CN108079696A - A kind of device for removing conductive dust, method and application thereof - Google Patents
A kind of device for removing conductive dust, method and application thereof Download PDFInfo
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Classifications
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
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- B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/0002—Casings; Housings; Frame constructions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/56—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with multiple filtering elements, characterised by their mutual disposition
- B01D46/58—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with multiple filtering elements, characterised by their mutual disposition connected in parallel
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- Chemical Kinetics & Catalysis (AREA)
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Abstract
本发明涉及一种除导电粉尘的装置、方法及其用途,所述装置包括通过花板互相隔离的净气室和除尘室;所述除尘室中设有多孔金属过滤管;所述多孔金属过滤管的底端封口,顶端与花板之间通过法兰与所述法兰之下的绝缘垫件实现气体密封和电绝缘;所述法兰的外侧和所述法兰以下10~20cm的多孔金属过滤管外侧均涂覆有绝缘涂层;所述多孔金属过滤管通过外部高压电源进行荷电。此装置兼具多孔金属过滤管耐温高、强度好、可焊接的优势,且清灰容易,气阻随粉饼增厚而上升的速度较慢,是具有低气阻、高通量的高效除尘装置;绝缘涂层解决了多孔金属过滤管和除尘滑板之间的绝缘,提高除尘效率和安全性,非常适于非腐蚀性气氛下的导电粉尘的去除和收集。
The invention relates to a device, method and application for removing conductive dust. The device includes a clean air chamber and a dust removal chamber separated from each other by flower plates; the dust removal chamber is provided with a porous metal filter tube; the porous metal filter The bottom end of the tube is sealed, and the flange and the insulating gasket under the flange realize gas sealing and electrical insulation between the top end and the flower plate; The outside of the metal filter tube is coated with an insulating coating; the porous metal filter tube is charged by an external high-voltage power supply. This device has the advantages of high temperature resistance, good strength, and weldability of the porous metal filter tube, and it is easy to clean the dust. The air resistance rises slowly with the thickness of the powder cake. It is a high-efficiency dust removal with low air resistance and high flux. Device; the insulation coating solves the insulation between the porous metal filter tube and the dust removal slide, improves the dust removal efficiency and safety, and is very suitable for the removal and collection of conductive dust in a non-corrosive atmosphere.
Description
技术领域technical field
本发明涉及有色冶金技术领域,尤其涉及一种除导电粉尘的装置、方法及其用途。The invention relates to the technical field of nonferrous metallurgy, in particular to a device, method and application for removing conductive dust.
背景技术Background technique
在有色冶金领域存在众多需要在高温下去除导电粉尘的工业需求,例如氮气下将铝业喷雾制备超细铝粉、转炉炼铜等等。这些场合急需能够耐受高温且能够充分除尘的可靠技术。此外,由于粉尘具有较高附加值,除尘的效果必须稳定可靠。In the field of non-ferrous metallurgy, there are many industrial needs that need to remove conductive dust at high temperature, such as spraying aluminum industry under nitrogen to prepare ultra-fine aluminum powder, converter copper smelting, etc. Reliable technology that can withstand high temperatures and adequately remove dust is urgently needed in these applications. In addition, due to the high added value of dust, the effect of dust removal must be stable and reliable.
目前工业除尘领域已经有了很多成熟技术,例如:机械除尘、湿法除尘、袋式除尘、电除尘以及静电布袋复合除尘等等。机械除尘是利用降尘室、旋风分离器等机械装置进行除尘的方法,湿法除尘是利用喷淋塔、水膜除尘器或文丘里除尘器进行除尘的方法,常见于处理尘埃颗粒尺寸较大的气体,对于需要去除微细颗粒且气体温度较高的场合,机械除尘和湿法除尘都难以胜任。At present, there are many mature technologies in the field of industrial dust removal, such as: mechanical dust removal, wet dust removal, bag dust removal, electrostatic dust removal and electrostatic bag composite dust removal and so on. Mechanical dedusting is a method of dust removal using dust chambers, cyclone separators and other mechanical devices. Wet dedusting is a method of dedusting using spray towers, water film dust collectors or Venturi dust collectors. It is often used to deal with large dust particles. Gas, for the occasions where fine particles need to be removed and the gas temperature is high, both mechanical dust removal and wet dust removal are difficult to do.
袋式除尘的除尘效率很高,对粉尘的粒径范围波动的耐受性好,即使微细的粉尘也可成功获得很高的截留率,然而,袋式除尘的压降较大,对于风机等气体传输设备的动力载荷要求高,此外,目前常见的布袋难以耐受高温,对于废气中含有红热颗粒和引燃颗粒的烧结烟气而言,使用布袋除尘常常发生“烧袋”事故。此外,常见的工业废气处理工段,废气的压力很低,对于压降较大的袋式除尘,常常需要提高风机压头来应付布袋的压降,甚至需要重新选购风机。在通过喷雾法生产超细铝粉的工业装置中,袋式收尘是获取产品铝粉的唯一方法,然而随着对铝粉的超细化,粉饼阻力上升很快,需要频繁对布袋进行再生。The dust removal efficiency of the bag type dust collector is very high, and it has good tolerance to the fluctuation of the particle size range of the dust. Even fine dust can successfully obtain a high retention rate. However, the pressure drop of the bag type dust collector is relatively large. The dynamic load requirements of gas transmission equipment are high. In addition, the common cloth bags are difficult to withstand high temperature. For the sintering flue gas containing red hot particles and ignition particles in the waste gas, "burning bag" accidents often occur when using cloth bag dust removal. In addition, in the common industrial waste gas treatment section, the pressure of the waste gas is very low. For the bag type dust collector with a large pressure drop, it is often necessary to increase the pressure head of the fan to cope with the pressure drop of the bag, and even need to purchase a new fan. In an industrial device that produces ultra-fine aluminum powder by spraying, bag dust collection is the only way to obtain the product aluminum powder. However, with the ultra-fine aluminum powder, the resistance of the powder cake rises rapidly, and the bag needs to be regenerated frequently .
电除尘也是当前非常常用和高效除尘手段,该方法是首先对气体中的粉尘荷电、而后通过电场力将其从气流中去除并固定在电极板表面的除尘方法。该方法可用于高温废气处理,且只有很小的压降阻力,但其缺点在于对粉尘的导电率、气体湿度都有一定要求,导电的粉体即使落在收尘极板上也会很快失去电荷并重新荷载相反电荷,进而被弹出收尘极板,所以电除尘是无法去除导电粉尘的。此外,电除尘的电晕极是在频繁产生火花的情况下工作的,因此当气氛中含有氧气时,有发生粉尘爆炸的潜在危险。另外,电除尘器能否成功荷电和气体的成分关系很大,对于气体成分主要为氮气且氧气含量很少的情况,电除尘器是不能有效对粉尘荷电的。Electrostatic precipitator is also a very common and efficient dust removal method at present. This method is to first charge the dust in the gas, and then remove it from the air flow by electric field force and fix it on the surface of the electrode plate. This method can be used for high-temperature exhaust gas treatment, and has only a small pressure drop resistance, but its disadvantage is that it has certain requirements on the conductivity of the dust and the humidity of the gas. Even if the conductive powder falls on the dust collecting plate, it will quickly It loses charge and reloads the opposite charge, and then is ejected from the dust collecting plate, so electric dust removal cannot remove conductive dust. In addition, the corona electrode of electrostatic precipitator works under the condition of frequent sparks, so when the atmosphere contains oxygen, there is a potential danger of dust explosion. In addition, whether the electrostatic precipitator can successfully charge is closely related to the composition of the gas. For the case where the gas composition is mainly nitrogen and the oxygen content is very small, the electrostatic precipitator cannot effectively charge the dust.
目前利用金属粉末压制成型的多孔金属过滤管的制备已经非常成熟,中国钢铁科技集团有限公司已经具备多孔金属过滤板、过滤管的大规模生产能力,所生产的过滤管在煤气化、煤液化、有色冶金、高温除尘领域取得工业应用,这类多孔金属过滤管具有强度好、不易断裂、可焊接等诸多优点,但其缺点也很明显,第一,过滤管为均质材料,很难获得梯度孔隙,因此微细粉尘容易钻进管体内部而导致堵塞,第二,过滤管压降较大,尤其在过滤微细粉尘时过滤压降上升较快,第三,金属管不耐腐蚀,除尘气体中含有腐蚀性组份时,金属管常常因为腐蚀而导致堵孔。At present, the preparation of porous metal filter tubes formed by pressing metal powder is very mature. China Iron and Steel Technology Group Co., Ltd. already has the large-scale production capacity of porous metal filter plates and filter tubes. The filter tubes produced are used in coal gasification, coal liquefaction, Industrial applications have been achieved in the fields of non-ferrous metallurgy and high-temperature dust removal. This type of porous metal filter tube has many advantages such as good strength, not easy to break, and can be welded, but its disadvantages are also obvious. First, the filter tube is a homogeneous material, and it is difficult to obtain a gradient Pores, so fine dust is easy to drill into the inside of the pipe body and cause blockage. Second, the pressure drop of the filter pipe is relatively large, especially when filtering fine dust. When containing corrosive components, metal pipes often cause plugging due to corrosion.
本研究团队曾利用表面导电的陶瓷过滤管为过滤介质,开发了一种用于导电粉尘的除尘方法并公开在CN105149092A中,所采用的技术手段主要是在陶瓷管表面的导电过滤层上荷载高电压,当导电粉尘到达导电陶瓷管表面时,粉尘会被导电陶瓷管荷电,带电的导电粉尘之间因为静电相斥的作用而在陶瓷管表面形成疏松的粉饼,从而大大降低粉饼的过滤压降。然而实践该技术方案也遇到了一定的操作困难,首先,导电陶瓷管脆性大,其长度难以超过2m,导致除尘器占地较大;第二,导电陶瓷管强度差,不耐磕碰,给安装过程造成了较大困难;第三,由于外接高压电源的引入线在除尘器含导电粉尘的一侧,很容易在穿墙瓷件上沉积导电粉尘,从而导致高压电与接地的设备壳体导通,进而发生电击穿事故。Our research team has used the surface conductive ceramic filter tube as the filter medium to develop a dust removal method for conductive dust and disclosed it in CN105149092A. Voltage, when the conductive dust reaches the surface of the conductive ceramic tube, the dust will be charged by the conductive ceramic tube, and the charged conductive dust will form a loose powder cake on the surface of the ceramic tube due to the electrostatic repulsion, thereby greatly reducing the filter pressure of the powder cake drop. However, the practice of this technical solution also encountered certain operational difficulties. First, the conductive ceramic tube is brittle, and its length cannot exceed 2m, resulting in a large area occupied by the dust collector; second, the conductive ceramic tube has poor strength and is not resistant to bumps. The process has caused great difficulties; third, because the lead-in line of the external high-voltage power supply is on the side of the dust collector containing conductive dust, it is easy to deposit conductive dust on the wall-penetrating porcelain parts, resulting in high-voltage and grounded equipment shells conduction, and then an electrical breakdown accident occurs.
发明内容Contents of the invention
鉴于现有技术中存在的问题,本发明的目的之一在于提供一种针对导电粉尘的除尘方法,通过一种简单的方法获得具有低气阻、高通量的高效除尘装置。该装置兼具多孔金属过滤管强度高、不易断裂、可焊接的优势,且清灰容易,气阻随粉饼增厚而上升的速度较慢。In view of the problems existing in the prior art, one of the objectives of the present invention is to provide a dust removal method for conductive dust, and obtain a high-efficiency dust removal device with low air resistance and high flux through a simple method. The device has the advantages of high strength, not easy to break, and weldable porous metal filter tube, and it is easy to clean the dust, and the air resistance increases slowly with the thickness of the powder cake.
为达此目的,本发明采用如下技术方案:For reaching this purpose, the present invention adopts following technical scheme:
第一方面,本发明提供一种除导电粉尘的装置,通过花板互相隔离的净气室和除尘室;所述除尘室中设有多孔金属过滤管;所述多孔金属过滤管的底端封口,顶端与花板之间通过法兰与所述法兰之下的绝缘垫件实现气体密封和电绝缘;所述法兰的外侧和所述法兰以下10~20cm的多孔金属过滤管外侧均涂覆有绝缘涂层;所述多孔金属过滤管通过外部高压电源进行荷电。In the first aspect, the present invention provides a device for removing conductive dust, a clean air room and a dust removal room separated from each other by flower plates; a porous metal filter tube is arranged in the dust removal room; the bottom end of the porous metal filter tube is sealed , between the top end and the flower plate, gas sealing and electrical insulation are realized through the flange and the insulating gasket under the flange; the outside of the flange and the outside of the porous metal filter tube 10-20 cm below the flange are both Coated with an insulating coating; the porous metal filter tube is charged by an external high voltage power supply.
除尘过程中当导电粉尘到达多孔金属过滤管表面时将被荷载同种电荷,导致导电粉尘之间互相推斥,形成气阻很小的疏松粉饼,使后续的除尘过程不易产生过高的压降,且粉饼容易再生。本发明多孔金属过滤管耐高温、强度好、可焊接,非常适合用于非腐蚀性气氛下的导电粉尘的去除和收集,其导电性也是涂有导电涂层的陶瓷管无法比拟的。通过涂覆绝缘涂料,巧妙地解决了多孔金属过滤管和花板之间的绝缘这一技术难题,本发明相较于现有技术中的绝缘垫件的方式所具备的优势至少包括:绝缘涂料与法兰和多孔金属过滤管之间更服帖,绝缘效果更佳更稳定,同时,在涂刷绝缘涂料的部位上,涂料封闭了多孔金属过滤管的过滤孔道,完全封闭了气体流动,可以防止导电粉尘的沉积,此外,绝缘涂料为多孔金属过滤管和设备花板之间提供了有效和必要的静电隔离区间,绝缘效果可靠。During the dust removal process, when the conductive dust reaches the surface of the porous metal filter tube, it will be loaded with the same kind of charge, causing the conductive dust to repel each other, forming a loose powder cake with small air resistance, so that the subsequent dust removal process is not easy to produce excessive pressure drop. , and the powder cake is easy to regenerate. The porous metal filter tube of the present invention has the advantages of high temperature resistance, good strength and weldability, and is very suitable for removing and collecting conductive dust in a non-corrosive atmosphere, and its conductivity is incomparable to that of a ceramic tube coated with a conductive coating. By coating the insulating paint, the technical problem of insulation between the porous metal filter pipe and the flower plate is skillfully solved. Compared with the insulating pad in the prior art, the advantages of the present invention include at least: insulating paint It is more docile with the flange and the porous metal filter tube, and the insulation effect is better and more stable. At the same time, on the part where the insulating paint is painted, the paint seals the filter channels of the porous metal filter tube, completely sealing off the gas flow, which can prevent The deposition of conductive dust, in addition, the insulating coating provides an effective and necessary electrostatic isolation interval between the porous metal filter tube and the equipment flower plate, and the insulation effect is reliable.
优选地,所述法兰的上部加盖一陶瓷压盖,所述陶瓷压盖通过固定在所述花板上的螺栓来压紧所述法兰。Preferably, the upper part of the flange is covered with a ceramic gland, and the ceramic gland compresses the flange through bolts fixed on the flower plate.
优选地,外部高压电源借助焊接在所述法兰上的导线对所述多孔金属过滤管进行荷电。Preferably, the external high-voltage power supply charges the porous metal filter tube by means of wires welded on the flange.
优选地,所述导线安置在除尘器的净气室内。通过创造性地采用在净气室的洁净气体一侧连接高压电源的方式,相较于在连接在含粉尘一侧的方式,有效防止穿墙瓷件表面沉积导电粉尘而导致的电击穿,大大提高安全性。Preferably, the wires are placed in the clean air chamber of the dust collector. By creatively adopting the method of connecting the high-voltage power supply on the clean gas side of the clean gas chamber, compared with the method of connecting to the dust-containing side, it can effectively prevent the electrical breakdown caused by the deposition of conductive dust on the surface of the through-wall porcelain, greatly greatly Improve security.
优选地,所述外部高压电源是脉冲电源。Preferably, the external high-voltage power supply is a pulse power supply.
优选地,所述多孔金属过滤管的过滤孔道为2~200μm,例如2μm、5μm、10μm、20μm、30μm、50μm、80μm、100μm、120μm、150μm、180μm或200μm等。Preferably, the filter pores of the porous metal filter tube are 2-200 μm, such as 2 μm, 5 μm, 10 μm, 20 μm, 30 μm, 50 μm, 80 μm, 100 μm, 120 μm, 150 μm, 180 μm or 200 μm.
优选地,所述绝缘垫件包括绝缘石棉垫片。Preferably, the insulating gasket includes an insulating asbestos gasket.
优选地,所述净气室设有加压气体反吹口。含有导电粉尘的气体穿过多孔金属过滤管后粉尘留在多孔金属过滤管外部形成疏松粉饼,当粉饼加厚时通过顶部压缩气体的反吹将粉饼打落,并实现多孔金属过滤管的再生。Preferably, the clean gas chamber is provided with a pressurized gas blowback port. After the gas containing conductive dust passes through the porous metal filter tube, the dust remains outside the porous metal filter tube to form a loose powder cake. When the powder cake thickens, the powder cake is knocked off by the back blowing of the compressed gas at the top, and the regeneration of the porous metal filter tube is realized.
优选地,所述除尘室的底部设有集灰仓。顶部压缩气体的反吹打落的导电粉尘落入除尘器下部的灰斗中方便回收。Preferably, a dust bin is provided at the bottom of the dust removal chamber. The conductive dust knocked down by the blowback of the compressed gas at the top falls into the ash hopper at the lower part of the dust collector for easy recovery.
为了进一步解决多孔金属过滤管和除尘器花板之间的绝缘问题,本发明引入了绝缘喉衬。优选地,当所述多孔金属过滤管上荷载的电压超过5kV时,所述法兰和花板之间衬垫一陶瓷喉衬,所述陶瓷喉衬和花板之间,以及,所述陶瓷喉衬和所述法兰之间,均设有绝缘垫件。In order to further solve the insulation problem between the porous metal filter pipe and the flower plate of the dust collector, the invention introduces an insulating throat liner. Preferably, when the voltage loaded on the porous metal filter tube exceeds 5kV, a ceramic throat liner is lined between the flange and the flower plate, between the ceramic throat liner and the flower plate, and the ceramic An insulating pad is provided between the throat liner and the flange.
优选地,所述陶瓷喉衬包括50瓷喉衬、95瓷喉衬或石英喉衬。Preferably, the ceramic throat lining includes 50 porcelain throat lining, 95 porcelain throat lining or quartz throat lining.
优选地,所述陶瓷喉衬的下缘距所述花板5cm以上。Preferably, the lower edge of the ceramic throat lining is more than 5cm away from the flower plate.
优选地,所述陶瓷喉衬的厚度大于等于4mm。Preferably, the thickness of the ceramic throat lining is greater than or equal to 4mm.
优选地,当所述多孔金属过滤管上荷载的电压超过5kV且操作温度不高于100℃时,所述多孔法兰和花板之间衬垫一橡胶喉衬或一塑料喉衬。当使用橡胶喉衬或者塑料喉衬时,由于喉衬可以起到气体密封的作用,所以喉衬与多孔金属过滤管和喉衬与花板之间的绝缘垫件可以省略。Preferably, when the voltage loaded on the porous metal filter tube exceeds 5kV and the operating temperature is not higher than 100°C, a rubber throat liner or a plastic throat liner is lined between the porous flange and the flower plate. When rubber throat liner or plastic throat liner is used, since the throat liner can act as a gas seal, the insulating gasket between the throat liner and the porous metal filter pipe and between the throat liner and the flower plate can be omitted.
优选地,所述橡胶喉衬包括丁苯橡胶喉衬、天然橡胶喉衬、丁氰橡胶喉衬、氯丁橡胶喉衬、顺丁橡胶喉衬、硅橡胶喉衬或氟橡胶喉衬中的任意一种。Preferably, the rubber throat liner includes any of styrene-butadiene rubber throat liner, natural rubber throat liner, nitrile rubber throat liner, neoprene rubber throat liner, butadiene rubber throat liner, silicon rubber throat liner or fluororubber throat liner A sort of.
优选地,所述塑料喉衬包括聚四氟乙烯喉衬、聚乙烯喉衬、聚丙烯喉衬、聚甲醛喉衬、酚醛树脂喉衬或聚苯乙烯喉衬中的任意一种。Preferably, the plastic throat liner includes any one of polytetrafluoroethylene throat liner, polyethylene throat liner, polypropylene throat liner, polyoxymethylene throat liner, phenolic resin throat liner or polystyrene throat liner.
优选地,所述塑料喉衬或橡胶喉衬的下缘距所述花板5cm以上。Preferably, the lower edge of the plastic throat liner or rubber throat liner is more than 5cm away from the flower plate.
优选地,所述塑料喉衬或橡胶喉衬的厚度大于等于4mm。Preferably, the thickness of the plastic or rubber throat lining is greater than or equal to 4mm.
优选地,所述绝缘涂层的厚度为400~1000μm,例如400μm、500μm、600μm、700μm、800μm、900μm或1000μm等。Preferably, the insulating coating has a thickness of 400-1000 μm, such as 400 μm, 500 μm, 600 μm, 700 μm, 800 μm, 900 μm or 1000 μm.
优选地,所述绝缘涂层的面电阻不低于1MΩ/cm2。Preferably, the surface resistance of the insulating coating is not lower than 1MΩ/cm 2 .
优选地,当除尘室内的气体温度在120℃以下时,所述绝缘涂层包括聚氨酯涂料、聚酯涂料、环氧涂料、聚酯-环氧复合粉末涂料、酚醛树脂涂料、脲醛树脂涂料或聚乙烯醇缩醛涂料中的任意一种。Preferably, when the gas temperature in the dedusting chamber is below 120°C, the insulating coating includes polyurethane coating, polyester coating, epoxy coating, polyester-epoxy composite powder coating, phenolic resin coating, urea-formaldehyde resin coating or polyester coating. Any of the vinyl acetal coatings.
优选地,当除尘室内的气体温度高于120℃时,所述绝缘涂层包括环氧涂料或环氧改性硅树脂涂料。Preferably, when the gas temperature in the dedusting chamber is higher than 120° C., the insulating coating includes epoxy paint or epoxy-modified silicone resin paint.
为进一步提绝缘涂料的绝缘性能,优选地,当除尘室内的气体温度高于120℃时,所述绝缘涂层中添加有绝缘粉。In order to further improve the insulating performance of the insulating coating, preferably, when the gas temperature in the dedusting chamber is higher than 120° C., insulating powder is added to the insulating coating.
优选地,所述绝缘粉包括氧化铝粉、BN粉、BaSO4粉、硅微粉或硅藻土中的任意一种或至少两种的组合,优选BN粉,BN粉不仅提高绝缘涂层的绝缘性能而且提高绝缘涂层的导热性避免高温时绝缘涂层膨胀甚至崩裂。Preferably, the insulating powder includes any one or a combination of at least two of alumina powder, BN powder, BaSO powder, microsilica powder or diatomaceous earth, preferably BN powder, which not only improves the insulation of the insulating coating performance and improve the thermal conductivity of the insulating coating to avoid expansion or even cracking of the insulating coating at high temperatures.
优选地,所述绝缘粉的添加量所述绝缘涂层的5wt%~70wt%,例如5wt%、6wt%、7wt%、8wt%、10wt%、12wt%、15wt%、18wt%、20wt%、22wt%、25wt%、28wt%、30wt%、40wt%、45wt%、50wt%、55wt%、60wt%、65wt%或70wt%等。Preferably, the insulating powder is added in an amount of 5wt% to 70wt% of the insulating coating, such as 5wt%, 6wt%, 7wt%, 8wt%, 10wt%, 12wt%, 15wt%, 18wt%, 20wt%, 22wt%, 25wt%, 28wt%, 30wt%, 40wt%, 45wt%, 50wt%, 55wt%, 60wt%, 65wt% or 70wt%, etc.
优选地,所述绝缘粉的粒度为150目~1000目,例如150目、200目、400目、600目、800目或1000目等。Preferably, the particle size of the insulating powder is 150 mesh to 1000 mesh, such as 150 mesh, 200 mesh, 400 mesh, 600 mesh, 800 mesh or 1000 mesh.
本发明对多孔金属过滤管的数量、排布方式、长度不做限制,只要能保证设备在合理的气布比下操作即可。对外接高压电源的位置、高压气体反吹口的位置、给多孔金属过滤管供电的导线的排布方式也不做限制。给多孔金属过滤管供电的导线只要保证每根多孔金属过滤管都能成功电荷便可、外接高压电源的连接只要保证和装置箱体充分绝缘便可。The present invention does not limit the quantity, arrangement and length of the porous metal filter tubes, as long as the equipment can be operated under a reasonable air-to-cloth ratio. There are also no restrictions on the location of the external high-voltage power supply, the location of the high-pressure gas blowback port, and the arrangement of the wires that supply power to the porous metal filter tube. It is only necessary to ensure that each porous metal filter tube can be successfully charged for the wires that supply power to the porous metal filter tubes, and it is sufficient to ensure that the connection of the external high-voltage power supply is fully insulated from the device box.
第二方面,本发明提供一种除导电粉尘的方法,所述除导电粉尘的方法通过如第一方面所述除导电粉尘的装置实现。In the second aspect, the present invention provides a method for removing conductive dust, and the method for removing conductive dust is realized by the device for removing conductive dust as described in the first aspect.
优选地,除导电粉尘时,所述多孔金属过滤管的荷电电压为1~10kV,例如1kV、2kV、3kV、4kV、5kV、6kV、7kV、8kV、9kV或10kV等;Preferably, when removing conductive dust, the charging voltage of the porous metal filter tube is 1-10kV, such as 1kV, 2kV, 3kV, 4kV, 5kV, 6kV, 7kV, 8kV, 9kV or 10kV;
优选地,除导电粉尘时,设置外部高压电源的脉冲电压为1kV~10kV,例如1kV、2kV、3kV、4kV、5kV、6kV、7kV、8kV、9kV或10kV等;脉冲宽度为75~120μS,例如70μS、80μS、90μS、100μS、110μS或120μS等。Preferably, when removing conductive dust, the pulse voltage of the external high-voltage power supply is set to 1kV-10kV, such as 1kV, 2kV, 3kV, 4kV, 5kV, 6kV, 7kV, 8kV, 9kV or 10kV, etc.; the pulse width is 75-120μS, such as 70μS, 80μS, 90μS, 100μS, 110μS or 120μS etc.
第三方面,本发明提供一种如第一方面所述除导电粉尘的装置的用途,所述除导电粉尘的装置用于净化含尘气体和回收导电粉尘。本发明可以用于高温且不含腐蚀组分的气体中分离导电粉尘,而这恰恰是制备导电粉尘常见的气体工况。In a third aspect, the present invention provides the use of the device for removing conductive dust as described in the first aspect, the device for removing conductive dust is used for purifying dust-containing gas and recovering conductive dust. The invention can be used for separating conductive dust in a gas with high temperature and no corrosive components, which is just a common gas working condition for preparing conductive dust.
与现有技术相比,本发明至少具有如下有益效果:Compared with the prior art, the present invention has at least the following beneficial effects:
1.本发明除导电粉尘的装置兼具多孔金属过滤管耐温高、强度好、可焊接的优势,且清灰容易,气阻随粉饼增厚而上升的速度较慢,是具有低气阻、高通量的适用于导电粉尘的高效除尘装置;1. The device for removing conductive dust of the present invention has the advantages of high temperature resistance, good strength, and weldability of porous metal filter tubes, and is easy to clean, and the air resistance rises slowly with the thickness of the powder cake, so it has low air resistance , High-throughput high-efficiency dust removal device suitable for conductive dust;
2.在多孔金属过滤管上部外侧涂覆绝缘涂料,解决了多孔金属过滤管和除尘滑板之间的绝缘,提高除尘效率和安全性;2. Coating insulating paint on the outside of the upper part of the porous metal filter tube, which solves the insulation between the porous metal filter tube and the dust removal slide, and improves the efficiency and safety of dust removal;
3.本发明创造性地采用在洁净气体一侧连接高压电源的方法,相较于在连接在含粉尘一侧,防止电穿击,安全性增加。3. The present invention creatively adopts the method of connecting a high-voltage power supply on the clean gas side, which prevents electrical breakdown and increases safety compared to connecting to the dust-containing side.
附图说明Description of drawings
图1为本发明实施例1中除尘装置的结构示意图;Fig. 1 is the structural representation of dust removal device in the embodiment 1 of the present invention;
图2为本发明实施例1中除尘装置的A-A面剖视图;Fig. 2 is the A-A plane sectional view of dust removal device in the embodiment 1 of the present invention;
图3为本发明实施例1中除尘装置局部的放大图;Figure 3 is an enlarged view of a part of the dust removal device in Example 1 of the present invention;
图4为本发明实施例1中各部件在花板上的安装方式示意图Fig. 4 is a schematic diagram of the installation method of each component on the flower plate in Embodiment 1 of the present invention
图中标记示意为:1:洁净气箱上盖板;2:净气室;3:花板;4:法兰;5:多孔金属过滤管管体;51:多孔金属过滤管顶部绝缘涂料;61:陶瓷压盖;62:陶瓷喉衬;63:绝缘石棉垫片;7:压紧螺栓;9:管壁;10:粉饼;11:导线;12:含尘气流入口;13:加压气体反吹口;14:集灰仓;15:除尘室;16:外部高压电源The marks in the figure are as follows: 1: Clean air box upper cover; 2: Clean air chamber; 3: Flower plate; 4: Flange; 5: Porous metal filter tube body; 51: Porous metal filter tube top insulating paint; 61: ceramic gland; 62: ceramic throat lining; 63: insulating asbestos gasket; 7: compression bolt; 9: pipe wall; 10: powder cake; 11: wire; 12: dusty air inlet; 13: pressurized gas Blowback port; 14: Ash collection bin; 15: Dust removal room; 16: External high voltage power supply
具体实施方式Detailed ways
下面结合附图并通过具体实施方式来进一步说明本发明的技术方案。但下述的实施例仅仅是本发明的简易例子,并不代表或限制本发明的权利保护范围,本发明的保护范围以权利要求书为准。The technical solutions of the present invention will be further described below in conjunction with the accompanying drawings and through specific implementation methods. However, the following embodiments are only simple examples of the present invention, and do not represent or limit the protection scope of the present invention, and the protection scope of the present invention shall be determined by the claims.
实施例1Example 1
一种除导电粉尘的装置,如图1所示,包括通过花板3互相隔离的净气室2和除尘室15;A device for removing conductive dust, as shown in Figure 1, includes a clean air chamber 2 and a dust removal chamber 15 isolated from each other by a flower plate 3;
净气室2的顶端设有洁净气箱上盖板1,侧面设有加压气体反吹口13;The top of the clean gas chamber 2 is provided with an upper cover plate 1 of the clean gas box, and a pressurized gas blowback port 13 is provided on the side;
除尘室15的侧面设有含尘气流入口12,底部设有集灰仓14,室内设有多孔金属过滤管5;如图3、图4所示,多孔金属过滤管5的底端封口,多孔金属过滤管5的顶端与花板3之间通过法兰4与法兰4之下的绝缘石棉垫片63实现气体密封和电绝缘;法兰4的上部加盖的陶瓷压盖61通过固定在花板3上的压紧螺栓7来压紧法兰4;法兰4的外侧和其以下20cm的多孔金属过滤管5外侧均涂覆有绝缘涂层51;如图2所示,外部高压电源16借助焊接在法兰4上的导线11对多孔金属过滤管5进行荷电,导线11安置在净气室2内。The side of dedusting chamber 15 is provided with dust-containing airflow inlet 12, and the bottom is provided with ash collection bin 14, and indoor is provided with porous metal filter pipe 5; As shown in Figure 3, Figure 4, the bottom end sealing of porous metal filter pipe 5, porous Between the top of the metal filter tube 5 and the flower plate 3, gas sealing and electrical insulation are realized through the flange 4 and the insulating asbestos gasket 63 under the flange 4; the ceramic gland 61 on the top of the flange 4 is fixed on the The compression bolt 7 on the flower plate 3 is used to compress the flange 4; the outer side of the flange 4 and the outer side of the porous metal filter tube 5 of 20 cm below it are all coated with an insulating coating 51; as shown in Figure 2, the external high-voltage power supply 16 charges the porous metal filter tube 5 by means of the wire 11 welded on the flange 4 , and the wire 11 is placed in the clean gas chamber 2 .
如图3所示,当金属过滤管5上荷载的电压超过5kV时,法兰4和花板3之间衬垫厚4mm的陶瓷喉衬62,陶瓷喉衬62和花板3之间,以及,陶瓷喉衬62和法兰4之间,均设有绝缘石棉垫片63;陶瓷喉衬62的下缘距花板3为5cm。当多孔金属过滤管5上荷载的电压超过5kV且操作温度不高于100℃时,陶瓷喉衬更换为橡胶喉衬或塑料喉衬。As shown in Figure 3, when the voltage loaded on the metal filter tube 5 exceeds 5kV, a ceramic throat lining 62 with a thickness of 4mm is lined between the flange 4 and the flower plate 3, between the ceramic throat lining 62 and the flower plate 3, and , Between the ceramic throat lining 62 and the flange 4, an insulating asbestos gasket 63 is provided; the lower edge of the ceramic throat lining 62 is 5 cm from the flower plate 3. When the voltage loaded on the porous metal filter tube 5 exceeds 5kV and the operating temperature is not higher than 100°C, the ceramic throat liner is replaced with a rubber throat liner or a plastic throat liner.
除尘过程中,如图3所示,除尘室15中的含尘气流从多孔金属过滤管5外侧通过管壁9实现过滤后净气进入管内后流入净气室2,同时导电粉尘被截留在管壁9的外侧形成输送的粉饼10。During the dust removal process, as shown in Figure 3, the dust-laden airflow in the dust removal chamber 15 passes through the pipe wall 9 from the outside of the porous metal filter tube 5 to achieve filtration. After the clean air enters the pipe, it flows into the clean air chamber 2. The outer side of the wall 9 forms the conveyed powder cake 10 .
实施例2Example 2
装置与实施例1的区别仅在于:多孔金属过滤管为9根,长度为1m,直径为50mm、壁厚为10mm的铜质多孔金属过滤管,其平均气孔尺寸为2μm,法兰的外侧和其以下10cm的多孔金属过滤管外侧均涂覆有绝缘涂层,涂料成分为掺杂70wt%150目SiC颗粒的环氧改性硅树脂涂料,环氧为E21环氧,硅树脂为康宁公司E6108型硅树脂,两者间使用KH-550型硅烷连接,涂料厚度1000μm,面电阻20MΩ/cm2,陶瓷喉衬的陶瓷为95瓷,喉衬厚度4mm,喉衬下缘低于花板下平面5cm。The difference between the device and Example 1 is only that: the porous metal filter tube is 9, the length is 1m, the diameter is 50mm, the copper porous metal filter tube with a wall thickness of 10mm, its average pore size is 2 μm, the outside of the flange and The outside of the porous metal filter tube 10cm below it is coated with an insulating coating. The coating composition is epoxy-modified silicone resin coating doped with 70wt% 150 mesh SiC particles, the epoxy is E21 epoxy, and the silicone resin is Corning E6108 Type silicone resin, KH-550 type silane is used to connect the two, the thickness of the coating is 1000μm, the surface resistance is 20MΩ/cm 2 , the ceramic of the ceramic throat lining is 95 porcelain, the thickness of the throat lining is 4mm, and the lower edge of the throat lining is lower than the lower plane of the flower plate 5cm.
用此装置除导电粉尘的方法:通过外部高压电源将多孔金属过滤管荷电电压设置为10kV,非常适合用于超细铝粉的过滤去除,对于D50为4μm的超细铝粉,该装置在相同过滤条件下的粉饼阻力为常规过滤装置的一半。The method of using this device to remove conductive dust: set the charging voltage of the porous metal filter tube to 10kV through an external high-voltage power supply, which is very suitable for filtering and removing ultra-fine aluminum powder. For ultra-fine aluminum powder with a D50 of 4 μm, the device is The powder cake resistance under the same filtering conditions is half of that of conventional filtering devices.
实施例3Example 3
装置与实施例1的区别仅在于:多孔金属过滤管为17根长度为1m,直径为100mm、壁厚为5mm的不锈钢质多孔金属过滤管,其平均气孔尺寸为200μm,法兰的外侧和其以下20cm的多孔金属过滤管外侧均涂覆有绝缘涂层,涂料成分为掺杂5wt%1000目BN颗粒的环氧涂料,涂料厚度400μm,面电阻10MΩ/cm2。The difference between the device and Example 1 is that the porous metal filter tubes are 17 porous metal filter tubes with a length of 1 m, a diameter of 100 mm, and a stainless steel porous metal filter tube with a wall thickness of 5 mm. The average pore size is 200 μm. The outer sides of the porous metal filter tubes with a thickness of 400 μm and surface resistance of 10 MΩ/cm 2 are coated with an insulating coating on the outer side of the porous metal filter tube of 20 cm below.
用此装置除导电粉尘的方法:外部高压电源电压1kV,脉冲宽度75μS将多孔金属过滤管荷电,非常适合用于超细铝粉的过滤去除。The method of using this device to remove conductive dust: the external high-voltage power supply voltage is 1kV, and the pulse width is 75μS to charge the porous metal filter tube, which is very suitable for filtering and removing ultra-fine aluminum powder.
实施例4Example 4
装置与实施例1的区别仅在于:多孔金属过滤管为20根长度为2m,直径为200mm、壁厚为10mm的铜质多孔过滤管,其平均气孔尺寸为10μm,多孔过滤管按相邻的三个管束构成等边三角形的原则排布管束,管束间距40cm,多孔金属过滤管法兰外侧和从法兰向下15cm的多孔金属过滤管外侧涂覆绝缘涂料,涂料成分为掺杂25wt%400目α-Al2O3颗粒的聚酯涂料,涂料厚度1000μm,面电阻15MΩ/cm2。The difference between the device and Example 1 is only that: the porous metal filter tubes are 20 lengths of 2m, a diameter of 200mm, and a copper porous filter tube with a wall thickness of 10mm, and its average pore size is 10 μm. The three tube bundles form an equilateral triangle to arrange the tube bundles, the distance between the tube bundles is 40cm, and the outside of the flange of the porous metal filter tube and the outside of the porous metal filter tube 15cm down from the flange are coated with insulating paint, and the composition of the paint is doped 25wt% 400 The polyester coating of α-Al 2 O 3 particles, the thickness of the coating is 1000 μm, and the surface resistance is 15MΩ/cm 2 .
用此装置除导电粉尘的方法:外部高压电源将多孔金属过滤管荷电3kV的直流电压,非常适合用于铜粉的过滤去除。The method of using this device to remove conductive dust: the external high-voltage power supply charges the porous metal filter tube with a DC voltage of 3kV, which is very suitable for the filtration and removal of copper powder.
实施例5Example 5
装置与实施例1的区别仅在于:多孔金属过滤管为20根长度为2m,直径为200mm、壁厚为10mm的不锈钢质多孔金属过滤管,其平均气孔尺寸为15μm,按照相邻四个管子构成正方形的方式排布管束,管束间距50cm,多孔金属过滤管法兰外侧和从法兰向下20cm的多孔金属过滤管外侧涂覆绝缘涂料,涂料成分为掺杂25%400目硅微粉颗粒的酚醛树脂涂料,涂料厚度1000μm,面电阻14MΩ/cm2,陶瓷喉衬的成分为石英。The difference between the device and Example 1 is that the porous metal filter tubes are 20 stainless steel porous metal filter tubes with a length of 2m, a diameter of 200mm, and a wall thickness of 10mm. The average pore size is 15 μm. The tube bundles are arranged in a square manner, the tube bundle spacing is 50cm, the outside of the flange of the porous metal filter tube and the outside of the porous metal filter tube 20cm down from the flange are coated with insulating paint, and the paint composition is doped with 25% 400 mesh silicon powder particles Phenolic resin paint, paint thickness 1000μm, surface resistance 14MΩ/cm 2 , the composition of the ceramic throat lining is quartz.
用此装置除导电粉尘的方法:通过外部脉冲电源对多孔金属过滤进行荷电,荷电电压1kV,脉冲宽度120μS,非常适合用于超细铁粉的过滤。The method of using this device to remove conductive dust: charge the porous metal filter through an external pulse power supply, the charging voltage is 1kV, and the pulse width is 120μS, which is very suitable for filtering ultrafine iron powder.
实施例6Example 6
装置与实施例1的区别仅在于:多孔金属过滤管为20根长度为3m,直径为400mm、壁厚为30mm的铜质多孔过滤管,其平均气孔尺寸为10μm,按相邻的三个管束构成等边三角形的原则排布管束,管束间距52cm,多孔金属过滤管法兰外侧和从法兰向下20cm的多孔金属过滤管外侧涂覆绝缘涂料,涂料成分为掺杂25wt%800目重晶石颗粒的聚氨酯涂料,涂料厚度1000μm,面电阻11MΩ/cm2。The difference between the device and Example 1 is only that: the porous metal filter tubes are 20 copper porous filter tubes with a length of 3m, a diameter of 400mm, and a wall thickness of 30mm. The average pore size is 10 μm. The principle of forming an equilateral triangle is to arrange the tube bundles, the distance between the tube bundles is 52cm, and the outside of the flange of the porous metal filter tube and the outside of the porous metal filter tube 20cm down from the flange are coated with insulating paint. Polyurethane coating of stone particles, coating thickness 1000μm, surface resistance 11MΩ/cm 2 .
用此装置除导电粉尘的方法:通过外部高压电源对多孔金属过滤进行荷电,荷载电压为2kV的直流电压,非常适合用于石墨粉的过滤去除。The method of using this device to remove conductive dust: charge the porous metal filter through an external high-voltage power supply, and the load voltage is a DC voltage of 2kV, which is very suitable for filtering and removing graphite powder.
实施例7Example 7
装置与实施例1的区别仅在于:多孔金属过滤管为20根长度为3m,直径为400mm、壁厚为30mm的铜质多孔过滤管,其平均气孔尺寸为10μm,按相邻的三个管束构成等边三角形的原则排布管束,管束间距52cm,多孔金属过滤管法兰外侧和从法兰向下20cm的多孔金属过滤管外侧涂覆绝缘涂料,涂料成分为掺杂25wt%800目重晶石颗粒的聚氨酯涂料,涂料厚度1000μm,面电阻11MΩ/cm2,在多孔金属过滤管和除尘器花板之间加装一个聚四氟乙烯喉衬,喉衬厚度5mm,喉衬下缘低于花板下平面10cm。The difference between the device and Example 1 is only that: the porous metal filter tubes are 20 copper porous filter tubes with a length of 3m, a diameter of 400mm, and a wall thickness of 30mm. The average pore size is 10 μm. The principle of forming an equilateral triangle is to arrange the tube bundles, the distance between the tube bundles is 52cm, and the outside of the flange of the porous metal filter tube and the outside of the porous metal filter tube 20cm down from the flange are coated with insulating paint. Polyurethane coating of stone particles, coating thickness 1000μm, surface resistance 11MΩ/cm 2 , install a polytetrafluoroethylene throat liner between the porous metal filter tube and the dust collector flower plate, the thickness of the throat liner is 5mm, and the lower edge of the throat liner is lower than The lower plane of the flower board is 10cm.
用此装置除导电粉尘的方法:通过外部高压电源对多孔金属过滤进行荷电,荷载电压为2kV的直流电压,非常适合用于石墨粉的过滤去除。The method of using this device to remove conductive dust: charge the porous metal filter through an external high-voltage power supply, and the load voltage is a DC voltage of 2kV, which is very suitable for filtering and removing graphite powder.
实施例8Example 8
装置与实施例1的区别仅在于:多孔金属过滤管为20根长度为3m,直径为400mm、壁厚为30mm的不锈钢多孔过滤管,其平均气孔尺寸为5μm,按相邻的三个管束构成等边三角形的原则排布管束,管束间距52cm,多孔金属过滤管法兰外侧和从法兰向下20cm的多孔金属过滤管外侧涂覆绝缘涂料,涂料成分为掺杂20wt%400目重晶石颗粒的环氧涂料,涂料厚度1000μm,面电阻18MΩ/cm2,在多孔金属过滤管和除尘器花板之间加装一个硅橡胶喉衬,喉衬厚度8mm,喉衬下缘低于花板下平面8cm。The difference between the device and Example 1 is that the porous metal filter tubes are 20 stainless steel porous filter tubes with a length of 3m, a diameter of 400mm, and a wall thickness of 30mm. The tube bundles are arranged in an equilateral triangle, the tube bundle spacing is 52cm, the outside of the flange of the porous metal filter tube and the outside of the porous metal filter tube 20cm down from the flange are coated with insulating paint, and the paint composition is doped with 20wt% 400 mesh barite Particle epoxy paint, paint thickness 1000μm, surface resistance 18MΩ/cm 2 , install a silicone rubber throat liner between the porous metal filter tube and the flower plate of the dust collector, the thickness of the throat liner is 8mm, and the lower edge of the throat liner is lower than the flower plate The lower plane is 8cm.
用此装置除导电粉尘的方法:通过外部高压电源对多孔金属过滤进行荷电,荷载电压为10kV的直流电压,非常适合用于镍粉的过滤去除。The method of using this device to remove conductive dust: charge the porous metal filter through an external high-voltage power supply, and the load voltage is a DC voltage of 10kV, which is very suitable for the filtration and removal of nickel powder.
对比例1Comparative example 1
与实施例1的区别仅在于:用绝缘垫片代替绝缘涂料,具体地,采用常见的弹性石棉垫代替绝缘涂料,由于弹性石棉垫的绝缘性有限,且当被压紧时厚度大大下降,导致装置只能在低于1000V的条件下工作,否则发生带电的多孔金属过滤管和花板之间的电击穿事故,即使在低于1000V电压下工作也偶尔发生电击穿,这导致导电粉尘荷电不足,其间的静电斥力较小,粉饼疏松程度没有明显改变,对于D50为4μm的超细铝粉,对比例1与实施例2相比,粉饼阻力增加了一倍。The only difference from Example 1 is that insulating gaskets are used instead of insulating coatings, specifically, common elastic asbestos mats are used instead of insulating coatings. Since the insulating properties of elastic asbestos mats are limited, and the thickness decreases greatly when compressed, resulting in The device can only work under the condition of less than 1000V, otherwise there will be an electrical breakdown accident between the charged porous metal filter tube and the flower plate, even if it works at a voltage lower than 1000V, electrical breakdown will occasionally occur, which will cause conductive dust Insufficient charge, the electrostatic repulsion therebetween is small, and the looseness of the powder cake has no obvious change. For the ultrafine aluminum powder with a D50 of 4 μm, compared with Example 2 in Comparative Example 1, the resistance of the powder cake doubles.
对比例2Comparative example 2
与对比例1的区别仅在于:将多孔金属过滤管替换为SiC多孔陶瓷管,其表面涂覆导电多孔陶瓷涂层,涂层的导电组分为铜粉。此时无法实现在净气室一侧接导线,改为在导电多孔陶瓷过滤管下部安置电极导架,电极导架和外部高压电源相连接,结构如CN105149092A附图所示。The only difference from Comparative Example 1 is that the porous metal filter tube is replaced by a SiC porous ceramic tube, the surface of which is coated with a conductive porous ceramic coating, and the conductive component of the coating is copper powder. At this time, it is impossible to connect wires on one side of the clean gas chamber. Instead, an electrode guide frame is placed on the lower part of the conductive porous ceramic filter tube, and the electrode guide frame is connected to an external high-voltage power supply. The structure is as shown in the accompanying drawing of CN105149092A.
相同电压下,对于D50为4μm的超细铝粉,对比例2与实施例2相比,除尘过程仅仅持续5min时,就发生了外接高压电源的击穿事故,原因在于超细铝粉在外接高压电源引入除尘器的穿墙瓷件上沉积,导致高压电源引入线和设备壳体之间导通,从而发生短路击穿事故。Under the same voltage, for the ultrafine aluminum powder with D50 of 4 μm, compared with Example 2 in Comparative Example 2, when the dust removal process lasted only 5 minutes, a breakdown accident of an external high-voltage power supply occurred. The high-voltage power supply is introduced into the wall-through ceramic parts of the dust collector to deposit, resulting in conduction between the high-voltage power supply lead-in line and the equipment shell, resulting in a short-circuit breakdown accident.
申请人声明,本发明通过上述实施例来说明本发明的详细工艺设备和工艺流程,但本发明并不局限于上述详细工艺设备和工艺流程,即不意味着本发明必须依赖上述详细工艺设备和工艺流程才能实施。所属技术领域的技术人员应该明了,对本发明的任何改进,对本发明产品各原料的等效替换及辅助成分的添加、具体方式的选择等,均落在本发明的保护范围和公开范围之内。The applicant declares that the present invention illustrates the detailed process equipment and process flow of the present invention through the above-mentioned examples, but the present invention is not limited to the above-mentioned detailed process equipment and process flow, that is, it does not mean that the present invention must rely on the above-mentioned detailed process equipment and process flow process can be implemented. Those skilled in the art should understand that any improvement of the present invention, the equivalent replacement of each raw material of the product of the present invention, the addition of auxiliary components, the selection of specific methods, etc., all fall within the scope of protection and disclosure of the present invention.
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