CN106566436A - 一种上转换发光型eva光伏胶膜的制备方法 - Google Patents
一种上转换发光型eva光伏胶膜的制备方法 Download PDFInfo
- Publication number
- CN106566436A CN106566436A CN201610936619.2A CN201610936619A CN106566436A CN 106566436 A CN106566436 A CN 106566436A CN 201610936619 A CN201610936619 A CN 201610936619A CN 106566436 A CN106566436 A CN 106566436A
- Authority
- CN
- China
- Prior art keywords
- preparation
- temperature
- conversion luminescence
- agent
- glued membrane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 28
- 238000004020 luminiscence type Methods 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000005038 ethylene vinyl acetate Substances 0.000 claims abstract description 31
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims abstract description 31
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 13
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 13
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 9
- 229920005989 resin Polymers 0.000 claims abstract description 7
- 239000011347 resin Substances 0.000 claims abstract description 7
- 238000010345 tape casting Methods 0.000 claims abstract 3
- 239000012528 membrane Substances 0.000 claims description 13
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 10
- AIYUHDOJVYHVIT-UHFFFAOYSA-M caesium chloride Chemical compound [Cl-].[Cs+] AIYUHDOJVYHVIT-UHFFFAOYSA-M 0.000 claims description 10
- 229910000077 silane Inorganic materials 0.000 claims description 10
- 238000007669 thermal treatment Methods 0.000 claims description 9
- 229910004650 HoF3 Inorganic materials 0.000 claims description 5
- 229910019322 PrF3 Inorganic materials 0.000 claims description 5
- 229910009523 YCl3 Inorganic materials 0.000 claims description 5
- 229910009520 YbF3 Inorganic materials 0.000 claims description 5
- FDIFPFNHNADKFC-UHFFFAOYSA-K trifluoroholmium Chemical compound F[Ho](F)F FDIFPFNHNADKFC-UHFFFAOYSA-K 0.000 claims description 5
- PCMOZDDGXKIOLL-UHFFFAOYSA-K yttrium chloride Chemical compound [Cl-].[Cl-].[Cl-].[Y+3] PCMOZDDGXKIOLL-UHFFFAOYSA-K 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims description 2
- 239000002313 adhesive film Substances 0.000 claims description 2
- 238000005660 chlorination reaction Methods 0.000 claims description 2
- 229920006026 co-polymeric resin Polymers 0.000 claims description 2
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical compound C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000010992 reflux Methods 0.000 claims description 2
- 238000002242 deionisation method Methods 0.000 claims 1
- 238000000227 grinding Methods 0.000 claims 1
- 235000006708 antioxidants Nutrition 0.000 abstract description 11
- 239000000463 material Substances 0.000 abstract description 9
- 238000002156 mixing Methods 0.000 abstract description 3
- 238000004806 packaging method and process Methods 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 2
- 238000002834 transmittance Methods 0.000 abstract description 2
- 238000009966 trimming Methods 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract 3
- 239000006087 Silane Coupling Agent Substances 0.000 abstract 1
- 229920000058 polyacrylate Polymers 0.000 abstract 1
- 238000005096 rolling process Methods 0.000 abstract 1
- 238000004513 sizing Methods 0.000 abstract 1
- -1 β-(3,5- di-tert-butyl-hydroxy phenyl) propanoic acid octadecanol ester Chemical class 0.000 description 8
- 150000002148 esters Chemical class 0.000 description 4
- OBNCKNCVKJNDBV-UHFFFAOYSA-N ethyl butyrate Chemical compound CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 3
- 150000001451 organic peroxides Chemical class 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 2
- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 2
- IGFHQQFPSIBGKE-UHFFFAOYSA-N 4-nonylphenol Chemical class CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- NKLOIQIDDWPNFE-UHFFFAOYSA-N [SiH4].C(C)(C)(C)OOC(C)(C)C Chemical compound [SiH4].C(C)(C)(C)OOC(C)(C)C NKLOIQIDDWPNFE-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 150000008301 phosphite esters Chemical class 0.000 description 2
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 2
- SPTHWAJJMLCAQF-UHFFFAOYSA-N 1,2-di(propan-2-yl)benzene;hydrogen peroxide Chemical compound OO.CC(C)C1=CC=CC=C1C(C)C SPTHWAJJMLCAQF-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- JTXMVXSTHSMVQF-UHFFFAOYSA-N 2-acetyloxyethyl acetate Chemical compound CC(=O)OCCOC(C)=O JTXMVXSTHSMVQF-UHFFFAOYSA-N 0.000 description 1
- YOCHOHIOBBCVFR-UHFFFAOYSA-N 3-tert-butyl-2,2-dimethyloctane Chemical compound CCCCCC(C(C)(C)C)C(C)(C)C YOCHOHIOBBCVFR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 229920006226 ethylene-acrylic acid Polymers 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- DKTKWMAFBNGURD-UHFFFAOYSA-N tert-butyl 2-ethylhexyl carbonate Chemical class CCCCC(CC)COC(=O)OC(C)(C)C DKTKWMAFBNGURD-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
- C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09J123/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
-
- H01L31/0481—
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/206—Applications use in electrical or conductive gadgets use in coating or encapsulating of electronic parts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Photovoltaic Devices (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Inorganic Chemistry (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
本发明涉及光伏胶膜技术领域，尤其是一种上转换发光型EVA光伏胶膜的制备方法；制备方法包括以下步骤：乙烯‑醋酸乙烯共聚物，与上转光剂、抗氧剂、交联剂和硅烷偶联剂按比例充分混合，采用流延法工艺，混料‑挤出‑流延‑测厚‑压花‑定型‑切边‑收卷‑包装；挤出机的第一加热区的温度为260‑320℃，第二加热区的温度为320‑400℃，第三加热区的温度为330‑400℃，连接区的温度为330‑400℃，换网区的温度为330‑400℃；选用上转换发光材料中包含乙烯‑丙烯酸聚合物，与主体EVA树脂相容性好，胶膜在400～1200nm之间的透光率可以达到90％以上，不妨碍太阳能电池对紫外‑可见光的利用。
Description
技术领域
本发明涉及光伏胶膜技术领域，尤其是一种上转换发光型EVA光伏胶膜的制备方法。
背景技术
EVA(乙烯-醋酸乙烯共聚物)是一种热塑性高分子材料，由于成本低、成型方便、光学性能突出、力学性能和电性能优异等，作为太阳能电池封装材料被广泛应用。同时由于硅半导体具有固定的带隙(1.12eV)，传统的晶体硅太阳电池无法完全吸收转换自然的太阳光能量，波长大于1200nm的红外光无法被硅太阳电池所利用，这部分的能量大于太阳光全部能量的30％，而且红外辐射造成电池片工作温度大幅提高，从而降低发电功率，目前市场上的电池片，工作温度每升高1℃，输出功率下降0.3～0.5％。
发明内容
本发明的目的是：克服现有技术中的不足，提供一种上转换发光型EVA光伏胶膜的制备方法，采用该方法制备的EVA光伏胶膜冷却效果好，透明性更好。
为实现上述目的，本发明采用的技术方案如下：
一种上转换发光型EVA光伏胶膜的制备方法，所述制备方法包括以下步骤：乙烯-醋酸乙烯共聚物(EVA)，与上转光剂、抗氧剂、交联剂和硅烷偶联剂按比例充分混合，采用流延法工艺生产，工艺流程为：混料-挤出-流延-测厚-压花-定型-切边-收卷-包装；挤出机的第一加热区的温度为260-320℃，第二加热区的温度为320-400℃，第三加热区的温度为330-400℃，连接区的温度为330-400℃，换网区的温度为330-400℃；
其中乙烯-醋酸乙烯共聚物树脂86.20-96.85％、氯化(乙烯-醋酸乙烯)共聚物树脂1.0-7.5％、上转换发光剂0.2-105％、抗氧剂0.3-2.0％、交联剂0.45-2.0％、硅烷偶联剂0.10-1.10％。
优选的，所述上转光剂采用以下制备方法：将PrF3、ErBr3、HoF3、TmCl3、YbF3、YCl3、GeS、GaS、CsCl按比例加入到一定量去离子水中，加热回流并搅拌至澄清，加入PVB，搅拌至澄清，蒸发掉去离子水，研磨。
优选的，所述PrF3、ErBr3、HoF3、TmCl3、YbF3、YCl3、GeS、GaS、CsCl和PVB的质量比为：1-2％：1-2％：1-2％：1-2％：1-2％：1-3％：3-7％：3-7％：3-6％：73-79％。
优选的，所述PVB中乙烯醇摩尔含量为5～35％。
优选的，所述上转光剂的粒径大小为100nm～3μm。
优选的，所述EVA胶膜的厚度为350～750μm。
采用本发明的技术方案的有益效果是：
1、选用上转换发光材料，能够将1200～2500nm以上的红外线转换为400-1100nm波长的可见光与近红外光，封装之后的电池片温度大幅降低，且1200～2500nm的红外光也被有效利用，电池片输出功率大幅提高。
2、选用上转换发光材料中包含乙烯-丙烯酸聚合物，与主体EVA树脂相容性好，胶膜在400～1200nm之间的透光率可以达到90％以上，不妨碍太阳能电池对紫外-可见光的利用。
具体实施方式
下面结合具体实施例对本发明做进一步说明。
使用的材料为：
主料：乙烯-醋酸乙烯共聚物(EVA)。VA含量为33％，融指(MI)30，美国陶氏集团生产。
氯化EVA：氯的含量为30％，起到增强上转换发光材料相容性的作用。
上转换发光剂按照PrF3：ErBr3：HoF3：TmCl3：YbF3：YCl3：GeS：GaS：CsCl:PVB＝2:2:2:2:2:2:5:5:5:72制备。将EVA树脂、红外屏蔽剂、抗氧剂、交联剂、硅烷偶联剂5种材料按表1的比例充分混合均匀，加入到挤出机料斗，进行熔融挤出，挤出机、模头各区域的温度湿度80～90℃，经模头挤出，途经流延辊冷却，再经测厚、压花工序后进行定型，最后再切边、收卷，包装入库，挤出机的第一加热区的温度为260-320℃，第二加热区的温度为320-400℃，第三加热区的温度为330-400℃，连接区的温度为330-400℃，换网区的温度为330-400℃。然后进行透射率、耐老化测试和电池片功率测试。
表1—不同实施实例配方和性能
实施例3为优选实施方式。
实施例1-5中的抗氧剂包括主抗氧剂和辅抗氧剂，主抗氧剂与辅抗氧剂的质量比为8:1，主抗氧基为β-(3,5-二叔丁基-4-羟基苯基)丙酸十八碳醇酯；辅抗氧剂为三(4-壬基酚)亚磷酸酯和/或亚磷酸三(2,4-二叔丁基苯基)酯，优选为三(4-壬基酚)亚磷酸酯和亚磷酸三(2,4-二叔丁基苯基)酯的复配物，实施例1-5中辅抗氧剂选用的是三(4-壬基酚)亚磷酸酯和亚磷酸三(2,4-二叔丁基苯基)酯的复配物。
本发明中的交联剂包括交联固化剂和助交联剂，交联固化剂与助交联剂的质量比为10:1，其中，交联固化剂包括有机过氧化物和/或偶氮化合物，有机过氧化物包括为过氧化异丙苯、二叔丁基过氧化物、过氧化氢二异丙苯、2,5-二甲基-2,5二叔丁基过氧化己烷、4,4-二(叔戊基过氧)戊酸正丁基酯，过氧化2-乙基己基碳酸叔丁酯、3,3-二(叔丁基过氧)丁酸乙酯中的一种或几种；助交联剂包括三烯丙基异氰脲酸酯、三聚氰酸三烯丙酯、三羟甲基丙烷三甲基丙烯酸酯、二甲基丙烯酸二乙二醇酯中的一种或多种混合。实施例1-5中交联固化剂选用的是有机过氧化物4,4-二(叔戊基过氧)戊酸正丁基酯和3,3-二(叔丁基过氧)丁酸乙酯的混合物，其质量比为1:1，助交联剂选用的是三烯丙基异氰脲酸酯和三羟甲基丙烷三甲基丙烯酸酯的混合区，其质量比为1:1。
本发明中的硅烷偶联剂为乙烯基三乙氧基硅烷、乙烯基三甲氧基硅烷、乙烯基三过氧化叔丁基硅烷、乙烯基三乙酰氧基硅烷、乙烯基三(β-甲氧基乙氧基)硅烷中的至少一种。实施例1-5中的硅烷偶联剂选用的是乙烯基三过氧化叔丁基硅烷和乙烯基三(β-甲氧基乙氧基)硅烷的混合物，质量比为1:1。
表2—不同实施实例配方和性能(EVA树脂：氯化EVA树脂：上转换发光材料：抗氧剂：交联剂：硅烷偶联剂＝93.3:4.0:0.8:1.0:0.8:0.1)
本发明中EVA光伏胶膜的厚度为350～750μm。
尽管上述实施例已对本发明的技术方案进行了详细地描述，但是本发明的技术方案并不限于以上实施例，在不脱离本发明的思想和宗旨的情况下，对本发明的技术方案所做的任何改动都将落入本发明的权利要求书所限定的范围。
Claims (6)
1.一种上转换发光型EVA光伏胶膜的制备方法，其特征在于，所述制备方法包括以下步骤：乙烯-醋酸乙烯共聚物(EVA)，与上转光剂、抗氧剂、交联剂和硅烷偶联剂按比例充分混合，采用流延法工艺生产，工艺流程为：混料-挤出-流延-测厚-压花-定型-切边-收卷-包装；挤出机的第一加热区的温度为260-320℃，第二加热区的温度为320-400℃，第三加热区的温度为330-400℃，连接区的温度为330-400℃，换网区的温度为330-400℃；
其中乙烯-醋酸乙烯共聚物树脂86.20-96.85％、氯化(乙烯-醋酸乙烯)共聚物树脂1.0-7.5％、上转换发光剂0.2-105％、抗氧剂0.3-2.0％、交联剂0.45-2.0％、硅烷偶联剂0.10-1.10％。
2.根据权利要求1所述的一种上转换发光型EVA光伏胶膜的制备方法，其特征在于，所述上转光剂采用以下制备方法：将PrF3、ErBr3、HoF3、TmCl3、YbF3、YCl3、GeS、GaS、CsCl按比例加入到一定量去离子水中，加热回流并搅拌至澄清，加入PVB，搅拌至澄清，蒸发掉去离子水，研磨。
3.根据权利要求2所述的一种上转换发光型EVA光伏胶膜的制备方法，其特征在于，所述PrF3、ErBr3、HoF3、TmCl3、YbF3、YCl3、GeS、GaS、CsCl和PVB的质量比为：1-2％：1-2％：1-2％：1-2％：1-2％：1-3％：3-7％：3-7％：3-6％：73-79％。
4.根据权利要求2中所述的一种上转换发光型EVA光伏胶膜的制备方法，其特征在于：所述PVB中乙烯醇摩尔含量为5～35％。
5.根据权利要求1所述的一种上转换发光型EVA光伏胶膜的制备方法，其特征在于：所述上转光剂的粒径大小为100nm～3μm。
6.根据权利要求1所述的一种上转换发光型EVA光伏胶膜的制备方法，其特征在于：所述EVA胶膜的厚度为350～750μm。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610936619.2A CN106566436B (zh) | 2016-11-01 | 2016-11-01 | 一种上转换发光型eva光伏胶膜的制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610936619.2A CN106566436B (zh) | 2016-11-01 | 2016-11-01 | 一种上转换发光型eva光伏胶膜的制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106566436A true CN106566436A (zh) | 2017-04-19 |
| CN106566436B CN106566436B (zh) | 2018-09-14 |
Family
ID=58533511
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610936619.2A Active CN106566436B (zh) | 2016-11-01 | 2016-11-01 | 一种上转换发光型eva光伏胶膜的制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106566436B (zh) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111607233A (zh) * | 2020-06-29 | 2020-09-01 | 南京大学 | 一种含硅高透明阻燃eva转光膜及其制备方法 |
| CN114716948A (zh) * | 2022-04-28 | 2022-07-08 | 苏州赛伍应用技术股份有限公司 | 一种uv光转换封装材料及其制备方法和应用 |
| CN118325506A (zh) * | 2024-05-06 | 2024-07-12 | 苏州易昇光学材料股份有限公司 | 可同时实现上转换、下转换的光转化胶膜的制备方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101320756A (zh) * | 2007-12-28 | 2008-12-10 | 徐耀平 | 增加太阳能光伏电池光电转化率的透明薄膜的制备 |
| CN102911612A (zh) * | 2012-11-12 | 2013-02-06 | 阿特斯(中国)投资有限公司 | 一种荧光eva胶膜 |
| CN103923374A (zh) * | 2014-03-28 | 2014-07-16 | 江苏斯威克新材料有限公司 | 一种降低光伏组件产生pid现象的eva胶膜及其制备工艺 |
| CN104194661A (zh) * | 2014-08-26 | 2014-12-10 | 常州斯威克光伏新材料有限公司 | 一种转光封装胶膜、其制备工艺及应用 |
-
2016
- 2016-11-01 CN CN201610936619.2A patent/CN106566436B/zh active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101320756A (zh) * | 2007-12-28 | 2008-12-10 | 徐耀平 | 增加太阳能光伏电池光电转化率的透明薄膜的制备 |
| CN102911612A (zh) * | 2012-11-12 | 2013-02-06 | 阿特斯(中国)投资有限公司 | 一种荧光eva胶膜 |
| CN103923374A (zh) * | 2014-03-28 | 2014-07-16 | 江苏斯威克新材料有限公司 | 一种降低光伏组件产生pid现象的eva胶膜及其制备工艺 |
| CN104194661A (zh) * | 2014-08-26 | 2014-12-10 | 常州斯威克光伏新材料有限公司 | 一种转光封装胶膜、其制备工艺及应用 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111607233A (zh) * | 2020-06-29 | 2020-09-01 | 南京大学 | 一种含硅高透明阻燃eva转光膜及其制备方法 |
| CN114716948A (zh) * | 2022-04-28 | 2022-07-08 | 苏州赛伍应用技术股份有限公司 | 一种uv光转换封装材料及其制备方法和应用 |
| CN118325506A (zh) * | 2024-05-06 | 2024-07-12 | 苏州易昇光学材料股份有限公司 | 可同时实现上转换、下转换的光转化胶膜的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106566436B (zh) | 2018-09-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106566436B (zh) | 一种上转换发光型eva光伏胶膜的制备方法 | |
| CN104830024B (zh) | 有机无机混成树脂、包含其的模塑组合物、以及光电装置 | |
| CN108034391A (zh) | 一种具有光转换功能的太阳能电池eva封装胶膜材料及其制备方法 | |
| CN103881596A (zh) | 一种黑色红外反射型光伏eva胶膜 | |
| CN109401682A (zh) | 一种高水汽阻隔性的eva封装胶膜 | |
| CN102766412A (zh) | 一种新型光伏封装胶膜、其制备方法及其使用方法 | |
| CN106566435B (zh) | 一种上转换发光型eva光伏胶膜 | |
| CN107731947A (zh) | 一种光伏组件封装用胶膜及其制备方法以及含有该胶膜的光伏组件 | |
| CN106189932A (zh) | 高光电转化效率的太阳能电池组件及其制备方法 | |
| CN104263260B (zh) | 无机纳米光交联促进剂和纳米复合光交联eva胶膜及其制备方法 | |
| JP2016088995A (ja) | 光半導体封止用樹脂組成物及び光半導体装置 | |
| CN113943537A (zh) | 一种黑色高反复合封装胶膜及其制备方法 | |
| CN106590471B (zh) | 一种红外屏蔽型eva光伏胶膜 | |
| CN104497898B (zh) | 一种可转换紫外波长的太阳能电池封装eva胶膜 | |
| CN106634649A (zh) | 一种红外屏蔽型eva光伏胶膜的制备方法 | |
| JP2013075944A (ja) | エチレン−酢酸ビニル共重合体組成物、ガラス接着性シートおよび太陽電池モジュール | |
| CN104022175B (zh) | 太阳能电池封装用的荧光含氟聚合物薄膜及其制备方法 | |
| CN108395855A (zh) | 一种太阳能电池专用封装材料及其制备方法 | |
| CN104479571A (zh) | 一种稀土荧光染料共增效eva胶膜及其制作方法 | |
| CN104152065B (zh) | 一种具有转光效应的eva封装胶膜 | |
| CN106098915A (zh) | 一种应用于led植物生长灯芯片封装的纳米钙钛矿改性硅胶 | |
| CN102504711A (zh) | 一种太阳能电池封装用乙烯-醋酸乙烯共聚物胶膜及其制备方法 | |
| CN105969250A (zh) | 双玻组件用透明eva封装胶膜的生产工艺 | |
| CN105936739A (zh) | 一种应用于led植物生长灯芯片封装的导热聚光室温固化改性环氧树脂胶 | |
| CN103725209B (zh) | 一种eva薄膜及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |