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CN105969046A - Disease-suppression antibacterial beautiful sealant and preparation technology thereof - Google Patents

Disease-suppression antibacterial beautiful sealant and preparation technology thereof Download PDF

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Publication number
CN105969046A
CN105969046A CN201610324688.8A CN201610324688A CN105969046A CN 105969046 A CN105969046 A CN 105969046A CN 201610324688 A CN201610324688 A CN 201610324688A CN 105969046 A CN105969046 A CN 105969046A
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China
Prior art keywords
agent
parts
component
antibacterial
disease
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CN201610324688.8A
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Inventor
戴军喜
戴军城
吴星
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Suzhou Long Environmental Protection Technology Co Ltd
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Suzhou Long Environmental Protection Technology Co Ltd
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Priority to CN201610324688.8A priority Critical patent/CN105969046A/en
Publication of CN105969046A publication Critical patent/CN105969046A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Inorganic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

The invention provides a disease-suppression antibacterial beautiful sealant and a preparation technology thereof. The disease-suppression antibacterial beautiful sealant comprises a component A and a component B, wherein the component A comprises 50-90 parts of epoxy resin, 1-5 parts of benzyl alcohol, 0.2-1.2 parts of antifoaming agent, 1-9 parts of fumed silica, 0.3-1.2 parts of thixotropic agent, 0.2-0.8 part of silver antibacterial agent, 0.5-1.2 parts of ultraviolet light absorber, 1-6 parts of water repellent agent, 3-40 parts of toner and 1-20 parts of flexibility aid; and the component B comprises 10-20 parts of polyether amine, 9-35 parts of alicyclic amine, 25-45 parts of epoxy resin, 20-40 parts of benzyl alcohol, 0.5-2 parts of antifoaming agent, 0.5-4 parts of fumed silica, 1-5 parts of thixotropic agent and 0.2-0.9 part of silver antibacterial agent. In the invention, the active viruses and bacteria existing in the joints can be suppressed while the joints are filled for beautifying, and the sources of indoor microbial pollution are reduced.

Description

Press down the antibacterial joint trimming agent of disease and preparation technology thereof
Technical field
The present invention relates to a kind of joint trimming agent, particularly relate to one and press down the antibacterial joint trimming agent of disease and preparation technology thereof.
Background technology
World Health Organization's investigation shows, indoor biological pollutes the health the most gradually swallowing people, and when house pet is played indoor, the hair come off connects homoecious acarid and can enter in gap, ground simultaneously.Additionally, be scattered in ground food debris, also falling within gap, ground when sweeping, become the grain ration of microorganism, these indoor microbes carry out the propagation of virus and antibacterial.Can not be ignored is that slit surfaces easily becomes black mould after four or five months simultaneously, brickwork joint blackening meeting breed bacteria, produces abnormal flavour, affects environment, be detrimental to health, and this antibacterial was especially apparent in summer, brought all multi-risk Systems to people's life.
Therefore, in fitment process, in order to fill up the gap existed between ceramic tile, joint trimming agent the most all can be filled between these gaps, so either the hall of kitchen or toilet, even business finishing all can have the figure of joint trimming agent to occur.
But, existing joint trimming agent and gap filler are more to pay close attention to the performances such as flintiness, rub resistance, color be beautiful, to suppression gap virus anti-microbial property aspect Shortcomings.Thus, existing joint trimming agent and gap filler suppression gap virus antibacterial effect are the most inconspicuous, it is impossible to reduce indoor microorganism pollution source and reduce its injury to human body.
Specifically, existing gap filler, form for major ingredient stirring with white cement, be divided into and have sandbox and without sandbox.But, above-mentioned joint trimming agent and gap filler are without water proofing property, so by gap filler time length, the moisture in air can be absorbed, and sewage can infilter brickwork joint when cleaning, and causes wiping dirtier and dirtier black, turn to be yellow mouldy, thus multiply substantial amounts of antibacterial and pathogenic bacteria, affect people healthy.
Additionally, existing one-component joint trimming agent aesthetics makes moderate progress than above-mentioned gap filler, it is bright in luster abundant, and pliability is also preferable, but this one-component joint trimming agent easily occurs shrinking after complete solidification of constructing, of long duration easy to fall off.And re-form gap, and easily shelter evil people and countenance evil practices, non-watertight, easily go mouldy, bonding force is poor, and hardness is low, not resistant, not scrubbing resistance.Further, existing double-component joint trimming agent, service life surpasses common one-component joint trimming agent, it is bright in luster abundant, and contractility is the least, is fully cured rear intensity the highest, and its surface can form the three-dimensional-structure macromolecule layer that layer of transparent is highly cross-linked, there is good gloss.The antibacterial effect but above-mentioned double-component joint trimming agent does not sterilize.
It addition, existing aqua type joint trimming agent, water resistance is preferable, but after construction, easily evaporation is subsided serious after causing solidification, bubble and cavity, the aesthetic property that impact is overall occurs.And the life-span only have 2 to 5 years.
Therefore, for the problems referred to above, it is necessary to propose further solution.
Summary of the invention
It is an object of the invention to provide one and press down the antibacterial joint trimming agent of disease and preparation technology thereof, to overcome the deficiencies in the prior art.
For achieving the above object, the present invention provides one to press down the antibacterial joint trimming agent of disease, and it includes component A and the B component that volume ratio is 1:1;
Described component A includes by weight: epoxy resin 50-90 part, benzyl alcohol 1-5 part, defoamer 0.2-1.2 part, aerosil 1-9 part, thixotropic agent 0.3-1.2 part, silver antibacterial agent 0.2-0.8 part, UV absorbent 0.5-1.2 part, water repellent agent 1-6 part, toner 3-40 part, pliable and tough auxiliary agent 1-20 part;
Described B component includes by weight: polyetheramine 10-20 part, aliphatic cyclic amine 9-35 part, epoxy resin 25-45 part, benzyl alcohol 20-40 part, defoamer 0.5-2 part, aerosil 0.5-4 part, thixotropic agent 1-5 part, silver antibacterial agent 0.2-0.9 part.
As the improvement pressing down the antibacterial joint trimming agent of disease of the present invention, in described component A, described toner includes pearlescent flake pigments and glitter powder.
As the improvement pressing down the antibacterial joint trimming agent of disease of the present invention, described silver antibacterial agent is silver ion antimicrobial agent or nano silver antimicrobials.
As the improvement pressing down the antibacterial joint trimming agent of disease of the present invention, described in press down component A and the B component that the antibacterial joint trimming agent of disease includes that volume ratio is 1:1;
Described component A includes by weight: epoxy resin 80 parts, benzyl alcohol 3 parts, defoamer 0.7 part, aerosil 4 parts, thixotropic agent 0.7 part, silver antibacterial agent 0.5 part, UV absorbent 0.6 part, water repellent agent 1 part, toner 8 parts, pliable and tough auxiliary agent 1.5 parts;
Described B component includes by weight: polyetheramine 15 parts, aliphatic cyclic amine 22 parts, epoxy resin 28 parts, benzyl alcohol 29 parts, defoamer 1.2 parts, aerosil 2.3 parts, thixotropic agent 2 parts, silver antibacterial agent 0.5 part.
For achieving the above object, the present invention also provides for a kind of basis and presses down the preparation technology of the antibacterial joint trimming agent of disease as above, it preparation process including component A and the preparation process of B component:
The preparation process of described component A includes:
Weigh epoxy resin 50-90 part, benzyl alcohol 1-5 part, defoamer 0.2-1.2 part, aerosil 1-9 part, thixotropic agent 0.3-1.2 part, silver antibacterial agent 0.2-0.8 part, UV absorbent 0.5-1.2 part, water repellent agent 1-6 part, toner 3-40 part, pliable and tough auxiliary agent 1-20 part, the each material weighed is carried out under conditions of high-speed stirred mixing dispersion, it is then refluxed for reaction, and sucking filtration, it is thus achieved that described component A;
The preparation process of described B component includes:
Weigh polyetheramine 10-20 part and aliphatic cyclic amine 9-35 part, react stand-by, then, weigh each material in the following order and join in reaction system: thixotropic agent 1-5 part, silver antibacterial agent 0.2-0.9 part.Epoxy resin 25-45 part, benzyl alcohol 20-40 part, defoamer 0.5-2 part, aerosil 0.5-4 part, carry out mixing dispersion, then sucking filtration, it is thus achieved that described B component under conditions of low rate mixing by reaction system.
As the improvement pressing down the antibacterial joint trimming agent of disease of the present invention, described high-speed stirred is 1400-2800 rev/min, and mixing the scattered time is 5-30 minute.
As the improvement pressing down the antibacterial joint trimming agent of disease of the present invention, the time of described back flow reaction is 1 hour.
As the improvement pressing down the antibacterial joint trimming agent of disease of the present invention, described low rate mixing is 300-500 rev/min.
As the improvement pressing down the antibacterial joint trimming agent of disease of the present invention, in the preparation process of described B component, reaction temperature is less than 60 DEG C.
Compared with prior art, the invention has the beneficial effects as follows: the present invention press down the antibacterial joint trimming agent of disease can filling chink bring attractive in appearance while, live present in suppression gap and send out sexually transmitted disease (STD) poison (such as H5N1 type virus and SARS virus) and antibacterial (such as Bacillus cercus, Salmonella, escherichia coli, bacillus pyocyaneus, Staphylococcus aureus, enterococcus, intestinal tube hemorrhagic coliform, candidiasis, bakers' yeast, Aspergillus niger, chaetomium globosum, penicillium, tinea alba bacterium etc.), reduce indoor microorganism pollution source, reduce microorganism pollute the injury to human body and reduce environmental pollution.Additionally, the antibacterial joint trimming agent of disease that presses down of the present invention uses silver antibacterial agent, so it is not likely to produce Drug resistance bacterium.
The present invention to press down disease antibacterial joint trimming agent range wide, can be widely used in the gap of various construction materials, scrubbing resistance, abrasion-resistant, hard, waterproof, difficult drop-off, not sagging, anti-mildew, bright color does not fades, adhesion strength big, length in service life, environmental protection.
The present invention to press down disease antibacterial joint trimming agent production cost relatively low, it is only necessary to add a small amount of silver antibacterial agent and just can reach good antibacterial effect, energy-conserving and environment-protective.Preparation technology is simple, easy to process, adds and be uniformly dispersed together with filler, and production efficiency improves, product easy construction, safe fanout free region.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in detail; but it should explanation is; these embodiments not limitation of the present invention; those of ordinary skill in the art are according to the equivalent transformation in these embodiment institute work energy, method or structure or replacement, within belonging to protection scope of the present invention.
The present invention presses down component A and the B component that the antibacterial joint trimming agent of disease includes that volume ratio is 1:1.
Wherein, described component A includes by weight: epoxy resin 50-90 part, benzyl alcohol 1-5 part, defoamer 0.2-1.2 part, aerosil 1-9 part, thixotropic agent 0.3-1.2 part, silver antibacterial agent 0.2-0.8 part, UV absorbent 0.5-1.2 part, water repellent agent 1-6 part, toner 3-40 part, pliable and tough auxiliary agent 1-20 part;
Described B component includes by weight: polyetheramine 10-20 part, aliphatic cyclic amine 9-35 part, epoxy resin 25-45 part, benzyl alcohol 20-40 part, defoamer 0.5-2 part, aerosil 0.5-4 part, thixotropic agent 1-5 part, silver antibacterial agent 0.2-0.9 part.
Preferably, in described component A, described silver antibacterial agent can be silver ion antimicrobial agent or nano silver antimicrobials.Described toner includes pearlescent flake pigments and glitter powder.
Be preferably carried out mode as one, described in press down component A and the B component that the antibacterial joint trimming agent of disease includes that volume ratio is 1:1.Wherein, described component A includes by weight: epoxy resin 80 parts, benzyl alcohol 3 parts, defoamer 0.7 part, aerosil 4 parts, thixotropic agent 0.7 part, silver antibacterial agent 0.5 part, UV absorbent 0.6 part, water repellent agent 1 part, toner 8 parts, pliable and tough auxiliary agent 1.5 parts;Described B component includes by weight: polyetheramine 15 parts, aliphatic cyclic amine 22 parts, epoxy resin 28 parts, benzyl alcohol 29 parts, defoamer 1.2 parts, aerosil 2.3 parts, thixotropic agent 2 parts, silver antibacterial agent 0.5 part.
Based on pressing down the antibacterial joint trimming agent of disease as above, the present invention also provides for a kind of preparation technology, and this preparation technology includes the preparation process of component A and the preparation process of B component:
The preparation process of described component A includes: weigh epoxy resin 50-90 part, benzyl alcohol 1-5 part, defoamer 0.2-1.2 part, aerosil 1-9 part, thixotropic agent 0.3-1.2 part, silver antibacterial agent 0.2-0.8 part, UV absorbent 0.5-1.2 part, water repellent agent 1-6 part, toner 3-40 part, pliable and tough auxiliary agent 1-20 part, the each material weighed is carried out under conditions of high-speed stirred mixing dispersion, it is then refluxed for reaction, and sucking filtration, it is thus achieved that described component A.
Wherein, the purpose carrying out high-speed stirred is: owing to raw material viscosity is high, the speed of high-speed stirred is fast, is conducive to improving dispersibility so that between raw material more can comprehensive mix homogeneously, after aerosil merges simultaneously, the transparency is more preferably.And make the pigment in component A the most gorgeous, other material transparent Du Genggao in addition to toner in component A.Preferably, described high-speed stirred is 1400-2800 rev/min, and mixing the scattered time is 5-30 minute.The time of described back flow reaction is 1 hour.Furthermore, it is necessary to explanation, during high speed dispersion, in container, temperature controls within 70 DEG C.Therefore, in whipping process, after component A cooling more than 70 DEG C, easily lump hardening.Therefore, it should avoid component A to be filled to occur in product packaging the phenomenon of caking.
The preparation process of described B component includes: weighs polyetheramine 10-20 part and aliphatic cyclic amine 9-35 part, reacts stand-by, then, weighs each material in the following order and joins in reaction system: thixotropic agent 1-5 part, silver antibacterial agent 0.2-0.9 part.Epoxy resin 25-45 part, benzyl alcohol 20-40 part, defoamer 0.5-2 part, aerosil 0.5-4 part, carry out mixing dispersion, then sucking filtration, it is thus achieved that described B component under conditions of low rate mixing by reaction system.
Wherein, carry out the slowest purpose and be: in order to avoid temperature is too high, cause caking solidification.And temperature can become slightly yellow more than the raw material of 60 degrees Celsius of B component, the color that the toner in component A can be made to embody is the purest.Furthermore, it is necessary to explanation, in the preparation process of described B component, each material must be added in strict accordance with described order, to avoid the generation of side reaction.Preferably, described low rate mixing is 300-500 rev/min.
In addition, when adding each material in particular order, each material the most repeatedly can be joined in reaction system, so, put at times and temperature can be controlled below 60 DEG C, simultaneously so that the epoxy resin being added in B component and benzyl alcohol in time, be sufficiently dispersed in polyetheramine and aliphatic cyclic amine, avoid the phenomenon that uneven curing occurs in a reservoir, thus the too high material clumps solidification caused of temperature can be avoided.
In sum, the present invention press down the antibacterial joint trimming agent of disease can filling chink bring attractive in appearance while, live present in suppression gap and send out sexually transmitted disease (STD) poison (such as H5N1 type virus and SARS virus) and antibacterial (such as Bacillus cercus, Salmonella, escherichia coli, bacillus pyocyaneus, Staphylococcus aureus, enterococcus, intestinal tube hemorrhagic coliform, candidiasis, bakers' yeast, Aspergillus niger, chaetomium globosum, penicillium, tinea alba bacterium etc.), reduce indoor microorganism pollution source, reduce microorganism and pollute the injury to human body and reduce environmental pollution.Additionally, the antibacterial joint trimming agent of disease that presses down of the present invention uses silver antibacterial agent, so it is not likely to produce Drug resistance bacterium.
The present invention to press down disease antibacterial joint trimming agent range wide, can be widely used in the gap of various construction materials, scrubbing resistance, abrasion-resistant, hard, waterproof, difficult drop-off, not sagging, anti-mildew, bright color does not fades, adhesion strength big, length in service life, environmental protection.
The present invention to press down disease antibacterial joint trimming agent production cost relatively low, it is only necessary to add a small amount of silver antibacterial agent and just can reach good antibacterial effect, energy-conserving and environment-protective.Preparation technology is simple, easy to process, adds and be uniformly dispersed together with filler, and production efficiency improves, product easy construction, safe fanout free region.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and without departing from the spirit or essential characteristics of the present invention, it is possible to realize the present invention in other specific forms.Therefore, no matter from the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is limited by claims rather than described above, it is intended that all changes fallen in the implication of equivalency and scope of claim included in the present invention.
In addition, it is to be understood that, although this specification is been described by according to embodiment, but the most each embodiment only comprises an independent technical scheme, this narrating mode of description is only for clarity sake, description should can also be formed, through appropriately combined, other embodiments that it will be appreciated by those skilled in the art that as an entirety, the technical scheme in each embodiment by those skilled in the art.

Claims (9)

1. one kind is pressed down the antibacterial joint trimming agent of disease, it is characterised in that described in press down component A and the B component that the antibacterial joint trimming agent of disease includes that volume ratio is 1:1;
Described component A includes by weight: epoxy resin 50-90 part, benzyl alcohol 1-5 part, defoamer 0.2-1.2 part, aerosil 1-9 part, thixotropic agent 0.3-1.2 part, silver antibacterial agent 0.2-0.8 part, UV absorbent 0.5-1.2 part, water repellent agent 1-6 part, toner 3-40 part, pliable and tough auxiliary agent 1-20 part;
Described B component includes by weight: polyetheramine 10-20 part, aliphatic cyclic amine 9-35 part, epoxy resin 25-45 part, benzyl alcohol 20-40 part, defoamer 0.5-2 part, aerosil 0.5-4 part, thixotropic agent 1-5 part, silver antibacterial agent 0.2-0.9 part.
The most according to claim 1 press down the antibacterial joint trimming agent of disease, it is characterised in that in described component A, described toner includes pearlescent flake pigments and glitter powder.
The most according to claim 1 press down the antibacterial joint trimming agent of disease, it is characterised in that described silver antibacterial agent is silver ion antimicrobial agent or nano silver antimicrobials.
The most according to claim 1 press down the antibacterial joint trimming agent of disease, it is characterised in that described in press down component A and the B component that the antibacterial joint trimming agent of disease includes that volume ratio is 1:1;
Described component A includes by weight: epoxy resin 80 parts, benzyl alcohol 3 parts, defoamer 0.7 part, aerosil 4 parts, thixotropic agent 0.7 part, silver antibacterial agent 0.5 part, UV absorbent 0.6 part, water repellent agent 1 part, toner 8 parts, pliable and tough auxiliary agent 1.5 parts;
Described B component includes by weight: polyetheramine 15 parts, aliphatic cyclic amine 22 parts, epoxy resin 28 parts, benzyl alcohol 29 parts, defoamer 1.2 parts, aerosil 2.3 parts, thixotropic agent 2 parts, silver antibacterial agent 0.5 part.
5. one kind according to the preparation technology pressing down the antibacterial joint trimming agent of disease described in any one of claim 1-4, it is characterised in that described preparation technology includes the preparation process of component A and the preparation process of B component:
The preparation process of described component A includes:
Weigh epoxy resin 50-90 part, benzyl alcohol 1-5 part, defoamer 0.2-1.2 part, aerosil 1-9 part, thixotropic agent 0.3-1.2 part, silver antibacterial agent 0.2-0.8 part, UV absorbent 0.5-1.2 part, water repellent agent 1-6 part, toner 3-40 part, pliable and tough auxiliary agent 1-20 part, the each material weighed is carried out under conditions of high-speed stirred mixing dispersion, it is then refluxed for reaction, and sucking filtration, it is thus achieved that described component A;
The preparation process of described B component includes:
Weigh polyetheramine 10-20 part and aliphatic cyclic amine 9-35 part, react stand-by, then, weigh each material in the following order and join in reaction system: thixotropic agent 1-5 part, silver antibacterial agent 0.2-0.9 part, epoxy resin 25-45 part, benzyl alcohol 20-40 part, defoamer 0.5-2 part, aerosil 0.5-4 part, reaction system is carried out under conditions of low rate mixing mixing dispersion, then sucking filtration, it is thus achieved that described B component.
The preparation technology pressing down the antibacterial joint trimming agent of disease the most according to claim 5, it is characterised in that described high-speed stirred is 1400-2800 rev/min, mixing the scattered time is 5-30 minute.
The preparation technology pressing down the antibacterial joint trimming agent of disease the most according to claim 5, it is characterised in that the time of described back flow reaction is 1 hour.
The preparation technology pressing down the antibacterial joint trimming agent of disease the most according to claim 5, it is characterised in that described low rate mixing is 300-500 rev/min.
The preparation technology pressing down the antibacterial joint trimming agent of disease the most according to claim 5, it is characterised in that in the preparation process of described B component, reaction temperature is less than 60 DEG C.
CN201610324688.8A 2016-05-13 2016-05-13 Disease-suppression antibacterial beautiful sealant and preparation technology thereof Pending CN105969046A (en)

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Cited By (19)

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CN107151473A (en) * 2017-07-11 2017-09-12 合肥尚涵装饰工程有限公司 A kind of new joint trimming agent and preparation method thereof
CN107189636A (en) * 2017-07-03 2017-09-22 芜湖市科迪防水节能科技有限公司 A kind of aqueous double-component epoxy joint trimming agent and preparation method thereof
CN107337905A (en) * 2017-08-09 2017-11-10 青州市众鑫新材料科技有限公司 A kind of environmentally friendly two-component crystal nanometer glaze joint trimming agent and preparation method thereof
CN107652835A (en) * 2017-09-21 2018-02-02 福州三坊建材有限公司 A kind of two-component antibacterial anti-fouling epoxy joint trimming agent and preparation method thereof
CN108129063A (en) * 2018-02-06 2018-06-08 合肥广民建材有限公司 A kind of antibacterial water-proof floor tile gap filler and its preparation, application method
CN108676460A (en) * 2018-05-03 2018-10-19 广州挚业化工有限公司 A kind of brilliant color terrace decorative paint and preparation method thereof
CN109385176A (en) * 2018-08-22 2019-02-26 嘉力丰科技股份有限公司 A kind of bi-component fluosilicic modified epoxy joint trimming agent and preparation method thereof
CN109401535A (en) * 2018-09-25 2019-03-01 江苏理工学院 A kind of nano silver joint trimming agent and preparation method thereof
CN109486455A (en) * 2017-09-12 2019-03-19 上海域金澜优电子商务有限公司 A kind of novel nano fungus and mildew resistance water-base epoxy joint trimming agent
CN109749577A (en) * 2018-12-18 2019-05-14 科顺防水科技股份有限公司 A kind of quick-dry type joint trimming agent and preparation method thereof
CN109852312A (en) * 2019-01-11 2019-06-07 张增清 A kind of gold porcelain joint trimming agent
CN112048264A (en) * 2020-08-05 2020-12-08 中山市卡施力顿建材有限公司 Antibacterial joint mixture and preparation method thereof
CN112940661A (en) * 2021-04-08 2021-06-11 杭州华圩新材料科技有限公司 Two-component antibacterial mildew-proof seam beautifying agent and preparation method thereof
CN113025102A (en) * 2021-02-26 2021-06-25 中科院广州化学有限公司 Amphiphilic polyether amine nano composite supramolecular antibacterial coating and preparation method and application thereof
CN113355003A (en) * 2020-03-07 2021-09-07 常州市众力高建材科技有限公司 Novel diffuse-reverse-color matte seam beautifying agent and preparation method thereof
CN114790357A (en) * 2022-05-17 2022-07-26 潮州市猛犸象建材科技有限公司 Bi-component epoxy crack sealer capable of being used for wet construction and preparation method thereof
CN114958138A (en) * 2022-05-09 2022-08-30 潮州市猛犸象建材科技有限公司 Method for preparing high-viscosity low-resistance seam beautifying agent by using new material
CN115093772A (en) * 2022-08-16 2022-09-23 北京吉时吉兴贸易有限公司 Bi-component crack sealer and construction process thereof
CN115448641A (en) * 2022-08-02 2022-12-09 梅州市金诚防水材料有限公司 Water-based color sand crack beautifying agent

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CN107189636A (en) * 2017-07-03 2017-09-22 芜湖市科迪防水节能科技有限公司 A kind of aqueous double-component epoxy joint trimming agent and preparation method thereof
CN107151473A (en) * 2017-07-11 2017-09-12 合肥尚涵装饰工程有限公司 A kind of new joint trimming agent and preparation method thereof
CN107337905A (en) * 2017-08-09 2017-11-10 青州市众鑫新材料科技有限公司 A kind of environmentally friendly two-component crystal nanometer glaze joint trimming agent and preparation method thereof
CN109486455A (en) * 2017-09-12 2019-03-19 上海域金澜优电子商务有限公司 A kind of novel nano fungus and mildew resistance water-base epoxy joint trimming agent
CN107652835A (en) * 2017-09-21 2018-02-02 福州三坊建材有限公司 A kind of two-component antibacterial anti-fouling epoxy joint trimming agent and preparation method thereof
CN107652835B (en) * 2017-09-21 2019-10-25 福州三坊建材有限公司 A kind of two-component antibacterial anti-fouling epoxy joint trimming agent and preparation method thereof
CN108129063A (en) * 2018-02-06 2018-06-08 合肥广民建材有限公司 A kind of antibacterial water-proof floor tile gap filler and its preparation, application method
CN108676460B (en) * 2018-05-03 2020-06-30 广州挚业化工有限公司 Crystal color floor decorative coating and preparation method thereof
CN108676460A (en) * 2018-05-03 2018-10-19 广州挚业化工有限公司 A kind of brilliant color terrace decorative paint and preparation method thereof
CN109385176A (en) * 2018-08-22 2019-02-26 嘉力丰科技股份有限公司 A kind of bi-component fluosilicic modified epoxy joint trimming agent and preparation method thereof
CN109401535A (en) * 2018-09-25 2019-03-01 江苏理工学院 A kind of nano silver joint trimming agent and preparation method thereof
CN109749577A (en) * 2018-12-18 2019-05-14 科顺防水科技股份有限公司 A kind of quick-dry type joint trimming agent and preparation method thereof
CN109852312A (en) * 2019-01-11 2019-06-07 张增清 A kind of gold porcelain joint trimming agent
CN113355003A (en) * 2020-03-07 2021-09-07 常州市众力高建材科技有限公司 Novel diffuse-reverse-color matte seam beautifying agent and preparation method thereof
CN112048264A (en) * 2020-08-05 2020-12-08 中山市卡施力顿建材有限公司 Antibacterial joint mixture and preparation method thereof
CN113025102A (en) * 2021-02-26 2021-06-25 中科院广州化学有限公司 Amphiphilic polyether amine nano composite supramolecular antibacterial coating and preparation method and application thereof
CN112940661A (en) * 2021-04-08 2021-06-11 杭州华圩新材料科技有限公司 Two-component antibacterial mildew-proof seam beautifying agent and preparation method thereof
CN114958138A (en) * 2022-05-09 2022-08-30 潮州市猛犸象建材科技有限公司 Method for preparing high-viscosity low-resistance seam beautifying agent by using new material
CN114790357A (en) * 2022-05-17 2022-07-26 潮州市猛犸象建材科技有限公司 Bi-component epoxy crack sealer capable of being used for wet construction and preparation method thereof
CN115448641A (en) * 2022-08-02 2022-12-09 梅州市金诚防水材料有限公司 Water-based color sand crack beautifying agent
CN115093772A (en) * 2022-08-16 2022-09-23 北京吉时吉兴贸易有限公司 Bi-component crack sealer and construction process thereof

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Application publication date: 20160928