotrimethylenephosphonic acid aluminium and its preparation method and application |
| CN108853861A (en) * | 2018-08-20 | 2018-11-23 | 常州扬鹏科技有限公司 | From temperature sensitive type fire-extinguishing composite and preparation method thereof |
| CN111408095A (en) * | 2020-03-27 | 2020-07-14 | 浙江蓝盾电工新材料科技有限公司 | Lithium battery foam extinguishing agent |
| CN112175294A (en) * | 2020-10-26 | 2021-01-05 | 江苏昊晟塑业科技有限公司 | Flame-retardant foamed polypropylene and preparation method thereof |
| CN113679996A (en) * | 2021-08-17 | 2021-11-23 | 湖南神州防务科技有限公司 | High-ammonium-polyphosphate-based forest dry powder extinguishing agent and preparation method thereof |
| CN115340711A (en) * | 2022-05-26 | 2022-11-15 | 浙江农林大学 | Efficient preparation and application of nitrogen-phosphorus grafted bamboo charcoal-based flame retardant |
| CN115197475A (en) * | 2022-07-18 | 2022-10-18 | 福州大学 | DOPO/ATMP modified chitosan loaded aluminum-based single-component intumescent flame retardant, and preparation method and application thereof |
| CN115197475B (en) * | 2022-07-18 | 2023-05-23 | 福州大学 | DOPO/ATMP modified chitosan-loaded aluminum-based single-component intumescent flame retardant as well as preparation method and application thereof |
| CN115850849A (en) * | 2023-02-17 | 2023-03-28 | 广东南洋电缆股份有限公司 | Freely-bendable wear-resistant weather-resistant halogen-free low-smoke cable material, preparation method thereof and application thereof in robot |
| CN115850849B (en) * | 2023-02-17 | 2023-04-18 | 广东南洋电缆股份有限公司 | Freely-bendable wear-resistant weather-resistant halogen-free low-smoke cable material, preparation method thereof and application thereof in robot |
| CN117046026A (en) * | 2023-06-27 | 2023-11-14 | 湖北及安盾消防科技有限公司 | Chemical coolant and application thereof in aerosol fire extinguishment |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013091385A1 (en) | 2013-06-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103170082A (en) | Fire-extinguishing composition containing amino acid compounds | |
| RU2554638C2 (en) | Composition forming fire-extinguishing agent due to chemical reaction of ingredients at high temperature | |
| CN102179026B (en) | Fire extinguishing composition generating extinguishant by pyrolysis | |
| CN102179027B (en) | Ferrocene extinguishing composition | |
| RU2580915C2 (en) | Flame retardant composition containing organic acid | |
| JP2013541362A5 (en) | ||
| JP2013541363A5 (en) | ||
| RU2610120C2 (en) | Flame-extinguishing composition based on copper salts |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130626 |