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CN108107494A - A kind of anti-blue light lens coating method - Google Patents

A kind of anti-blue light lens coating method Download PDF

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Publication number
CN108107494A
CN108107494A CN201711354886.XA CN201711354886A CN108107494A CN 108107494 A CN108107494 A CN 108107494A CN 201711354886 A CN201711354886 A CN 201711354886A CN 108107494 A CN108107494 A CN 108107494A
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China
Prior art keywords
film layer
substrate
membrane material
plating
blue light
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Chinese (zh)
Inventor
吴晓彤
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Ott Road (zhangzhou) Optical Technology Co Ltd
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Ott Road (zhangzhou) Optical Technology Co Ltd
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Priority to CN201711354886.XA priority Critical patent/CN108107494A/en
Publication of CN108107494A publication Critical patent/CN108107494A/en
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/14Protective coatings, e.g. hard coatings
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/18Coatings for keeping optical surfaces clean, e.g. hydrophobic or photo-catalytic films

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physical Vapour Deposition (AREA)

Abstract

The present invention discloses a kind of anti-blue light lens coating method, and manufacturing method is that membrane system is deposited respectively in the molding substrate outer surface of macromolecule resin material and inner surface to form anti-blue light eyeglass, and manufacturing method specifically includes following steps:1)Substrate is cleaned;2)Drying after substrate cleaning:3)Cleaning again before substrate coating in the vacuum chamber of vacuum evaporation plating machine:4)The plated film of substrate:The plated film of substrate is included in the outer surface plating membrane system of substrate and plates membrane system in the inner surface of substrate.With the injury of harmful blue light and ultraviolet light to human body is prevented, which also has the function of oil-stain-preventing and regulates and controls from main optical the anti-blue light eyeglass that the present invention manufactures simultaneously.

Description

A kind of anti-blue light lens coating method
Technical field
The present invention relates to a kind of anti-blue light lens coating methods.
Background technology
People have known that ultraviolet light can damage eyes, and the irradiation of long-term ultraviolet light can trigger cataract.Equally, Blue light is the high-energy visible ray that wavelength is 400 ~ 500nm, and blue light is can be directed through cornea, eyes crystal, through regard Nethike embrane, blue light can stimulate retina to generate a large amount of radical ions so that the atrophy of retinal pigment epithelium, and cause light The death of sensitive cells, retinal pigment epithelium are very strong to the light absorption effect of blue region, absorb blue light spoke One of the main reason for retinal pigment epithelium atrophy can be made by penetrating, this is also generation maculopathy;Blue ray radiation ingredient is got over Height is bigger to cellula visualis injury, and the atrophy of retinal pigment epithelium can make the image of retina thicken, to fuzzy Image ciliary muscle can do continuous adjusting, aggravate the working strength of ciliary muscle, cause visual fatigue.In ultraviolet light and blue light Under the action of can cause the visual fatigue of people, eyesight can be gradually reduced, and easily cause dry and astringent, photophobia, fatigue on ocular vision Wait early onsets cataract, spontaneous macular diseases.
The optical mirror slip universal functionality sold currently on the market is single, and main is exactly for no anti-blue light and the purple of correcting defects of vision The function of outside line, also without the plano lens and optical mirror slip suitable for general population's anti-blue light and ultraviolet light.
The content of the invention
It is an object of the invention to provide a kind of anti-blue light lens coating method, anti-blue light eyeglass that this method manufactures With the injury of harmful blue light and ultraviolet light to human body is prevented, which also has the work(regulated and controled from main optical simultaneously Energy.
To achieve the above object, the present invention uses following technical scheme:
A kind of anti-blue light lens coating method, the manufacturing method are that membrane system is deposited respectively in substrate outer surface and inner surface to be formed Anti-blue light eyeglass, the manufacturing method specifically include following steps:
1)Substrate is cleaned;
2)Drying after substrate cleaning:Substrate after cleaning is taken off with isopropanol it is dry, it is de- it is dry after substrate drawn slowly using isopropanol It is dry, then be placed in dustless plated film constant temperature roaster more than when 60 DEG C~75 DEG C bakings 8 are small;
3)Stiffened processing:By eyeglass substrate immerse methyl silicon resin reinforced solution in, 115-125 DEG C of stiffened treatment temperature, 2 it is small when Eyeglass substrate is taken out afterwards and is sent to dry solidification in drying baker, 120 DEG C of drying temperature, 60 minutes hardening times;
4)Annealing:By stiffened, treated that eyeglass makes annealing treatment:
5)Secondary cleaning:Eyeglass substrate after annealing is placed in vacuum coating cabin, with hall ion source to eyeglass substrate Carry out ion bombardment 3-5 minutes;
6)The plated film of substrate:The plated film of substrate is included in the outer surface plating membrane system of substrate and plates membrane system in the inner surface of substrate;
A, the outer surface plating membrane system of substrate sequentially include plating shock resistance strengthen film layer, plating uvioresistant film layer, plating anti-blue light film layer, Plate optics regulation and control film layer, plating oil-stain-preventing film layer;
Film layer is strengthened in A1, plating shock resistance:Vacuum degree in vacuum chamber is adjusted to less than or equal to 2.0 × 10-3Pa, using electricity Sub- rifle, after the membrane material of shock resistance reinforcing film layer is evaporated, the membrane material is with nanoscale molecular shape under the action of ion source Formula is deposited on substrate outer surface, forms shock resistance and strengthens film layer, the thickness that film layer is strengthened in shock resistance is 0.1-600 nanometers;It is described The membrane material that film layer is strengthened in shock resistance is silica;
A2, plating uvioresistant film layer:After using electron gun, the membrane material of uvioresistant film layer is evaporated, in the effect of ion source Under the membrane material surfaces of step A1 moderate resistance shock peening film layers is deposited in the form of nanoscale molecular, form uvioresistant film Layer, the thickness of uvioresistant film layer is 0.1-600 nanometers;The membrane material of the uvioresistant film layer includes following weight ratio ingredient Mixture:Silica 20%-80%;Zirconium oxide 20%-80%;
A3, plating antireflective coating:After using electron gun, the membrane material of antireflective coating is evaporated, the film under the action of ion source Material is deposited on the surface of step A2 moderate resistance ultraviolet light film layers in the form of nanoscale molecular, forms antireflective coating, the thickness of antireflective coating It spends for 60-300 nanometers;The membrane material of the antireflective coating is calcirm-fluoride;
A4, plating optics regulation and control film layer:After using electron gun, the membrane material of optics regulation and control film layer is evaporated, in the effect of ion source Under the membrane material surface of anti-blue light film layer in step A3 is deposited in the form of nanoscale molecular, form optics regulation and control film layer, light The thickness for learning regulation and control film layer is 0.1-600 nanometers;The membrane material of the optics regulation and control film layer includes the mixing of following weight ratio ingredient Object:Aluminium 40%-60%;Silica 40%-60%;
A5, plating oil-stain-preventing film layer:After using electron gun, the membrane material of oil-stain-preventing film layer is evaporated, the institute under the action of ion source The surface that membrane material is deposited on optics regulation and control film layer in step A4 in the form of nanoscale molecular is stated, forms oil-stain-preventing film layer, oil-stain-preventing The thickness of film layer is 0.1-600 nanometers;The membrane material of the oil-stain-preventing film layer includes the mixture of following weight ratio ingredient:Magnesium fluoride 60%-80%;Zirconium oxide 20%-40%;
Oil-stain-preventing film layer plated film is completed, and after the completion of the outer surface plating membrane system of substrate, is transferred to the inner surface plating membrane system of substrate;
B, the inner surface plating membrane system of substrate sequentially include plating shock resistance strengthen film layer, plating uvioresistant film layer, plating anti-blue light film layer, Plate oil-stain-preventing film layer;
Film layer is strengthened in B1, plating shock resistance:Using electron gun, after the membrane material of shock resistance reinforcing film layer is evaporated, in ion source Under the action of the membrane material be deposited on substrate interior surface in the form of nanoscale molecular, form shock resistance and strengthen film layer, shock resistance is strong The thickness for changing film layer is 0.1-600 nanometers;The membrane material that film layer is strengthened in the shock resistance is silica;
B2, plating uvioresistant film layer:After using electron gun, the membrane material of uvioresistant film layer is evaporated, in the effect of ion source Under the membrane material surfaces of step A1 moderate resistance shock peening film layers is deposited in the form of nanoscale molecular, form uvioresistant film Layer, the thickness of uvioresistant film layer is 0.1-600 nanometers;The membrane material of the uvioresistant film layer includes following weight ratio ingredient Mixture:Silica 20%-80%;Zirconium oxide 20-80%;
Repeat step B2 at least once more than, form more than the two layers uvioresistant film layer being stacked with;
B3, plating anti-blue light film layer:After using electron gun, the membrane material of anti-blue light film layer is evaporated, the institute under the action of ion source The surface that membrane material is deposited on step B2 moderate resistance ultraviolet light film layers in the form of nanoscale molecular is stated, forms anti-blue light film layer, anti-blue light The thickness of film layer is 0.1-600 nanometers;The membrane material of the anti-blue light film layer includes the mixture of following weight ratio ingredient:Tin oxide 30%-60%;Rubidium 10%-40%;Platinum 10%-40%;
Repeat step B3 at least once more than, form more than the two layers anti-blue light film layer being stacked with;
B4, plating oil-stain-preventing film layer:After using electron gun, the membrane material of oil-stain-preventing film layer is evaporated, the institute under the action of ion source The surface that membrane material is deposited on anti-blue light film layer in step B3 in the form of nanoscale molecular is stated, forms oil-stain-preventing film layer, oil-stain-preventing film The thickness of layer is 0.1-600 nanometers;The membrane material of the oil-stain-preventing film layer includes the mixture of following weight ratio ingredient:Magnesium fluoride 60%-80%;Zirconium oxide 20%-40%.
The step 1)In, the cleaning of substrate is as follows:
A, substrate is cleaned using organic cleaning solvent, and aids in cleaning with ultrasonic wave;
B, the substrate cleaned through step a is cleaned using aqueous cleaning agent, and aids in cleaning with ultrasonic wave;
C, the substrate for handling step b sequentially carries out tap water rinse and distilled water rinsing.
The substrate is molded for macromolecule resin.
The effect of film layer is strengthened in the shock resistance of substrate outer surface and inner surface:The impact resistance of eyeglass can the 1st, improved, Eyeglass do not allow it is broken avoid injury eyes;2nd, the adhesive force of eyeglass is improved, can be had as the medium for plating next tunic layer Fine cementation to be not easy delamination between film layer.
The effect of the uvioresistant film layer of substrate outer surface and inner surface:Corrosion-resistant, anti-oxidant, stop ultraviolet light.
The effect of the anti-blue light film layer of substrate outer surface and inner surface:For the blue light absorption rate that wavelength is 380-500nm Reach up to more than 33% and various harmful rays, make the visual field apparent bright, and can also effective protect eyes, Extenuate visual fatigue.
The effect of substrate outer surface optics regulation and control film layer:It make use of the principle of zoom camera camera lens, rather dark or In the too strong environment of light, optics regulation and control film layer have it is certain from main optical regulate and control, play the role of photo-equilibrium so that Yong Hugeng It is fast to adapt to environment;Long depending on overtaxing one's nerves, for a long time against computer, LCD screen, eyes be present with ache, be dry and astringent, eye is swollen, sheds tears etc. regards Feel fatigue phenomenon, the processing of film is regulated and controled by optics can alleviate visual fatigue.
The effect of the oil-stain-preventing film layer of substrate outer surface and inner surface:Oil-stain-preventing film layer will plate the film layer of substrate surface Cover, and can Jiang Shui and oil reduced with the contact area of eyeglass, oil and water droplet is made to be not easy to be adhered to lens surface.
The present invention uses the principle of electron beam vacuum evaporation, has after being accelerated in the electric field using electrically charged particle certain Ion is guided into and is intended to the electrode made of the substrate of plated film by the characteristics of kinetic energy, and by electron gun with high temperature bombardment that high-purity is golden Belong to oxide component, the nano molecular being evaporated makes it move to substrate and finally in deposition on substrate along certain direction The method of film forming.This invention technology is combined the trajectory of electron motion in the special distributed controll electric field in magnetic field, is changed with this Into the technique of plated film so that coating film thickness and uniformity are controllable, and the film layer compactness prepared is good, cohesive force is strong and degree of purity It is high.
The present invention is coated with the film layer of antiultraviolet and harmful blue light to eye injury on optical mirror slip, therefore people make Durings with LED lamplight, computer, mobile phone, TV and micro-wave oven etc., using this optical mirror slip to correcting defects of vision and need not correct defects of vision People can play effectively, comprehensively prevent when using these electric appliances generated harmful blue light and ultraviolet light to human eye portion and The radiation of brain, it is ensured that health and eyesight is delayed to deepen, and still maintain the number of degrees of existing optical mirror slip correct vision And delay the increase of the number of degrees, become apparent from visual effect.In addition, the cooperation between film layer of the present invention and film layer is finally in optics A kind of film layer of white clear is formed on eyeglass(Platinum film layer), the optical mirror slip film layer that occurs currently on the market be mostly blue film or Partial veil, that is, eyeglass background color band blue light and green light, blue film or partial veil are in face of screen and light emitting source body because having blue light or green light Background color is attached on optical mirror slip, can so obscure the authenticity of vision, similary to be also present with blue or green against light Halation, the film layer of white clear(Platinum film layer)Optical mirror slip can overcome the disadvantages that(Blue film and partial veil)The deficiency of optical mirror slip visual effect Part, but the optical mirror slip of the filtering noxious blue light of energy is blank product currently on the market, and eyeglass of the invention can not only be effective The harmful blue light of filter 23 more than 3%, light transmittance keep more than 79%, and clarity and authenticity for vision have well Contribution, can effectively alleviate visual fatigue by the filtering to harmful blue light.
Description of the drawings
The present invention is described in further details below in conjunction with the drawings and specific embodiments:
Fig. 1 is the whole exploded view of the present invention.
Specific embodiment
As shown in Figure 1, a kind of anti-blue light lens coating method, the manufacturing method is in 1 outer surface of substrate and inner surface Membrane system is deposited respectively and forms anti-blue light eyeglass, the manufacturing method specifically includes following steps:
1)Substrate is cleaned;
2)Drying after substrate cleaning:Substrate after cleaning is taken off with isopropanol it is dry, it is de- it is dry after substrate drawn slowly using isopropanol It is dry, then be placed in dustless plated film constant temperature roaster more than when 60 DEG C~75 DEG C bakings 8 are small;
3)Stiffened processing:By eyeglass substrate immerse methyl silicon resin reinforced solution in, 115-125 DEG C of stiffened treatment temperature, 2 it is small when Eyeglass substrate is taken out afterwards and is sent to dry solidification in drying baker, 120 DEG C of drying temperature, 60 minutes hardening times;
4)Annealing:By stiffened, treated that eyeglass makes annealing treatment:
5)Secondary cleaning:Eyeglass substrate after annealing is placed in vacuum coating cabin, with hall ion source to eyeglass substrate Carry out ion bombardment 3-5 minutes;
6)The plated film of substrate 1:The outer surface plating membrane system and the inner surface plated film in substrate 1 that the plated film of substrate 1 is included in substrate 1 System;
A, the outer surface plating membrane system of substrate 1 sequentially includes plating shock resistance reinforcing film layer 2, plating uvioresistant film layer 3, plating anti-blue light film Layer 4, plating optics regulation and control film layer 5, plating oil-stain-preventing film layer 6;
Film layer 2 is strengthened in A1, plating shock resistance:Vacuum degree in vacuum chamber is adjusted to less than or equal to 2.0 × 10-3Pa, using electricity Sub- rifle, after the membrane material of shock resistance reinforcing film layer 2 is evaporated, the membrane material is with nanoscale molecular shape under the action of ion source Formula is deposited on substrate outer surface, forms shock resistance and strengthens film layer 2, the thickness that film layer 2 is strengthened in shock resistance is 0.1-600 nanometers;Institute It states shock resistance and strengthens the membrane material of film layer 2 as silica;
A2, plating uvioresistant film layer 3:After using electron gun, the membrane material of uvioresistant film layer 3 is evaporated, in the work of ion source The surface of step A1 moderate resistance shock peenings film layer 2 is deposited in the form of nanoscale molecular with the lower membrane material, forms uvioresistant Film layer 3, the thickness of uvioresistant film layer 3 is 0.1-600 nanometers;The membrane material of the uvioresistant film layer 3 includes following weight ratio The mixture of component:Silica 20%-80%;Zirconium oxide 20%-80%;
A3, plating antireflective coating 4:It is described under the action of ion source after using electron gun, the membrane material of antireflective coating is evaporated Membrane material is deposited on the surface of step A2 moderate resistance ultraviolet light film layers in the form of nanoscale molecular, forms antireflective coating 4, antireflective coating Thickness is 60-300 nanometers;The membrane material of the antireflective coating is calcirm-fluoride;
A4, plating optics regulation and control film layer 5:After using electron gun, the membrane material of optics regulation and control film layer 5 is evaporated, in the work of ion source The surface of anti-blue light film layer 4 in step A3 is deposited in the form of nanoscale molecular with the lower membrane material, forms optics regulation and control film layer 5, the thickness of optics regulation and control film layer 5 is 0.1-600 nanometers;The membrane material of the optics regulation and control film layer 5 includes following weight ratio ingredient Mixture:Aluminium 40%-60%;Silica 40%-60%;
A5, plating oil-stain-preventing film layer 6:After using electron gun, the membrane material of oil-stain-preventing film layer 6 is evaporated, under the action of ion source The membrane material is deposited on the surface of optics regulation and control film layer 5 in step A4 in the form of nanoscale molecular, forms oil-stain-preventing film layer 6, prevents The thickness of greasy dirt film layer 6 is 0.1-600 nanometers;The membrane material of the oil-stain-preventing film layer 6 includes the mixture of following weight ratio ingredient: Magnesium fluoride 60%-80%;Zirconium oxide 20%-40%;
6 plated film of oil-stain-preventing film layer is completed, and after the completion of the outer surface plating membrane system of substrate 1, is transferred to the inner surface plating membrane system of substrate 1;
B, the inner surface plating membrane system of substrate 1 sequentially includes plating shock resistance reinforcing film layer 7, plating uvioresistant film layer 8, plating anti-blue light film Layer 9, plating oil-stain-preventing film layer 10;
Film layer 7 is strengthened in B1, plating shock resistance:Using electron gun, after the membrane material of shock resistance reinforcing film layer 7 is evaporated, in ion The membrane material is deposited on 1 inner surface of substrate in the form of nanoscale molecular under the action of source, forms shock resistance and strengthens film layer 7, anti-impact It hits and strengthens the thickness of film layer 7 as 0.1-600 nanometers;The membrane material that film layer 7 is strengthened in the shock resistance is silica;
B2, plating uvioresistant film layer 8:After using electron gun, the membrane material of uvioresistant film layer 8 is evaporated, in the work of ion source The surface of step A1 moderate resistance shock peenings film layer 7 is deposited in the form of nanoscale molecular with the lower membrane material, forms uvioresistant Film layer 8, the thickness of uvioresistant film layer 8 is 0.1-600 nanometers;The membrane material of the uvioresistant film layer 8 includes following weight ratio The mixture of component:Silica 20%-80%;Zirconium oxide 20-80%;
Repeat step B2 at least once more than, form more than the two layers uvioresistant film layer 8 being stacked with;
B3, plating anti-blue light film layer 9:After using electron gun, the membrane material of anti-blue light film layer 9 is evaporated, under the action of ion source The membrane material is deposited on the surface of step B2 moderate resistance ultraviolet lights film layer 8 in the form of nanoscale molecular, forms anti-blue light film layer 9, prevents The thickness of blue light film layer 9 is 0.1-600 nanometers;The membrane material of the anti-blue light film layer 9 includes the mixture of following weight ratio ingredient: Tin oxide 30%-60%;Rubidium 10%-40%;Platinum 10%-40%;
Repeat step B3 at least once more than, form more than the two layers anti-blue light film layer 9 being stacked with;
B4, plating oil-stain-preventing film layer 10:After using electron gun, the membrane material of oil-stain-preventing film layer 10 is evaporated, in the effect of ion source Under the membrane material surface of anti-blue light film layer 9 in step B3 is deposited in the form of nanoscale molecular, form oil-stain-preventing film layer 10, prevent The thickness of greasy dirt film layer 10 is 0.1-600 nanometers;The membrane material of the oil-stain-preventing film layer 10 includes the mixing of following weight ratio ingredient Object:Magnesium fluoride 60%-80%;Zirconium oxide 20%-40%.
The step 1)In, the cleaning of substrate 1 is as follows:
A, substrate 1 is cleaned using organic cleaning solvent, and aids in cleaning with ultrasonic wave;
B, the substrate 1 cleaned through step a is cleaned using aqueous cleaning agent, and aids in cleaning with ultrasonic wave;
C, the substrate 1 for handling step b sequentially carries out tap water rinse and distilled water rinsing.
The substrate 1 is molded for macromolecule resin.Macromolecule resin substrate 1 is with resin(A variety of high-molecular compounds Mixture)The optical mirror slip of synthesis is processed by accurate chemical technology for raw material;Its material advantage has 1, anti-impact force By force, it is non-friable, anti-impact force be 8-10 kg/cms, 2, translucency it is good, resin lens can be effective by coating film treatment Injury of the filtering noxious light to human eye;3rd, light weight, weight every square centimeter is at 0.83-1.5 grams;4th, convenient for adding Work, optical mirror slip and aspherical optical mirror slip such as high index of refraction (1.499-1.74).
In coating process of the present invention, monitored using the full optical spectrum end-point analytical technology of multi-wavelength between 280 nanometers to 760 nanometers Light wave variation and perspective rate, using quartz crystal monitoring system, utilize the measure of the change of quartz crystal frequency of oscillation, monitoring plating Membrane material evaporation rate frequency, evaporation rate frequency resolution are 0.01 nanometer per second, 6 rotations of quartz crystal monitoring system Formula crystal film thickness sensor can improve the precision of coating film thickness, make the trueness error of film thickness between 0.1 nanometer.
The embodiment of the membrane system of 1 outer surface of substrate:
The embodiment of the 3 membrane material component of uvioresistant film layer of 1 outer surface of substrate:
Embodiment 1:Silica 20%, zirconium oxide 80%.
Embodiment 2:Silica 80%, zirconium oxide 20%.
Embodiment 3:Silica 50%, zirconium oxide 50%.
The embodiment of the optics regulation and control 5 membrane material component of film layer of 1 outer surface of substrate:
Embodiment 1:Aluminium 40%, silica 60%.
Embodiment 2:Aluminium 60%, silica 40%.
Embodiment 3:Aluminium 50%, silica 50%.
The embodiment of the 6 membrane material component of oil-stain-preventing film layer of 1 inner surface of substrate:
Embodiment 1:Magnesium fluoride 60%, zirconium oxide 40%.
Embodiment 2:Magnesium fluoride 80%, zirconium oxide 20%.
Embodiment 3:Magnesium fluoride 70%, zirconium oxide 30%.
The embodiment of the membrane system of 1 inner surface of substrate:
The embodiment of the 8 membrane material component of uvioresistant film layer of 1 inner surface of substrate:
Embodiment 1:Silica 20%, zirconium oxide 80%.
Embodiment 2:Silica 80%, zirconium oxide 20%.
Embodiment 3:Silica 50%, zirconium oxide 50%.
The embodiment of the 9 membrane material component of anti-blue light film layer of 1 inner surface of substrate:
Embodiment 1:Tin oxide 30%;Rubidium 40%;Platinum 40%.
Embodiment 2:Silica 60%, rubidium 10%;Platinum 30%.
Embodiment 3:Silica 55%, rubidium 35%;Platinum 10%.
The embodiment of the 10 membrane material component of oil-stain-preventing film layer of 1 inner surface of substrate:
Embodiment 1:Magnesium fluoride 60%, zirconium oxide 40%.
Embodiment 2:Magnesium fluoride 80%, zirconium oxide 20%.
Embodiment 3:Magnesium fluoride 70%, zirconium oxide 30%.

Claims (3)

1. a kind of anti-blue light lens coating method is included in substrate outer surface and inner surface and membrane system formation anti-blue light is deposited respectively Eyeglass, it is characterised in that:The film plating process specifically includes following steps:
1)Substrate is cleaned;
2)Drying after substrate cleaning:Substrate after cleaning is taken off with isopropanol it is dry, it is de- it is dry after substrate drawn slowly using isopropanol It is dry, then be placed in dustless plated film constant temperature roaster more than when 60 DEG C~75 DEG C bakings 8 are small;
3)Stiffened processing:By eyeglass substrate immerse methyl silicon resin reinforced solution in, 115-125 DEG C of stiffened treatment temperature, 2 it is small when Eyeglass substrate is taken out afterwards and is sent to dry solidification in drying baker, 120 DEG C of drying temperature, 60 minutes hardening times;
4)Annealing:By stiffened, treated that eyeglass makes annealing treatment:
5)Secondary cleaning:Eyeglass substrate after annealing is placed in vacuum coating cabin, with hall ion source to eyeglass substrate Carry out ion bombardment 3-5 minutes;
6)The plated film of substrate:The plated film of substrate is included in the outer surface plating membrane system of substrate and plates membrane system in the inner surface of substrate;
A, the outer surface plating membrane system of substrate sequentially includes plating shock resistance reinforcing film layer, plating uvioresistant film layer, plating antireflective coating, plating Optics regulation and control film layer, plating oil-stain-preventing film layer;
Film layer is strengthened in A1, plating shock resistance:Vacuum degree in vacuum chamber is adjusted to less than or equal to 2.0 × 10-3Pa, using electronics Rifle, after the membrane material of shock resistance reinforcing film layer is evaporated, the membrane material is in the form of nanoscale molecular under the action of ion source Substrate outer surface is deposited on, shock resistance is formed and strengthens film layer, the thickness that film layer is strengthened in shock resistance is 0.1-600 nanometers;It is described anti- The membrane material of shock peening film layer is silica;
A2, plating uvioresistant film layer:After using electron gun, the membrane material of uvioresistant film layer is evaporated, in the effect of ion source Under the membrane material surfaces of step A1 moderate resistance shock peening film layers is deposited in the form of nanoscale molecular, form uvioresistant film Layer, the thickness of uvioresistant film layer is 0.1-600 nanometers;The membrane material of the uvioresistant film layer includes following weight ratio ingredient Mixture:Silica 20%-80%;Zirconium oxide 20%-80%;
A3, plating antireflective coating:After using electron gun, the membrane material of antireflective coating is evaporated, the film under the action of ion source Material is deposited on the surface of step A2 moderate resistance ultraviolet light film layers in the form of nanoscale molecular, forms antireflective coating, the thickness of antireflective coating It spends for 60-300 nanometers;The membrane material of the antireflective coating is calcirm-fluoride;
A4, plating optics regulation and control film layer:After using electron gun, the membrane material of optics regulation and control film layer is evaporated, in the effect of ion source Under the membrane material surface of anti-blue light film layer in step A3 is deposited in the form of nanoscale molecular, form optics regulation and control film layer, light The thickness for learning regulation and control film layer is 0.1-600 nanometers;The membrane material of the optics regulation and control film layer includes the mixing of following weight ratio ingredient Object:Aluminium 40%-60%;Silica 40%-60%;
A5, plating oil-stain-preventing film layer:After using electron gun, the membrane material of oil-stain-preventing film layer is evaporated, the institute under the action of ion source The surface that membrane material is deposited on optics regulation and control film layer in step A4 in the form of nanoscale molecular is stated, forms oil-stain-preventing film layer, oil-stain-preventing The thickness of film layer is 0.1-600 nanometers;The membrane material of the oil-stain-preventing film layer includes the mixture of following weight ratio ingredient:Magnesium fluoride 60%-80%;Zirconium oxide 20%-40%;
Oil-stain-preventing film layer plated film is completed, and after the completion of the outer surface plating membrane system of substrate 1, is transferred to the inner surface plating membrane system of substrate 1;
B, the inner surface plating membrane system of substrate sequentially include plating shock resistance strengthen film layer, plating uvioresistant film layer, plating anti-blue light film layer, Plate oil-stain-preventing film layer;
Film layer is strengthened in B1, plating shock resistance:Using electron gun, after the membrane material of shock resistance reinforcing film layer is evaporated, in ion source Under the action of the membrane material be deposited on substrate interior surface in the form of nanoscale molecular, form shock resistance and strengthen film layer, shock resistance is strong The thickness for changing film layer is 0.1-600 nanometers;The membrane material that film layer is strengthened in the shock resistance is silica;
B2, plating uvioresistant film layer:After using electron gun, the membrane material of uvioresistant film layer is evaporated, in the effect of ion source Under the membrane material surfaces of step A1 moderate resistance shock peening film layers is deposited in the form of nanoscale molecular, form uvioresistant film Layer, the thickness of uvioresistant film layer is 0.1-600 nanometers;The membrane material of the uvioresistant film layer includes following weight ratio ingredient Mixture:Silica 20%-80%;Zirconium oxide 20-80%;
Repeat step B2 at least once more than, form more than the two layers uvioresistant film layer being stacked with;
B3, plating anti-blue light film layer:After using electron gun, the membrane material of anti-blue light film layer is evaporated, the institute under the action of ion source The surface that membrane material is deposited on step B2 moderate resistance ultraviolet light film layers in the form of nanoscale molecular is stated, forms anti-blue light film layer, anti-blue light The thickness of film layer is 0.1-600 nanometers;The membrane material of the anti-blue light film layer includes the mixture of following weight ratio ingredient:Tin oxide 30%-60%;Rubidium 10%-40%;Platinum 10%-40%;
Repeat step B3 at least once more than, form more than the two layers anti-blue light film layer being stacked with;
B4, plating oil-stain-preventing film layer:After using electron gun, the membrane material of oil-stain-preventing film layer is evaporated, the institute under the action of ion source The surface that membrane material is deposited on anti-blue light film layer in step B3 in the form of nanoscale molecular is stated, forms oil-stain-preventing film layer, oil-stain-preventing film The thickness of layer is 0.1-600 nanometers;The membrane material of the oil-stain-preventing film layer includes the mixture of following weight ratio ingredient:Magnesium fluoride 60%-80%;Zirconium oxide 20%-40%.
2. a kind of anti-blue light lens coating method according to claim 1, it is characterised in that:The step 1)In, to base The cleaning of piece is as follows:
A, substrate is cleaned using organic cleaning solvent, and aids in cleaning with ultrasonic wave;
B, the substrate cleaned through step a is cleaned using aqueous cleaning agent, and aids in cleaning with ultrasonic wave;
C, the substrate for handling step b sequentially carries out tap water rinse and distilled water rinsing.
3. a kind of anti-blue light lens coating method according to claim 1, it is characterised in that:The substrate is high score subtree Fat is molded.
CN201711354886.XA 2017-12-15 2017-12-15 A kind of anti-blue light lens coating method Pending CN108107494A (en)

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Publication number Priority date Publication date Assignee Title
CN108863103A (en) * 2018-08-31 2018-11-23 嘉善银升玻璃有限公司 A kind of processing method of oil-stain-preventing glass
CN110303752A (en) * 2019-08-02 2019-10-08 翔实光电科技(昆山)有限公司 A kind of reduction touch screen blue light overflow method
CN112034538A (en) * 2020-04-21 2020-12-04 江苏新唯尊光学眼镜有限公司 Blue-light-proof anti-ultraviolet lens and production process thereof
CN113009713A (en) * 2021-04-07 2021-06-22 江苏万新光学有限公司 Ultralow-reflection clear-background-color blue-light-proof resin lens and preparation method thereof
US11448901B2 (en) * 2019-12-27 2022-09-20 He Cheng Optical Co., Ltd. Anti UV420 lens
CN115505879A (en) * 2022-09-30 2022-12-23 广州市博泰光学科技有限公司 Optical lens coating method

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CN201724040U (en) * 2010-07-07 2011-01-26 苏坛 LED lamp tube capable of increasing transparency and luminance brightness
CN103984120A (en) * 2014-05-30 2014-08-13 奥特路(漳州)光学科技有限公司 Method for manufacturing blue light-resistant optical lens
CN106772707A (en) * 2016-12-13 2017-05-31 江苏康耐特光学有限公司 A kind of preparation method of the antifog plated film resin lens of anti-blue light

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CN1985190A (en) * 2004-05-26 2007-06-20 株式会社腾龙 Anti-reflection film
CN201724040U (en) * 2010-07-07 2011-01-26 苏坛 LED lamp tube capable of increasing transparency and luminance brightness
CN103984120A (en) * 2014-05-30 2014-08-13 奥特路(漳州)光学科技有限公司 Method for manufacturing blue light-resistant optical lens
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108863103A (en) * 2018-08-31 2018-11-23 嘉善银升玻璃有限公司 A kind of processing method of oil-stain-preventing glass
CN110303752A (en) * 2019-08-02 2019-10-08 翔实光电科技(昆山)有限公司 A kind of reduction touch screen blue light overflow method
US11448901B2 (en) * 2019-12-27 2022-09-20 He Cheng Optical Co., Ltd. Anti UV420 lens
CN112034538A (en) * 2020-04-21 2020-12-04 江苏新唯尊光学眼镜有限公司 Blue-light-proof anti-ultraviolet lens and production process thereof
CN113009713A (en) * 2021-04-07 2021-06-22 江苏万新光学有限公司 Ultralow-reflection clear-background-color blue-light-proof resin lens and preparation method thereof
CN115505879A (en) * 2022-09-30 2022-12-23 广州市博泰光学科技有限公司 Optical lens coating method

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