CN101457490A - Deep color coating dyeing method for all-cotton yarn card fabric - Google Patents
Deep color coating dyeing method for all-cotton yarn card fabric Download PDFInfo
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- CN101457490A CN101457490A CNA2008102427275A CN200810242727A CN101457490A CN 101457490 A CN101457490 A CN 101457490A CN A2008102427275 A CNA2008102427275 A CN A2008102427275A CN 200810242727 A CN200810242727 A CN 200810242727A CN 101457490 A CN101457490 A CN 101457490A
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- deep color
- dyeing method
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- 238000004043 dyeing Methods 0.000 title claims abstract description 61
- 238000000034 method Methods 0.000 title claims abstract description 52
- 239000004744 fabric Substances 0.000 title claims abstract description 43
- 229920000742 Cotton Polymers 0.000 title claims abstract description 26
- 238000009500 colour coating Methods 0.000 title claims abstract description 16
- 239000000049 pigment Substances 0.000 claims abstract description 27
- 230000008569 process Effects 0.000 claims abstract description 17
- 239000000835 fiber Substances 0.000 claims abstract description 11
- 150000001768 cations Chemical class 0.000 claims abstract description 6
- 239000011248 coating agent Substances 0.000 claims description 13
- 238000000576 coating method Methods 0.000 claims description 13
- 241001584775 Tunga penetrans Species 0.000 claims description 9
- 239000000853 adhesive Substances 0.000 claims description 9
- 230000001070 adhesive effect Effects 0.000 claims description 9
- 239000003607 modifier Substances 0.000 claims description 7
- 238000010186 staining Methods 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 7
- 102000004190 Enzymes Human genes 0.000 claims description 3
- 108090000790 Enzymes Proteins 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 230000001105 regulatory effect Effects 0.000 claims description 3
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 claims description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
- 229920006243 acrylic copolymer Polymers 0.000 claims description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical group CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 2
- 239000007859 condensation product Substances 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 claims description 2
- 230000008595 infiltration Effects 0.000 claims description 2
- 238000001764 infiltration Methods 0.000 claims description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 2
- 238000012805 post-processing Methods 0.000 claims description 2
- 238000002203 pretreatment Methods 0.000 claims description 2
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- 238000007493 shaping process Methods 0.000 claims description 2
- 150000003512 tertiary amines Chemical class 0.000 claims description 2
- 238000012545 processing Methods 0.000 abstract description 13
- 238000007639 printing Methods 0.000 abstract description 10
- 239000000126 substance Substances 0.000 abstract description 10
- 238000012986 modification Methods 0.000 abstract description 6
- 230000004048 modification Effects 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 2
- 238000009979 jig dyeing Methods 0.000 abstract 2
- 239000003973 paint Substances 0.000 abstract 1
- 238000004045 reactive dyeing Methods 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 14
- 239000000654 additive Substances 0.000 description 7
- 230000000996 additive effect Effects 0.000 description 7
- 239000000985 reactive dye Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- PLXMOAALOJOTIY-FPTXNFDTSA-N Aesculin Natural products OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)[C@H]1Oc2cc3C=CC(=O)Oc3cc2O PLXMOAALOJOTIY-FPTXNFDTSA-N 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000012362 glacial acetic acid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 238000007634 remodeling Methods 0.000 description 2
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 238000009980 pad dyeing Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
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Abstract
The invention discloses a deep color coating dyeing method for all-cotton yarn card fabric, which sequentially comprises the following steps: a pretreatment process; (b) a cation modification step; (c) a reactive dyeing process; (d) a pigment dyeing process; (e) a color fixing procedure; (f) and (5) post-treatment working procedure. Wherein the devices used in the cation modification process, the paint dyeing process and the color fixing process are open-width jig dyeing machines. The method is simple and convenient, easy to process and good in effect, and can be used for pigment dyeing of all-cotton fabrics by traditional chemical fiber printing and dyeing enterprises by using the existing equipment without changing the existing equipment, so that the product line is expanded; the method can be popularized in printing and dyeing enterprises which take chemical fiber fabrics as main processing objects and a jig dyeing machine as processing equipment so as to adapt to the current trends of small orders, multiple color samples and short production period; and the process is flexible, and different styles can be processed according to the requirements of customers.
Description
Technical field
The present invention relates to a kind of textile printing and dyeing field, especially relate to a kind of deep color coating dyeing method of all cotton yarn fabric.
Background technology
Coating all is to be widely used on stamp for a long time, and in recent years, owing to improving constantly of coating and printing and dyeing assistant performance, pigment dyeing technique had also grown up fast.Coating does not have affinity and reactivity to fiber, does not possess the condition that fabric is dyed on directly.And in cellulosic fibre materials such as cotton, contain hydroxyl, and have only and fabric is carried out chemical graft earlier handle, make the fiber after the chemical modification have affinity and reactivity to organic pigment, make the fabric after the pigment dyeing have certain COLOR FASTNESS.
Pigment dyeing has that Dry Sack is bright-coloured, chromatogram is complete, technological process is short, easy to operate, applied widely, processing cost is low, advantage such as low in the pollution of the environment, in dyeing and finishing processing, increasing application is arranged, though pigment dyeing has very big superiority, but, the reason of coating self structure can only dye shallow, middle look because causing the fabric of pigment dyeing to be faced with, the shortcoming of crock fastness difference has limited its fast development.
Patent of invention about the pigment dyeing aspect has had much now, general direction emphatically all is short flow process, environmental protection etc., or adopts the mode of long vehicle pad dyeing to process, but as traditional chemical fibre printing and dyeing enterprise, the production emphasis is a chemical ﹠ blended fabric, based on Batch Process equipment; And current order is tending towards little order, many chromatographys, uses intermittently that equipment processing has flexibly, advantage fast.
So, be necessary to solve the technological process problem of dye jigger pigment dyeing, and the coating deep colour dyeing problem of improving highly dense yarn card fabric, utilize existing equipment to carry out the demand of the pigment dyeing of all-cotton fabric to adapt to traditional chemical fibre printing and dyeing enterprise.
Summary of the invention
The objective of the invention is: a kind of deep color coating dyeing method of all cotton yarn fabric is provided, simple and convenient, the easy processing of this method, effective, need not to change existing equipment, just can make traditional chemical fibre printing and dyeing enterprise utilize existing equipment to carry out the pigment dyeing of all-cotton fabric, expanded product line; Can be that main processing object, dye jigger are that the printing and dyeing enterprise of process equipment is promoted with chemical ﹠ blended fabric, to adapt to current little order, polychrome sample, trend with short production cycle; And technology is flexible, can require the processing different-style according to client's sample.
Technical scheme of the present invention is: a kind of deep color coating dyeing method of all cotton yarn fabric, and this method comprises by following steps successively and forming:
(a) pretreatment procedure; (b) cation-modified operation; (c) vital staining operation; (d) pigment dyeing operation; (e) fixation operation; (f) postprocessing working procedures.
Described pretreatment procedure adopts cold dome to add the mode of freshening, and cold dome is wanted fully, and freshening needs kiering even, well-done, makes fiber fluffy help the infiltration of coating, pre-treatment after washing.
Described cation-modified operation, pigment dyeing operation, fixation operation institute use equipment to be the open width dye jigger.
The cation modifier that described cation-modified operation adopted is that main component is the condensation product of tertiary amine and epoxychloropropane, and molecular formula is as follows:
Cloudy lotus dyestuff is deepened, also can be made on the coating and dye, reduce adhesive consumption.
The cation modifier consumption is 5% (o.w.f) in the described cation-modified operation, and regulating pH value is 9~9.5, and bath raio is 1:20, and 70~75 ℃ are incubated 30 minutes.
Described vital staining operation bakes at the high-temperature shaping machine after padding machine pads.
Described pigment dyeing operation adopts dye jigger processing, suitably adds adhesive and makes coating anchor at fabric face.
The adhesive that described fixation operation is used is that main component is butyl acrylate, methyl methacrylate, fine, the acrylic copolymer of propylene, is the low form pigment dyeing adhesive specially of emulsifying agent with the propenyl polyoxyethylene ether.
In addition, to sample, not to the needs additive color, available active additive color need not the coating additive color as the sample look before fixation, and additive color is finished and got final product fixation after coloured light is aimed at.
After finishing, described fixation operation also can use cellulose ferment enzyme treatment process as required, to satisfy the needs of different Fabric Style.
Described fabric is a specification greater than 68 * 68 all cotton yarn fabric.
Further describing of technical solution of the present invention is: the fabric pretreatment after washing, modification in dye jigger then, wherein the modifier consumption is 5% (o.w.f), regulating pH value is 9~9.5; bath raio is 1:20, and 70~75 ℃ are incubated 30 minutes, and speed wants slow in the time of modification thinner material; slowly add in batches, heats up and tries one's best slowly; Go up REACTIVE DYES then, baked 2~3 minutes after crossing the setting machine padding machine, the padding machine pick-up is 60%, pigment dyeing then, its prescription consists of coating, pigment dyeing deep-dyeing agent DF (20g/L), dyeing back oven dry, pad then adhesive PD (20~30g/L), hexahydroxide resin (5~10g/L) solution, oven dry in 160 ℃ * 5 minutes, as the need additive color, can go up activity once more, can use cellulose ferment enzyme to handle subsequently, can obtain washing, do styles such as old according to client's sample style.
The present invention has following advantage compared to existing technology:
1. deep color coating dyeing method of all cotton yarn fabric of the present invention, simple and convenient, the easy processing of method, effective need not change equipment, can make traditional chemical fibre printing and dyeing enterprise utilize existing equipment to carry out the pigment dyeing of all-cotton fabric, has expanded product line.Can be that main processing object, dye jigger are that the printing and dyeing enterprise of process equipment is promoted with chemical ﹠ blended fabric, to adapt to current little order, polychrome sample, trend with short production cycle.
2. deep color coating dyeing method of all cotton yarn fabric of the present invention, technology is flexible, can require the processing different-style according to client's sample.
The specific embodiment
Embodiment one:
Grey cloth: all cotton yarn; Specification: 21 x, 21/108 x 58; Color: dark brown
Step: cold wash after the fabric pretreatment, REACTIVE DYES is gone up in modification in dye jigger then then, bake after crossing the setting machine padding machine, pigment dyeing then, the dyeing back with the REACTIVE DYES additive color to sample being aimed at fixation.
The modified technique prescription:
Modifier L | 10%(o.w.f) |
Glacial acetic acid | Regulate PH=9~9.5 |
Bath raio | 1:20 |
Holding temperature: | 70~75℃ |
Temperature retention time | 30min |
Heating rate | 5 ℃ of per pass |
The vital staining technical recipe:
The B black | 0.95(o.w.f) |
The 3RS Huang | 2.2(o.w.f) |
3BS is red | 1.48(o.w.f) |
The baking temperature pick-up | 160℃ 60% |
Bake the time | 3min |
The pigment dyeing technique prescription:
Coating | 3.625g/L |
Adhesive PD | 30g/L |
Hexahydroxide resin | 5g/L |
Pigment dyeing deep-dyeing agent DF | 20g/L |
Dyeing temperature | 70℃ |
Temperature retention time | 6 roads |
Heating rate | 5 ℃ of per pass |
Embodiment two:
Grey cloth: all cotton yarn; Specification: 40 x, 40/133 x 72; Color: dark blue
Step: cold wash after the fabric pretreatment, REACTIVE DYES is gone up in modification in dye jigger then then, bake after crossing the setting machine padding machine, pigment dyeing then, the dyeing back with the REACTIVE DYES additive color to sample being aimed at fixation.
The modified technique prescription:
Modifier L | 10%(o.w.f) |
Glacial acetic acid | Regulate PH=9~9.5 |
Bath raio | 1:20 |
Holding temperature: | 70~75℃ |
Temperature retention time | 30min |
Heating rate | 5 ℃ of per pass |
The vital staining technical recipe:
BED is black | 1.26(o.w.f) |
The B black | 2.1(o.w.f) |
3BS is red | 0.35(o.w.f) |
The baking temperature pick-up | 160℃ 60% |
Bake the time | 4min |
The pigment dyeing technique prescription
Coating | 2.65g/L |
Adhesive PD | 30g/L |
Hexahydroxide resin | 5g/L |
Pigment dyeing deep-dyeing agent DF | 20g/L |
Dyeing temperature | 70℃ |
Temperature retention time | 6 roads |
Heating rate | 5 ℃ of per pass |
Test result:
Test the doing of finished product fabric that above two kinds of prescriptions process, wet friction, Washing, the water-fast COLOR FASTNESS of washing adopts GB/T 3921.1 national standards test (with the variable color of gray scale evaluation sample and the staining of adjacent fabric), do the wet friction COLOR FASTNESS and adopt the test of GB/T 3920 national standards, the result is as follows:
Can find out that from above test result water-fast the washing with colorfastness to rubbing of all cotton yarn fabric through the present invention's processing all can be up to state standards.
Should be pointed out that for the present invention also to have the embodiment of multiple conversion and remodeling, be not limited to the specific embodiment of above-mentioned embodiment through proving absolutely.The foregoing description is as just explanation of the present invention, rather than limitation of the present invention.In a word, protection scope of the present invention should comprise those conspicuous to those skilled in the art conversion or substitute and remodeling.
Claims (8)
1. a deep color coating dyeing method of all cotton yarn fabric is characterized in that, this method comprises by following steps successively and forming:
(a) pretreatment procedure; (b) cation-modified operation; (c) vital staining operation; (d) pigment dyeing operation; (e) fixation operation; (f) postprocessing working procedures;
Described cation-modified operation, pigment dyeing operation, fixation operation institute use equipment to be the open width dye jigger.
2. deep color coating dyeing method of all cotton yarn fabric according to claim 1, it is characterized in that: described pretreatment procedure adopts cold dome to add the mode of freshening, and cold dome is wanted fully, and freshening needs kiering even, well-done, make fiber fluffy help the infiltration of coating, pre-treatment after washing.
3. deep color coating dyeing method of all cotton yarn fabric according to claim 1 is characterized in that: the cation modifier that described cation-modified operation adopted is that main component is the condensation product of tertiary amine and epoxychloropropane.
4. deep color coating dyeing method of all cotton yarn fabric according to claim 3, it is characterized in that: the cation modifier consumption is 5% (o.w.f) in the described cation-modified operation, regulating pH value is 9~9.5, and bath raio is 1:20, and 70~75 ℃ are incubated 30 minutes.
5. deep color coating dyeing method of all cotton yarn fabric according to claim 1 is characterized in that: described vital staining operation bakes at the high-temperature shaping machine after padding machine pads.
6. deep color coating dyeing method of all cotton yarn fabric according to claim 1, it is characterized in that: the adhesive that described fixation operation is used is that main component is butyl acrylate, methyl methacrylate, fine, the acrylic copolymer of propylene, is the low form pigment dyeing adhesive specially of emulsifying agent with the propenyl polyoxyethylene ether.
7. deep color coating dyeing method of all cotton yarn fabric according to claim 1 is characterized in that: also comprise after described fixation operation is finished and use cellulose ferment enzyme treatment process.
8. deep color coating dyeing method of all cotton yarn fabric according to claim 1 is characterized in that: described fabric is a specification greater than 68 * 68 all cotton yarn fabric.
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CNA2008102427275A CN101457490A (en) | 2008-12-26 | 2008-12-26 | Deep color coating dyeing method for all-cotton yarn card fabric |
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CNA2008102427275A CN101457490A (en) | 2008-12-26 | 2008-12-26 | Deep color coating dyeing method for all-cotton yarn card fabric |
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Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101864668A (en) * | 2010-06-18 | 2010-10-20 | 上海工程技术大学 | Modifier for improving dye-uptake of kawokawofibers, preparation method thereof and use thereof |
CN101994249A (en) * | 2010-10-18 | 2011-03-30 | 武汉纺织大学 | Pigment dyeing method for loose cotton fiber |
CN102383302A (en) * | 2011-08-29 | 2012-03-21 | 江苏金辰针纺织有限公司 | Environment-friendly paint dyeing method |
CN102392343A (en) * | 2011-06-24 | 2012-03-28 | 南通大学 | Pretreatment and bath-treatment method for modifying cotton fabrics |
CN101748602B (en) * | 2009-12-14 | 2012-06-13 | 嵊州盛泰色织科技有限公司 | Archaizing processing method of piece-dyeing fabric |
CN102605649A (en) * | 2012-03-15 | 2012-07-25 | 常州大学 | Pigment dyeing method of denim yarn |
CN102851962A (en) * | 2012-09-06 | 2013-01-02 | 青岛大学 | Method for carrying out cationic modification upon cotton fabric by using paint dyeing wastewater |
CN103173994A (en) * | 2011-06-24 | 2013-06-26 | 南通大学 | Co-bath treatment method for modification pretreatment of fabric |
CN103173995A (en) * | 2011-06-24 | 2013-06-26 | 南通大学 | Co-bath treatment method with simple process for modification pretreatment of cotton fabric |
CN103556497A (en) * | 2013-10-15 | 2014-02-05 | 山东岱银纺织集团股份有限公司 | Dyeing method for multilevel-color jean yarns |
CN103774460A (en) * | 2013-12-23 | 2014-05-07 | 武汉纺织大学 | Method for improving dyeing depth of cotton fiber aggregate pigment |
CN105274752A (en) * | 2015-10-22 | 2016-01-27 | 宁波大千纺织品有限公司 | Method for preparing imitation jean snowflake nostalgic fabric |
CN105951417A (en) * | 2016-05-07 | 2016-09-21 | 鲁泰纺织股份有限公司 | Dyeing method of bleached cellulose fiber clothes |
CN106758316A (en) * | 2016-12-08 | 2017-05-31 | 武汉纺织大学 | A kind of cowboy's warp thread coating dyeing method |
CN108914544A (en) * | 2018-07-20 | 2018-11-30 | 启东市新利来制衣有限公司 | A kind of fabric water-proof treatment technology of the washing containing bluish dogbane and cotton fiber |
CN108951205A (en) * | 2018-07-20 | 2018-12-07 | 石狮市聚祥漂染有限公司 | A kind of making fabric three-dimensional sense good dyeing, which is washed, takes off method |
CN109235061A (en) * | 2018-07-06 | 2019-01-18 | 新天龙集团有限公司 | The more pattern cotton figured cloth metals of single side material infect color forming method |
CN110055776A (en) * | 2019-05-20 | 2019-07-26 | 上海帛阳纺织科技有限公司 | A kind of dyeing fabric method of energy-saving and emission-reduction |
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2008
- 2008-12-26 CN CNA2008102427275A patent/CN101457490A/en active Pending
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CN101864668A (en) * | 2010-06-18 | 2010-10-20 | 上海工程技术大学 | Modifier for improving dye-uptake of kawokawofibers, preparation method thereof and use thereof |
CN101864668B (en) * | 2010-06-18 | 2012-05-30 | 上海工程技术大学 | Modifier for improving dyeing rate of kapok fiber and preparation method and application thereof |
CN101994249B (en) * | 2010-10-18 | 2012-06-06 | 武汉纺织大学 | Pigment dyeing method for loose cotton fiber |
CN101994249A (en) * | 2010-10-18 | 2011-03-30 | 武汉纺织大学 | Pigment dyeing method for loose cotton fiber |
CN103173995A (en) * | 2011-06-24 | 2013-06-26 | 南通大学 | Co-bath treatment method with simple process for modification pretreatment of cotton fabric |
CN102392343A (en) * | 2011-06-24 | 2012-03-28 | 南通大学 | Pretreatment and bath-treatment method for modifying cotton fabrics |
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CN102383302B (en) * | 2011-08-29 | 2013-08-07 | 江苏金辰针纺织有限公司 | Environment-friendly paint dyeing method |
CN102383302A (en) * | 2011-08-29 | 2012-03-21 | 江苏金辰针纺织有限公司 | Environment-friendly paint dyeing method |
CN102605649A (en) * | 2012-03-15 | 2012-07-25 | 常州大学 | Pigment dyeing method of denim yarn |
CN102851962B (en) * | 2012-09-06 | 2014-12-10 | 青岛大学 | Method for carrying out cationic modification upon cotton fabric by using paint dyeing wastewater |
CN102851962A (en) * | 2012-09-06 | 2013-01-02 | 青岛大学 | Method for carrying out cationic modification upon cotton fabric by using paint dyeing wastewater |
CN103556497A (en) * | 2013-10-15 | 2014-02-05 | 山东岱银纺织集团股份有限公司 | Dyeing method for multilevel-color jean yarns |
CN103774460A (en) * | 2013-12-23 | 2014-05-07 | 武汉纺织大学 | Method for improving dyeing depth of cotton fiber aggregate pigment |
CN105274752A (en) * | 2015-10-22 | 2016-01-27 | 宁波大千纺织品有限公司 | Method for preparing imitation jean snowflake nostalgic fabric |
CN105951417A (en) * | 2016-05-07 | 2016-09-21 | 鲁泰纺织股份有限公司 | Dyeing method of bleached cellulose fiber clothes |
CN106758316A (en) * | 2016-12-08 | 2017-05-31 | 武汉纺织大学 | A kind of cowboy's warp thread coating dyeing method |
CN109235061A (en) * | 2018-07-06 | 2019-01-18 | 新天龙集团有限公司 | The more pattern cotton figured cloth metals of single side material infect color forming method |
CN108914544A (en) * | 2018-07-20 | 2018-11-30 | 启东市新利来制衣有限公司 | A kind of fabric water-proof treatment technology of the washing containing bluish dogbane and cotton fiber |
CN108951205A (en) * | 2018-07-20 | 2018-12-07 | 石狮市聚祥漂染有限公司 | A kind of making fabric three-dimensional sense good dyeing, which is washed, takes off method |
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