CN101874501B - Insecticidal composition containing thiamethoxam and carbosulfan - Google Patents
Insecticidal composition containing thiamethoxam and carbosulfan Download PDFInfo
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- CN101874501B CN101874501B CN 201010150155 CN201010150155A CN101874501B CN 101874501 B CN101874501 B CN 101874501B CN 201010150155 CN201010150155 CN 201010150155 CN 201010150155 A CN201010150155 A CN 201010150155A CN 101874501 B CN101874501 B CN 101874501B
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- diacloden
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Abstract
The invention relates to an insecticidal composition containing thiamethoxam and carbosulfan, comprising active components, auxiliaries and a filler. The composition is characterized in that the active components are the thiamethoxam and the carbosulfan, wherein the weight percentage of the thiacloprid to the phoxim is 1-60:80-1. After the thiamethoxam and the carbosulfan are compounded, the composition has clear effect of synergy and sustainable prevention, enlarges the insecticidal spectrum, and has higher activity to aphid, scale insects, trialeurodes vaporariorum, rice planthopper, thrips palmi karny, stripedflea-beetle and the like.
Description
Technical field
The invention belongs to agricultural technology field, relate to a kind of effective active composition and contain the Pesticidal combination of Diacloden and carbosulfan for the application of control vegetables insect pest.
Background technology
Diacloden, English common name (thiamethoxam), molecular formula is C
8H
10ClN
5O
3S, chemical name 3-(2-chloro-1,3-thiazoles-5-ylmethyl)-5-methyl isophthalic acid, 3,5-oxadiazines-4-base fork (nitro) amine.
Diacloden is a kind of novel high-efficiency low-toxicity broad spectrum pesticide.Be second generation anabasine insecticide, the mechanism of action is similar to first generation anabasine insecticides such as Imidacloprids, but has higher activity.To insect have stomach toxicity, tag, systemic action, the characteristics such as speed of action is fast, the lasting period is long.Better to preventive effects such as sucking pest such as aphid, plant hopper, leafhopper, aleyrodids.
Carbosulfan, English common name carbosulafan, molecular formula is C
20H
32N
2O
3S, chemical name are 2,3-dihydro-2,2-dimethyl benzofuran-7-base (dibutylamino sulphur) methyl carbamate.
Carbosulfan is carbamate insecticide, is that poisonous Furadan plays insecticidal action at the insect bodies intracellular metabolite, and its insecticidal mechanism is the interference insect nervous system, suppresses cholinesterase, makes the muscle of insect and body of gland continue excitement, and causes insect death.Absorption in this medical instrument has insect and to tag and stomach poison function, and the lasting period is long, and insecticidal spectrum is wide, can be used for preventing and treating the various pests on fruit tree, paddy rice, the vegetables.
Often there is defective in various degree in the insecticide variety that contains the single-activity component on agricultural insect pests control: insect develops immunity to drugs easily after using continuously, and access times are many will the weighting ring environment pollution.And that different component carries out is composite, can effectively overcome above shortcoming.Simultaneously, the synergistic effect that utilizes two kinds of active components to be mixed and to produce can improve preventive effect, reduces the consumption of active ingredient, saves drug cost, delays the generation of pest resistance to insecticide, reduces environmental pollution, is the important means of integrated control insect.At present, Diacloden and carbosulfan composite and use and there is no the people and reported.
Summary of the invention
In order to satisfy the needs of pesticide producing, take full advantage of two kinds of active components be mixed the synergistic effect that produces, improve preventive effect, reduce agricultural cost and delay the generation of pest resistance to insecticide, the present invention proposes the composite Pesticidal combination that contains Diacloden and carbosulfan.
The object of the present invention is achieved like this: a kind of Pesticidal combination that contains Diacloden and carbosulfan, comprise effective active component, auxiliary agent and filler, and the weight hundred of effective active composition Diacloden and carbosulfan is than being 1～60: 80～1.
The described Pesticidal combination that contains Diacloden and carbosulfan, the percentage by weight of Diacloden and carbosulfan are 1～40: 60～5.
The described Pesticidal combination that contains Diacloden and carbosulfan, the percentage by weight of Diacloden and carbosulfan are 5～15: 40～5.
Described Diacloden and the carbosulfan insecticidal composite of containing, the percentage by weight of Diacloden and carbosulfan is 5～10: 40～10.
Described Diacloden and the carbosulfan insecticidal composite of containing, the optimum activity proportioning of Diacloden and carbosulfan is 5: 1～1: 15, preferred proportioning is 1: 1～1: 10.
The described Pesticidal combination that contains Diacloden and carbosulfan adds conventional auxiliary agent by method well-known in the art, can be made into wetting powder, water dispersible granules, microcapsule suspending agent, aqueous emulsion, microemulsion.
The described Pesticidal combination that contains Diacloden and carbosulfan is mainly used in anti-eliminating aphis, scale insect, trialeurodes vaporariorum, rice fulgorid, thrips and striped flea-beetle.
The invention has the advantages that:
(1) Diacloden and carbosulfan composite after, fully different to the mechanism of action of target pest, both are composite to have notable synergistic and lasting effect;
(2) enlarged insecticidal spectrum, aphid, thrips, rice fulgorid have been had special efficacy;
(3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution;
(4), insect good to person poultry safety, Environmental compatibility is difficult for developing immunity to drugs.
Embodiment
To further instruction of the present invention, the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.First by Toxicity Determination, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC＜80 are antagonism, and 80≤CTC≤120 are summation action, and CTC＞120 are synergistic effect, on this basis, carry out field trial again.
Application Example one
For the examination insect: cotton aphid, for subsequent use after 3 generations of artificial feeding.
Test medicine: agricultural chemicals Co., Ltd of U.S. nation provides by Shaanxi.
Experimental scheme: effective lethal concentration scope of determining the former medicine of Diacloden, the former medicine of carbosulfan and the two different proportioning mixture through preliminary experiment, each medicament designs respectively five gradient concentrations by active constituent content and processes, and does contrast with the space management that does not contain former medicine.
Test method: respectively the mother liquor of Diacloden, carbosulfan and each mixed agent is diluted to above 5 series concentration during test, places respectively beaker for subsequent use.Adopt and to soak first the method that connects worm behind the leaf, the fresh cotton floral leaf of the same size that does not contact any medicament soaked in the liquid that configures behind the 5s take out, naturally dry, put into insect box, then connect for the examination aphid, under 25 ℃ of conditions, raise, every processing repeats for 3 times, every to repeat used examination borer population be 20, establishes simultaneously blank, checks dead borer population in 72h, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50Value.If the contrast lethality then is considered as invalid test greater than 10%.Computing formula is as follows:
The cotton aphid corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least squares, and calculates thus the value of every kind of medicament.Calculate co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula following (take Diacloden as the standard medicament, its toxicity index is 100):
TI * the P of the theoretical toxicity index (TTI) of M=Diacloden
DiaclodenTI * the P of+carbosulfan
Carbosulfan
In the formula: M is the mixture of different proportionings
P
CarbosulfanBe carbosulfan shared ratio in composition
P
DiaclodenBe Diacloden shared ratio in composition
Result of the test is as shown in table 1:
The different proportionings from carbosulfan of table 1 Diacloden are to the toxicity test of cotton aphid
As shown in Table 1, Diacloden and carbosulfan and composite product are to cotton aphid Toxicity Determination experiment discovery, the virulence of Diacloden is higher than carbosulfan, co-toxicity coefficient is all greater than 120 when Diacloden and carbosulfan proportioning are 1: 1,1: 5,1: 10,1: 15,1: 20, show obvious synergistic effect, Diacloden thus: carbosulfan all had synergistic function between 1: 1 to 1: 20, especially when Diacloden: during carbosulfan=1: 10, co-toxicity coefficient is maximum, and synergistic effect is the most obvious.
Application example two
20% Diacloden carbosulfan wetting powder is prevented and treated the rice hoppers test of pesticide effectiveness
Diacloden 10%, carbosulfan 10%, polycarboxylate 2%, alkylphenol-polyethenoxy are phonetic 2%, lauryl sodium sulfate 2%, moistening bleeding agent F 2%, white carbon 32%, diatomite 40% mixture are carried out air-flow crushing, make 20% Diacloden carbosulfan wetting powder.This prescription is by 1000 times of dilution sprayings, and preventing and treating the rice hoppers effect in 72 hours behind the medicine is 94.74%～96.61%.25% Diacloden water dispersible granules and 20% carbosulfan missible oil dilute respectively 2500 times and 300 times of uses according to same method, and 72 hours preventive effects are respectively 80.25% and 76.45% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example three
The 30% Diacloden carbosulfan wetting powder control cotton aphid test of pesticide effectiveness
Diacloden 25%, carbosulfan 5%, alkyl benzene sulfonate calcium salt 4%, neopelex 2%, spaonin powder 4%, white carbon 30%, diatomite 30%, mixture carries out air-flow crushing, makes 30% Diacloden carbosulfan wetting powder.This prescription is by 1500 times of dilution sprayings, and 72 hours control cotton aphid effects are 94.52%～97.37% behind the medicine.25% Diacloden water dispersible granules and 20% carbosulfan missible oil dilute respectively 2500 times and 300 times of uses according to same method, and 72 hours preventive effects are respectively 81.17% and 77.43% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example four
The 16% Diacloden carbosulfan water dispersible granules control rape aphid test of pesticide effectiveness
Diacloden 1%, carbosulfan 15%, lignosulfonates 6%, neopelex 4%, ammonium sulfate 2%, white carbon 34%, starch 38% mix making 16% Diacloden carbosulfan water dispersible granules.This proportioning is by 1000 times of dilution sprayings, 72 hours control rape aphid effects are 93.84%～96.02% behind the medicine, 25% Diacloden water dispersible granules and 20% carbosulfan missible oil are according to same method, dilute respectively 3000 times and 250 times of uses, 72 hours preventive effects are respectively 80.11% and 77.52% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example five
The 25% Diacloden carbosulfan water dispersible granules control cotton thrips test of pesticide effectiveness
Diacloden 5%, carbosulfan 20%, sodium lignin sulfonate 5%, pull open powder 5%, urea 2%, white carbon 25%, starch 20%, kaolin 18%, mix making 25% Diacloden carbosulfan water dispersible granules.This proportioning is by 1500 times of dilution sprayings, 72 hours control cotton thrips effects are 94.86%～96.63% behind the medicine, 25% Diacloden water dispersible granules and 20% carbosulfan missible oil are according to same method, dilute respectively 2500 times and 350 times of uses, 72 hours preventive effects are respectively 80.13% and 77.41% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example six
The 45% Diacloden carbosulfan EC rape striped flea-beetle test of pesticide effectiveness
Diacloden 15%, carbosulfan 30%, alkylphenol polyoxyethylene class 12%, cyclohexanone 20%, pyrrolidones 15%, silicone oil 0.1%, phosphite ester 0.2%, deionized water adds to 100%, mixes to make 45% Diacloden carbosulfan missible oil.This proportioning is by 1800 times of dilution sprayings, 72 hours control rape striped flea-beetle effects are 95.43%～97.12% behind the medicine, 25% Diacloden water dispersible granules and 20% carbosulfan missible oil are according to same method, dilute respectively 3000 times and 300 times of uses, 72 hours preventive effects are respectively 82.55% and 79.74% behind the medicine.Find that in test the present composition has no adverse effects to the target crop, to beneficial insect safety.
Application example seven
48% Diacloden aqueous carbosulfan emulsion control cucumber Control of Aphids
Diacloden 8%, carbosulfan 40%, cyclohexanone 18%, toluene 13%, farming breast 400
#4%, 600
#Phosphate 4%, propane diols 4%, polyvinyl alcohol 1%, silicone oil 0.4%, deionized water supplies 100%, makes 48% Diacloden aqueous carbosulfan emulsion.This proportioning is by 2000 times of dilution sprayings, 72 hours control cucumber aphid effects are 94.21%～97.54% behind the medicine, 25% Diacloden water dispersible granules and 20% carbosulfan missible oil are according to same method, dilute respectively 3000 times and 350 times of uses, 72 hours preventive effects are respectively 83.45% and 80.72% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example eight
35% Diacloden aqueous carbosulfan emulsion is prevented and treated the rice hoppers test of pesticide effectiveness
Diacloden 5%, carbosulfan 30%, acetonitrile 20%, N-pyrrolidones 8%, farming breast 600
#3%, the farming breast 400
#4%, ethylene glycol 4%, polyethylene glycol 1%, silicone oil 0.4%, deionized water supplies 100%, makes 35% Diacloden aqueous carbosulfan emulsion.This proportioning is by 1500 times of dilution sprayings, preventing and treating the rice hoppers effect in 72 hours behind the medicine is 94.16%～96.72%, 25% Diacloden water dispersible granules and 20% carbosulfan missible oil are according to same method, dilute respectively 2500 times and 300 times of uses, 72 hours preventive effects are respectively 81.53% and 79.56% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example nine
The 30% Diacloden carbosulfan microemulsion control oranges and tangerines scale insect test of pesticide effectiveness
With Diacloden 5%, carbosulfan 25%, DMF 17%, toluene 5%, ethylene glycol monomethyl ether 4%, ethyl acetate 4%, farming breast 34
#6%, triethanolamine salt 6%, ethylene glycol 2%, silicone oil 0.4%, deionized water supplies 100%, makes 30% Diacloden carbosulfan microemulsion.This proportioning is by 1200 times of dilution sprayings, 72 hours control oranges and tangerines scale insect effects are 94.67%～96.40% behind the medicine, 25% Diacloden water dispersible granules and 20% carbosulfan missible oil are according to same method, dilute respectively 3000 times and 300 times of uses, 72 hours preventive effects are respectively 81.47% and 79.76% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example ten
The 15% Diacloden carbosulfan microemulsion control cotton trialeurodes vaporariorum test of pesticide effectiveness
With Diacloden 5%, carbosulfan 10%, NOP 17%, methyl alcohol 8%, N-pyrrolidones 4%, tween 4%, farming breast 600
#3%, Nongru-700
#5%, propane diols 3%, silicone oil 0.4%, deionized water supplies 100%, makes 15% Diacloden carbosulfan microemulsion.This proportioning is by 1000 times of dilution sprayings, 72 hours control cotton trialeurodes vaporariorum effects are 94.59%～97.34% behind the medicine, 25% Diacloden water dispersible granules and 20% carbosulfan missible oil are according to same method, dilute respectively 3000 times and 300 times of uses, 72 hours preventive effects are respectively 80.71% and 79.35% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example 11
21% Diacloden carbosulfan microcapsule suspending agent control oranges and tangerines Control of Aphids
Diacloden 1%, carbosulfan 20%, alkyl polyoxyethylene ether 10%, sorbitan monostearate 8%, shitosan 10%, dimethylbenzene 12%, methyl alcohol 5%, deionized water are supplied 100%, 21% Diacloden carbosulfan microcapsule suspending agent of system.This proportioning is by 1200 times of dilution sprayings, 72 hours control oranges and tangerines aphid effects are 92.83%～95.37% behind the medicine, 25% Diacloden water dispersible granules and 20% carbosulfan missible oil are according to same method, dilute respectively 3000 times and 300 times of uses, 72 hours preventive effects are respectively 81.35% and 79.75% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example 12
12% Diacloden carbosulfan microcapsule suspending agent control watermelon Control of Aphids
Diacloden 2%, carbosulfan 10%, phenyl phenol polyoxy ethyl ether 10%, alkyl benzene calcium sulfonate 8%, gelatin 10%, acetone 12%, hexane 5%, deionized water are supplied 100%, 12% Diacloden carbosulfan microcapsule suspending agent of system.This proportioning is by 1200 times of dilution sprayings, 72 hours control watermelon aphid effects are 92.89%～96.07% behind the medicine, 25% Diacloden water dispersible granules and 20% carbosulfan missible oil are according to same method, dilute respectively 3000 times and 300 times of uses, 72 hours preventive effects are respectively 81.55% and 78.43% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Claims (5)
1. a Pesticidal combination that contains Diacloden and carbosulfan comprises effective active component, auxiliary agent and filler, it is characterized in that: the weight ratio of effective active composition Diacloden and carbosulfan is 1:1 ~ 1:20.
2. the Pesticidal combination that contains Diacloden and carbosulfan according to claim 1, it is characterized in that: the weight ratio of Diacloden and carbosulfan is 1:5 ~ 1:15.
3. the Pesticidal combination that contains Diacloden and carbosulfan according to claim 1, it is characterized in that: composition is made wetting powder, water dispersible granules, microcapsule suspending agent, aqueous emulsion, microemulsion.
4. the application of Pesticidal combination on the control crop pest that contains Diacloden and carbosulfan according to claim 1.
5. application according to claim 4 is characterized in that: described insect comprises aphid, scale insect, trialeurodes vaporariorum, rice fulgorid, thrips, striped flea-beetle.
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| CN101874501B true CN101874501B (en) | 2013-01-23 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102210315B (en) * | 2011-04-29 | 2013-06-19 | 中国农业大学 | Carbosulfan microcapsule suspending agent and preparation method thereof |
| CN103109842A (en) * | 2013-01-27 | 2013-05-22 | 成都科利隆生化有限公司 | Seed treating agent with dual function of preventing diseases and pests |
| CN104663700A (en) * | 2014-12-03 | 2015-06-03 | 浙江天一农化有限公司 | Micro-capsule suspending agent containing thiamethoxam and carbosulfan and preparation method of micro-capsule suspending agent |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1220578A (en) * | 1996-04-29 | 1999-06-23 | 诺瓦蒂斯公司 | Pesticidal compositions |
| CN1451279A (en) * | 2002-12-06 | 2003-10-29 | 苏州富美实植物保护剂有限公司 | Insecticide composition contg. carbosulfan and imidecloprid |
-
2010
- 2010-04-20 CN CN 201010150155 patent/CN101874501B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1220578A (en) * | 1996-04-29 | 1999-06-23 | 诺瓦蒂斯公司 | Pesticidal compositions |
| CN1451279A (en) * | 2002-12-06 | 2003-10-29 | 苏州富美实植物保护剂有限公司 | Insecticide composition contg. carbosulfan and imidecloprid |
Non-Patent Citations (2)
| Title |
|---|
| 吡虫啉与丁硫克百威不同配比对稻飞虱的联合毒力;肖艳松 等;《农药研究与应用》;20070228;第11卷(第1期);第31-32页 * |
| 肖艳松 等.吡虫啉与丁硫克百威不同配比对稻飞虱的联合毒力.《农药研究与应用》.2007,第11卷(第1期),第31-32页. |
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Address after: 715500 Shaanxi Pucheng County agricultural base industrial park Patentee after: Shaanxi Meibang pesticide Co.,Ltd. Address before: 710075, Xi'an high tech Zone, Shaanxi hi tech Zone, Jinqiao International C block, 15 Floor Patentee before: Shaanxi Meibang pesticide Co.,Ltd. |
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Address after: 715500 Pucheng high tech Industrial Development Zone, Weinan, Shaanxi Patentee after: SHAANXI MEIBANG PHARMACEUTICAL GROUP Co.,Ltd. Address before: 715500 Industrial Park of Agrochemical Base in Pucheng County, Shaanxi Province Patentee before: Shaanxi Meibang pesticide Co.,Ltd. |
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