CN101874501A - Insecticidal composition containing thiamethoxam and carbosulfan - Google Patents
Insecticidal composition containing thiamethoxam and carbosulfan Download PDFInfo
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- CN101874501A CN101874501A CN2010101501555A CN201010150155A CN101874501A CN 101874501 A CN101874501 A CN 101874501A CN 2010101501555 A CN2010101501555 A CN 2010101501555A CN 201010150155 A CN201010150155 A CN 201010150155A CN 101874501 A CN101874501 A CN 101874501A
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- carbosulfan
- thiophene worm
- worm piperazine
- medicine
- pesticidal combination
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Abstract
The invention relates to an insecticidal composition containing thiamethoxam and carbosulfan, comprising active components, auxiliaries and a filler. The composition is characterized in that the active components are the thiamethoxam and the carbosulfan, wherein the weight percentage of the thiacloprid to the phoxim is 1-60:80-1. After the thiamethoxam and the carbosulfan are compounded, the composition has clear effect of synergy and sustainable prevention, enlarges the insecticidal spectrum, and has higher activity to aphid, scale insects, trialeurodes vaporariorum, rice planthopper, thrips palmi karny, stripedflea-beetle and the like.
Description
Technical field
The invention belongs to agricultural technology field, relate to the application that Pesticidal combination that a kind of effective active composition contains thiophene worm piperazine and carbosulfan is used to prevent and treat the vegetables insect pest.
Background technology
Thiophene worm piperazine, English common name (thiamethoxam), molecular formula is C
8H
10ClN
5O
3S, chemical name 3-(2-chloro-1,3-thiazoles-5-ylmethyl)-5-methyl isophthalic acid, 3,5-oxadiazines-4-base fork (nitro) amine.
Thiophene worm piperazine is a kind of novel high-efficiency low-toxicity broad spectrum pesticide.Be second generation anabasine insecticide, the mechanism of action is similar to first generation anabasine insecticides such as Imidacloprids, but has higher activity.To insect have stomach toxicity, tag, systemic action, characteristics such as speed of action is fast, the lasting period is long.Better to preventive effects such as sucking pest such as aphid, plant hopper, leafhopper, aleyrodids.
Carbosulfan, English common name carbosulafan, molecular formula is C
20H
32N
2O
3S, chemical name are 2,3-dihydro-2,2-dimethyl benzofuran-7-base (dibutylamino sulphur) methyl carbamate.
Carbosulfan is a carbamate insecticide, is the poisonous red insecticidal action that rises of furans at the insect bodies intracellular metabolite, and its insecticidal mechanism is the interference insect nervous system, suppresses cholinesterase, makes muscle of insect and body of gland continue excitement, and causes insect death.Absorption in this medical instrument has insect and to tag and stomach poison function, and the lasting period is long, and insecticidal spectrum is wide, can be used for preventing and treating the various pests on fruit tree, paddy rice, the vegetables.
Often there is defective in various degree in the insecticide variety that contains the single-activity component on agricultural insect pests control: use the back insect to be easy to generate pesticide resistance continuously, access times are many will the weighting ring environment pollution.And that different component carries out is composite, can effectively overcome above shortcoming.Simultaneously, utilizing two kinds of synergistic effects that active component is mixed and is produced, can improve preventive effect, reduce the consumption of active ingredient, save drug cost, delay the generation of pest resistance to insecticide, reduce environmental pollution, is the important means of integrated control insect.At present, still nobody reported in the composite and application of thiophene worm piperazine and carbosulfan.
Summary of the invention
In order to satisfy the needs of pesticide producing, make full use of two kinds of active components be mixed the synergistic effect that produced, improve preventive effect, reduce agricultural cost and delay the generation of pest resistance to insecticide, the present invention proposes the composite Pesticidal combination that contains thiophene worm piperazine and carbosulfan.
The object of the present invention is achieved like this: a kind of Pesticidal combination that contains thiophene worm piperazine and carbosulfan, comprise effective active component, auxiliary agent and filler, and the weight hundred of effective active composition thiophene worm piperazine and carbosulfan is than being 1～60: 80～1.
The described Pesticidal combination that contains thiophene worm piperazine and carbosulfan, the percentage by weight of thiophene worm piperazine and carbosulfan are 1～40: 60～5.
The described Pesticidal combination that contains thiophene worm piperazine and carbosulfan, the percentage by weight of thiophene worm piperazine and carbosulfan are 5～15: 40～5.
Described thiophene worm piperazine and the carbosulfan insecticidal composite of containing, the percentage by weight of thiophene worm piperazine and carbosulfan is 5～10: 40～10.
Described thiophene worm piperazine and the carbosulfan insecticidal composite of containing, the optimum activity proportioning of thiophene worm piperazine and carbosulfan is 5: 1～1: 15, preferred proportioning is 1: 1～1: 10.
The described Pesticidal combination that contains thiophene worm piperazine and carbosulfan adds conventional auxiliary agent by method well-known in the art, can be made into wetting powder, water dispersible granules, microcapsule suspending agent, aqueous emulsion, microemulsion.
The described Pesticidal combination that contains thiophene worm piperazine and carbosulfan is mainly used in and anti-eliminates aphis, scale insect, trialeurodes vaporariorum, rice fulgorid, thrips and striped flea-beetle.
The invention has the advantages that:
(1) thiophene worm piperazine and carbosulfan composite after, different fully to the mechanism of action of target pest, both are composite to have notable synergistic and lasting effect;
(2) enlarged insecticidal spectrum, aphid, thrips, rice fulgorid have been had special efficacy;
(3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution;
(4), insect good to person poultry safety, Environmental compatibility is difficult for developing immunity to drugs.
Embodiment
To further instruction of the present invention, the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Pass through Toxicity Determination earlier, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC＜80 are antagonism, and 80≤CTC≤120 are summation action, and CTC＞120 are synergistic effect, on this basis, carry out field trial again.
Application Example one
For the examination insect: cotton aphid, standby after 3 generations of artificial feeding.
Test medicine: agricultural chemicals Co., Ltd of U.S. nation provides by Shaanxi.
Experimental scheme: effective lethal concentration scope of determining the former medicine of thiophene worm piperazine, the former medicine of carbosulfan and the two different proportioning mixture through preliminary experiment, each medicament designs five gradient concentrations respectively by active constituent content and handles, and does contrast with the space management that does not contain former medicine.
Test method: respectively the mother liquor of thiophene worm piperazine, carbosulfan and each mixed agent is diluted to above 5 series concentration during test, places beaker standby respectively.Adopt and to soak the method that connects worm behind the leaf earlier, the fresh cotton floral leaf of the same size that does not contact any medicament soaked in the soup that configures behind the 5s take out, dry naturally, put into insect box, connect then, under 25 ℃ of conditions, raise for the examination aphid, every processing repeats for 3 times, every to repeat used examination borer population be 20, establishes blank simultaneously, checks dead borer population in 72h, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50Value.If the contrast lethality then is considered as invalid test greater than 10%.Computing formula is as follows:
The cotton aphid corrected mortality is converted into probit value (y), and concentration of treatment (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least squares, and calculates the value of every kind of medicament thus.Calculate co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula following (with thiophene worm piperazine is the standard medicament, and its toxicity index is 100):
TI * the P of the theoretical toxicity index (TTI) of M=thiophene worm piperazine
Thiophene worm piperazineTI * the P of+carbosulfan
Carbosulfan
In the formula: M is the mixture of different proportionings
P
CarbosulfanBe carbosulfan shared ratio in composition
P
Thiophene worm piperazineBe thiophene worm piperazine shared ratio in composition
Result of the test is as shown in table 1:
The different proportionings with carbosulfan of table 1 thiophene worm piperazine are to the toxicity test of cotton aphid
As shown in Table 1, thiophene worm piperazine and carbosulfan and composite product are to cotton aphid Toxicity Determination experiment discovery, the virulence of thiophene worm piperazine is higher than carbosulfan, co-toxicity coefficient is all greater than 120 when thiophene worm piperazine and carbosulfan proportioning are 1: 1,1: 5,1: 10,1: 15,1: 20, show obvious synergistic effect, thiophene worm piperazine thus: carbosulfan all had synergistic function between 1: 1 to 1: 20, especially when thiophene worm piperazine: during carbosulfan=1: 10, co-toxicity coefficient maximum, synergistic effect are the most obvious.
Application example two
20% thiophene worm piperazine carbosulfan wetting powder is prevented and treated the rice hoppers test of pesticide effectiveness
Thiophene worm piperazine 10%, carbosulfan 10%, polycarboxylate 2%, alkylphenol-polyethenoxy are phonetic 2%, lauryl sodium sulfate 2%, moistening bleeding agent F 2%, white carbon 32%, diatomite 40% mixture are carried out comminution by gas stream, make 20% thiophene worm piperazine carbosulfan wetting powder.This prescription is by 1000 times of dilution sprayings, and preventing and treating the rice hoppers effect in 72 hours behind the medicine is 94.74%～96.61%.25% thiophene worm piperazine water dispersible granules and 20% carbosulfan missible oil dilute 2500 times and 300 times of uses respectively according to same quadrat method, and 72 hours preventive effects are respectively 80.25% and 76.45% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example three
The 30% thiophene worm piperazine carbosulfan wetting powder control cotton aphid test of pesticide effectiveness
Thiophene worm piperazine 25%, carbosulfan 5%, alkyl benzene sulfonate calcium salt 4%, neopelex 2%, spaonin powder 4%, white carbon 30%, diatomite 30%, mixture carries out comminution by gas stream, makes 30% thiophene worm piperazine carbosulfan wetting powder.This prescription is by 1500 times of dilution sprayings, and 72 hours control cotton aphid effects are 94.52%～97.37% behind the medicine.25% thiophene worm piperazine water dispersible granules and 20% carbosulfan missible oil dilute 2500 times and 300 times of uses respectively according to same quadrat method, and 72 hours preventive effects are respectively 81.17% and 77.43% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example four
The 16% thiophene worm piperazine carbosulfan water dispersible granules control rape aphid test of pesticide effectiveness
Thiophene worm piperazine 1%, carbosulfan 15%, lignosulfonates 6%, neopelex 4%, ammonium sulfate 2%, white carbon 34%, starch 38%, the mixed 16% thiophene worm piperazine carbosulfan water dispersible granules that gets.This proportioning is by 1000 times of dilution sprayings, 72 hours control rape aphid effects are 93.84%～96.02% behind the medicine, 25% thiophene worm piperazine water dispersible granules and 20% carbosulfan missible oil are according to same quadrat method, dilute 3000 times and 250 times of uses respectively, 72 hours preventive effects are respectively 80.11% and 77.52% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example five
The 25% thiophene worm piperazine carbosulfan water dispersible granules control cotton thrips test of pesticide effectiveness
Thiophene worm piperazine 5%, carbosulfan 20%, sodium lignin sulfonate 5%, draw back powder 5%, urea 2%, white carbon 25%, starch 20%, kaolin 18%, mixed 25% thiophene worm piperazine carbosulfan water dispersible granules.This proportioning is by 1500 times of dilution sprayings, 72 hours control cotton thrips effects are 94.86%～96.63% behind the medicine, 25% thiophene worm piperazine water dispersible granules and 20% carbosulfan missible oil are according to same quadrat method, dilute 2500 times and 350 times of uses respectively, 72 hours preventive effects are respectively 80.13% and 77.41% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example six
The 45% thiophene worm piperazine carbosulfan missible oil control rape striped flea-beetle test of pesticide effectiveness
Thiophene worm piperazine 15%, carbosulfan 30%, alkylphenol polyoxyethylene class 12%, cyclohexanone 20%, pyrrolidones 15%, silicone oil 0.1%, phosphite ester 0.2%, deionized water adds to 100%, the mixed 45% thiophene worm piperazine carbosulfan missible oil that gets.This proportioning is by 1800 times of dilution sprayings, 72 hours control rape striped flea-beetle effects are 95.43%～97.12% behind the medicine, 25% thiophene worm piperazine water dispersible granules and 20% carbosulfan missible oil are according to same quadrat method, dilute 3000 times and 300 times of uses respectively, 72 hours preventive effects are respectively 82.55% and 79.74% behind the medicine.Find that in test the present composition has no adverse effects to the target crop, to beneficial insect safety.
Application example seven
The 48% thiophene worm piperazine carbosulfan aqueous emulsion control cucumber aphid test of pesticide effectiveness
Thiophene worm piperazine 8%, carbosulfan 40%, cyclohexanone 18%, toluene 13%, farming breast 400
#4%, 600
#Phosphate 4%, propane diols 4%, polyvinyl alcohol 1%, silicone oil 0.4%, deionized water supplies 100%, makes 48% thiophene worm piperazine carbosulfan aqueous emulsion.This proportioning is by 2000 times of dilution sprayings, 72 hours control cucumber aphid effects are 94.21%～97.54% behind the medicine, 25% thiophene worm piperazine water dispersible granules and 20% carbosulfan missible oil are according to same quadrat method, dilute 3000 times and 350 times of uses respectively, 72 hours preventive effects are respectively 83.45% and 80.72% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example eight
35% thiophene worm piperazine carbosulfan aqueous emulsion is prevented and treated the rice hoppers test of pesticide effectiveness
Thiophene worm piperazine 5%, carbosulfan 30%, acetonitrile 20%, N-pyrrolidones 8%, farming breast 600
#3%, the farming breast 400
#4%, ethylene glycol 4%, polyethylene glycol 1%, silicone oil 0.4%, deionized water supplies 100%, makes 35% thiophene worm piperazine carbosulfan aqueous emulsion.This proportioning is by 1500 times of dilution sprayings, preventing and treating the rice hoppers effect in 72 hours behind the medicine is 94.16%～96.72%, 25% thiophene worm piperazine water dispersible granules and 20% carbosulfan missible oil are according to same quadrat method, dilute 2500 times and 300 times of uses respectively, 72 hours preventive effects are respectively 81.53% and 79.56% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example nine
The 30% thiophene worm piperazine carbosulfan microemulsion control oranges and tangerines scale insect test of pesticide effectiveness
With thiophene worm piperazine 5%, carbosulfan 25%, N, dinethylformamide 17%, toluene 5%, ethylene glycol monomethyl ether 4%, ethyl acetate 4%, farming breast 34
#6%, triethanolamine salt 6%, ethylene glycol 2%, silicone oil 0.4%, deionized water supplies 100%, makes 30% thiophene worm piperazine carbosulfan microemulsion.This proportioning is by 1200 times of dilution sprayings, 72 hours control oranges and tangerines scale insect effects are 94.67%～96.40% behind the medicine, 25% thiophene worm piperazine water dispersible granules and 20% carbosulfan missible oil are according to same quadrat method, dilute 3000 times and 300 times of uses respectively, 72 hours preventive effects are respectively 81.47% and 79.76% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example ten
The 15% thiophene worm piperazine carbosulfan microemulsion control cotton trialeurodes vaporariorum test of pesticide effectiveness
With thiophene worm piperazine 5%, carbosulfan 10%, N-octylpyrrolidone 17%, methyl alcohol 8%, N-pyrrolidones 4%, tween 4%, farming breast 600
#3%, Nongru-700
#5%, propane diols 3%, silicone oil 0.4%, deionized water supplies 100%, makes 15% thiophene worm piperazine carbosulfan microemulsion.This proportioning is by 1000 times of dilution sprayings, 72 hours control cotton trialeurodes vaporariorum effects are 94.59%～97.34% behind the medicine, 25% thiophene worm piperazine water dispersible granules and 20% carbosulfan missible oil are according to same quadrat method, dilute 3000 times and 300 times of uses respectively, 72 hours preventive effects are respectively 80.71% and 79.35% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example 11
The 21% thiophene worm piperazine carbosulfan microcapsule suspending agent control oranges and tangerines aphid test of pesticide effectiveness
Thiophene worm piperazine 1%, carbosulfan 20%, alkyl polyoxyethylene ether 10%, sorbitan monostearate 8%, shitosan 10%, dimethylbenzene 12%, methyl alcohol 5%, deionized water are supplied 100%, 21% thiophene worm piperazine carbosulfan microcapsule suspending agent of system.This proportioning is by 1200 times of dilution sprayings, 72 hours control oranges and tangerines aphid effects are 92.83%～95.37% behind the medicine, 25% thiophene worm piperazine water dispersible granules and 20% carbosulfan missible oil are according to same quadrat method, dilute 3000 times and 300 times of uses respectively, 72 hours preventive effects are respectively 81.35% and 79.75% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example 12
The 12% thiophene worm piperazine carbosulfan microcapsule suspending agent control watermelon aphid test of pesticide effectiveness
Thiophene worm piperazine 2%, carbosulfan 10%, phenyl phenol polyoxy ethyl ether 10%, alkyl benzene calcium sulfonate 8%, gelatin 10%, acetone 12%, hexane 5%, deionized water are supplied 100%, 12% thiophene worm piperazine carbosulfan microcapsule suspending agent of system.This proportioning is by 1200 times of dilution sprayings, 72 hours control watermelon aphid effects are 92.89%～96.07% behind the medicine, 25% thiophene worm piperazine water dispersible granules and 20% carbosulfan missible oil are according to same quadrat method, dilute 3000 times and 300 times of uses respectively, 72 hours preventive effects are respectively 81.55% and 78.43% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Claims (6)
1. a Pesticidal combination that contains thiophene worm piperazine and carbosulfan comprises effective active component, auxiliary agent and filler, it is characterized in that: the percentage by weight of effective active composition thiophene worm piperazine and carbosulfan is 1～60: 80～1.
2. the Pesticidal combination that contains thiophene worm piperazine and carbosulfan according to claim 1 is characterized in that: the percentage by weight of thiophene worm piperazine and carbosulfan is 1～40: 60～5.
3. the Pesticidal combination that contains thiophene worm piperazine and carbosulfan according to claim 2 is characterized in that: the percentage by weight of thiophene worm piperazine and carbosulfan is 5～15: 40～5.
4. the Pesticidal combination that contains thiophene worm piperazine and carbosulfan according to claim 1 is characterized in that: composition is made wetting powder, water dispersible granules, microcapsule suspending agent, aqueous emulsion, microemulsion.
5. the application of Pesticidal combination on the control crop pest that contains thiophene worm piperazine and carbosulfan according to claim 1.
6. the Pesticidal combination that contains thiophene worm piperazine and carbosulfan according to claim 5 anti-ly eliminate aphis, application on the scale insect, trialeurodes vaporariorum, rice fulgorid, thrips, striped flea-beetle.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010150155 CN101874501B (en) | 2010-04-20 | 2010-04-20 | Insecticidal composition containing thiamethoxam and carbosulfan |
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|---|---|---|---|
| CN 201010150155 CN101874501B (en) | 2010-04-20 | 2010-04-20 | Insecticidal composition containing thiamethoxam and carbosulfan |
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| Publication Number | Publication Date |
|---|---|
| CN101874501A true CN101874501A (en) | 2010-11-03 |
| CN101874501B CN101874501B (en) | 2013-01-23 |
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|---|---|---|---|
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102210315A (en) * | 2011-04-29 | 2011-10-12 | 中国农业大学 | Carbosulfan microcapsule suspending agent and preparation method thereof |
| CN103109842A (en) * | 2013-01-27 | 2013-05-22 | 成都科利隆生化有限公司 | Seed treating agent with dual function of preventing diseases and pests |
| CN104663700A (en) * | 2014-12-03 | 2015-06-03 | 浙江天一农化有限公司 | Micro-capsule suspending agent containing thiamethoxam and carbosulfan and preparation method of micro-capsule suspending agent |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1220578A (en) * | 1996-04-29 | 1999-06-23 | 诺瓦蒂斯公司 | Pesticidal compositions |
| CN1451279A (en) * | 2002-12-06 | 2003-10-29 | 苏州富美实植物保护剂有限公司 | Insecticide composition contg. carbosulfan and imidecloprid |
-
2010
- 2010-04-20 CN CN 201010150155 patent/CN101874501B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1220578A (en) * | 1996-04-29 | 1999-06-23 | 诺瓦蒂斯公司 | Pesticidal compositions |
| CN1451279A (en) * | 2002-12-06 | 2003-10-29 | 苏州富美实植物保护剂有限公司 | Insecticide composition contg. carbosulfan and imidecloprid |
Non-Patent Citations (1)
| Title |
|---|
| 肖艳松 等: "吡虫啉与丁硫克百威不同配比对稻飞虱的联合毒力", 《农药研究与应用》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102210315A (en) * | 2011-04-29 | 2011-10-12 | 中国农业大学 | Carbosulfan microcapsule suspending agent and preparation method thereof |
| CN102210315B (en) * | 2011-04-29 | 2013-06-19 | 中国农业大学 | Carbosulfan microcapsule suspending agent and preparation method thereof |
| CN103109842A (en) * | 2013-01-27 | 2013-05-22 | 成都科利隆生化有限公司 | Seed treating agent with dual function of preventing diseases and pests |
| CN104663700A (en) * | 2014-12-03 | 2015-06-03 | 浙江天一农化有限公司 | Micro-capsule suspending agent containing thiamethoxam and carbosulfan and preparation method of micro-capsule suspending agent |
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| CN101874501B (en) | 2013-01-23 |
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Address after: 715500 Shaanxi Pucheng County agricultural base industrial park Patentee after: Shaanxi Meibang pesticide Co.,Ltd. Address before: 710075, Xi'an high tech Zone, Shaanxi hi tech Zone, Jinqiao International C block, 15 Floor Patentee before: Shaanxi Meibang pesticide Co.,Ltd. |
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Address after: 715500 Pucheng high tech Industrial Development Zone, Weinan, Shaanxi Patentee after: SHAANXI MEIBANG PHARMACEUTICAL GROUP Co.,Ltd. Address before: 715500 Industrial Park of Agrochemical Base in Pucheng County, Shaanxi Province Patentee before: Shaanxi Meibang pesticide Co.,Ltd. |
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Granted publication date: 20130123 |