CN101991522B - Tick repellent toilet water and preparation method thereof - Google Patents
Tick repellent toilet water and preparation method thereof Download PDFInfo
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- CN101991522B CN101991522B CN2010105328527A CN201010532852A CN101991522B CN 101991522 B CN101991522 B CN 101991522B CN 2010105328527 A CN2010105328527 A CN 2010105328527A CN 201010532852 A CN201010532852 A CN 201010532852A CN 101991522 B CN101991522 B CN 101991522B
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Abstract
The invention discloses tick repellent toilet water and a preparation method thereof. The tick repellent toilet water is prepared from the following raw materials in percentage by weight: 0.1-7% of deet, 0.1-0.5% of rotenone, 0.1-1% of volatile oil of whiteflower hogfennel roots, 0.1-1% of essence, 1-3% of PEG40 hydrogenated castor oil, 48-60% of ethanol and 30-50% of water. The tick repellent toilet water provided by the invention has the following advantages that: the main active ingredients of the preparation, namely deet, rotenone and volatile oil of whiteflower hogfennel roots, exert synergistic effect through compounding, and the repelling activity of the compounded repellent toilet water is obviously higher than that of repellent toilet water with single active ingredient; the tick repellent toilet water not only has obvious repelling effect on ticks, but also has good repelling effect on mosquitoes; the preparation is safe to human and pets; the production cost is low, and the preparation process is simpler; and the preparation is especially applicable to travelers, field workers or marching armies.
Description
Technical field
Be specifically related to a kind of Ticks worm repellant floral water and preparation method thereof, belong to household chemicals and health medicament field.
Background technology
Along with the change of global temperature rising and natural environment, the distribution of hematophagus enlarges, density raises, and is increasing to the harm that the field man causes.Using efficient repellant to protect, is to reduce hematophagus to cause mechanical damage and the effective means that reduces the insect-borne diseases sickness rate to the people.More the whole nation was economized the deadly incident of Ticks insect stings was taken place this year, caused people's fear.
Ticks belongs to Parasitiformes, Ixodides, and Ixodoidea comprises hard Ticks section, soft ticks section and receives Ticks section, kind surplus the world known 850.Kind surplus the kind of the known Ticks of China has 110 at present comprises soft ticks and two types of hard Tickss, and wherein majority can be invaded human body.Common important harm kind has 14 kinds: (1) ixodes persulcatus.Mainly being distributed in northeast, Xinjiang and Tibet in China, is the pathogen preserver and main communication media of forest encephalitis, also is the communication media of Lyme disease.(2) Ixodes crenulatus.Mainly being distributed in northeast, the Inner Mongol, northwest and Tibet in China, is one of preserver of bacillus pestis.(3) Haemaphysalis japonica.Mainly being distributed in northeast, Shanxi, Gansu and Qinghai in China, is the communication media of forest encephalitis and Lyme disease.(4) Qinghai blood Ticks.Mainly being distributed in Ningxia, Gansu, Qinghai, Sichuan and Yunnan in China, is the communication media of sheep and goat Tai Shi babesiasis.(5) haemaphysalis conicinna.Mainly be distributed in northeast, Xinjiang in China, the Inner Mongol accounts for and Shanxi, is the communication media of forest encephalitis, Q heat, north Asia spotted fever, Xinjiang hemorrhagic fever.(6) dermacentor silvarum.Mainly being distributed in northeast, Shandong, Xinjiang, Hebei, the Inner Mongol and Shanxi in China, is that forest encephalitis, Q heat, north Asia spotted fever and soil draw the sick communication media of logical sequence bacterium.(7) grassland leather Ticks.Mainly being distributed in northeast, North China, northwest and Yunnan in China, is the communication media of north Asia spotted fever and brucellosis.(8) China's leather Ticks.Mainly being distributed in northeast, North China, Shandong and Xinjiang in China, is the communication media of sheep and cattle brucellosis.(9) Hyalomma asiaticum.Mainly being distributed in the Inner Mongol and northwest in China, is the communication media of Xinjiang hemorrhagic fever.(10) Hyalomma dctritum.Mainly being distributed in northeast, North China, Xinjiang, Shandong, Guizhou and Jiangsu in China, is the communication media of the annular Tai Shi babesiasis of cattle, also can carry the pathogen of Q heat and north Asia spotted fever.(11) boophilus microplus.Except that the some areas in northwest and northeast, all there is distribution other various places in China, are the communication medias of redwater fever.(12) brown dog tick.In the most of provinces and regions of China distribution being arranged all, is the communication media of north Asia spotted fever and Q heat.(13) adobe tick.Mainly being distributed in North China and northwest in China, is the communication media of Q heat.(14) ornithodoros lahorensis.Mainly being distributed in Gansu, Xinjiang and Tibet in China, is the communication media of Q heat.
Summary of the invention
The purpose of this invention is to provide Ticks worm repellant floral water that a kind of, preparation technology good to Ticks worm repellent effect is simple, production cost is relatively low and preparation method thereof.
For reaching above purpose, the technical scheme that the present invention adopts is:
A kind of Ticks worm repellant floral water; By weight percentage, its composition of raw materials consists of: diethyltoluamide 0.1-7%, rotenone 0.1-0.5%, Radix Peucedani volatile oil 0.1-1%, essence 0.1-1%, PEG40 castor oil hydrogenated 1-3%, ethanol 48-60% and water 30-50%.
Said essence is a kind of in Fructus Citri Limoniae essence and the Herba Menthae essence.
The method for preparing of Ticks worm repellant floral water: water, ethanol, diethyltoluamide, rotenone, PEG40 castor oil hydrogenated and Radix Peucedani volatile oil are added agitated reactor by proportioning raw materials; Stirred 2-3 hour, and added essence again, stirred 1-2 hour; Left standstill the Ticks worm repellant floral water that makes 4-6 hour.
Diethyltoluamide, chemical name are N, and N-diethyl-3-methylbenzene amide has the wide spectrum repellent action, and most hematophagus is had effect preferably.At present, from result of use, stability, economical etc. take all factors into consideration, diethyltoluamide is still human body and uses topmost insect repellent in worldwide.
Rotenone (rotenone) belongs to flavone compound, and its chemical name is [2R-(2 α, 6a α; 12a α)] 12a-tetrahydrochysene-8-1,2.12; 9-dimethoxy-2-(1-methoxy vinyl)-[I]-.alpha.-5:6-benzopyran [3,4-b]-furo-[2,3-h] [1]-.alpha.-5:6-benzopyrans-6 (6aH)-ketone.Present known rotenone has higher biological activity to 800 various pests of 137 sections of 15 orders, and is especially remarkably productive to the aphid mite pest, and to people's safety, easy photodissociation becomes the chemical compound of nontoxic or low toxicity, residence time weak point in environment, environmentally safe.Higgs human rotenone solution such as (1994) after nine months, on one's body can not find louse (Bovicola ovis) sheep to the sheep bathing.
Radix Peucedani volatile oil contains 50 number of chemical materials, and main component is australene, nopinene and caryophyllene.Concrete composition can be with reference to " GC/FTIR of Radix Peucedani chemical composition of volatile oil analyzes " (Liu Buming, Zhang Huiling, imperial firm, " Guangxi chemical industry " the 1st phase of nineteen ninety-five).It is used for development as Ticks worm repellant (medical faunae control, 2002,18 (5): 234-235), grassland leather Ticks, Haemaphysalis japonica, Qinghai blood Ticks and brown dog tick are had biological activity preferably existing bibliographical information.
Essence, PEG40 castor oil hydrogenated, ethanol 4 and water % are conventional batchings, have no side effect.
Through detecting, the Ticks worm repellant floral water of the present invention's configuration has no side effect to the person poultry safety.
The active component of Ticks worm repellant floral water provided by the invention includes diethyltoluamide, rotenone and Radix Peucedani volatile oil; Said composition has than remarkable role in synergy the repellent activity of Ticks worm; Repellant floral water after composite is to the repellent activity of the Ticks worm repellant floral water apparently higher than the single-activity composition, and this Ticks worm repellant floral water is not seen has the pertinent literature report.
Compare with existing repellant floral water, Ticks worm repellant floral water provided by the invention has the following advantages:
(1) the main active diethyltoluamide of preparation, rotenone and Radix Peucedani volatile oil are brought into play synergistic function after composite; Repellant floral water after composite is to the repellent activity of the Ticks worm repellant floral water apparently higher than the single-activity composition; Not only the Ticks worm there is significant repellent effect, and mosquito is also had good repellent effect;
(2) preparation is to people, pet safe;
(3) production cost is cheaper, and preparation technology is simpler, is suitable for large-scale industrial production;
(4) this preparation is suitable for travelling outdoors especially, field man or march army use.
The specific embodiment
For a better understanding of the present invention, the present invention is described further, but the scope that the present invention requires to protect is not limited to the represented scope of embodiment below in conjunction with embodiment.
Embodiment 1: take by weighing diethyltoluamide 0.10kg, rotenone 0.50kg, Radix Peucedani volatile oil 0.40kg; PEG40 castor oil hydrogenated 1.00kg, ethanol 50.00kg and water 47.70kg stirred 2 hours in agitated reactor; Add Fructus Citri Limoniae essence 0.30kg again; Stirred 1 hour, left standstill 4.5 hours, the Ticks worm repellant floral water that makes gets final product through the vacuum filling machine fill.
Embodiment 2: take by weighing diethyltoluamide 5.00kg, rotenone 0.10kg, Radix Peucedani volatile oil 0.20kg, PEG40 castor oil hydrogenated 1.50kg, ethanol 60.00kg and water 32.50kg.In agitated reactor, stirred 2.5 hours, add Herba Menthae essence 0.70kg again, stirred 1.5 hours, left standstill 4 hours, the Ticks worm repellant floral water that makes gets final product through the vacuum filling machine fill.
Embodiment 3: take by weighing diethyltoluamide 3.00kg, rotenone 0.20kg, Radix Peucedani volatile oil 0.50kg; PEG40 castor oil hydrogenated 1.90kg, ethanol 52.00kg and water 42.00kg stirred 2 hours in agitated reactor; Add Fructus Citri Limoniae essence 0.40kg again; Stirred 1.5 hours, left standstill 6 hours, the Ticks worm repellant floral water that makes gets final product through the vacuum filling machine fill.
Embodiment 4: take by weighing diethyltoluamide 4.00kg, rotenone 0.15kg, Radix Peucedani volatile oil 0.35kg; PEG40 castor oil hydrogenated 2.00kg, ethanol 58.00kg and water 35.00kg stirred 3 hours in agitated reactor; Add Herba Menthae essence 0.50kg again; Stirred 2 hours, left standstill 4 hours, the Ticks worm repellant floral water that makes gets final product through the vacuum filling machine fill.
Embodiment 5: take by weighing diethyltoluamide 1.80kg, rotenone 0.30kg, Radix Peucedani volatile oil 0.10kg; PEG40 castor oil hydrogenated 2.20kg, ethanol 55.00kg and water 40.00kg stirred 2 hours in agitated reactor; Add Fructus Citri Limoniae essence 0.60kg again; Stirred 1 hour, left standstill 5 hours, the Ticks worm repellant floral water that makes gets final product through the vacuum filling machine fill.
Embodiment 6: take by weighing diethyltoluamide 7.00kg, rotenone 0.25kg, Radix Peucedani volatile oil 0.75kg; PEG40 castor oil hydrogenated 3.00kg, ethanol 56.00kg and water 32.00kg stirred 3 hours in agitated reactor; Add Herba Menthae essence 1.00kg again; Stirred 1.5 hours, left standstill 5.5 hours, the Ticks worm repellant floral water that makes gets final product through the vacuum filling machine fill.
Embodiment 7: take by weighing diethyltoluamide 2.00kg, rotenone 0.45kg, Radix Peucedani volatile oil 1.00kg; PEG40 castor oil hydrogenated 2.10kg, ethanol 51.00kg and water 43.00kg stirred 3 hours in agitated reactor; Again to adding Fructus Citri Limoniae essence 0.45kg; Stirred 1.5 hours, left standstill 5 hours, the Ticks worm repellant floral water that makes gets final product through the vacuum filling machine fill.
Embodiment 8: take by weighing diethyltoluamide 0.80kg, rotenone 0.35kg, Radix Peucedani volatile oil 0.65kg; PEG40 castor oil hydrogenated 2.80kg, ethanol 57.00kg and water 38.20kg stirred 2 hours in agitated reactor; Add Herba Menthae essence 0.20kg again; Stirred 1 hour, left standstill 6 hours, the Ticks worm repellant floral water that makes gets final product through the vacuum filling machine fill.
Embodiment 9: take by weighing diethyltoluamide 3.60kg, rotenone 0.40kg, Radix Peucedani volatile oil 0.90kg; PEG40 castor oil hydrogenated 2.50kg, ethanol 53.00kg and water 39.50kg stirred 2.5 hours in agitated reactor; Add Fructus Citri Limoniae essence 0.10kg again; Stirred 1 hour, left standstill 4 hours, the Ticks worm repellant floral water that makes gets final product through the vacuum filling machine fill.
Embodiment 10: take by weighing diethyltoluamide 5.40kg, rotenone 0.15kg, Radix Peucedani volatile oil 0.45kg; PEG40 castor oil hydrogenated 1.20kg, ethanol 54.00kg and water 38.00kg stirred 2.5 hours in agitated reactor; Add Herba Menthae essence 0.80kg again; Stirred 1 hour, left standstill 5 hours, the Ticks worm repellant floral water that makes gets final product through the vacuum filling machine fill.
The repellent activity of Ticks worm repellant floral water is measured
1, repellent activity is measured
With the filter paper of 15 cm diameters, cut off the circle of 13 cm diameters to the center, stay wide 2 centimetres annular paper circle, evenly be added on this paper circle with 2 milliliters of repellant floral water.After 1 hour, on paper circle conglutinate glass plate, the filter paper that cuts off is put back into the center.Glass plate is maintained 38 ℃, under intensive illumination, be placed on paper central authorities to 10-15 grassland leather Ticks, observe the number of times that they cross peripheral paper circle, and the paper circle of establishing with the repellant floral water is experimental control, calculate the repellent percentage rate.
2, result's statistics and evaluation
The repellent activity of Ticks worm repellant floral water is measured the result and is seen table 1.Sample 1-5 is respectively from the Ticks worm repellant floral water of embodiment 1-5 in the table.The Ticks worm repellant floral water and the embodiment 1-5 of other embodiment preparation are similar, and more than 90%, the repellent percentage rate of 4h is more than 84% like the repellent percentage rate of 2h, and the repellent percentage rate of 8h is more than 78%; The tabulation that differs of concrete testing result.
Table 1: Ticks worm repellant floral water is measured the repellent activity of grassland leather Ticks
Repellent activity is measured the result and is shown, all greater than 90%, the repellent percentage rate of 4h is up to 89.5% to this Ticks worm repellant floral water to the repellent percentage rate of Ticks worm 2h, and the repellent percentage rate behind the 8h is about 80%.Above data show that Ticks worm repellant floral water provided by the invention not only has good repellent effect to the Ticks worm, and hold effect length, and the repellent time, more commercial repellant floral water was long.In addition, Ticks worm repellant floral water provided by the invention is to people, pet safe, and safe and convenient to use, production cost is cheaper, and preparation technology is simpler, is suitable for large-scale industrial production.
Claims (3)
1. Ticks worm repellant floral water; It is characterized in that; By weight percentage, its composition of raw materials consists of: diethyltoluamide 0.1-7%, rotenone 0.1-0.5%, Radix Peucedani volatile oil 0.1-1%, essence 0.1-1%, PEG40 castor oil hydrogenated 1-3%, ethanol 48-60% and water 30-50%;
During preparation, water, ethanol, diethyltoluamide, rotenone, PEG40 castor oil hydrogenated and Radix Peucedani volatile oil are added agitated reactor, stirred 2-3 hour, add essence again, stirred 1-2 hour, left standstill the Ticks worm repellant floral water that makes 4-6 hour by proportioning raw materials.
2. Ticks worm repellant floral water according to claim 1 is characterized in that: said essence is a kind of in Fructus Citri Limoniae essence and the Herba Menthae essence.
3. the method for preparing of claim 1 or 2 said Ticks worm repellant floral water; It is characterized in that: water, ethanol, diethyltoluamide, rotenone, PEG40 castor oil hydrogenated and Radix Peucedani volatile oil are added agitated reactor by proportioning raw materials; Stirred 2-3 hour, and added essence again, stirred 1-2 hour; Left standstill 4-6 hour, and made Ticks worm repellant floral water.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2010105328527A CN101991522B (en) | 2010-11-03 | 2010-11-03 | Tick repellent toilet water and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2010105328527A CN101991522B (en) | 2010-11-03 | 2010-11-03 | Tick repellent toilet water and preparation method thereof |
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| Publication Number | Publication Date |
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| CN101991522A CN101991522A (en) | 2011-03-30 |
| CN101991522B true CN101991522B (en) | 2012-08-22 |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103735462A (en) * | 2014-01-15 | 2014-04-23 | 张一文 | Cool and refreshing floral water for relieving itching |
| CN103735465A (en) * | 2014-01-15 | 2014-04-23 | 张一文 | Child floral water and preparation method thereof |
| CN106490053A (en) * | 2016-09-26 | 2017-03-15 | 塔里木大学 | A kind of Tickss worm repellant medicament and preparation method thereof |
| CN106474363A (en) * | 2016-09-26 | 2017-03-08 | 塔里木大学 | A kind of dog is pasted with tick is driven |
| CN111034729A (en) * | 2019-12-30 | 2020-04-21 | 河南安进生物技术股份有限公司 | Tick repellent, preparation method thereof and application thereof to tick repelling |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1401237A (en) * | 2002-08-05 | 2003-03-12 | 西北农林科技大学无公害农药研究服务中心 | Animal ectoparasite preventing and treating agent |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1401237A (en) * | 2002-08-05 | 2003-03-12 | 西北农林科技大学无公害农药研究服务中心 | Animal ectoparasite preventing and treating agent |
Non-Patent Citations (1)
| Title |
|---|
| 李雍龙.防治原则.《人体寄生虫学》.人民卫生出版社,2008,(第7版), * |
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