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CN108437589A - A kind of good fabric of curtain anti-microbial property - Google Patents

A kind of good fabric of curtain anti-microbial property Download PDF

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Publication number
CN108437589A
CN108437589A CN201810138544.2A CN201810138544A CN108437589A CN 108437589 A CN108437589 A CN 108437589A CN 201810138544 A CN201810138544 A CN 201810138544A CN 108437589 A CN108437589 A CN 108437589A
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CN
China
Prior art keywords
antiseptic
precoat
fibre
zno
microbial property
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810138544.2A
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Chinese (zh)
Inventor
韦德远
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuzhou Well Trading Co Ltd
Original Assignee
Wuzhou Well Trading Co Ltd
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Filing date
Publication date
Application filed by Wuzhou Well Trading Co Ltd filed Critical Wuzhou Well Trading Co Ltd
Priority to CN201810138544.2A priority Critical patent/CN108437589A/en
Publication of CN108437589A publication Critical patent/CN108437589A/en
Pending legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/06—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by a fibrous or filamentary layer mechanically connected, e.g. by needling to another layer, e.g. of fibres, of paper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/047—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material made of fibres or filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D01F1/103—Agents inhibiting growth of microorganisms
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/20—All layers being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0223—Vinyl resin fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0253—Polyolefin fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0261—Polyamide fibres
    • B32B2262/0269—Aromatic polyamide fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0276—Polyester fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0276—Polyester fibres
    • B32B2262/0284—Polyethylene terephthalate [PET] or polybutylene terephthalate [PBT]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/21—Anti-static
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/212—Electromagnetic interference shielding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The present invention relates to a kind of good fabrics of curtain anti-microbial property, including the first precoat, the second precoat, third precoat and the fourth face bed of material being arranged from top to bottom, first precoat is formed by polyester fiber and polyphenylsulfone nylon blending woven, second precoat is formed by polyimide fiber and vinylon fibre blending woven, the third precoat is formed by polyaniline conductive dacron fibre and polypropylene fibre blending woven, and the fourth face bed of material is formed by apocynum fibre and banana fiber blending woven；Polyester fiber described in first precoat is a kind of antibacterial polyester fibre, and forming process is：Antiseptic I, antiseptic II are prepared first, is mixed to form antimicrobial mix, is then blended with antimicrobial mix using pure PET slices, prepare antibacterial modified PET slices, then antibacterial polyester fibre is obtained by melt spinning mode；Include according to weight percent：I 0.5~0.7wt.% of antiseptic, II 0.9~1.1wt.% of antiseptic, polyester fiber surplus.

Description

A kind of good fabric of curtain anti-microbial property
Technical field
The present invention relates to window curtain fabric technical field more particularly to a kind of good fabrics of curtain anti-microbial property.
Background technology
With the continuous development of science and technology, the textile fiber for meeting people's difference needs emerges one after another, and is disappeared with meeting The demand of the person of expense plays increasingly important role in daily life.
With the continuous development of industry, the market of fiber is also constantly expanding, but all effect is more single mostly for fiber, Manufactured fabric does not have other functions substantially other than wearing beauty, and the practicability of fabric is caused to substantially reduce.
Invention content
The present invention is intended to provide a kind of good fabric of curtain anti-microbial property, set forth above to solve the problems, such as.
A kind of good fabric of curtain anti-microbial property is provided in the embodiment of the present invention, including be arranged from top to bottom First precoat, the second precoat, third precoat and the fourth face bed of material, first precoat is by polyester fiber and polyphenyl Sulfonamide fiber blend weaves, and second precoat is formed by polyimide fiber and vinylon fibre blending woven, institute It states third precoat to be formed by polyaniline conductive dacron fibre and polypropylene fibre blending woven, the fourth face bed of material is by spreading out Flaxen fiber and banana fiber blending woven form；
Polyester fiber described in first precoat is a kind of antibacterial polyester fibre, and forming process is：It prepares first anti- Microbial inoculum I, antiseptic II, are mixed to form antimicrobial mix, are then blended, are prepared with antimicrobial mix using pure PET slices Antibacterial modified PET slices, then antibacterial polyester fibre is obtained by melt spinning mode；Include according to weight percent：Antiseptic I 0.5~0.7wt.%, II 0.9~1.1wt.% of antiseptic, polyester fiber surplus.
The technical solution that the embodiment of the present invention provides can include the following benefits：
The present invention is combined using multilayered structure, with intensity is high, heat-resisting quantity is good, anti-radiation performance is good, static electricity resistance Feature good, drapability is good.
The additional aspect of the present invention and advantage will be set forth in part in the description, and will partly become from the following description Obviously, or practice through the invention is recognized.It should be understood that above general description and following detailed description are only It is exemplary and explanatory, the present invention can not be limited.
Description of the drawings
Using attached drawing, the invention will be further described, but the embodiment in attached drawing does not constitute any limit to the present invention System, for those of ordinary skill in the art, without creative efforts, can also obtain according to the following drawings Other attached drawings.
Fig. 1 is the structural schematic diagram of fabric described in embodiment of the present invention.
Specific implementation mode
Example embodiments are described in detail here, and the example is illustrated in the accompanying drawings.Following description is related to When attached drawing, unless otherwise indicated, the same numbers in different drawings indicate the same or similar elements.Following exemplary embodiment Described in embodiment do not represent and the consistent all embodiments of the present invention.On the contrary, they be only with it is such as appended The example of the consistent device and method of some aspects being described in detail in claims, of the invention.
The embodiment of the present invention is related to a kind of good fabric of curtain anti-microbial property, in conjunction with Fig. 1, including sets from top to bottom The first precoat 1, the second precoat 2, third precoat 3 and the fourth face bed of material 4 set, first precoat 1 is by polyester Fiber and polyphenylsulfone nylon blending woven form, and second precoat 2 is blended by polyimide fiber and vinylon fibre It weaving, the third precoat 3 is formed by polyaniline conductive dacron fibre and polypropylene fibre blending woven, and the described 4th Precoat 4 is formed by apocynum fibre and banana fiber blending woven.
Parts by weight shared by each ingredient are respectively in first precoat 1：The polyester fiber accounts for 46 parts, the polyphenyl Sulfonamide fiber accounts for 23 parts；
Parts by weight shared by 2 each ingredients are respectively in second precoat：The polyimide fiber accounts for 51 parts, described Vinylon fibre accounts for 33 parts；
Parts by weight shared by 3 each ingredients are respectively in the third precoat：The polyaniline conductive dacron fibre accounts for 11 Part, the polypropylene fibre accounts for 61 parts；
Parts by weight shared by each ingredient are respectively in the fourth face bed of material 4：The apocynum fibre accounts for 47 parts, the perfume (or spice) Any of several broadleaf plants fasciated fiber accounts for 47 parts.
In a preferred embodiment of the present invention, first precoat 1, the second precoat 2, third precoat 3 and The fourth face bed of material 4 is linked together using the method for sewing.
The present invention is combined using multilayered structure, with intensity is high, heat-resisting quantity is good, anti-radiation performance is good, static electricity resistance Feature good, drapability is good.
A kind of embodiment is that the polyester fiber described in the first precoat 1 is a kind of antibacterial polyester fibre, is formed Cheng Wei：Antiseptic I, antiseptic II are prepared first, is mixed to form antimicrobial mix, then using pure PET slices and antiseptic Mixture is blended, and prepares antibacterial modified PET slices, then obtain antibacterial polyester fibre by melt spinning mode.
Inorganic antiseptic is broadly divided into two types：Metal ion type and oxide type；In addition, Nano grade is inorganic anti- Microbial inoculum has better antibacterial effect since particle specific surface area increase can preferably adsorb microorganism.Anti-biotic material Refer to by adding a small amount of chemical substance so that a kind of functional material of the material with anti-microbial property, anti-biotic material include Natural antibacterial agent, organic antibacterial agent, inorganic antiseptic.Wherein, inorganic antiseptic have inorganic constituents stability, antibacterial wide spectrum, The advantages that chemical stability is good, washing fastness is good, durable antibacterial effect, good thermal stability.For the special-purpose of polyester fiber, Inorganic antibacterial dosage form polyester fiber has become the research emphasis of polyester fiber.Based on background as above, in technical solution of the present invention, By being modified to antiseptic, antiseptic is blended with PET slices, then remelted spinning obtains antibacterial polyester fibre.Its In, on the one hand, use the shortcomings that dual anti-microbial inoculum is blended with PET slices, can effectively make up single antiseptic, two kinds of antiseptics In conjunction with playing a role, unexpected technique effect is played so that antibiotic property, the washability of antibacterial polyester fibre obtain substantially It improves.
Specifically, which is nanometer Fe-ZnO antiseptics, which is Ni-ZnO antiseptics；It is above-mentioned anti- In bacterium polyester fiber, include according to weight percent：
I 0.5~0.7wt.% of antiseptic,
II 0.9~1.1wt.% of antiseptic,
Polyester fiber surplus.By controlling the percentage of antiseptic, anti-microbial property can be maximumlly played.
Wherein, which is the nanometer Fe-ZnO antiseptics prepared using agglutinating nature yeast；The nanometer Fe-ZnO is anti- Microbial inoculum shows as nano-particle, grain size 600nm, wherein Fe is 3 with ZnO molar ratios:10.Nano zine oxide is a kind of important Inorganic antiseptic, have many advantages, such as higher thermal stability, do not decompose；The energy gap of zinc oxide and titanium dioxide phase Closely, while also there is higher bactericidal properties, photocatalytic activity, but due to being limited by energy gap, it is general only ultraviolet Just there is catalytic activity under illumination, ultraviolet light content is relatively low in natural light, limits utilization rate of the zinc oxide to solar radiation, To constrain its practical application in antibacterial.In technical solution of the present invention, creative is made using Fe-ZnO nano-particles Addition for antiseptic, Fe enables to antiseptic for visible wavelength range influx and translocation, and anti-microbial property enhancing achieves Unexpected technique effect.
The part material for preparing the antiseptic I is as follows：
The preparation process of above-mentioned antiseptic I is：0.1M zinc nitrates and the ferric nitrate of 0.03M are weighed respectively, are dissolved in 200ml distilled water, then magnetic agitation is to transparent；Add citric acid, magnetic agitation to abundant dissolving, wherein so that nitric acid The molar ratio of zinc and citric acid is 1:1.5；Add ammonium hydroxide (30wt.%) with constant pressure titration dripping, pH=8 is adjusted, in 86 DEG C of perseverances Tepidarium evaporable water forms wet gel, then it is dry solidifying to obtain Fe-ZnO for 24 hours up to constant weight for drying in 80 DEG C of vacuum drying chambers Glue；1h will be calcined at xerogel in air 540 DEG C, cooled to room temperature obtains antiseptic I, i.e. nanometer Fe-ZnO antibacterials Agent.
Wherein, which is the Ni nanoparticle-ZnO antiseptics prepared using agglutinating nature yeast, and the Ni nanoparticle-ZnO is anti- Microbial inoculum shows as nano-particle, grain size 550nm, wherein Ni is 7 with ZnO molar ratios:10.In technical solution of the present invention, create Property be used as antiseptic, the addition of Ni to enable to antiseptic for visible wavelength range absorption using Ni-ZnO nano-particles Enhancing, anti-microbial property enhancing, achieves unexpected technique effect.
The part material for preparing the antiseptic II is as follows：
The preparation process of above-mentioned antiseptic II is：0.1M zinc nitrates and the nickel nitrate of 0.07M are weighed respectively, are dissolved in 200ml distilled water, then magnetic agitation is to transparent；Add citric acid, magnetic agitation to abundant dissolving, wherein so that nitric acid The molar ratio of zinc and citric acid is 1:1.1；Add ammonium hydroxide (30wt.%) with constant pressure titration dripping, pH=7.6 is adjusted, at 95 DEG C Water bath with thermostatic control evaporable water forms wet gel, then it is dry solidifying to obtain Ni-ZnO for 24 hours up to constant weight for drying in 80 DEG C of vacuum drying chambers Glue；1h will be calcined at xerogel in air 480 DEG C, cooled to room temperature obtains antiseptic II, i.e. Ni nanoparticle-ZnO antibacterials Agent.
After antiseptic I, antiseptic II is prepared, antiseptic is mixed：By above-mentioned antiseptic I, antiseptic II according to matter Amount ratio is 0.5~0.7：0.9~1.1 mixing, grinds 5h, obtains mixture E, mixture E, which is then put into mass fraction, is In 1.2% oxalic acid solution, filtrate is calcined 3h by acidification 2h, filtering, cleaning in nitrogen after dry at 585 DEG C, After cooling, 3h is ground, antimicrobial mix is obtained.In technical solution of the present invention, by mixing antiseptic I and antiseptic II, Acidification, calcination processing so that antiseptic I, antiseptic II can be adulterated mutually, play unexpected technique effect so that The anti-microbial property of polyester fiber greatly increases.
Then antibacterial polyester fibre is prepared using blending method：Above-mentioned antimicrobial mix and ethylene glycol are mixed, after stirring Ultrasound 5h at room temperature, obtains mixed liquor；Then mixed liquor and p-phthalic acid, catalyst aid are esterified, polymerize, obtains To polyester master particle；Wherein, esterification temperature is 280 DEG C, pressure 400KPa, and it is anti-that polycondensation is carried out when esterification yield reaches more than 94.5% It answers, condensation temperature is 300 DEG C, is evacuated to 50Mpa, when polycondensation to inherent viscosity is 0.65, discharging, blank；Then, by polyester Master batch melts, and is then fed into filter and is filtered, after metering, into spinning pack, by the tow of ejection carry out it is cooling, It oils, preoriented yarn is wound into after deflector roll, wherein spinning temperature is 290 DEG C, spinning speed 3200m/min；Then, gather Ester preoriented yarn can be prepared into antibacterial polyester fibre after a roller, hot tank, two rollers, scroll tube, winding, wherein draft speed is 570m/min, draw ratio 3.1, a roll temperature are 90 DEG C, and two roll temperatures are 140 DEG C.
Embodiment 1
In the present embodiment, a kind of antibacterial polyester fibre prepares antiseptic I, antiseptic II first, and it is mixed to be mixed to form antiseptic Object is closed, is then blended with antimicrobial mix using pure PET slices, prepares antibacterial modified PET slices, then pass through melt spinning side Formula obtains antibacterial polyester fibre.
In above-mentioned antibacterial polyester fibre, include according to weight percent：I 0.5wt.% of antiseptic, antiseptic II 0.9wt.%, polyester fiber surplus.
Wherein, antiseptic I is the nanometer Fe-ZnO antiseptics prepared using agglutinating nature yeast；The nanometer Fe-ZnO antibacterials Agent shows as nano-particle, grain size 600nm, wherein Fe is 3 with ZnO molar ratios:10.
The antiseptic II is the Ni nanoparticle-ZnO antiseptics prepared using agglutinating nature yeast, the Ni nanoparticle-ZnO antiseptics Show as nano-particle, grain size 550nm, wherein Ni is 7 with ZnO molar ratios:10.
Embodiment 2
In the present embodiment, a kind of antibacterial polyester fibre prepares antiseptic I, antiseptic II first, and it is mixed to be mixed to form antiseptic Object is closed, is then blended with antimicrobial mix using pure PET slices, prepares antibacterial modified PET slices, then pass through melt spinning side Formula obtains antibacterial polyester fibre.
In above-mentioned antibacterial polyester fibre, include according to weight percent：I 0.6wt.% of antiseptic, antiseptic II 1.0wt.%, polyester fiber surplus.
Wherein, antiseptic I is the nanometer Fe-ZnO antiseptics prepared using agglutinating nature yeast；The nanometer Fe-ZnO antibacterials Agent shows as nano-particle, grain size 600nm, wherein Fe is 3 with ZnO molar ratios:10.
The antiseptic II is the Ni nanoparticle-ZnO antiseptics prepared using agglutinating nature yeast, the Ni nanoparticle-ZnO antiseptics Show as nano-particle, grain size 550nm, wherein Ni is 7 with ZnO molar ratios:10.
Embodiment 3
In the present embodiment, a kind of antibacterial polyester fibre prepares antiseptic I, antiseptic II first, and it is mixed to be mixed to form antiseptic Object is closed, is then blended with antimicrobial mix using pure PET slices, prepares antibacterial modified PET slices, then pass through melt spinning side Formula obtains antibacterial polyester fibre.
In above-mentioned antibacterial polyester fibre, include according to weight percent：I 0.7wt.% of antiseptic, antiseptic II 1.1wt.%, polyester fiber surplus.
Wherein, antiseptic I is the nanometer Fe-ZnO antiseptics prepared using agglutinating nature yeast；The nanometer Fe-ZnO antibacterials Agent shows as nano-particle, grain size 600nm, wherein Fe is 3 with ZnO molar ratios:10.
The antiseptic II is the Ni nanoparticle-ZnO antiseptics prepared using agglutinating nature yeast, the Ni nanoparticle-ZnO antiseptics Show as nano-particle, grain size 550nm, wherein Ni is 7 with ZnO molar ratios:10.
The polyester fiber obtained for Examples 1 to 3 carries out antibacterial test using concussion method, the following table is fiber sample into After row oscillating contact 30h, test result of the polyester fiber to Escherichia coli and staphylococcus aureus antibacterial effect：
According to GB 20944.3-2008-T it is found that when fiber or fabric are to Escherichia coli and staphylococcus aureus Fiber or fabric can be evaluated when bacteriostasis rate >=70% has antibacterial effect.
It can be seen that in embodiment 1-3, by adding antiseptic I, antiseptic II and forming antimicrobial mix, gather Ester fiber has excellent antibacterial effect.
Using FZ/T73023-2006《Antibiosis knitting product》The simplification wash conditions and program of middle appendix C, to embodiment 1~ Polyester fiber carries out standard wash in 3, and wash conditions and step are：2g/L standard synthetic detergents, bath raio 1:30, water temperature 40 ± 3 DEG C, sample is put into, 5min is washed, then cleans 2min with tap water at normal temperatures, is calculated as washing 1 time.
Anti-microbial property after being washed 100 times the following table is polyester fiber in Examples 1 to 3：
It can be seen that, by 100 times washing after, the bacteriostasis rate of antibacterial polyester fibre is declined slightly, but still have compared with Good antibacterial effect, anti-scourability are good.
The foregoing is merely the preferred modes of the present invention, are not intended to limit the invention, all spirit and original in the present invention Within then, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of good fabric of curtain anti-microbial property, which is characterized in that including be arranged from top to bottom the first precoat, Two precoats, third precoat and the fourth face bed of material, first precoat are mixed by polyester fiber and polyphenylsulfone nylon Spinning weaves, and second precoat is formed by polyimide fiber and vinylon fibre blending woven, the third precoat It is formed by polyaniline conductive dacron fibre and polypropylene fibre blending woven, the fourth face bed of material is by apocynum fibre and banana Fasciated fiber blending woven forms；
Polyester fiber described in first precoat is a kind of antibacterial polyester fibre, and forming process is：Antiseptic is prepared first I, antiseptic II is mixed to form antimicrobial mix, is then blended with antimicrobial mix using pure PET slices, prepares antibacterial Modified PET is sliced, then obtains antibacterial polyester fibre by melt spinning mode；Include according to weight percent：Antiseptic I 0.5 ~0.7wt.%, II 0.9~1.1wt.% of antiseptic, polyester fiber surplus.
2. a kind of good fabric of curtain anti-microbial property according to claim 1, which is characterized in that first fabric Parts by weight shared by each ingredient are respectively in layer：The polyester fiber accounts for 46 parts, and the polyphenylsulfone nylon accounts for 23 parts.
3. a kind of good fabric of curtain anti-microbial property according to claim 1, which is characterized in that second fabric Parts by weight shared by each ingredient are respectively in layer：The polyimide fiber accounts for 51 parts, and the vinylon fibre accounts for 33 parts.
4. a kind of good fabric of curtain anti-microbial property according to claim 1, which is characterized in that the third fabric Parts by weight shared by each ingredient are respectively in layer：The polyaniline conductive dacron fibre accounts for 11 parts, and the polypropylene fibre accounts for 61 Part.
5. a kind of good fabric of curtain anti-microbial property according to claim 1, which is characterized in that the fourth face material Parts by weight shared by each ingredient are respectively in layer：The apocynum fibre accounts for 47 parts, and the banana fiber accounts for 47 parts.
6. a kind of good fabric of curtain anti-microbial property according to claim 1, which is characterized in that the antiseptic I For the nanometer Fe-ZnO antiseptics prepared using agglutinating nature yeast, the nanometer Fe-ZnO antiseptics show as nano-particle, grain Diameter is 600nm, wherein Fe is 3 with ZnO molar ratios:10.
7. a kind of good fabric of curtain anti-microbial property according to claim 6, which is characterized in that the antiseptic I Preparation process be：0.1M zinc nitrates and the ferric nitrate of 0.03M are weighed respectively, is dissolved in 200ml distilled water, and then magnetic force stirs It mixes to transparent；Add citric acid, magnetic agitation to abundant dissolving, wherein so that the molar ratio of zinc nitrate and citric acid is 1: 1.5；Add ammonium hydroxide (30wt.%) with constant pressure titration dripping, adjust pH=8, is formed in 86 DEG C of water bath with thermostatic control evaporable waters wet solidifying Glue, then drying obtains Fe-ZnO xerogel for 24 hours up to constant weight in 80 DEG C of vacuum drying chambers；By 540 DEG C in air of xerogel Lower calcining 1h, cooled to room temperature obtain antiseptic I, i.e. nanometer Fe-ZnO antiseptics.
8. a kind of good fabric of curtain anti-microbial property according to claim 1, which is characterized in that the antiseptic II For the Ni nanoparticle-ZnO antiseptics prepared using agglutinating nature yeast, the Ni nanoparticle-ZnO antiseptics show as nano-particle, grain size For 550nm, wherein Ni is 7 with ZnO molar ratios:10.
9. a kind of good fabric of curtain anti-microbial property according to claim 8, which is characterized in that the antiseptic II Preparation process be：0.1M zinc nitrates and the nickel nitrate of 0.07M are weighed respectively, is dissolved in 200ml distilled water, and then magnetic force stirs It mixes to transparent；Add citric acid, magnetic agitation to abundant dissolving, wherein so that the molar ratio of zinc nitrate and citric acid is 1: 1.1；Add ammonium hydroxide (30wt.%) with constant pressure titration dripping, adjusts pH=7.6, formed in 95 DEG C of water bath with thermostatic control evaporable waters wet Gel, then drying obtains Ni-ZnO xerogel for 24 hours up to constant weight in 80 DEG C of vacuum drying chambers；By xerogel in air 480 1h is calcined at DEG C, cooled to room temperature obtains antiseptic II, i.e. Ni nanoparticle-ZnO antiseptics.
10. a kind of good fabric of curtain anti-microbial property according to claim 1, which is characterized in that the mixing shape It is at antimicrobial mix：By above-mentioned antiseptic I, antiseptic II according to mass ratio be 0.5~0.7：0.9~1.1 mixing, grinds 5h is ground, mixture E is obtained, is then put into mixture E in the oxalic acid solution that mass fraction is 1.2%, acidification 2h, mistake Filtrate after dry, in nitrogen calcined 3h, after cooling, grind 3h, obtain antimicrobial mix by filter, cleaning at 585 DEG C. In technical solution of the present invention, by the way that antiseptic I and antiseptic II are mixed, are acidified, calcination processing so that antiseptic I, antiseptic II can mutually adulterate, and play unexpected technique effect so that the anti-microbial property of polyester fiber greatly increases.
CN201810138544.2A 2018-02-10 2018-02-10 A kind of good fabric of curtain anti-microbial property Pending CN108437589A (en)

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