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CN106824134A - A kind of high efficiency composition adsorbent - Google Patents

A kind of high efficiency composition adsorbent Download PDF

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Publication number
CN106824134A
CN106824134A CN201710162640.6A CN201710162640A CN106824134A CN 106824134 A CN106824134 A CN 106824134A CN 201710162640 A CN201710162640 A CN 201710162640A CN 106824134 A CN106824134 A CN 106824134A
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CN
China
Prior art keywords
high efficiency
diatomite
efficiency composition
activated carbon
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710162640.6A
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Chinese (zh)
Inventor
吴肖颜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
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Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201710162640.6A priority Critical patent/CN106824134A/en
Publication of CN106824134A publication Critical patent/CN106824134A/en
Withdrawn legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/103Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26Synthetic macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/285Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/308Dyes; Colorants; Fluorescent agents

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The invention discloses a kind of high efficiency composition adsorbent, the invention is that, by diatomite, activated carbon, glass microballoon, bentonite, surface modifier is mixed with and forms.High efficiency composition adsorbent of the invention, mainly with diatomite, activated carbon, glass microballoon is main raw material(s), greatly reduces dependence of the adsorbent to activated carbon, effectively reduces the cost of adsorbent.Simultaneously by diatomite, bentonite, by carbonization, and polyacrylamide, surface is modified activated carbon raw material in Sodium Polyacrylate, substantially increases the abundant loose structure of particle specific area.There is potential application value to the heavy metal in sewage and organic dyestuff pollution.With wide commercial application prospect.

Description

A kind of high efficiency composition adsorbent
Technical field
The present invention relates to chemical field, and in particular to a kind of high efficiency composition adsorbent.
Background technology
With the development of economic society, the life of mineral smelting, machine-building, Chemical Manufacture, electronic product and instrument etc. Plurality of heavy metal waste water is produced during product, serious ecological environment harm is caused.Heavy metal enters food chain from agricultural product, Eventually enter into human body, and the problem being enriched with human body, sewage disposal adsorbent is main based on clay, sludge, for industry The treatment of sewage has good effect.
The content of the invention
Present invention aim at, there is provided a kind of high efficiency composition adsorbent, the technical solution adopted by the present invention is as follows:
A kind of high efficiency composition adsorbent, it is characterised in that be mixed with by weight percentage by following components and formed:
Diatomite 25-35 parts
Activated carbon 15-30 parts
Glass microballoon 10-20 parts
Bentonite 5-15 parts
Surface modifier 15-30 parts.
One of preferably, described diatomite particle diameter is in 300-500 mesh.
One of preferably, after described diatomite is through pickling, under nitrogen protection in 800-1000 DEG C of high temperature Carbonization treatment.
One of preferably, described particle size of glass microspheres is in 1-8mm.
One of preferably, described surface modifier is by the polyacrylamide and 1mol/L of 2mol/L Sodium Polyacrylate mixing composition.
One of preferably, described diatomite, bentonite, activated carbon need to through the polyacrylamide of 2mol/L and The Sodium Polyacrylate surface of 1mol/L is modified.
The present invention is relative to the beneficial effect of prior art:High efficiency composition adsorbent of the invention, mainly with diatomite, Activated carbon, glass microballoon is main raw material(s), greatly reduces dependence of the adsorbent to activated carbon, effectively reduces adsorbent Cost.Simultaneously by diatomite, bentonite, activated carbon raw material are by carbonization, and polyacrylamide, surface in Sodium Polyacrylate It is modified, substantially increase the abundant loose structure of particle specific area.Have to the heavy metal in sewage and organic dyestuff pollution Potential application value.With wide commercial application prospect.
Specific embodiment
Design of the invention and the technique effect for producing are clearly and completely described below with reference to embodiment, with It is completely understood by the purpose of the present invention, feature and effect.Obviously, described embodiment is that a part of the invention is implemented Example, rather than whole embodiments, based on embodiments of the invention, those skilled in the art is not before creative work is paid Obtained other embodiment is put, the scope of protection of the invention is belonged to.
Embodiment 1:A kind of high efficiency composition adsorbent, is mixed with and formed by weight percentage by following components:
28 parts of diatomite
25 parts of activated carbon
18 parts of glass microballoon
10 parts of bentonite
19 parts of surface modifier.
Embodiment 2:A kind of high efficiency composition adsorbent, is mixed with and formed by weight percentage by following components:
32 parts of diatomite
20 parts of activated carbon
15 parts of glass microballoon
8 parts of bentonite
25 parts of surface modifier.
One of preferably, described diatomite particle diameter is in 300-500 mesh.
One of preferably, after described diatomite is through pickling, under nitrogen protection in 800-1000 DEG C of high temperature Carbonization treatment.
One of preferably, described particle size of glass microspheres is in 1-8mm.
One of preferably, described diatomite, bentonite, activated carbon need to through the polyacrylamide of 2mol/L and The Sodium Polyacrylate surface of 1mol/L is modified.
Better embodiment of the invention is illustrated above, but the invention is not limited to the implementation Example, those of ordinary skill in the art can also make a variety of equivalent modifications or replace on the premise of without prejudice to spirit of the invention Change, these equivalent modifications or replacement are all contained in the application claim limited range.

Claims (6)

1. a kind of high efficiency composition adsorbent, it is characterised in that be mixed with by weight percentage by following components and formed:
Diatomite 25-35 parts
Activated carbon 15-30 parts
Glass microballoon 10-20 parts
Bentonite 5-15 parts
Surface modifier 15-30 parts.
2. high efficiency composition adsorbent according to claim 1, it is characterised in that described diatomite particle diameter is in 300-500 Mesh.
3. high efficiency composition adsorbent according to claim 1, it is characterised in that described diatomite be through pickling after, in In 800-1000 DEG C of high temperature cabonization treatment under nitrogen protection.
4. high efficiency composition adsorbent according to claim 1, it is characterised in that described particle size of glass microspheres is in 1-8mm.
5. high efficiency composition adsorbent according to claim 1, it is characterised in that described surface modifier is by 2mol/L Polyacrylamide and 1mol/L Sodium Polyacrylate mixing composition.
6. high efficiency composition adsorbent according to claim 1, it is characterised in that described diatomite, bentonite, activated carbon Need to be modified through the Sodium Polyacrylate surface of the polyacrylamide of 2mol/L and 1mol/L.
CN201710162640.6A 2017-03-18 2017-03-18 A kind of high efficiency composition adsorbent Withdrawn CN106824134A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710162640.6A CN106824134A (en) 2017-03-18 2017-03-18 A kind of high efficiency composition adsorbent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710162640.6A CN106824134A (en) 2017-03-18 2017-03-18 A kind of high efficiency composition adsorbent

Publications (1)

Publication Number Publication Date
CN106824134A true CN106824134A (en) 2017-06-13

Family

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Family Applications (1)

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CN201710162640.6A Withdrawn CN106824134A (en) 2017-03-18 2017-03-18 A kind of high efficiency composition adsorbent

Country Status (1)

Country Link
CN (1) CN106824134A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107551990A (en) * 2017-09-27 2018-01-09 重庆三峡学院 A kind of preparation of magnesium hydroxide adsorbent for Dye Adsorption and its adsorption method
CN108502948A (en) * 2018-04-23 2018-09-07 苏州清荷坊环保科技有限公司 A kind of rural sewage filter screen
CN108772039A (en) * 2018-07-02 2018-11-09 信阳师范学院 A kind of preparation method of the magnetic Nano material containing Fe
CN109200672A (en) * 2018-09-03 2019-01-15 安徽中韩净化设备有限公司 A kind of cleaning equipment filtering material
CN110479209A (en) * 2019-09-03 2019-11-22 邓晖 A kind of natural minerals/absorbent charcoal composite material and preparation method thereof
CN115945166A (en) * 2022-12-29 2023-04-11 山西创玺天诚环境工程有限公司 Preparation method of composite adsorbent for coking wastewater and composite adsorbent

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005213309A (en) * 2004-01-28 2005-08-11 Seiichi Manabe Method for reclaiming edible oil and apparatus for reclaiming edible oil
CN103084139A (en) * 2012-12-20 2013-05-08 中国科学院生态环境研究中心 Alumina de-fluorination adsorption material loaded by hard carrier and preparation method of alumina de-fluorination adsorption material
CN103316628A (en) * 2013-06-27 2013-09-25 昆明理工大学 Preparation method and application of adsorbent
CN104289195A (en) * 2014-09-23 2015-01-21 尤明 Activated carbon diatomite particles with well-developed pores and low cost and method for preparing activated carbon diatomite particles with well-developed pores and low cost.
CN105771931A (en) * 2016-04-21 2016-07-20 苏州云舒新材料科技有限公司 Reusable sewage treatment adsorbent
CN106315704A (en) * 2015-07-07 2017-01-11 魏忠 Graphene sewage purifying agent

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005213309A (en) * 2004-01-28 2005-08-11 Seiichi Manabe Method for reclaiming edible oil and apparatus for reclaiming edible oil
CN103084139A (en) * 2012-12-20 2013-05-08 中国科学院生态环境研究中心 Alumina de-fluorination adsorption material loaded by hard carrier and preparation method of alumina de-fluorination adsorption material
CN103316628A (en) * 2013-06-27 2013-09-25 昆明理工大学 Preparation method and application of adsorbent
CN104289195A (en) * 2014-09-23 2015-01-21 尤明 Activated carbon diatomite particles with well-developed pores and low cost and method for preparing activated carbon diatomite particles with well-developed pores and low cost.
CN106315704A (en) * 2015-07-07 2017-01-11 魏忠 Graphene sewage purifying agent
CN105771931A (en) * 2016-04-21 2016-07-20 苏州云舒新材料科技有限公司 Reusable sewage treatment adsorbent

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107551990A (en) * 2017-09-27 2018-01-09 重庆三峡学院 A kind of preparation of magnesium hydroxide adsorbent for Dye Adsorption and its adsorption method
CN107551990B (en) * 2017-09-27 2020-06-09 重庆三峡学院 Preparation of magnesium hydroxide adsorbent for dye adsorption and adsorption method thereof
CN108502948A (en) * 2018-04-23 2018-09-07 苏州清荷坊环保科技有限公司 A kind of rural sewage filter screen
CN108772039A (en) * 2018-07-02 2018-11-09 信阳师范学院 A kind of preparation method of the magnetic Nano material containing Fe
CN108772039B (en) * 2018-07-02 2021-01-01 信阳师范学院 Preparation method of Fe-containing magnetic nano material
CN109200672A (en) * 2018-09-03 2019-01-15 安徽中韩净化设备有限公司 A kind of cleaning equipment filtering material
CN110479209A (en) * 2019-09-03 2019-11-22 邓晖 A kind of natural minerals/absorbent charcoal composite material and preparation method thereof
CN115945166A (en) * 2022-12-29 2023-04-11 山西创玺天诚环境工程有限公司 Preparation method of composite adsorbent for coking wastewater and composite adsorbent

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Application publication date: 20170613

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