CN101999356A - Sterilization composition containing fluopicolide and metalaxyl and application thereof - Google Patents
Sterilization composition containing fluopicolide and metalaxyl and application thereof Download PDFInfo
- Publication number
- CN101999356A CN101999356A CN2010105719380A CN201010571938A CN101999356A CN 101999356 A CN101999356 A CN 101999356A CN 2010105719380 A CN2010105719380 A CN 2010105719380A CN 201010571938 A CN201010571938 A CN 201010571938A CN 101999356 A CN101999356 A CN 101999356A
- Authority
- CN
- China
- Prior art keywords
- metalaxyl
- fluorine pyrrole
- pyrrole bacterium
- bacterium amine
- sterilization composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a sterilization composition containing fluopicolide and metalaxyl and application thereof. The sterilization composition contains the fluopicolide, the metalaxyl and pesticide preparation auxiliary components, wherein the weight part ratio of the fluopicolide to the metalaxyl is 5:1-1:15; and the formulation of the sterilization composition is one of oil suspending agent, wettable powder, water dispersible granules, effervescent tablets and aqueous suspending agent. The sterilization composition is used for preventing and controlling cucumber downy mildew. The sterilization composition has obvious synergy on prevention and control effects compared with a single agent, reduces the consumption of pesticides, reduces the application cost, prolongs the service life of preparations, and reduces the adverse effect of the pesticides on the ecological environment.
Description
Technical field
The bactericidal composition that the present invention relates to is to be active ingredient with fluorine pyrrole bacterium amine and metalaxyl, is used to prevent and treat the crop pest on the agricultural, is particularly useful for preventing and treating cucumber downy mildew.
Background technology
In the crop growth process, be subjected to various diseases dip-dyes, particularly fungal disease easily, its kind is many, and it is serious to cause harm, and for a long time, chemical control is to prevent and treat the main effective means of disease.Yet, because long-term single drug and the medication of non-science, caused many pathogens that the agricultural chemicals of current use has been produced resistance, using dosage and medication number of times increase year by year and still are difficult to effectively control development of disease, simultaneously, agricultural chemicals to the harm of ecotope also increase thereupon, also difficult secure to the safety of crop.Therefore, be badly in need of the bactericide new varieties of efficient, low toxicity, safety, environmental protection.
Fluorine pyrrole bacterium amine, english common name fluopicolide, the platymiscium source bactericide, this medicine protectiveness is good, permeability is strong, and the true guiding principle fungus diseases of oomycetes is had higher biologically active, has good control efficiency.Can to protecting blade not to be subjected to infection process after the young shoot processing, can also distribute from the conduction of leaves of plants basal orientation blade tip direction from root along the plant xylem to whole strain crop.
Metalaxyl; english common name metalaxyl; belong to the anilide bactericide; it is a kind of systemic fungicide with protection and therapeutic action; can be absorbed by the root of plant, stem, leaf, and transfer to each organ of plant, can do the cauline leaf processing with moisture content in the plant corpus; seed treatment and soil treatment are effective to downy mildew, phytophthora, the caused disease of pythium spp.Because metalaxyl uses for years, disease has produced serious pesticide resistance.
Being mixed of different pesticide species is the common methods of the agriculture resistance disease of control.By the formulation of pesticide screening, filter out rational prescription, can effectively improve actual control efficiency, reduce dosage, reduce cost, delay the generation of disease drug resistance, be the important means of the disease comprehensive regulation.Fluorine pyrrole bacterium amine and metalaxyl are mixed and have big synergistic effect, still do not have relevant report at present.
Summary of the invention
The technical problem that the present invention need solve provide a kind of efficient, low toxicity and the lasting period long, be applied to administer the bactericidal composition that contains fluorine pyrrole bacterium amine and metalaxyl of cucumber downy mildew.
For addressing the above problem, the technical solution adopted in the present invention is: a kind of bactericidal composition that contains fluorine pyrrole bacterium amine and metalaxyl, the ratio of weight and number of fluorine pyrrole bacterium amine and metalaxyl is 5: 1～1: 15.
The present invention also contains the required auxiliary element of preparation pesticidal preparations, comprise one or more mixing in solvent, emulsifier, wetting agent, stabilizing agent, dispersant, thickener, defoamer, antifreezing agent, disintegrant, binding agent, filler, filler, the medium etc., be known substance, be various auxiliary agents commonly used in the pesticidal preparations, can change to some extent according to different situations, be not particularly limited.
The present invention can be mixed with the application forms that suitable agricultural such as oil-suspending agent, wetting powder, water dispersible granules, effervescent tablet, aqueous suspension agent is used according to well known to a person skilled in the art method.
The present invention is used for the control of disease control, the especially cucumber downy mildew of crops such as cucumber, tomato, grape, lupulus, vegetables, cucurbit.
Early stage or the use of disease initial stage of origination should take place in disease in the present invention when using.
The present invention adopts the method for spraying to use usually, also can adopt agricultural to go up other operation techniques of using as required.
Composition pesticide provided by the invention has following beneficial effect:
1, the present invention shows obvious synergistic effect in certain ratio range, and control efficiency is significantly improved than single agent, has reduced the using dosage of agricultural chemicals, has reduced drug cost, has reduced the adverse effect of agricultural chemicals to ecotope;
2, the combination of two kinds of bactericide of the present invention has enlarged fungicidal spectrum;
3, two kinds of effective ingredient mechanism of action provided by the invention have nothing in common with each other, and can overcome the long-term single shortcoming that makes with medicament be easy to generate resistance, prolong the service life of medicament.
4, the present invention is to crop safety.
Embodiment
In order to understand essence of the present invention better, be described further by following examples, but the present invention is not limited to these embodiment.In these embodiments, unless otherwise indicated, all percentages all are weight percentage.
Embodiment 1 (12% fluorine pyrrole bacterium amine metalaxyl oil-suspending agent)
Fluorine pyrrole bacterium amine 10%, metalaxyl 2%, emulsifier fatty alcohol-polyoxyethylene ether 4%, calcium dodecyl benzene sulfonate 5%, triphenyl vinyl phenol polyoxyethylene poly-oxygen propylene aether 3%, defoamer epoxidized soybean oil 1%, antifreezing agent glycerine 0.5%, surplus are methylated vegetable oil.Above-mentioned prescription is added in the mixing kettle in proportion successively, promptly make 12% fluorine pyrrole bacterium amine metalaxyl oil-suspending agent after stirring.
This embodiment is used to prevent and treat cucumber downy mildew, and 12% fluorine pyrrole bacterium amine metalaxyl oil-suspending agent consumption, 70 gram/mus are converted water spray, and 7 days, 14 days preventive effects are 77.2%, 85.6% behind the medicine.687.5 grams per liter fluorine pyrrole bacterium amine Propamocarb salt suspension agent consumption 70 gram/mus are converted water spray, 10 days, 15 days preventive effects are 73.6%, 84.7% behind the medicine.58% mancozeb metalaxyl wetting powder consumption, 160 gram/mus are converted water spray, and 10 days, 15 days preventive effects are 70.1%, 81.3% behind the medicine.
12% fluorine pyrrole bacterium amine metalaxyl oil-suspending agent control cucumber downy mildew effect is significantly better than 687.5 amine Propamocarb salt suspension agent of grams per liter fluorine pyrrole bacterium and 58% mancozeb metalaxyl wetting powders, illustrate that fluorine pyrrole bacterium amine of the present invention and metalaxyl composition can prevent and treat cucumber downy mildew preferably, reduce dosage, reduce cost, delay the generation of disease drug resistance.
Embodiment 2 (30% fluorine pyrrole bacterium amine metalaxyl wetting powder)
Fluorine pyrrole bacterium amine 15%, metalaxyl 15%, wetting agent draw back powder 3%, dispersant naphthalenesulfonate formaldehyde condensation compound 6%, filler talcum powder 15%, surplus is a filler kaolin.Above-mentioned prescription entered in the blender after the coarse crushing in proportion mix, behind comminution by gas stream, promptly make 30% fluorine pyrrole bacterium amine metalaxyl wetting powder again.
This embodiment is used to prevent and treat cucumber downy mildew, and 30% fluorine pyrrole bacterium amine metalaxyl wetting powder consumption, 20 gram/mus are converted water spray, and 7 days, 14 days preventive effects are 87.4%, 93.3% behind the medicine.687.5 grams per liter fluorine pyrrole bacterium amine Propamocarb salt suspension agent consumption 70 gram/mus are converted water spray, 10 days, 15 days preventive effects are 73.6%, 84.7% behind the medicine.58% mancozeb metalaxyl wetting powder consumption, 160 gram/mus are converted water spray, and 10 days, 15 days preventive effects are 70.1%, 81.3% behind the medicine.
30% fluorine pyrrole bacterium amine metalaxyl wetting powder control cucumber downy mildew effect is significantly better than 687.5 amine Propamocarb salt suspension agent of grams per liter fluorine pyrrole bacterium and 58% mancozeb metalaxyl wetting powders, illustrate that fluorine pyrrole bacterium amine of the present invention and metalaxyl composition can prevent and treat cucumber downy mildew preferably, reduce dosage, reduce cost, delay the generation of disease drug resistance.
Embodiment 3 (12% fluorine pyrrole bacterium amine metalaxyl water dispersible granules)
Fluorine pyrrole bacterium amine 2%, metalaxyl 10%, wetting agent lauryl sodium sulfate 6%, dispersant polycarboxylate 4%, disintegrant sodium chloride 2%, binding agent polyethylene glycol 3%, stabilizing agent soluble starch 3%, surplus is a carrier kaolin.Dry pulverization process, granulation, drying, screening make 12% fluorine pyrrole bacterium amine metalaxyl water dispersible granules in proportion with above-mentioned prescription.
This embodiment is used to prevent and treat cucumber downy mildew, and 12% fluorine pyrrole bacterium amine metalaxyl water dispersible granules consumption, 70 gram/mus are converted water spray, and 7 days, 14 days preventive effects are 88.7%, 95.1% behind the medicine.687.5 grams per liter fluorine pyrrole bacterium amine Propamocarb salt suspension agent consumption 70 gram/mus are converted water spray, 7 days, 14 days preventive effects are 73.6%, 84.7% behind the medicine.58% mancozeb metalaxyl wetting powder consumption, 160 gram/mus are converted water spray, and 10 days, 15 days preventive effects are 70.1%, 81.3% behind the medicine.
12% fluorine pyrrole bacterium amine metalaxyl water dispersible granules control cucumber downy mildew effect is significantly better than 687.5 amine Propamocarb salt suspension agent of grams per liter fluorine pyrrole bacterium and 58% mancozeb metalaxyl wetting powders, illustrate that fluorine pyrrole bacterium amine of the present invention and metalaxyl composition can prevent and treat cucumber downy mildew preferably, reduce dosage, reduce cost, delay the generation of disease drug resistance.
Embodiment 4 (11% fluorine pyrrole bacterium amine metalaxyl effervescent tablet)
Fluorine pyrrole bacterium amine 1%, metalaxyl 10%, neopelex 5%, calcium dodecyl benzene sulfonate 3%, thickener polyvinyl alcohol 4%, sodium bicarbonate 30%, anhydrous citric acid 32%, surplus is a microcrystalline cellulose.Above-mentioned prescription Central Plains medicine, auxiliary agent are crushed to certain fineness through cracker; Behind the tablet press machine compressing tablet; Make 11% fluorine pyrrole bacterium amine metalaxyl effervescent tablet.
This embodiment is used to prevent and treat cucumber downy mildew, and 11% fluorine pyrrole bacterium amine metalaxyl effervescent tablet consumption, 70 gram/mus are converted water spray, and 10 days, 20 days preventive effects are 84.1%, 87.7% behind the medicine.687.5 grams per liter fluorine pyrrole bacterium amine Propamocarb salt suspension agent consumption 70 gram/mus are converted water spray, 7 days, 14 days preventive effects are 73.6%, 84.7% behind the medicine.58% mancozeb metalaxyl wetting powder consumption, 160 gram/mus are converted water spray, and 10 days, 15 days preventive effects are 70.1%, 81.3% behind the medicine.
11% fluorine pyrrole bacterium amine metalaxyl effervescent tablet control cucumber downy mildew effect is significantly better than 687.5 amine Propamocarb salt suspension agent of grams per liter fluorine pyrrole bacterium and 58% mancozeb metalaxyl wetting powders, illustrate that fluorine pyrrole bacterium amine of the present invention and metalaxyl composition can prevent and treat cucumber downy mildew preferably, reduce dosage, reduce cost, delay the generation of disease drug resistance.
Embodiment 5 (16% fluorine pyrrole bacterium amine metalaxyl aqueous suspension agent)
Fluorine pyrrole bacterium amine 1%, metalaxyl 15%, emulsifier triphenyl vinyl phenol polyoxyethylene poly-oxygen propylene aether 3%, wetting agent calcium dodecyl benzene sulfonate 3%, dispersant alkylphenol polyoxyethylene formaldehyde condensation products sulphate 2%, antifreeze glycol 0.2%, stabilizing agent xanthan gum 0.1%, defoamer organosilicon 0.4%, glycerine 5%, thickener gum Arabic 0.1%, surplus are deionized water.Above-mentioned prescription is pulverized in proportion in advance, added in the sand mill and grind, allotment makes 16% fluorine pyrrole bacterium amine metalaxyl aqueous suspension agent after high shear mixing.
This embodiment is used to prevent and treat cucumber downy mildew, and 16% fluorine pyrrole bacterium amine metalaxyl aqueous suspension agent consumption, 25 gram/mus are converted water spray, and 10 days, 20 days preventive effects are 83.8%, 87.2% behind the medicine.687.5 grams per liter fluorine pyrrole bacterium amine Propamocarb salt suspension agent consumption 70 gram/mus are converted water spray, 7 days, 14 days preventive effects are 73.6%, 84.7% behind the medicine.58% mancozeb metalaxyl wetting powder consumption, 160 gram/mus are converted water spray, and 10 days, 15 days preventive effects are 70.1%, 81.3% behind the medicine.
16% fluorine pyrrole bacterium amine metalaxyl aqueous suspension agent control cucumber downy mildew effect is significantly better than 687.5 amine Propamocarb salt suspension agent of grams per liter fluorine pyrrole bacterium and 58% mancozeb metalaxyl wetting powders, illustrate that fluorine pyrrole bacterium amine of the present invention and metalaxyl composition can prevent and treat cucumber downy mildew preferably, reduce dosage, reduce cost, delay the generation of disease drug resistance.
Biologicall test embodiment 1: fluorine pyrrole bacterium amine and metalaxyl are mixed combination to cucumber downy mildew germ toxicity test
Be mixed to the virulence of bacterium of downy mildew of cucumber for further understanding fluorine pyrrole bacterium amine and metalaxyl, the inventor is mixed to fluorine pyrrole bacterium amine and metalaxyl and has carried out a large amount of formulation screening tests.
Selecting susceptible cucumber variety for use is Chang Chun Mi Ci, and seedling grows to 4-6 sheet leaf period.Wash the mould germ sporangium of the sick bloom of cucumber downy mildew with 4 ℃ of distilled water, (concentration is every milliliter 1 * 10 to be made into suspension
5Individual～1 * 10
7Individual sporangium), deposit under 4 ℃ standby.
With acetone solution fluorine pyrrole former medicine of bacterium amine and the former medicine of metalaxyl, according to the result of preliminary experiment two an amount of former medicines are made into different proportionings, with the aqueous solution that contains surfactant 0.1% Tween 80 each is handled again that to be diluted to 5 series concentration gradients respectively stand-by.The dilution of fluorine pyrrole bacterium amine is 8mk/kg, 4mk/kg, 2mk/kg, 1mk/kg, 0.5mk/kg, 0.1mk/kg; The metalaxyl dilution is 160mk/kg, 80mk/kg, 40mk/kg, 20mk/kg, 10mk/kg, 5mk/kg; Five kinds of different proportionings of fluorine pyrrole bacterium amine and metalaxyl (ratio of effective ingredient is 5: 1,1: 1,1: 5,1: 10,1: 15) dilution is 32mk/kg, 16mk/kg, 8mk/kg, 4mk/kg, 2mk/kg.
Select the consistent cucumber seedling of growth, each processing selects for use 5 basins for the examination cucumber seedling, sprays the about 20ml of every basin under 50PSI pressure with the Pottor spray tower.24h connects bacterium after the chemicals treatment, the sick leaf of the cucumber downy mildew that picks up from the field is evenly shaken off conidium inoculate on cucumber seedling, then cucumber seedling is put into the greenhouse and cultivates, and the morbidity grouping standard complete stool according to cucumber downy mildew behind the 7d is investigated disease index.
According to survey data, calculate each concentration of treatment to mycelial growth inhibition rate by NY/T1156.2-2006 for examination target bacterium, unit is percentage (%).
Logarithm value with drug concentration (mg/L) is independent variable x, is dependent variable y with the probit value of inhibiting rate, sets up the virulence regression equation formula respectively, adopts DPS software to calculate the EC of single agent and each proportioning mixture
50The co-toxicity coefficient (CTC) of (95% confidence limit) and mixture.
According to the NY/T1156.6-2006 bactericide synergy criteria for classifying: co-toxicity coefficient (CTC) 〉=120 shows as synergistic effect; Co-toxicity coefficient (CTC)≤80 shows as antagonism; 80＜co-toxicity coefficient (CTC)＜120 shows as summation action.
Table 1, fluorine pyrrole bacterium amine and metalaxyl and different proportioning are to the toxicity test result of bacterium of downy mildew of cucumber
From result of the test table 1 as can be seen the composition pesticide of fluorine pyrrole bacterium amine and metalaxyl be between 5: 1～1: 15 at ratio of weight and number, co-toxicity coefficient (CTC value) promptly all shows obvious synergistic effect all greater than 120.Fluorine pyrrole bacterium amine and metalaxyl are mixed and have reasonability and feasibility, are worth carrying out the land for growing field crops and apply.
Claims (5)
1. a bactericidal composition that contains fluorine pyrrole bacterium amine and metalaxyl is characterized in that effective ingredient is fluorine pyrrole bacterium amine and metalaxyl.
2. a kind of bactericidal composition that contains fluorine pyrrole bacterium amine and metalaxyl according to claim 1, it is characterized in that: the ratio of weight and number of fluorine pyrrole bacterium amine and metalaxyl is 5: 1～1: 15.
3. a kind of bactericidal composition that contains fluorine pyrrole bacterium amine and metalaxyl according to claim 1 and 2 is characterized in that also containing the required auxiliary element of preparation bactericidal composition.
4. a kind of bactericidal composition that contains fluorine pyrrole bacterium amine and metalaxyl according to claim 1 and 2 is characterized in that: its formulation is a kind of in oil-suspending agent, wetting powder, water dispersible granules, effervescent tablet, the aqueous suspension agent.
5. an application that contains the bactericidal composition of fluorine pyrrole bacterium amine and metalaxyl is characterized in that preventing and treating cucumber downy mildew.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010571938 CN101999356B (en) | 2010-11-26 | 2010-11-26 | Sterilization composition containing fluopicolide and metalaxyl and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010571938 CN101999356B (en) | 2010-11-26 | 2010-11-26 | Sterilization composition containing fluopicolide and metalaxyl and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101999356A true CN101999356A (en) | 2011-04-06 |
| CN101999356B CN101999356B (en) | 2013-05-08 |
Family
ID=43807245
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010571938 Active CN101999356B (en) | 2010-11-26 | 2010-11-26 | Sterilization composition containing fluopicolide and metalaxyl and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101999356B (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102246760A (en) * | 2011-04-30 | 2011-11-23 | 江西海科瑞特作物科学有限公司 | Bactericidal composition containing fluopicolide and metalaxyl |
| CN102334493A (en) * | 2011-10-26 | 2012-02-01 | 陕西美邦农药有限公司 | Novel fluopicolide-containing antibacterial composition |
| CN102613233A (en) * | 2012-03-16 | 2012-08-01 | 广东中迅农科股份有限公司 | Synergetic acaricidal composition containing cyflumetofen and fenbutatin oxide |
| JP2014511835A (en) * | 2011-03-23 | 2014-05-19 | バイエル・インテレクチユアル・プロパテイー・ゲー・エム・ベー・ハー | Active compound combinations |
| CN104381266A (en) * | 2014-09-25 | 2015-03-04 | 北京燕化永乐生物科技股份有限公司 | Sterilization composition |
| CN106035379A (en) * | 2016-06-27 | 2016-10-26 | 中国烟草总公司郑州烟草研究院 | Bactericide composition containing phenylamide and benzamide bactericides and biocontrol bacterium, preparation and applications |
| CN106962348A (en) * | 2017-04-14 | 2017-07-21 | 广西南宁益土生物科技有限责任公司 | A kind of bactericidal composition for preventing and treating cucumber downy mildew |
| CN108013048A (en) * | 2017-12-31 | 2018-05-11 | 成都格瑞赛斯科技有限公司 | A kind of bactericidal composition and its application containing metalaxyl |
| CN109769843A (en) * | 2019-03-11 | 2019-05-21 | 西华大学 | A kind of bactericidal composition containing metalaxyl, pesticide and application |
| CN111937898A (en) * | 2020-08-24 | 2020-11-17 | 安徽华星化工有限公司 | Pesticide composition containing imidacloprid and fluopicolide and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1152253A (en) * | 1994-07-11 | 1997-06-18 | 希巴-盖吉股份公司 | Two-and three-component fungicidal mixtures |
| CN1917762A (en) * | 2004-02-12 | 2007-02-21 | 拜尔农科股份有限公司 | Fungicidal composition comprising a pyridylethylbenzamide derivative and a compound capable of inhibiting the spores germination or mycelium growth by acting on different metabolic routes |
| WO2007031507A1 (en) * | 2005-09-13 | 2007-03-22 | Bayer Cropscience Ag | Fungicide composition comprising an arylamidine derivative and two known fungicide compounds |
-
2010
- 2010-11-26 CN CN 201010571938 patent/CN101999356B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1152253A (en) * | 1994-07-11 | 1997-06-18 | 希巴-盖吉股份公司 | Two-and three-component fungicidal mixtures |
| CN1917762A (en) * | 2004-02-12 | 2007-02-21 | 拜尔农科股份有限公司 | Fungicidal composition comprising a pyridylethylbenzamide derivative and a compound capable of inhibiting the spores germination or mycelium growth by acting on different metabolic routes |
| WO2007031507A1 (en) * | 2005-09-13 | 2007-03-22 | Bayer Cropscience Ag | Fungicide composition comprising an arylamidine derivative and two known fungicide compounds |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014511835A (en) * | 2011-03-23 | 2014-05-19 | バイエル・インテレクチユアル・プロパテイー・ゲー・エム・ベー・ハー | Active compound combinations |
| JP2017025084A (en) * | 2011-03-23 | 2017-02-02 | バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングＢａｙｅｒ Ｉｎｔｅｌｌｅｃｔｕａｌ Ｐｒｏｐｅｒｔｙ ＧｍｂＨ | Active compound combination |
| CN102246760A (en) * | 2011-04-30 | 2011-11-23 | 江西海科瑞特作物科学有限公司 | Bactericidal composition containing fluopicolide and metalaxyl |
| CN102334493A (en) * | 2011-10-26 | 2012-02-01 | 陕西美邦农药有限公司 | Novel fluopicolide-containing antibacterial composition |
| CN102334493B (en) * | 2011-10-26 | 2014-06-18 | 陕西美邦农药有限公司 | Novel fluopicolide-containing antibacterial composition |
| CN102613233A (en) * | 2012-03-16 | 2012-08-01 | 广东中迅农科股份有限公司 | Synergetic acaricidal composition containing cyflumetofen and fenbutatin oxide |
| CN104381266A (en) * | 2014-09-25 | 2015-03-04 | 北京燕化永乐生物科技股份有限公司 | Sterilization composition |
| CN106035379A (en) * | 2016-06-27 | 2016-10-26 | 中国烟草总公司郑州烟草研究院 | Bactericide composition containing phenylamide and benzamide bactericides and biocontrol bacterium, preparation and applications |
| CN106962348A (en) * | 2017-04-14 | 2017-07-21 | 广西南宁益土生物科技有限责任公司 | A kind of bactericidal composition for preventing and treating cucumber downy mildew |
| CN108013048A (en) * | 2017-12-31 | 2018-05-11 | 成都格瑞赛斯科技有限公司 | A kind of bactericidal composition and its application containing metalaxyl |
| CN109769843A (en) * | 2019-03-11 | 2019-05-21 | 西华大学 | A kind of bactericidal composition containing metalaxyl, pesticide and application |
| CN111937898A (en) * | 2020-08-24 | 2020-11-17 | 安徽华星化工有限公司 | Pesticide composition containing imidacloprid and fluopicolide and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101999356B (en) | 2013-05-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101999356B (en) | Sterilization composition containing fluopicolide and metalaxyl and application thereof | |
| CN102696645B (en) | A kind of composition pesticide containing pyraclostrobin and Metalaxyl-M | |
| CN101548677B (en) | Sterilizing compound of ethirimol and triazole | |
| CN101653139A (en) | Compound bactericidal composition containing boscalid | |
| CN101647456A (en) | Antifungal composite with pyraclostrobin and cymoxanil | |
| CN101810181A (en) | Sterilizing pesticide combination, preparation method and application thereof | |
| CN101664033B (en) | Ethirimol-contained bactericide combination | |
| CN101849546A (en) | Pesticide composition | |
| CN104054712B (en) | Sterilization composition containing boscalid | |
| CN104365611B (en) | A kind of bactericidal composition and application containing amisulbrom and mandipropamid | |
| CN101617671B (en) | Compound bactericidal composition | |
| CN101524069B (en) | Sterilizing composition containing Hexaconazole | |
| CN101194620B (en) | Bactericide agent composition containing tebuconazole | |
| CN102640757B (en) | Compound pesticide sterilization composition containing trifloxystrobin | |
| CN101669479B (en) | Mite-killing combination | |
| CN105230642A (en) | Bactericidal composition containing isopyrazam and application thereof | |
| CN107047563A (en) | A kind of bactericidal composition for preventing and treating Zizyphus maurtiana powdery mildew | |
| CN101617658A (en) | Combination sterilization composition | |
| CN104488875A (en) | Bactericidal composition containing famoxadone and boscalid | |
| CN101647466B (en) | Sterilization combination | |
| CN104285989A (en) | Pesticide composition containing pyraclostrobin and propamidine | |
| CN104068033B (en) | Fungicidal composition containing boscalid | |
| CN102027934A (en) | Bactericidal composition containing fluopyram and difenoconazole and application thereof | |
| CN104137832A (en) | Bactericidal composition containing trifloxystrobin and oligosaccharins and use of bactericidal composition | |
| CN104012540A (en) | Synergistic sterilization composition and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20110406 Assignee: JIANGXI ZHONGXUN AGROCHEMICAL CO., LTD. Assignor: Guangdong Zhongxun Agricultural Technology Co., Ltd. Contract record no.: X2019440020026 Denomination of invention: Sterilization composition containing fluopicolide and metalaxyl and application thereof Granted publication date: 20130508 License type: Common License Record date: 20191203 |
|
| EE01 | Entry into force of recordation of patent licensing contract | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Sterilization composition containing fluopicolide and metalaxyl and application thereof Effective date of registration: 20200428 Granted publication date: 20130508 Pledgee: China Co truction Bank Corp Huizhou branch Pledgor: GUANGDONG ZHONGXUN AGRICULTURAL TECHNOLOGY Co.,Ltd. Registration number: Y2020980001916 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |