CN105907186A - High-temperature-resistant metal anti-rust wax - Google Patents
High-temperature-resistant metal anti-rust wax Download PDFInfo
- Publication number
- CN105907186A CN105907186A CN201610361773.1A CN201610361773A CN105907186A CN 105907186 A CN105907186 A CN 105907186A CN 201610361773 A CN201610361773 A CN 201610361773A CN 105907186 A CN105907186 A CN 105907186A
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- Prior art keywords
- wax
- minutes
- parts
- styrene
- rust
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Lubricants (AREA)
Abstract
The invention discloses high-temperature-resistant metal anti-rust wax which is prepared from the following components: styrene, polyethylene wax, epoxy resin, zinc stearate, rosin, fatty acid methyl ester, cis-butenedioic acid, citric acid, succinic acid, epoxy butyl oleate, polyvinyl alcohol and styrene-acrylic emulsion. A preparation method for the metal anti-rust wax is simple in process, is low in manufacutirng cost, and is suitable for large-scale popularization. The metal anti-rust wax disclosed by the invention has good mobility, good salt mist resistance, and high temperature resistance; polyethylene wax is modified and matched with synergistic effects of other components, so that the properties of the metal anti-rust wax are more stable, and therefore, the working service life of the metal anti-rust wax can be prolonged, the working service life of a protected metal product can further be prolonged; the metal anti-rust wax has spraying property at the normal temperature, can be quickly dried, can form a uniform and compact hard film protective layer, has good surface smoothness and excellent high temperature resistance, and has removal property.
Description
Technical field
The present invention relates to metal rust-proofing wax and make field, particularly relate to a kind of refractory metal rust-proofing wax.
Background technology
Iron and steel metalloid, under the conditions of natural storage, because environment and other factors make the easy corrosion of parts, thus reduces
Or lose use value, cause security incident and economic loss, the direct economic loss that China is caused every year because of corrosion of metal
Number is huge.Therefore, the application of metal rust-proofing wax is essential to metal coating, but existing metal rust-proofing wax Performance comparision
Single, protectiveness is not strong, and the persistent period is short.
Summary of the invention
It is an object of the invention to provide a kind of refractory metal rust-proofing wax.
The present invention is achieved through the following technical solutions:
A kind of refractory metal rust-proofing wax, is made up of following component, styrene 26 parts, Tissuemat E 64 parts, ring by weight
Epoxy resins 4 parts, zinc stearate 3 parts, Colophonium 1 part, fatty acid methyl ester 1 part, maleic acid 3 parts, citric acid 1 part, succinic acid 2
Part, epoxyoleic acid butyl ester 3 parts, polyvinyl alcohol 3 parts, styrene-acrylic emulsion 1 part；
Described Tissuemat E is through pretreatment: mixed with the styrene that weight portion is 6 by the Tissuemat E that weight portion is 64, then
Add the modifying agent of mixture quality 3%, uniformly after mixing, be heated to 105 DEG C, and process 1 hour with 250r/min centrifugation
After, use 350r/min speed instead and stir 1.5 hours, after standing 30 minutes, filter other material, only stay the polyethylene after process
Wax；Institute's modifying agent is made up of following component by weight: maleic anhydride 1, bentonite 0.5, vinylacetate 1, zinc stearate
0.2；Described bentonitic granularity is 300 mesh；Described bentonite was through 600 DEG C of temperature calcination 15 minutes；
Described Colophonium is through pretreatment: added to by Colophonium in the sodium carbonate liquor that mass concentration is 6.8%, airtight is heated to 98
DEG C, pressure keeps 1.8MPa, after continuing 30 minutes, naturally cools to room temperature, filters.
A kind of preparation method of refractory metal rust-proofing wax, it is made up of following making step:
1) styrene, epoxy resin, styrene-acrylic emulsion are mixed with the Tissuemat E through pretreatment, put in reactor, reaction
Still temperature is set to 62-65 DEG C, and speed of agitator is set to 900r/min, after the response time is 30min, stand-by；
2) by 1) in made raw material and citric acid, epoxyoleic acid butyl ester, polyvinyl alcohol the most admixed together, be heated to 66-68
DEG C, after magnetic stirrer 10 minutes, at the uniform velocity drip succinic acid, and complete dropping in 10 minutes, then proceed to stirring
After 10 minutes, it is cooled to room temperature；
3) by 2) in made raw material and zinc stearate, treated Colophonium, maleic acid is the most admixed together is heated to
55 DEG C, persistently it is slowly stirred, after reacting 40 minutes, adds fatty acid methyl ester, after continuing stirring 15 minutes, stop stirring, stand,
It is cooled to room temperature.
Tissuemat E is a kind of conventional material, the most of many uses, but there is the relatively low difficulty of surface tension
To be infiltrated, with the shortcoming such as many polar material poor compatibility；The present invention is by substantial amounts of experimentation, by using fixing joining
The maleic anhydride of ratio, bentonite, vinylacetate, zinc stearate coordinated carry out modified polyethylene wax, increase and functional poly
The polar active functional group of ethylene waxes, improves its surface tension, improves greatly and the compatibility of many polar materials, pole
The big resistance to marring that improve the metal rust-proofing wax made, anti-wear, adhesion inhibiting properties, and it is anti-to greatly improve metal
The heat-resisting quantity of rust wax, compared with similar-type products, surface is the most smooth.
By adding the epoxy resin of fixed mixing ratio, citric acid, epoxyoleic acid butyl ester, the synergism of polyvinyl alcohol, energy
Enough improving the film property of metal rust-proofing wax, and the film formed is more uniform and stable, film heat-resisting quantity is carried greatly
Height, is coated with membrane lifetime and improves 1.1 times compared with similar-type products, moreover it is possible to reduce drying time, improve yield rate.
By adding the succinic acid zinc stearate of fixed mixing ratio, treated Colophonium, maleic acid, fatty acid methyl ester
Synergism, it is possible to increase the dispersibility between each composition, promotes further the film property of metal rust-proofing wax and becomes film uniformity,
And the wearability of the film that can be formed, compactness, tough good and salt fog resistance, greatly improve metal rust-proofing wax indeformable
The temperature of flowing.
The invention has the beneficial effects as follows, compared with prior art:
Metal rust-proofing wax manufacture method of the present invention, technical process is simple, and low cost of manufacture is suitable to large-scale promotion.The present invention's
Metal rust-proofing wax, has good mobility and salt fog resistance, heat-resisting quantity, by being modified coordinating other to Tissuemat E
It is more stable that the synergism of composition enables to metal rust-proofing wax character, can not only extend the work longevity of metal rust-proofing wax
Life, moreover it is possible to extending the working life of the metal product protected, metal rust-proofing wax of the present invention has the sprayable property of room temperature, can be quick
It is dried, the dura mater overcoat of even compact good toughness can be formed, there is good surface flatness and excellent heat resistance, and
And possess removeability.
Detailed description of the invention
A kind of refractory metal rust-proofing wax, is made up of following component, styrene 26 parts, Tissuemat E 64 by weight
Part, epoxy resin 4 parts, zinc stearate 3 parts, Colophonium 1 part, fatty acid methyl ester 1 part, maleic acid 3 parts, citric acid 1 part, fourth two
Acid 2 parts, epoxyoleic acid butyl ester 3 parts, polyvinyl alcohol 3 parts, styrene-acrylic emulsion 1 part；
Described Tissuemat E is through pretreatment: mixed with the styrene that weight portion is 6 by the Tissuemat E that weight portion is 64, then
Add the modifying agent of mixture quality 3%, uniformly after mixing, be heated to 105 DEG C, and process 1 hour with 250r/min centrifugation
After, use 350r/min speed instead and stir 1.5 hours, after standing 30 minutes, filter other material, only stay the polyethylene after process
Wax；Institute's modifying agent is made up of following component by weight: maleic anhydride 1, bentonite 0.5, vinylacetate 1, zinc stearate
0.2；Described bentonitic granularity is 300 mesh；Described bentonite was through 600 DEG C of temperature calcination 15 minutes；
Described Colophonium is through pretreatment: added to by Colophonium in the sodium carbonate liquor that mass concentration is 6.8%, airtight is heated to 98
DEG C, pressure keeps 1.8MPa, after continuing 30 minutes, naturally cools to room temperature, filters.
A kind of preparation method of refractory metal rust-proofing wax, it is made up of following making step:
1) styrene, epoxy resin, styrene-acrylic emulsion are mixed with the Tissuemat E through pretreatment, put in reactor, reaction
Still temperature is set to 62-65 DEG C, and speed of agitator is set to 900r/min, after the response time is 30min, stand-by；
2) by 1) in made raw material and citric acid, epoxyoleic acid butyl ester, polyvinyl alcohol the most admixed together, be heated to 66-68
DEG C, after magnetic stirrer 10 minutes, at the uniform velocity drip succinic acid, and complete dropping in 10 minutes, then proceed to stirring
After 10 minutes, it is cooled to room temperature；
3) by 2) in made raw material and zinc stearate, treated Colophonium, maleic acid is the most admixed together is heated to
55 DEG C, persistently it is slowly stirred, after reacting 40 minutes, adds fatty acid methyl ester, after continuing stirring 15 minutes, stop stirring, stand,
It is cooled to room temperature.
By test comparison metal rust-proofing wax of the present invention and common metal rust-proofing wax:
Table 1
Can be seen that metal rust-proofing wax of the present invention has obvious advantage than existing metal rust-proofing wax in each performance by table 1.
Claims (2)
1. a refractory metal rust-proofing wax, it is characterised in that be made up of following component by weight, styrene 26 parts, poly-
Ethylene waxes 64 parts, epoxy resin 4 parts, zinc stearate 3 parts, Colophonium 1 part, fatty acid methyl ester 1 part, maleic acid 3 parts, citric acid
1 part, succinic acid 2 parts, epoxyoleic acid butyl ester 3 parts, polyvinyl alcohol 3 parts, styrene-acrylic emulsion 1 part；
Described Tissuemat E is through pretreatment: is mixed with the styrene that weight portion is 6 by the Tissuemat E that weight portion is 64, then adds
Add the modifying agent of mixture quality 3%, uniformly after mixing, be heated to 105 DEG C, and process 1 hour with 250r/min centrifugation
After, use 350r/min speed instead and stir 1.5 hours, after standing 30 minutes, filter other material, only stay the polyethylene after process
Wax；Institute's modifying agent is made up of following component by weight: maleic anhydride 1, bentonite 0.5, vinylacetate 1, zinc stearate
0.2；Described bentonitic granularity is 300 mesh；Described bentonite was through 600 DEG C of temperature calcination 15 minutes；
Described Colophonium is through pretreatment: added to by Colophonium in the sodium carbonate liquor that mass concentration is 6.8%, airtight is heated to 98
DEG C, pressure keeps 1.8MPa, after continuing 30 minutes, naturally cools to room temperature, filters.
The preparation method of a kind of refractory metal rust-proofing wax the most according to claim 1, it is characterised in that it is by following system
Make as step:
1) styrene, epoxy resin, styrene-acrylic emulsion are mixed with the Tissuemat E through pretreatment, put in reactor, reaction
Still temperature is set to 62-65 DEG C, and speed of agitator is set to 900r/min, after the response time is 30min, stand-by；
2) by 1) in made raw material and citric acid, epoxyoleic acid butyl ester, polyvinyl alcohol the most admixed together, be heated to 66-68
DEG C, after magnetic stirrer 10 minutes, at the uniform velocity drip succinic acid, and complete dropping in 10 minutes, then proceed to stirring
After 10 minutes, it is cooled to room temperature；
3) by 2) in made raw material and zinc stearate, treated Colophonium, maleic acid is the most admixed together is heated to
55 DEG C, persistently it is slowly stirred, after reacting 40 minutes, adds fatty acid methyl ester, after continuing stirring 15 minutes, stop stirring, stand,
It is cooled to room temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610361773.1A CN105907186A (en) | 2016-05-26 | 2016-05-26 | High-temperature-resistant metal anti-rust wax |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610361773.1A CN105907186A (en) | 2016-05-26 | 2016-05-26 | High-temperature-resistant metal anti-rust wax |
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| Publication Number | Publication Date |
|---|---|
| CN105907186A true CN105907186A (en) | 2016-08-31 |
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ID=56741470
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610361773.1A Pending CN105907186A (en) | 2016-05-26 | 2016-05-26 | High-temperature-resistant metal anti-rust wax |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102993834A (en) * | 2012-11-13 | 2013-03-27 | 合肥市田源精铸有限公司 | Metal rust resisting wax with PE (Poly Ethylene) wax serving as main raw material and preparation method thereof |
| CN102993802A (en) * | 2012-11-13 | 2013-03-27 | 合肥市田源精铸有限公司 | Modified nanoscale titanium dioxide-containing metal rust prevention wax and preparation method thereof |
| CN102993803A (en) * | 2012-11-13 | 2013-03-27 | 合肥市田源精铸有限公司 | Modified water-soluble nanoscale silica sol-containing metal rust-proof wax and preparation method thereof |
| CN102993805A (en) * | 2012-11-13 | 2013-03-27 | 合肥市田源精铸有限公司 | Modified acrylic latex emulsion-containing metal rust prevention wax and preparation method thereof |
| CN105131836A (en) * | 2015-08-21 | 2015-12-09 | 合肥市田源精铸有限公司 | Novel metal anti-rust wax |
| CN105154181A (en) * | 2015-08-21 | 2015-12-16 | 合肥市田源精铸有限公司 | Anti-rust wax for metal |
-
2016
- 2016-05-26 CN CN201610361773.1A patent/CN105907186A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102993834A (en) * | 2012-11-13 | 2013-03-27 | 合肥市田源精铸有限公司 | Metal rust resisting wax with PE (Poly Ethylene) wax serving as main raw material and preparation method thereof |
| CN102993802A (en) * | 2012-11-13 | 2013-03-27 | 合肥市田源精铸有限公司 | Modified nanoscale titanium dioxide-containing metal rust prevention wax and preparation method thereof |
| CN102993803A (en) * | 2012-11-13 | 2013-03-27 | 合肥市田源精铸有限公司 | Modified water-soluble nanoscale silica sol-containing metal rust-proof wax and preparation method thereof |
| CN102993805A (en) * | 2012-11-13 | 2013-03-27 | 合肥市田源精铸有限公司 | Modified acrylic latex emulsion-containing metal rust prevention wax and preparation method thereof |
| CN105131836A (en) * | 2015-08-21 | 2015-12-09 | 合肥市田源精铸有限公司 | Novel metal anti-rust wax |
| CN105154181A (en) * | 2015-08-21 | 2015-12-16 | 合肥市田源精铸有限公司 | Anti-rust wax for metal |
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| PB01 | Publication | ||
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Application publication date: 20160831 |