CN102533143A - Solar cell packaging glue film - Google Patents
Solar cell packaging glue film Download PDFInfo
- Publication number
- CN102533143A CN102533143A CN2012100405916A CN201210040591A CN102533143A CN 102533143 A CN102533143 A CN 102533143A CN 2012100405916 A CN2012100405916 A CN 2012100405916A CN 201210040591 A CN201210040591 A CN 201210040591A CN 102533143 A CN102533143 A CN 102533143A
- Authority
- CN
- China
- Prior art keywords
- solar cell
- glue film
- packaging glue
- cell packaging
- eva
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a solar cell packaging glue film. The solar cell packaging glue film is characterized by being obtained by mixing 89-96 % of EVA (MA-10), 0.5-5 % of peroxide-2-ethylhexyl butyl carbonate, 0.5-4% of 1,3,5-triallyl-s-triazine-2,4,6-triketone, 0.1-3 % of methyl acrylacyloxypropyl trimethoxysilane functional group silane, 0.05-0.1 % of 3,9-didecyl alkoxy-2,4,8,10-tetraoxa-3,9-diphospha azaspiro [5,5]hendecane, 0.2-1 % of 2-hydroxyl-4-octaoxy benzophenone and 0.2-1 % of di(2,2,6,6-tetramethyl-4-piperidyl)sebacate. The solar cell packaging glue film disclosed by the invention has the advantages of low temperature resistance, uneasiness for aging and changing color, very strong stability and easiness for storage; and the service life of a solar cell module can be prolonged while the solar cell packaging glue film disclosed by the invention is used for packaging solar cells.
Description
Technical field
The present invention relates to be used to encapsulate the glued membrane of photovoltaic apparatus, particularly a kind of packaging adhesive film for solar cell.
Background technology
Solar cell is if directly be exposed in the air, and its photoelectric transformation efficiency can descend very soon, loses practical value.So the research and development of the packaged material of solar cell are just very important.For reaching the purpose of separating atmospheric; Adopt transparent, light aging resisting, adhesiveproperties good, can bear that atmosphere changes and rubber-like ethene one vinyl acetate copolymer (EVA) glued membrane is sealed solar battery sheet; And be bonded together with the levels protecting materials, constitute solar module.
But there is flavescence easily after solar radiation in the existing EVA glued membrane that is used for solar cell, influences the transmittance of battery component, and in addition, the weathering resistance and the photo and thermal stability of EVA glued membrane are lower, badly influence the work-ing life of solar module.
Summary of the invention
In order to overcome the above-mentioned weak point that exists in the prior art, the object of the present invention is to provide a kind of low temperature resistant, anti-weather aging, stable high packaging adhesive film for solar cell.
In order to reach above-mentioned purpose, the present invention adopts following concrete technical scheme: a kind of packaging adhesive film for solar cell is characterized in that: contain EVA (MA-10), the peroxo--2-ethylhexyl carbonic acid tert-butyl ester, 1,3; 5-triallyl-guanamine, 4,6-triketone, methacryloxy functional groups silane, 3; 9-didecyl alkoxyl group-2,4,8; 10-four oxa-s-3,9-two phospha spiral shell [5.5] undecanes, 2-hydroxyl-4-octyloxy UVNUL MS-40 and two (2,2; 6,6-tetramethyl--4-piperidyl) sebate, it is following that each organizes the quality ratio range:
EVA?(MA-10) 89%～96%
Peroxo--2-ethylhexyl carbonic acid the tert-butyl ester 0.5%～5%
1,3,5-triallyl-guanamine, 4,6-triketone 0.5%～4%
Methacryloxy functional groups silane 0.1%～3%
3,9-didecyl alkoxyl group-2,4,8,10-four oxa-s-3,9-two phospha spiral shell [5.5] undecanes 0.05%～1%
2-hydroxyl-4-octyloxy UVNUL MS-40 0.2%～1%
Two (2,2,6,6-tetramethyl--4-piperidyl) sebate 0.2%～1%
Compared with prior art; The present invention has following outstanding advantage and effect: low temperature resistant, difficult aging, the variable color of the present invention; Have very strong stability, store easily, the present invention is used to encapsulate the work-ing life that solar cell can improve solar module.
Embodiment
Mode through embodiment further specifies the present invention below, therefore the present invention is not limit
Among described scope of embodiments.
Embodiment 1
Get mass percent 89% EVA (MA-10), the 4% peroxo--2-ethylhexyl carbonic acid tert-butyl ester, 3%1,3,5-triallyl-guanamine, 4; 6-triketone, 2% methacryloxy functional groups silane, 0.3%3,9-didecyl alkoxyl group-2,4; 8,10-four oxa-s-3,9-two phospha spiral shell [5.5] undecanes, 0.7%2-hydroxyl-4-octyloxy UVNUL MS-40,1% pair (2; 2,6,6-tetramethyl--4-piperidyl) a kind of packaging adhesive film for solar cell of being mixed with after mixing of sebate.
Embodiment 2
Get mass percent 96% EVA (MA-10), the 1% peroxo--2-ethylhexyl carbonic acid tert-butyl ester, 1%1,3,5-triallyl-guanamine, 4; 6-triketone, 1% methacryloxy functional groups silane, 0.2%3,9-didecyl alkoxyl group-2,4; 8,10-four oxa-s-3,9-two phospha spiral shell [5.5] undecanes, 0.5%2-hydroxyl-4-octyloxy UVNUL MS-40,0.3% pair (2; 2,6,6～tetramethyl--4-piperidyl) a kind of packaging adhesive film for solar cell of being mixed with after mixing of sebate.
Claims (1)
1. a packaging adhesive film for solar cell is characterized in that: contain EVA (MA-10), the peroxo--2-ethylhexyl carbonic acid tert-butyl ester, 1,3,5-triallyl-guanamine; 4,6-triketone, methacryloxy functional groups silane, 3,9-didecyl alkoxyl group-2,4; 8,10-four oxa-s-3,9-two phospha spiral shell [5.5] undecanes, 2-hydroxyl-4-octyloxy UVNUL MS-40 and two (2,2; 6,6-tetramethyl--4-piperidyl) sebate, it is following that each organizes the quality ratio range:
EVA?(MA-10) 89%～96%
Peroxo--2-ethylhexyl carbonic acid the tert-butyl ester 0.5%～5%
1,3,5-triallyl-guanamine, 4,6-triketone 0.5%～4%
Methacryloxy functional groups silane 0.1%～3%
3,9-didecyl alkoxyl group-2,4,8,10-four oxa-s-3,9-two phospha spiral shell [5.5] undecanes 0.05%～1%
2-hydroxyl-4-octyloxy UVNUL MS-40 0.2%～1%
Two (2,2,6,6-tetramethyl--4-piperidyl) sebate 0.2%～1%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012100405916A CN102533143A (en) | 2012-02-22 | 2012-02-22 | Solar cell packaging glue film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012100405916A CN102533143A (en) | 2012-02-22 | 2012-02-22 | Solar cell packaging glue film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102533143A true CN102533143A (en) | 2012-07-04 |
Family
ID=46341221
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012100405916A Pending CN102533143A (en) | 2012-02-22 | 2012-02-22 | Solar cell packaging glue film |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102533143A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103012483A (en) * | 2012-12-04 | 2013-04-03 | 浙江海普顿新材料股份有限公司 | Phenol-free phosphite ester, as well as preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1699458A (en) * | 2005-05-27 | 2005-11-23 | 华南理工大学 | Aging-resistant EVA film adhesive for solar cell package and method for preparing same |
| CN101626039A (en) * | 2009-07-27 | 2010-01-13 | 江阴爱康太阳能器材有限公司 | Solar cell packaging EVA adhesive film capable of resisting heat, humidity, ultraviolet light and aging |
| CN102153958A (en) * | 2011-01-11 | 2011-08-17 | 广州市宝力达电气材料有限公司 | EVA (ethylene-vinyl acetate) adhesive film for heat-resistant solar battery, and preparation method and application thereof |
-
2012
- 2012-02-22 CN CN2012100405916A patent/CN102533143A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1699458A (en) * | 2005-05-27 | 2005-11-23 | 华南理工大学 | Aging-resistant EVA film adhesive for solar cell package and method for preparing same |
| CN101626039A (en) * | 2009-07-27 | 2010-01-13 | 江阴爱康太阳能器材有限公司 | Solar cell packaging EVA adhesive film capable of resisting heat, humidity, ultraviolet light and aging |
| CN102153958A (en) * | 2011-01-11 | 2011-08-17 | 广州市宝力达电气材料有限公司 | EVA (ethylene-vinyl acetate) adhesive film for heat-resistant solar battery, and preparation method and application thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103012483A (en) * | 2012-12-04 | 2013-04-03 | 浙江海普顿新材料股份有限公司 | Phenol-free phosphite ester, as well as preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102185029B (en) | Method for encapsulating crystalline silicon solar cell component | |
| CN104479574A (en) | Anti-reflective polyolefin photovoltaic module encapsulation adhesive film and manufacturing method thereof | |
| CN102153958A (en) | EVA (ethylene-vinyl acetate) adhesive film for heat-resistant solar battery, and preparation method and application thereof | |
| CN104109280B (en) | Solar module encapsulant compositions and the solar module using said composition | |
| CN108003801A (en) | A kind of light conversion POE glued membranes and its photovoltaic module of encapsulation | |
| CN106811150A (en) | A kind of photovoltaic component encapsulating glued membrane of high reflection polymer microballoon filling and preparation method thereof | |
| CN103937418A (en) | High-reflectivity white EVA (ethylene-vinyl acetate) adhesive film and preparation technique thereof | |
| JP2012142346A5 (en) | Solar cell module | |
| CN104804658A (en) | Black EVA (ethylene vinyl acetate copolymer) adhesive film and double-glazed photovoltaic module | |
| CN102044583A (en) | Solar battery assembly and laminating method thereof | |
| CN102533143A (en) | Solar cell packaging glue film | |
| CN201975406U (en) | Crystalline silicon solar cell component | |
| CN204303839U (en) | Solar cell backboard | |
| CN103739926A (en) | Fluorescent EVA (ethylene-vinyl acetate) glue film | |
| CN102898971B (en) | A kind of rare-earth light conversion agent and its preparation method and application | |
| CN102504711B (en) | Ethylene-vinyl acetate copolymer adhesive film for packaging solar batteries and preparation method thereof | |
| CN103725211B (en) | EVA film encapsulated in solar battery and preparation method of EVA film | |
| CN103725209B (en) | EVA film and preparation method thereof | |
| JP2011077236A (en) | Solar cell sealing material, and solar cell sealing sheet and solar cell using the same | |
| CN103642411B (en) | EVA (ethylene-vinyl acetate) adhesive film for solar cell packaging and preparation method thereof | |
| CN103904149B (en) | The encapsulating structure and method of a kind of crystal silicon solar batteries | |
| CN103724780B (en) | Eva film of a kind of solar cell package and preparation method thereof | |
| CN103642412B (en) | EVA (ethylene-vinyl acetate) adhesive film for solar cell packaging and preparation method thereof | |
| CN103724779B (en) | For the eva film and preparation method thereof of solar cell package | |
| CN103642117B (en) | EVA adhesive film of solar cell package and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20120704 |