CN106479292A - Decompose the preparation method of indoor formaldehyde interiro wall latex paint under a kind of normal temperature - Google Patents
Decompose the preparation method of indoor formaldehyde interiro wall latex paint under a kind of normal temperature Download PDFInfo
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- CN106479292A CN106479292A CN201610923007.XA CN201610923007A CN106479292A CN 106479292 A CN106479292 A CN 106479292A CN 201610923007 A CN201610923007 A CN 201610923007A CN 106479292 A CN106479292 A CN 106479292A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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Abstract
The invention discloses decomposing the preparation method of indoor formaldehyde interiro wall latex paint under a kind of normal temperature, belong to interiro wall latex paint preparing technical field.Basic copper carbonate and water are mixed to prepare slurries by the present invention, add hydrochloric acid, and lead to nitrogen exclusion air, intensification is filled with insulation reaction after hydrogen, and reactant is obtained powder thing through filtering, washing, dry, and reacts with silver cyanate, ammonium chloride heating stirring, with after through calcining, melting after, add ascorbic acid, the prepared mixed-powder of brium carbonate baking standby, after taking the mix and blends such as acrylic emulsion, titanium dioxide, process with ultrasonic disperse such as standby mixed-powders and interiro wall latex paint is obtained.The invention has the beneficial effects as follows：Preparation process of the present invention is simple, and gained interiro wall latex paint has stronger scrub performance；Interiro wall latex paint of the present invention effectively can decompose indoor formaldehyde at normal temperatures, purify the air of a room, and decomposition rate is fast, purification efficiency up to more than 98.5%.
Description
Technical field
The present invention relates to decomposing the preparation method of indoor formaldehyde interiro wall latex paint under a kind of normal temperature, belong to interiro wall latex paint system
Standby technical field.
Background technology
The maximum building coating kind of China's consumption is the interiro wall latex paint of high pigment volume concentration (PVC), its cheap and tool
There are appropriate decoration functions and widely applied.Interiro wall latex paint is the big class synthesis with acrylate copolymer emulsion as representative
Resin emulsion coating.Emulsion paint is water-dispersible paint, and it is that filler is after grinding distribution with synthetic resin emulsion as base-material
The coating for adding various auxiliary agents to refine.Interiro wall latex paint is the class coating with macromolecule emulsion as film forming matter, with synthesis
The class water paint that resin emulsion is formulated for base-material addition pigment, filler and various auxiliary agents.
Interiro wall latex paint is one of indoor wall, ceiling primary decoration material, and feature is good decorating effect, easy construction,
Environmental pollution is little, low cost, applies extremely wide.Interiro wall latex paint can be divided into dumb light paint, silk gloss paint, gloss paint and high lac varnish
Deng.It is good that dumb light paint has a nontoxic, tasteless, alkali resistance, safety and environmental protection easy construction, good leveling property, it is adaptable to industrial and mining enterprises, office
School, Comfortable Housing Project, civilian house.Silk gloss paint smooth coating is smooth, exquisite in texture, with silk gloss, excellent is water-fast resistance to
Alkalescence can, it is adaptable to hospital, residential building, office building, residential houses etc..Gloss paint pure color, gloss are soft, paint film is tough and tensile,
Adhesive force is strong, is the product of various interior wall paint first-selections.High lac varnish has super tall and erect covering power, firm attractive in appearance, light such as porcelain, and very high is attached
Put forth effort, high antimildew and antibacterial performance, be the preferably decorative material for internal wall such as luxurious hotels, temple, apartment, residential building, office building.But
Interiro wall latex paint scrub performance is poor and poor to purifying indoor formaldehyde effect at normal temperatures at present, and decomposition rate is slow.Therefore prepare
A kind of scrub resistance is strong, can fast decoupled indoor formaldehyde at normal temperatures interiro wall latex paint, have in association area and send out well
Exhibition prospect.
Content of the invention
The technical problem to be solved：Poor for current interiro wall latex paint scrub performance and right at normal temperatures
Purifying indoor formaldehyde effect is poor, the drawbacks of decomposition rate is slow, there is provided basic copper carbonate is mixed to prepare by one kind with deionized water
Slurries, addition hydrochloric acid, and lead to nitrogen exclusion air, and heating up and insulation reaction after hydrogen is filled with, reactant is through filtering, washing, dry
Prepared powder thing, with silver cyanate, ammonium chloride heating stirring react, with after through calcining, melting after, add ascorbic acid, brium carbonate
The prepared mixed-powder of baking is standby, after taking the mix and blends such as acrylic emulsion, titanium dioxide, with ultrasonic disperse such as standby mixed-powders
Process the method that interiro wall latex paint is obtained.Preparation process of the present invention is simple, and gained interiro wall latex paint scrub performance is strong, to interior
Formaldehyde decomposition speed is fast, and it is poor to purifying indoor formaldehyde effect at normal temperatures to efficiently solve the problems, such as, using after-purification efficiency high.
For solving above-mentioned technical problem, the present invention using technical scheme as described below is：
（1）In mass ratio 2:3, basic copper carbonate is mixed with deionized water, under 300～500r/min, 30～40min is stirred,
Prepared slurries, put it in reactor, while it is 30% to add 1～3% mass fraction of basic carbonate copper mass in reactor
Hydrochloric acid, and lead to nitrogen exclusion air in reactor, 140～160 DEG C are warming up to the stirring of 5 DEG C/min speed, be re-filled with hydrogen
Be 15～30kPa, 2～3h of insulation reaction to hydrogen dividing potential drop, room temperature is cooled to, reactant is obtained, after filtration, 1～2 is washed with ether
Secondary, 1～2h is dry in 50～60 DEG C of vacuum drying chambers, obtain powder thing；
（2）50～60g silver cyanate and 45～55g ammonium chloride is weighed, is sequentially placed in there-necked flask, after mixing, to flask
Middle 0.1～0.5% powder thing obtained above of addition mixture gross mass, and 60～70 DEG C are heated to, 2～3h of stirring reaction, instead
Should after reactant is placed in calcining furnace, at 800～850 DEG C calcine 1～2h；
（3）After the completion for the treatment of above-mentioned calcining, calcined material is put in smelting furnace, with 10 DEG C/min ramp to 1800～3000 DEG C,
Which is made to melt completely, then to being separately added into 0.1～0.5% ascorbic acid of fused mass quality and fused mass quality 0.5 in fused mass
～1.0% brium carbonate, melts 3～4h, cools to room temperature with the furnace, obtain mixed-powder, standby；
（4）Count by weight, weigh respectively 32～35 parts of acrylic emulsions, 15～23 parts of titanium dioxides, 18～20 parts of talcum powder,
5～7 parts of organobentonites, 1～3 part of dimethyl silicone polymer, 3～4 parts of sodium tripolyphosphates, 1～3 part of Nano Silver and 28～40 parts
Deionized water, is put in mixer, stirs 50～60min with 800～1000r/min, collects the mixture after stirring；
（5）Step is added in said mixture（3）Standby mixed-powder, addition are mixture gross mass 3～5%, then plus
Enter 0.2～0.4% lauryl sodium sulfate of mixture gross mass, after mixing, be placed in decentralized processing in 300～500W ultrasonic dispersers
1～2h, that is, be obtained a kind of interiro wall latex paint.
The application process of the present invention：Interior wall substrate surface dust, spot and other burs is removed, then concavo-convex position is used
Perching knife repair smooth after, the watering of inside wall base layer surface, it is 6～7% to keep substrate surface water content, with cylinder by system of the present invention
Decompose indoor formaldehyde interiro wall latex paint even roller under the normal temperature for obtaining and substrate surface is applied to, control roller coat thickness is 1～3mm, roller coat 2
～3 times, roller coat finishes curing conservation 3～5 days, you can.After testing, interiro wall latex paint of the present invention is to indoor formaldehyde decomposition rate
Hurry up, after 1～2h, indoor formaldehyde content declines 70～78%, after 3～5h, indoor formaldehyde content declines more than 98%, at normal temperatures to room
Interior formaldehyde has preferable clean-up effect, is worthy to be popularized and use.
Compared with additive method, Advantageous Effects are the present invention：
（1）Preparation process of the present invention is simple, and gained interiro wall latex paint has stronger scrub performance；
（2）Interiro wall latex paint of the present invention effectively can decompose indoor formaldehyde at normal temperatures, purify the air of a room, and decomposition rate is fast, only
Change efficiency up to more than 98.5%.
Specific embodiment
First in mass ratio 2:3, basic copper carbonate is mixed with deionized water, under 300～500r/min stirring 30～
40min, is obtained slurries, puts it in reactor, while adding 1～3% mass fraction of basic carbonate copper mass in reactor
For 30% hydrochloric acid, and lead to nitrogen in reactor air is excluded, 140～160 DEG C are warming up to the stirring of 5 DEG C/min speed, are re-filled with
Hydrogen is 15～30kPa, 2～3h of insulation reaction to hydrogen dividing potential drop, is cooled to room temperature, obtains reactant, washs 1 with ether after filtration
～2 times, 1～2h is dry in 50～60 DEG C of vacuum drying chambers, obtain powder thing；Weigh 50～60g silver cyanate and 45～55g chlorine
Change ammonium, be sequentially placed in there-necked flask, after mixing, in flask, add mixture gross mass 0.1～0.5% above-mentioned prepared
Powder thing, and be heated to 60～70 DEG C, 2～3h of stirring reaction, reactant is placed in calcining furnace after reaction, 800～850
1～2h is calcined at DEG C；After the completion for the treatment of above-mentioned calcining, calcined material is put in smelting furnace, with 10 DEG C/min ramp to 1800～
3000 DEG C so as to melt completely, then to being separately added into 0.1～0.5% ascorbic acid of fused mass quality and fused mass in fused mass
0.5～1.0% brium carbonate of quality, melts 3～4h, cools to room temperature with the furnace, obtain mixed-powder, standby；Count by weight, point
Another name take 32～35 parts of acrylic emulsions, 15～23 parts of titanium dioxides, 18～20 parts of talcum powder, 5～7 parts of organobentonites, 1～3
Part dimethyl silicone polymer, 3～4 parts of sodium tripolyphosphates, 1～3 part of Nano Silver and 28～40 parts of deionized waters, are put into mixer
In, 50～60min is stirred with 800～1000r/min, collects the mixture after stirring；Finally add in said mixture standby
Mixed-powder, addition are mixture gross mass 3～5%, add 0.2～0.4% dodecyl sulphur of mixture gross mass
Sour sodium, is placed in 1～2h of decentralized processing in 300～500W ultrasonic dispersers after mixing, that is, a kind of interiro wall latex paint is obtained.
Example 1
First in mass ratio 2:3, basic copper carbonate is mixed with deionized water, under 300r/min, 30min is stirred, slurry is obtained
Liquid, puts it in reactor, while it is 30% hydrochloric acid to add 1% mass fraction of basic carbonate copper mass in reactor, and to
Leading to nitrogen in reactor and air being excluded, 140 DEG C are warming up to the stirring of 5 DEG C/min speed, being re-filled with hydrogen to hydrogen dividing potential drop is
15kPa, insulation reaction 2h, room temperature is cooled to, reactant is obtained, washed with ether after filtration 1 time, then at 50 DEG C of vacuum drying chambers
In dry 1h, obtain powder thing；50g silver cyanate and 45g ammonium chloride is weighed, is sequentially placed in there-necked flask, after mixing, to burning
0.1% powder thing obtained above of mixture gross mass is added in bottle, and is heated to 60 DEG C, stirring reaction 2h, will reaction after reaction
Thing is placed in calcining furnace, calcines 1h at 800 DEG C；After the completion for the treatment of above-mentioned calcining, calcined material is put in smelting furnace, with 10 DEG C/min
Ramp is to 1800 DEG C so as to melt completely, then to be separately added in fused mass 0.1% ascorbic acid of fused mass quality and
0.5% brium carbonate of fused mass quality, melts 3h, cools to room temperature with the furnace, obtain mixed-powder, standby；Count by weight, respectively
Weigh 32 parts of acrylic emulsions, 15 parts of titanium dioxides, 18 parts of talcum powder, 5 parts of organobentonites, 1 part of dimethyl silicone polymer, 3 parts
Sodium tripolyphosphate, 1 part of Nano Silver and 28 parts of deionized waters, are put in mixer, stir 50min with 800r/min, collect stirring
Mixture afterwards；Finally standby mixed-powder is added in said mixture, addition is mixture gross mass 3%, adds
0.2% lauryl sodium sulfate of mixture gross mass, is placed in decentralized processing 1h in 300W ultrasonic dispersers after mixing, that is, be obtained one
Plant interiro wall latex paint.
Remove interior wall substrate surface dust, spot and other burs, then by concavo-convex position with perching knife repair smooth after, to
Interior wall substrate surface is sprinkled water, and it is 6% to keep substrate surface water content, will decompose indoor first with cylinder under normal temperature obtained in the present invention
Aldehyde interiro wall latex paint even roller is applied to substrate surface, and control roller coat thickness is 1mm, roller coat 2 times, and roller coat finishes curing conservation 3 days,
?.After testing, interiro wall latex paint of the present invention is fast to indoor formaldehyde decomposition rate, after after 1h, indoor formaldehyde content declines 70%, 3h
Indoor formaldehyde content declines 98.9%, has preferable clean-up effect to indoor formaldehyde at normal temperatures, is worthy to be popularized and use.
Example 2
First in mass ratio 2:3, basic copper carbonate is mixed with deionized water, under 400r/min, 35min is stirred, slurry is obtained
Liquid, puts it in reactor, while it is 30% hydrochloric acid to add 2% mass fraction of basic carbonate copper mass in reactor, and to
Leading to nitrogen in reactor and air being excluded, 150 DEG C are warming up to the stirring of 5 DEG C/min speed, being re-filled with hydrogen to hydrogen dividing potential drop is
22kPa, insulation reaction 3h, room temperature is cooled to, reactant is obtained, washed with ether after filtration 2 times, then at 55 DEG C of vacuum drying chambers
In dry 2h, obtain powder thing；55g silver cyanate and 50g ammonium chloride is weighed, is sequentially placed in there-necked flask, after mixing, to burning
0.3% powder thing obtained above of mixture gross mass is added in bottle, and is heated to 65 DEG C, stirring reaction 3h, will reaction after reaction
Thing is placed in calcining furnace, calcines 2h at 830 DEG C；After the completion for the treatment of above-mentioned calcining, calcined material is put in smelting furnace, with 10 DEG C/min
Ramp is to 2400 DEG C so as to melt completely, then to be separately added in fused mass 0.3% ascorbic acid of fused mass quality and
0.8% brium carbonate of fused mass quality, melts 4h, cools to room temperature with the furnace, obtain mixed-powder, standby；Count by weight, respectively
Weigh 34 parts of acrylic emulsions, 19 parts of titanium dioxides, 19 parts of talcum powder, 6 parts of organobentonites, 2 parts of dimethyl silicone polymers, 4 parts
Sodium tripolyphosphate, 2 parts of Nano Silvers and 34 parts of deionized waters, are put in mixer, stir 55min with 900r/min, collect stirring
Mixture afterwards；Finally standby mixed-powder is added in said mixture, addition is mixture gross mass 4%, adds
0.3% lauryl sodium sulfate of mixture gross mass, is placed in decentralized processing 2h in 400W ultrasonic dispersers after mixing, that is, be obtained one
Plant interiro wall latex paint.
Remove interior wall substrate surface dust, spot and other burs, then by concavo-convex position with perching knife repair smooth after, to
Interior wall substrate surface is sprinkled water, and it is 7% to keep substrate surface water content, will decompose indoor first with cylinder under normal temperature obtained in the present invention
Aldehyde interiro wall latex paint even roller is applied to substrate surface, and control roller coat thickness is 2mm, roller coat 3 times, and roller coat finishes curing conservation 4 days,
?.After testing, interiro wall latex paint of the present invention is fast to indoor formaldehyde decomposition rate, after after 2h, indoor formaldehyde content declines 74%, 4h
Indoor formaldehyde content declines 99.1%, has preferable clean-up effect to indoor formaldehyde at normal temperatures, is worthy to be popularized and use.
Example 3
First in mass ratio 2:3, basic copper carbonate is mixed with deionized water, under 500r/min, 40min is stirred, slurry is obtained
Liquid, puts it in reactor, while it is 30% hydrochloric acid to add 3% mass fraction of basic carbonate copper mass in reactor, and to
Leading to nitrogen in reactor and air being excluded, 160 DEG C are warming up to the stirring of 5 DEG C/min speed, being re-filled with hydrogen to hydrogen dividing potential drop is
30kPa, insulation reaction 3h, room temperature is cooled to, reactant is obtained, washed with ether after filtration 2 times, then at 60 DEG C of vacuum drying chambers
In dry 2h, obtain powder thing；60g silver cyanate and 55g ammonium chloride is weighed, is sequentially placed in there-necked flask, after mixing, to burning
0.5% powder thing obtained above of mixture gross mass is added in bottle, and is heated to 70 DEG C, stirring reaction 3h, will reaction after reaction
Thing is placed in calcining furnace, calcines 2h at 850 DEG C；After the completion for the treatment of above-mentioned calcining, calcined material is put in smelting furnace, with 10 DEG C/min
Ramp is to 3000 DEG C so as to melt completely, then to be separately added in fused mass 0.5% ascorbic acid of fused mass quality and
1.0% brium carbonate of fused mass quality, melts 4h, cools to room temperature with the furnace, obtain mixed-powder, standby；Count by weight, respectively
Weigh 35 parts of acrylic emulsions, 23 parts of titanium dioxides, 20 parts of talcum powder, 7 parts of organobentonites, 3 parts of dimethyl silicone polymers, 4 parts
Sodium tripolyphosphate, 3 parts of Nano Silvers and 40 parts of deionized waters, are put in mixer, stir 60min with 1000r/min, collect stirring
Mixture afterwards；Finally standby mixed-powder is added in said mixture, addition is mixture gross mass 5%, adds
0.4% lauryl sodium sulfate of mixture gross mass, is placed in decentralized processing 2h in 500W ultrasonic dispersers after mixing, that is, be obtained one
Plant interiro wall latex paint.
Remove interior wall substrate surface dust, spot and other burs, then by concavo-convex position with perching knife repair smooth after, to
Interior wall substrate surface is sprinkled water, and it is 7% to keep substrate surface water content, will decompose indoor first with cylinder under normal temperature obtained in the present invention
Aldehyde interiro wall latex paint even roller is applied to substrate surface, and control roller coat thickness is 3mm, roller coat 3 times, and roller coat finishes curing conservation 5 days,
?.After testing, interiro wall latex paint of the present invention is fast to indoor formaldehyde decomposition rate, after after 2h, indoor formaldehyde content declines 78%, 5h
Indoor formaldehyde content declines 99.4%, has preferable clean-up effect to indoor formaldehyde at normal temperatures, is worthy to be popularized and use.
Claims (1)
1. the preparation method of indoor formaldehyde interiro wall latex paint is decomposed under a kind of normal temperature, it is characterised in that specifically preparation process is：
（1）In mass ratio 2:3, basic copper carbonate is mixed with deionized water, under 300～500r/min, 30～40min is stirred,
Prepared slurries, put it in reactor, while it is 30% to add 1～3% mass fraction of basic carbonate copper mass in reactor
Hydrochloric acid, and lead to nitrogen exclusion air in reactor, 140～160 DEG C are warming up to the stirring of 5 DEG C/min speed, be re-filled with hydrogen
Be 15～30kPa, 2～3h of insulation reaction to hydrogen dividing potential drop, room temperature is cooled to, reactant is obtained, after filtration, 1～2 is washed with ether
Secondary, 1～2h is dry in 50～60 DEG C of vacuum drying chambers, obtain powder thing；
（2）50～60g silver cyanate and 45～55g ammonium chloride is weighed, is sequentially placed in there-necked flask, after mixing, to flask
Middle 0.1～0.5% powder thing obtained above of addition mixture gross mass, and 60～70 DEG C are heated to, 2～3h of stirring reaction, instead
Should after reactant is placed in calcining furnace, at 800～850 DEG C calcine 1～2h；
（3）After the completion for the treatment of above-mentioned calcining, calcined material is put in smelting furnace, with 10 DEG C/min ramp to 1800～3000 DEG C,
Which is made to melt completely, then to being separately added into 0.1～0.5% ascorbic acid of fused mass quality and fused mass quality 0.5 in fused mass
～1.0% brium carbonate, melts 3～4h, cools to room temperature with the furnace, obtain mixed-powder, standby；
（4）Count by weight, weigh respectively 32～35 parts of acrylic emulsions, 15～23 parts of titanium dioxides, 18～20 parts of talcum powder,
5～7 parts of organobentonites, 1～3 part of dimethyl silicone polymer, 3～4 parts of sodium tripolyphosphates, 1～3 part of Nano Silver and 28～40 parts
Deionized water, is put in mixer, stirs 50～60min with 800～1000r/min, collects the mixture after stirring；
（5）Step is added in said mixture（3）Standby mixed-powder, addition are mixture gross mass 3～5%, then plus
Enter 0.2～0.4% lauryl sodium sulfate of mixture gross mass, after mixing, be placed in decentralized processing in 300～500W ultrasonic dispersers
1～2h, that is, be obtained a kind of interiro wall latex paint.
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| CN201610923007.XA CN106479292A (en) | 2016-10-29 | 2016-10-29 | Decompose the preparation method of indoor formaldehyde interiro wall latex paint under a kind of normal temperature |
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| CN201610923007.XA CN106479292A (en) | 2016-10-29 | 2016-10-29 | Decompose the preparation method of indoor formaldehyde interiro wall latex paint under a kind of normal temperature |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2024006517A1 (en) * | 2022-07-01 | 2024-01-04 | Arxada, LLC | Copper containing compounds and compositions for antimicrobial paint and coating |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103509389A (en) * | 2013-09-22 | 2014-01-15 | 三棵树涂料股份有限公司 | Dustproof antibacterial emulsion paint and preparation method thereof |
| CN104497765A (en) * | 2015-01-26 | 2015-04-08 | 重庆索利特涂料有限公司 | Inner wall latex paint capable of removing formaldehyde and preparation method of inner wall latex paint |
| CN104893444A (en) * | 2015-05-29 | 2015-09-09 | 江苏恒智纳米科技有限公司 | Multifunctional aqueous nano-coating |
-
2016
- 2016-10-29 CN CN201610923007.XA patent/CN106479292A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103509389A (en) * | 2013-09-22 | 2014-01-15 | 三棵树涂料股份有限公司 | Dustproof antibacterial emulsion paint and preparation method thereof |
| CN104497765A (en) * | 2015-01-26 | 2015-04-08 | 重庆索利特涂料有限公司 | Inner wall latex paint capable of removing formaldehyde and preparation method of inner wall latex paint |
| CN104893444A (en) * | 2015-05-29 | 2015-09-09 | 江苏恒智纳米科技有限公司 | Multifunctional aqueous nano-coating |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2024006517A1 (en) * | 2022-07-01 | 2024-01-04 | Arxada, LLC | Copper containing compounds and compositions for antimicrobial paint and coating |
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Application publication date: 20170308 |