CN105907274A - Environment-friendly water-based metal anti-rust paint - Google Patents
Environment-friendly water-based metal anti-rust paint Download PDFInfo
- Publication number
- CN105907274A CN105907274A CN201610461635.0A CN201610461635A CN105907274A CN 105907274 A CN105907274 A CN 105907274A CN 201610461635 A CN201610461635 A CN 201610461635A CN 105907274 A CN105907274 A CN 105907274A
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- rust paint
- rust
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses environment-friendly water-based metal anti-rust paint. The paint is prepared from, by weight, 20-30 parts of water-based alcohol acid emulsion, 5-10 parts of carbomer resin, 3-10 parts of polyurethane, 1-2 parts of potassium oleate, 2-4 parts of sodium citrate, 0.5-1 part of sulfonated lignin, 1-3 parts of sodium cocoate, 1-2 parts of laurinol ammonium sulfate, 10-20 parts of inorganic filler, 1-2 parts of modifier, 2-8 parts of other auxiliaries and 10-20 parts of water. Through reasonable matching of the raw materials, the long-lasting environment-friendly water-based metal anti-rust paint which is high in adhesive force, drying speed and heat resistance, environmentally friendly and free of pollution is obtained; by adding the inorganic filler and the modifier to adjust and modify an anti-rust paint system, the superior properties of high polymer materials are improved, the corrosion resistance of the product is improved, and rust protection lasting time is prolonged; furthermore, the preparing method is simple, low in cost and suitable for large-scale production.
Description
Technical field
The present invention relates to a kind of antirust paint, be specifically related to a kind of environment-friendly type aqueous metallic anti-rust paint.
Background technology
Metal processing piece is during production and processing and transport, it is easy to because occurring electrochemical corrosion that corrosion occurs after contacting with the oxygen in air, dampness or other Korrosionsmedium in metal surface, this is accomplished by using antirust goods to form thin film in metal surface, anti-block and water act on metal surface and generate oxide and the mixture of hydroxide, thus prevent corrosion of metal.And antirust paint is exactly such a kind of goods; concrete; antirust paint is a kind of chemistry protecting metal surfaces from air, sea water etc. or the coating of electrochemical corrosion; and can form and store one layer of fine and close paint film, the corrosion that suppression dampness, oxygen and other chemical analysis cause on metal part surface.Existing antirust goods often produce bigger toxic action because adding oil-soluble antirust paint to environment, and make antirust cycle of antirust goods shorter because of the use of volatile solvent, need often to coat antirust goods in the case of obtaining preferable rust-proof effect, antirust inefficient.
Summary of the invention
Not enough for prior art, the invention provides a kind of efficient, long-acting environment-friendly type aqueous metallic anti-rust paint goods.
The present invention solves the technical scheme of above-mentioned technical problem employing: a kind of environment-friendly type aqueous metallic anti-rust paint, including the raw material of following parts by weight: water alcohol acid emulsion 20 ~ 30 parts, carbomer 5 ~ 10 parts, polyurethane 3 ~ 10 parts, potassium oleate 1 ~ 2 part, sodium citrate 2 ~ 4 parts, lignosulfonate 0.5 ~ 1 part, sodium cocoate 1 ~ 3 part, ammonium lauryl sulfate 1 ~ 2 part, inorganic filler 10 ~ 20 parts, modifying agent 1 ~ 2 part, other auxiliary agents 2 ~ 8 parts and 10 ~ 20 parts of water.
Further, described inorganic filler is nanometer hydroxyapatite powder and nanomete talc powder, and its mass parts is than for 1:1 ~ 3.
Further, described modifying agent is the plant acid solution of 1.5% concentration.
Further, one or more during other auxiliary agents described are dispersant, defoamer, auxiliary rheological agents, film former, anti-sudden strain of a muscle rust agent.
The preparation method of described a kind of environment-friendly type aqueous metallic anti-rust paint, comprises the following steps:
Be on the waiting list raw material according to described parts by weight, the raw material being on the waiting list is placed in dispersion machine fully dispersed be uniformly mixed after, filter roguing obtain the present invention antirust paint.
Compared with prior art, the beneficial effect that the present invention possesses: the present invention is by reasonable proportioning raw materials, it is thus achieved that efficient, the long-acting environment-friendly type aqueous metallic anti-rust paint goods that adhesive force is good, fast drying, heat resistance are good, environment friendly and pollution-free；Raw material with the addition of inorganic filler and modifying agent, by the regulation modification to antirust paint system, improve the premium properties of macromolecular material in raw material, add the rust resistance of goods and the long-lasting of anti-corrosion simultaneously, and the preparation method of the present invention is simple, low cost, it is suitable for large-scale production.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described further.
Embodiment 1: a kind of environment-friendly type aqueous metallic anti-rust paint, including the raw material of following parts by weight: water alcohol acid emulsion 25 parts, carbomer 8 parts, polyurethane 7 parts, potassium oleate 1.5 parts, sodium citrate 3 parts, lignosulfonate 0.7 part, sodium cocoate 2 parts, ammonium lauryl sulfate 1.5 parts, inorganic filler 15 parts, modifying agent 1.5 parts, other auxiliary agents 5 parts and 15 parts of water.
Further, described inorganic filler is nanometer hydroxyapatite powder and nanomete talc powder, and its mass parts is than for 1:2.
Further, described modifying agent is the plant acid solution of 1.5% concentration.
Further, other auxiliary agents described are dispersant, defoamer and film former.
The preparation method of described a kind of environment-friendly type aqueous metallic anti-rust paint, comprises the following steps:
Be on the waiting list raw material according to described parts by weight, the raw material being on the waiting list is placed in dispersion machine fully dispersed be uniformly mixed after, filter roguing obtain the present invention antirust paint.
Embodiment 2: a kind of environment-friendly type aqueous metallic anti-rust paint, including the raw material of following parts by weight: water alcohol acid emulsion 20 parts, carbomer 5 parts, polyurethane 3 parts, potassium oleate 1 part, sodium citrate 2 parts, lignosulfonate 0.5 part, sodium cocoate 1 part, ammonium lauryl sulfate 1 part, inorganic filler 10 parts, modifying agent 1 part, other auxiliary agents 2 parts and 10 parts of water.
Further, described inorganic filler is nanometer hydroxyapatite powder and nanomete talc powder, and its mass parts is than for 1:3；Described modifying agent is the plant acid solution of 1.5% concentration；Other auxiliary agents described are auxiliary rheological agents and anti-sudden strain of a muscle rust agent.
The preparation method of described a kind of environment-friendly type aqueous metallic anti-rust paint, its concrete steps are with embodiment 1.
Embodiment 3: a kind of environment-friendly type aqueous metallic anti-rust paint, including the raw material of following parts by weight: water alcohol acid emulsion 30 parts, carbomer 10 parts, polyurethane 10 parts, potassium oleate 2 parts, sodium citrate 4 parts, lignosulfonate 1 part, sodium cocoate 3 parts, ammonium lauryl sulfate 2 parts, inorganic filler 20 parts, modifying agent 2 parts, other auxiliary agents 8 parts and 20 parts of water.
Further, described inorganic filler is nanometer hydroxyapatite powder and nanomete talc powder, and its mass parts is than for 1:1；Described modifying agent is the plant acid solution of 1.5% concentration；Other auxiliary agents described are dispersant, defoamer, auxiliary rheological agents, film former, anti-sudden strain of a muscle rust agent.
The preparation method of described a kind of environment-friendly type aqueous metallic anti-rust paint, its concrete steps are with embodiment 1.
Embodiment 4: a kind of environment-friendly type aqueous metallic anti-rust paint, including the raw material of following parts by weight: water alcohol acid emulsion 20 parts, carbomer 10 parts, polyurethane 3 parts, potassium oleate 2 parts, sodium citrate 2 parts, lignosulfonate 1 part, sodium cocoate 1 part, ammonium lauryl sulfate 2 parts, inorganic filler 10 parts, modifying agent 2 parts, other auxiliary agents 2 parts and 20 parts of water.
Further, described inorganic filler is nanometer hydroxyapatite powder and nanomete talc powder, and its mass parts is than for 2:3；Described modifying agent is the plant acid solution of 1.5% concentration；Other auxiliary agents described are dispersant, auxiliary rheological agents and anti-sudden strain of a muscle rust agent.
The preparation method of described a kind of environment-friendly type aqueous metallic anti-rust paint, its concrete steps are with embodiment 1.
Embodiment 5: a kind of environment-friendly type aqueous metallic anti-rust paint, including the raw material of following parts by weight: water alcohol acid emulsion 28 parts, carbomer 6 parts, polyurethane 9 parts, potassium oleate 2 parts, sodium citrate 3 parts, lignosulfonate 0.5 part, sodium cocoate 2 parts, ammonium lauryl sulfate 1.5 parts, inorganic filler 12 parts, modifying agent 1 part, other auxiliary agents 6 parts and 14 parts of water.
Further, described inorganic filler is nanometer hydroxyapatite powder and nanomete talc powder, and its mass parts is than for 2:5；Described modifying agent is the plant acid solution of 1.5% concentration；Other auxiliary agents described are defoamer, auxiliary rheological agents, film former and anti-sudden strain of a muscle rust agent.
The preparation method of described a kind of environment-friendly type aqueous metallic anti-rust paint, its concrete steps are with embodiment 1.
Comparative example: a kind of environment-friendly type aqueous metallic anti-rust paint, including the raw material of following parts by weight: water alcohol acid emulsion 25 parts, carbomer 8 parts, polyurethane 7 parts, potassium oleate 1.5 parts, sodium citrate 3 parts, lignosulfonate 0.7 part, sodium cocoate 2 parts, ammonium lauryl sulfate 1.5 parts, inorganic filler 15 parts, other auxiliary agents 5 parts and 15 parts of water.
Further, described inorganic filler is nanometer hydroxyapatite powder and nanomete talc powder, and its mass parts is than for 1:2；Other auxiliary agents described are dispersant, defoamer and film former.
The preparation method of described a kind of environment-friendly type aqueous metallic anti-rust paint, its concrete steps are with embodiment 1.
The performance indications of embodiment of the present invention 1-5 and comparative example gained antirust paint are as shown in the table:
| Performance | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Comparative example |
| High temperature resistant/150 DEG C of h | ≥450 | ≥450 | ≥450 | ≥450 | ≥450 | ≥450 |
| Salt spray resistance/120h level | 3 | 3 | 3 | 3 | 3 | 2 |
| Resistance to water/30 DEG C 240h | Without bubbling/coming off | Without bubbling/coming off | Without bubbling/coming off | Without bubbling/coming off | Without bubbling/coming off | Play microvesicle, without coming off |
| Resistance to artificial weathering aging/GB/T9755-2001 1000h | Pass through | Pass through | Pass through | Pass through | Pass through | Do not pass through |
Claims (5)
1. an environment-friendly type aqueous metallic anti-rust paint, it is characterized in that, including the raw material of following parts by weight: water alcohol acid emulsion 20 ~ 30 parts, carbomer 5 ~ 10 parts, polyurethane 3 ~ 10 parts, potassium oleate 1 ~ 2 part, sodium citrate 2 ~ 4 parts, lignosulfonate 0.5 ~ 1 part, sodium cocoate 1 ~ 3 part, ammonium lauryl sulfate 1 ~ 2 part, inorganic filler 10 ~ 20 parts, modifying agent 1 ~ 2 part, other auxiliary agents 2 ~ 8 parts and 10 ~ 20 parts of water.
The environment-friendly type aqueous metallic anti-rust paint of one the most according to claim 1, it is characterised in that: described inorganic filler is nanometer hydroxyapatite powder and nanomete talc powder, and its mass parts is than for 1:1 ~ 3.
The environment-friendly type aqueous metallic anti-rust paint of one the most according to claim 1, it is characterised in that: described modifying agent is the plant acid solution of 1.5% concentration.
The environment-friendly type aqueous metallic anti-rust paint of one the most according to claim 1, it is characterised in that: other auxiliary agents described are one or more in dispersant, defoamer, auxiliary rheological agents, film former, anti-sudden strain of a muscle rust agent.
5. the preparation method of a kind of environment-friendly type aqueous metallic anti-rust paint described in any one of claim 1-5, it is characterised in that comprise the following steps:
Be on the waiting list raw material according to described parts by weight, the raw material being on the waiting list is placed in dispersion machine fully dispersed be uniformly mixed after, filter roguing obtain the present invention antirust paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610461635.0A CN105907274A (en) | 2016-06-23 | 2016-06-23 | Environment-friendly water-based metal anti-rust paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610461635.0A CN105907274A (en) | 2016-06-23 | 2016-06-23 | Environment-friendly water-based metal anti-rust paint |
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| Publication Number | Publication Date |
|---|---|
| CN105907274A true CN105907274A (en) | 2016-08-31 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610461635.0A Pending CN105907274A (en) | 2016-06-23 | 2016-06-23 | Environment-friendly water-based metal anti-rust paint |
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| CN (1) | CN105907274A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107033741A (en) * | 2017-05-27 | 2017-08-11 | 安徽誉林汽车部件有限公司 | A kind of auto parts machinery anticorrosion antirust paint coating and preparation method thereof |
| CN107974177A (en) * | 2017-12-08 | 2018-05-01 | 安徽雷萨重工机械有限公司 | A kind of surface of metal product antirusting treating method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101215441A (en) * | 2008-01-11 | 2008-07-09 | 孟祥开 | Water alcohol acid rust-having anti-corrosive paint and preparation method thereof |
| CN101591500A (en) * | 2009-06-23 | 2009-12-02 | 常州光辉化工有限公司 | Waterborne normal-temperature self-crosslinking acrylic acid modified alkyd antirust paint |
| CN103497655A (en) * | 2013-10-10 | 2014-01-08 | 青岛三立新源电器有限公司 | Environment-friendly metal antirust paint |
| CN104530941A (en) * | 2015-01-15 | 2015-04-22 | 徐强 | Waterborne alcohol acid antirust paint and preparation method thereof |
-
2016
- 2016-06-23 CN CN201610461635.0A patent/CN105907274A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101215441A (en) * | 2008-01-11 | 2008-07-09 | 孟祥开 | Water alcohol acid rust-having anti-corrosive paint and preparation method thereof |
| CN101591500A (en) * | 2009-06-23 | 2009-12-02 | 常州光辉化工有限公司 | Waterborne normal-temperature self-crosslinking acrylic acid modified alkyd antirust paint |
| CN103497655A (en) * | 2013-10-10 | 2014-01-08 | 青岛三立新源电器有限公司 | Environment-friendly metal antirust paint |
| CN104530941A (en) * | 2015-01-15 | 2015-04-22 | 徐强 | Waterborne alcohol acid antirust paint and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 李东光: "《金属表面处理剂配方手册》", 31 August 2015 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107033741A (en) * | 2017-05-27 | 2017-08-11 | 安徽誉林汽车部件有限公司 | A kind of auto parts machinery anticorrosion antirust paint coating and preparation method thereof |
| CN107974177A (en) * | 2017-12-08 | 2018-05-01 | 安徽雷萨重工机械有限公司 | A kind of surface of metal product antirusting treating method |
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Application publication date: 20160831 |