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CN102936119A - Interior wall decoration material composed of ecological inorganic minerals - Google Patents

Interior wall decoration material composed of ecological inorganic minerals Download PDF

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Publication number
CN102936119A
CN102936119A CN2012104439038A CN201210443903A CN102936119A CN 102936119 A CN102936119 A CN 102936119A CN 2012104439038 A CN2012104439038 A CN 2012104439038A CN 201210443903 A CN201210443903 A CN 201210443903A CN 102936119 A CN102936119 A CN 102936119A
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powder
internal wall
orders
inorganic mineral
decorative material
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CN102936119B (en
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陈胡星
邓妮
许远荣
诸晓峰
马先伟
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Zhejiang University ZJU
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Zhejiang University ZJU
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Abstract

The invention discloses an interior wall decoration material composed of ecological inorganic minerals. The material is composed of materials of, by weight, 15% to 30% of white cement, 5% to 20% of zeolite powder, 5% to 20% of roasted diatomite powder, 20% to 50% of quartz sand, 5% to 20% of ground calcium carbonate powder, 0.5% to 1% of nanometer titanium dioxide, 1% to 3% of dispersible emulsion powder, 0% to 3% of bentonite, 0% to 1.5% of pigments and 0% to 0.4% of cellulose ether. The material is almost composed of inorganic minerals, volatile organic compounds are not contained; and the material is ecological and environment friendly, has adsorption and self humidity adjusting effects and certain anti-microbial and air purifying effects simultaneously and is convenient for storage, transportation and usage.

Description

A kind of ecological inorganic mineral decorative material for internal wall
Technical field
The present invention relates to technical field of construction and decoration materials, be specifically related to a kind of ecological inorganic mineral decorative material for internal wall.
Background technology
Along with growth in the living standard, people are more and more higher to the requirement of the decoration of inner wall of building, not only require attractive in appearancely, more require amenity, safety, environmental protection.At present, decorative material for internal wall mostly is organic chemical industry's coating, usually contains the organism such as formaldehyde, benzene, and HUMAN HEALTH is produced to harm.In order to overcome the deficiency of traditional coating, people attach great importance to the exploitation of ecological environment-friendly type decorative material for internal wall, and obtain certain progress.
People add the material with decomposing organic matter effect on traditional coating base, or utilize inorganic materials to add organic binding agent to prepare finishing material, to reach the effect purified air.A kind of composite photocatalysis coating is disclosed in the Chinese patent application that publication number is CN102206450A, contain the components such as matrix material, nano titanium oxide, nanometer diatom ooze, bamboo carbon extracting solution, membrane-forming agent, can be initiatively, fast, lastingly, purify air in all directions, effectively suppress the harmful microbe breeding; But such coating not only cost is high, and its matrix material is various emulsions, store and transportation etc. all inconvenient.The Chinese patent application that publication number is CN101700965A discloses a kind of environment-friendly diatom ooze wall material powder, wall material and preparation method, according to weight percent, by following component proportion, is formed: diatomite in powder (calcining one-level) 30%~60%, kaolin powder (calcining one-level) 8%~9%, sepiolite powder (calcining one-level) 7%~8%, bentonite in powder (calcining one-level) 5%~8%, marble English rock dust (special one-level) 10%~30%, Attapulgite stone flour (dry superfine) 6%~10%, vermiculite power (calcining one-level) 3%~4%, tackifier 0.6%~0.7%, staple cellulose 0.3%~0.4%; It is prepared from raw materials such as the ceramic such as diatomite in powder, kaolin powder, cloud silica powder and tackifier, have cheap, purify air, the function such as moisture absorbing and deodorizing; But the raw materials cost of such material is higher, restricted its widespread use, pending improvement is arranged.
For fear of organic volatilization in chemistry painting industry, people also attempt directly usining sand-cement slurry as decorative material for internal wall.For example, the Chinese patent application that publication number is CN101948278A discloses a kind of color mortar coating, the raw material of following weight part ratio, consists of: cement 21-24, grey calcium 5-10, quartz sand 52-58, water-ground limestone 12-18, silicon powder 5-10, redispersable latex powder 2-4, hydrophober 0.25-0.35, thixotroping lubricant 0.35-0.45, hydroxypropylcelluloether ether 0.25-0.3 and ferric oxide mineral dye 1-5; Materials is comprised of cement, grey calcium, quartz sand, coarse whiting, silicon powder, latex powder, ether of cellulose and iron oxide pigment etc., have that cheap, pollution-free, good weatherability, fast colours are lasting, good ultraviolet resistance, with bottom, be combined well, the advantage such as not easy to crack, hydrophobic nature is good, studied and improved but also need select from material, form the many-side such as design from attractive in appearance, comfortable equal angles consideration.
Summary of the invention
The invention provides a kind of ecological inorganic mineral decorative material for internal wall, take zeolite powder, diatomite in powder, bentonite in powder is basis, using white cement as matrix material, be aided with the additives such as a small amount of titanium dioxide, pigment, ether of cellulose or auxiliary agent is prepared from simultaneously, have the function of coating and mortar concurrently, and have and purify air and the effect such as automatic humidity-regulating, be a kind of environmental decorative material for internal wall.
For realizing above target, the present invention adopts following technical solution:
A kind of ecological inorganic mineral decorative material for internal wall is comprised of the raw material of following weight percent:
Figure BDA00002370390600021
The weight percent sum of above-mentioned raw materials is 100%.
The main component of the white cement described in ecological inorganic mineral decorative material for internal wall of the present invention is tricalcium silicate (C 3S), Dicalcium Phosphate (Feed Grade) (C 2S) and tricalcium aluminate (C 3A), a main cohesive action after aquation.Described white cement should meet the requirement of GB/T 2015-2005 white portland cement national standard.
Zeolite powder described in ecological inorganic mineral decorative material for internal wall of the present invention is natural levigate the forming of Zeolite Rock.Described calcined diatomite powder is that natural diatomaceous earth is through high temperature (550 ℃-850 ℃) calcining and levigate forming.Zeolite powder and this bi-material of calcined diatomite powder are vesicular structure, and specific surface area is large, has the moisture adsorption and releasing effect, and its fineness requirement all is preferably 200 orders-400 order, and the moisture adsorption and releasing effect is more remarkable; Existing silicon powder does not have vesicular structure, and the moisture adsorption and releasing effect is not obvious.
Quartz sand described in ecological inorganic mineral decorative material for internal wall of the present invention plays the fine aggregate effect, and fineness requirement is preferably 40 orders-120 order.
Dicalcium powder described in ecological inorganic mineral decorative material for internal wall of the present invention is as filler, and fineness requirement is preferably 200 orders-400 order.
Nano titanium oxide described in ecological inorganic mineral decorative material for internal wall of the present invention plays antibiotic and air purification effect.
Polymer dispersion powder described in ecological inorganic mineral decorative material for internal wall of the present invention mainly plays auxiliary cohesive action.
Ether of cellulose described in ecological inorganic mineral decorative material for internal wall of the present invention mainly plays water retention; after making it to add water, moisture is difficult for losing; and progressively discharge within long period of time; it forms protective colloid after also dissolving in water simultaneously; " parcel " lives solid particulate; form one deck lubricant film at the solid particulate outside surface, improve in the mobility of whipping process and the slipping of construction.Consider the combined influence of ether of cellulose dispersiveness, water-retentivity and application property, in selecting, low viscous Vltra tears (HPMC) is advisable.Therefore, described ecological inorganic mineral decorative material for internal wall, preferably the raw material by following weight percent forms:
Figure BDA00002370390600031
Wilkinite main component described in ecological inorganic mineral decorative material for internal wall of the present invention is polynite, has the performance of adsorptivity and thixotroping, also has thickening power, and fineness requirement is preferably 200 orders-400 order.
Pigment described in ecological inorganic mineral decorative material for internal wall of the present invention is used to ecological inorganic mineral decorative material for internal wall color is provided, can select as required the pigment of respective color, as wanted, keep the reality color of ecological inorganic mineral decorative material for internal wall without adding pigment.
Further preferably, described ecological inorganic mineral decorative material for internal wall is comprised of the raw material of following weight percent:
Figure BDA00002370390600042
Described raw material all can adopt commercially available prod.
The preparation method of described ecological inorganic mineral decorative material for internal wall is very simple, only each raw material fully need to be mixed and can obtain ecological inorganic mineral decorative material for internal wall.
Described ecological inorganic mineral decorative material for internal wall is used also very convenient, in use, in described ecological inorganic mineral decorative material for internal wall, adds appropriate water, stirs, by whitewashing or the prior art such as spraying is applied to wall.
Compared with prior art, the present invention has following advantage:
Ecological inorganic mineral decorative material for internal wall of the present invention, it is all almost inorganic mineral material, a small amount of additive used is not also fully containing volatility and toxic substances such as formaldehyde, benzene, simultaneously, the materials such as diatomite used, zeolite also have absorption and automatic humidity-regulating effect, simultaneously nano titanium oxide also has certain antibiotic and air purification effect, thereby is a kind of multi-functional environmental finishing material, has the characteristics such as attractive in appearance, comfortable, safety and environmental protection concurrently.
Each component of ecological inorganic mineral decorative material for internal wall of the present invention is commercial goods, manufacture craft is simple, product is single dry powder material, add water and stir and can be used for whitewashing or spraying, store, transportation and use all very conveniently, can be used as the inner wall of building finishing material.
Embodiment
Below in conjunction with following embodiment, the present invention is made to further detailed description.
Described per-cent all is weight percentage.
Described white cement, quartz sand, calcined diatomite powder, zeolite powder, dicalcium powder, bentonite in powder, nano titanium oxide, pigment, polymer dispersion powder etc. are commercially available prod, and wherein the white cement main component is C 3S, C 2S and C 3A, meet the requirement of GB/T 2015-2005 white portland cement national standard, and strength grade is 42.5.The calcined diatomite powder is natural diatomaceous earth levigate powder formed after 700 ℃ ± 50 ℃ are calcined 2 hours, and fineness is 200 orders-400 orders.
Embodiment 1:
Press white cement 15%, 200 orders-400 purpose zeolite powder 5%, calcined diatomite powder 15%, 40 orders-120 purpose quartz sand 50%, 200 orders-400 purpose dicalcium powder 6.5%, 200 orders-400 purpose bentonite in powder 3%, nano titanium oxide 1%, iron oxide red pigment 1.5% and Wa Ke polymer dispersion powder (5044, Germany's watt gram) 3% take raw material, fully mix, obtain ecological inorganic mineral decorative material for internal wall.
Add suitable quantity of water (ecological inorganic mineral decorative material for internal wall dry powder: water=1:0.33 in above-mentioned ecological inorganic mineral decorative material for internal wall, weight ratio), stir by whitewashing or be sprayed at wall, obtain having the decorated wall surface of texture, can be used for the decoration of interior wall.
Embodiment 2:
Press white cement 20%, 200 orders-400 purpose zeolite powder 10%, calcined diatomite powder 10%, 40 orders-120 purpose quartz sand 40%, 200 orders-400 purpose dicalcium powder 12.4%, 200 orders-400 purpose bentonite in powder 3%, nano titanium oxide 1%, iron oxide yellow pigments 1%, HPMC 0.1% and Wa Ke polymer dispersion powder (5044, Germany's watt gram) 2.5% take raw material, fully mix, obtain ecological inorganic mineral decorative material for internal wall.
Add suitable quantity of water (ecological inorganic mineral decorative material for internal wall dry powder: water=1:0.35 in above-mentioned ecological inorganic mineral decorative material for internal wall, weight ratio), stir by whitewashing or be sprayed at wall, obtain having the decorated wall surface of texture, can be used for the decoration of interior wall.
Embodiment 3:
Press white cement 25%, 200 orders-400 purpose zeolite powder 15%, calcined diatomite powder 5%, 40 orders-120 purpose quartz sand 40%, 200 orders-400 purpose dicalcium powder 9.9%, 200 orders-400 purpose bentonite in powder 2%, nano titanium oxide 0.5%, green composite pigment 0.5%, HPMC 0.1% and Wa Ke polymer dispersion powder (5044, Germany's watt gram) 2% take raw material, fully mix, obtain ecological inorganic mineral decorative material for internal wall.
Add suitable quantity of water (ecological inorganic mineral decorative material for internal wall dry powder: water=1:0.37 in above-mentioned ecological inorganic mineral decorative material for internal wall, weight ratio), stir by whitewashing or be sprayed at wall, obtain having the decorated wall surface of texture, can be used for the decoration of interior wall.
Embodiment 4:
Press white cement 30%, 200 orders-400 purpose zeolite powder 15%, calcined diatomite powder 5%, 40 orders-120 purpose quartz sand 40%, 200 orders-400 purpose dicalcium powder 5.9%, 200 orders-400 purpose bentonite in powder 1.9%, nano titanium oxide 0.5%, cologne earth pigment 0.5%, HPMC 0.2% and Wa Ke polymer dispersion powder (5044, Germany's watt gram) 1% take raw material, fully mix, obtain ecological inorganic mineral decorative material for internal wall.
Add suitable quantity of water (ecological inorganic mineral decorative material for internal wall dry powder: water=1:0.38 in above-mentioned ecological inorganic mineral decorative material for internal wall, weight ratio), stir by whitewashing or be sprayed at wall, obtain having the decorated wall surface of texture, can be used for the decoration of interior wall.
Embodiment 5:
The calcined diatomite powder is natural diatomaceous earth levigate powder formed after 500 ℃ are calcined 2 hours, and fineness is 200 orders-400 orders.
Press white cement 20%, 200 orders-400 purpose zeolite powder 10.6%, calcined diatomite powder 15%, 40 orders-120 purpose quartz sand 30%, 200 orders-400 purpose dicalcium powder 20%, nano titanium oxide 1%, compound blue pigment 1%, HPMC 0.4% and Wa Ke polymer dispersion powder (5044, Germany's watt gram) 2% take raw material, fully mix, obtain ecological inorganic mineral decorative material for internal wall.
Add suitable quantity of water (ecological inorganic mineral decorative material for internal wall dry powder: water=1:0.4 in above-mentioned ecological inorganic mineral decorative material for internal wall, weight ratio), stir by whitewashing or be sprayed at wall, obtain having the decorated wall surface of texture, can be used for the decoration of interior wall.

Claims (9)

1. an ecological inorganic mineral decorative material for internal wall, is characterized in that, the raw material of following weight percent, consists of:
2. ecological inorganic mineral decorative material for internal wall according to claim 1, is characterized in that, the raw material of following weight percent, consists of:
3. ecological inorganic mineral decorative material for internal wall according to claim 1 and 2, is characterized in that, described calcined diatomite powder is that natural diatomaceous earth is through 550 ℃ of-850 ℃ of high-temperature calcinations and levigate forming.
4. ecological inorganic mineral decorative material for internal wall according to claim 1 and 2, is characterized in that, the fineness of described calcined diatomite powder is 200 orders-400 orders.
5. ecological inorganic mineral decorative material for internal wall according to claim 1 and 2, is characterized in that, the fineness of described zeolite powder is 200 orders-400 orders.
6. ecological inorganic mineral decorative material for internal wall according to claim 1 and 2, is characterized in that, described quartz sand fineness is 40 orders-120 orders.
7. ecological inorganic mineral decorative material for internal wall according to claim 1 and 2, is characterized in that, described dicalcium powder fineness is 200 orders-400 orders.
8. ecological inorganic mineral decorative material for internal wall according to claim 1 and 2, is characterized in that, described wilkinite fineness is 200 orders-400 orders.
9. ecological inorganic mineral decorative material for internal wall according to claim 1 and 2, is characterized in that, described ether of cellulose is Vltra tears.
CN201210443903.8A 2012-11-07 2012-11-07 Interior wall decoration material composed of ecological inorganic minerals Expired - Fee Related CN102936119B (en)

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CN104276787A (en) * 2013-07-04 2015-01-14 蒋闯隆 Preparation method of novel diatom ooze coating
CN103601442B (en) * 2013-10-31 2015-07-15 德高(广州)建材有限公司 Waterproof slurry with sterilization function for toilet bath room decoration surfaces
WO2015062332A1 (en) * 2013-10-31 2015-05-07 德高(广州)建材有限公司 Waterproof slurry having sterilization function
CN103601442A (en) * 2013-10-31 2014-02-26 德高(广州)建材有限公司 Waterproof slurry with sterilization function for toilet bath room decoration surfaces
CN103739267A (en) * 2014-01-10 2014-04-23 吉林省原叶环保材料有限公司 Diatom ooze coating material capable of effectively purifying indoor air
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