CN105838457A - Preparation method of novel alcohol ether environment friendly fuel - Google Patents
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Abstract
A preparation method of a novel alcohol ether environment friendly fuel includes the following steps: 1) purchasing the following raw materials, according to mass part, aromatic hydrocarbon, methylbenzene, methanol, tert-butanol, isobutanol, isopropanol, benzyl alcohol, ethanol, petroleum ether, ethyl ether, isopropyl ether, isooctane, dimethoxymethane, 3-dihydroxybutane, octane, diethyl carbonate, ethyl 2-ethyldioxyacetate, dibutyl phosphite, ethyl acetate, ethyl-propyl ketone, 501 antioxidant, a di-tert-butyl compound and a corrosion inhibitor; 2) mixing the methanol, the tert-butanol, the isobutanol, the isopropanol, the benzyl alcohol and the ethanol to obtain a mixture (A); 3) mixing the petroleum ether, the ethyl ether, the isopropyl ether, the isooctane, the dimethoxymethane, the 3-dihydroxybutane and the octane to obtain a mixture (B); 4) mixing the diethyl carbonate, the ethyl 2-ethyldioxyacetate, the dibutyl phosphite, the ethyl acetate, the ethyl-propyl ketone, the 501 antioxidant, the di-tert-butyl compound and the corrosion inhibitor to obtain a mixture (C); 5) mixing the mixtures (A) and (B) with aromatic hydrocarbon and the methylbenzene to obtain a mixture (D); and 6) uniformly mixing the mixtures (C) and (D) to prepare the fuel.
Description
Technical field
The present invention relates to fuel technology field, be specifically related to a kind of novel alcohol ether environment-friendly fuel, particularly for the field of preparation method of novel alcohol ether environment-friendly fuel of all types of automobiles.
Background technology
Show according to relevant information, China is a rich coal, oil-poor, one of country having gas, fast development along with national economy, automobile pollution is also constantly rising, tool statistics, within 2014, automobile quantity is more than 2.55 hundred million (wherein 1.2 hundred million is strong car), expect the year two thousand twenty total vehicle and will reach 3.5 hundred million, the year two thousand thirty will reach 5.2-6 hundred million, as can be seen here, within following 20 years, China will face the energy problem of sternness, if or else changing the energy to be overly dependent upon the situation of natural oil for a long time, the ability of energy sustainable development will be seriously undermined, if the fuel for motor vehicle of China excessively dependence on import oil, the alternative of International Politics field decision-making will be influenced whether, therefore, searching to oil replacement fuel, the China of rapid economic development is seemed even more important.
For now: domestic petroleum imbalance between supply and demand day is aobvious prominent, the interdependency of import is increased year by year, end the first half of the year in 2014, China's domestic oil consumption demand has broken through 4.9 hundred million tons, 5.56 hundred million tons will be reached to the end of the year 2014, expect the year two thousand twenty and will break through 7.5 hundred million tons, even up to will break through 800,000,000 tons, the external dependence degree of CNPC the most constantly expands, 70% likely it is up to the year two thousand twenty, but, China's natural gas gross reserves is 39 tcms, coal gross reserves is 114,500,000,000 tons, therefore, popularization and application novel alcohol ether environment-friendly fuel is used as supplementing of petroleum resources, China is had very important strategic importance.
The synthetic fuel of many different qualities is occurred in that on existing market, all use a high proportion of methanol as main material, and component and mass parts are more unreasonable than upper, imperfection, not science, thus cause the deficiency of technology content, the product produced by this component and mass parts ratio, in actually used kind excessively, cause engine power not enough, affected by vapour lock plus summer, also can cause excessive oil consumption, make electromotor cisco unity malfunction, defect based on prior art, now it is badly in need of one the most energy-conservation, environmental protection again, the novel vehicular fuel of the problems referred to above can be solved again, existing technical bottleneck is made up with this, for this, we are through research many times, test, preparation, practice, and the utilization on all types of automobiles, finally have developed one the most energy-conservation, the novel alcohol ether environment-friendly fuel of environmental protection again.
Summary of the invention
It is an object of the invention to provide the preparation method of a kind of novel alcohol ether environment-friendly fuel, reach both powerful and the problem of energy-conserving and environment-protective using during novel alcohol ether environment-friendly fuel solving all types of automobile.The purpose of the present invention is realized by techniques below scheme: this novel alcohol ether environment-friendly fuel is with common industrial chemicals and fuel additive as raw material, have good and cheap, function admirable, energy-conserving and environment-protective, easy to use, not stratified, gas is not stifled, not temperature influence, and solves the difficult problem meeting water stratification.Can mix with the GB gasoline, methanol gasoline, ethanol petrol, high-energy fuel and the alcohol-based fuel arbitrary proportion that occur on existing market, it has that burning is clean, powerful, stable, decrease the trouble cleaning electromotor, the harmful substance of discharge reduces more than 55% than the merchantable gasoline occurred on existing market, meets the relevant requirement of the People's Republic of China's " energy-conserving and environment-protective standard ".
For reaching the purpose of foregoing invention, the technical solution adopted in the present invention is: provide a kind of novel alcohol ether environment-friendly fuel, it is characterised in that each component and the mass parts ratio thereof of described novel alcohol ether environment-friendly fuel are as follows:
1 part of aromatic hydrocarbons, molecular formula is: C10H14；
Toluene 1 part, molecular formula is: C7H8；
Methanol 1 part, chemical formula is: CH3OH；
The tert-butyl alcohol 1 part, molecular formula is: C4H10O；
Isobutanol 1 part, molecular formula is: C4H10O；
Isopropanol 1 part, molecular formula is: C3H8O, (CH3) 2CHOH；
Benzyl alcohol 1 part, molecular formula is: C7H8O；
Ethanol 1 part, chemical formula is: CH3CH2OH；
Petroleum ether 1 part, chemical formula is: C5H12
C6H14 C7H16；
Ether 1 part, molecular formula is: C4H10O；
Diisopropyl ether 1 part, molecular formula is: C6H14O；
Isobutyltrimethylmethane. 1 part, chemical formula is: (CH3) 2CHCH2C (CH3) 3；
Dimethoxymethane 1 part, molecular formula is: C3H8O2；
3-dihydroxy butane 1 part, molecular structure: oxygen atom forms σ key with sp3 hybrid orbital, carbon atom forms σ key with sp3 hybrid orbital；
Octane 1 part, molecular formula is: C8H18, CH3 (CH2) 6CH3；
Diethyl carbonate 1 part, molecular formula is: C5H10O3；
2-ethylenedioxy ethyl acetate 1 part, molecular formula is: C8H16O4；
Dibutyl phosphite 1 part, chemical formula is: C8H19O3P；
Ethyl acetate 1 part, chemical formula is: C4H8O2；
1 part of second acetone, chemical formula is: C5H8O2；
501 1 part of antioxidant, molecular formula is: C15H24O；
Di-t-butyl 1 part, molecular formula is: C8H18O2；
Corrosion inhibitor 1 part, molecular formula is: C6H13N.
The preparation method of a kind of above-mentioned novel alcohol ether environment-friendly fuel, it is characterised in that described method comprises the steps:
A, choosing the clean aromatic hydrocarbons of high-quality 22%, molecular formula is: C10H14；Toluene 10%, molecular formula is: C7H8；Methanol 8%, chemical formula is: CH3OH；The tert-butyl alcohol 5%, molecular formula is: C4H10O；Isobutanol 4%, molecular formula is: C4H10O；Isopropanol 4%, molecular formula is: C3H8O, (CH3) 2CHOH；Benzyl alcohol 3%, molecular formula is: C7H8O；Ethanol 2%, chemical formula is: CH3CH2OH；Petroleum ether 6%, chemical formula is: C5H12 C6H14
C7H16；Ether 7%, molecular formula is: C4H10O；Diisopropyl ether 3%, molecular formula is: C6H14O；Isobutyltrimethylmethane. 5%, chemical formula is: (CH3) 2CHCH2C (CH3) 3；Dimethoxymethane 3%, molecular formula is: C3H8O2；3-dihydroxy butane 2%, molecular structure: oxygen atom forms σ key with sp3 hybrid orbital, carbon atom forms σ key with sp3 hybrid orbital；Octane 3%, molecular formula is: C8H18, CH3 (CH2) 6CH3；Diethyl carbonate 2%, molecular formula is: C5H10O3；2-ethylenedioxy ethyl acetate 2%, molecular formula is: C8H16O4；Dibutyl phosphite 2%, chemical formula is: C8H19O3P；Ethyl acetate 3%, chemical formula is: C4H8O2；Second acetone 2%, chemical formula is: C5H8O2；501 antioxidant 0.5%, molecular formula is: C15H24O；Di-t-butyl 1.1%, molecular formula is: C8H18O2；Corrosion inhibitor 0.4%, molecular formula is: C6H13N；It is contained in respective hermetic container standby respectively.
B, first above-mentioned methanol, the tert-butyl alcohol, isobutanol, isopropanol, benzyl alcohol and the ethanol chosen is mixed after a；Again petroleum ether, ether, diisopropyl ether, isobutyltrimethylmethane., dimethoxymethane, 3-dihydroxy butane and octane are mixed to obtain b；Then diethyl carbonate, 2-ethylenedioxy ethyl acetate, dibutyl phosphite, ethyl acetate, second acetone, 501 antioxidant, di-t-butyl and corrosion inhibitor are mixed to obtain c；And then a and b is mixed homogeneously with aromatic hydrocarbons and toluene obtain d again；The most again d with c is mixed homogeneously and obtain finished product novel alcohol ether environment-friendly fuel.
Novel alcohol ether environment-friendly fuel provided by the present invention is vehicle fuel, and it is with common industrial chemicals and fuel additive as raw material, gives full play to effect of each component:
Aromatic hydrocarbons, molecular formula is: C10H14, colourless transparent liquid, abnormal smells from the patient: have special odor, the aromatic hydrocarbons mixture of narrow fraction reformed arene extracting gained.Wherein contain benzene,toluene,xylene.Can be as Petropols, gasoline, the raw material of solvent.It is used as basic material in this novel alcohol ether environment-friendly fuel；
Toluene, molecular formula is: C7H8: achromaticity and clarification liquid.There is benzene sample gas taste.There is strong refractivity.Can be miscible with ethanol, ether, acetone, chloroform, Carbon bisulfide and glacial acetic acid, atomic it is dissolved in water.Relative density 0.866.Freezing point-95 DEG C.Boiling point 110.6 DEG C.Index of refraction 1.4967.Flash-point (closed-cup) 4.4 DEG C.Inflammable.Steam can form explosive mixture, explosion limit 1.2%～7.0%(volume with air).Toluene is used as solvent and high-knock rating gasoline additive in a large number, is also the important source material of organic chemical industry, but compared with the benzene simultaneously obtained from coal and oil and dimethylbenzene, current yield relative surplus.Burning host effect is acted primarily as in this novel alcohol ether environment-friendly fuel；
Methanol, chemical formula is: CH3OH:(Methanol, dried, CH4O) the simplest saturated monohydroxy alcohol of architecture, No. CAS has 67-56-1,170082-17-4, molecular weight 32.04, boiling point 64.7 DEG C.Also known as " another name for " or " another name for ".It is colourless to have the volatile liquid of alcohol smell.For manufacturing formaldehyde and pesticide etc., and it is used as organic extractant and the denaturant etc. of ethanol.Generally reacted by carbon monoxide and hydrogen and prepare.Comburant effect is acted primarily as in this novel alcohol ether environment-friendly fuel；
The tert-butyl alcohol, molecular formula is: C4H10O, and colourless crystallization is the most supercool, is then liquid in the presence of a small amount of water.There is the camphoraceous abnormal smells from the patient of class, have hygroscopicity, often replace n-butyl alcohol as coating and the solvent of medicine.As fuel additive for internal combustion engines (preventing carburetor) and antidetonator.As intermediate and the raw material for alkylation of production tert-butylation compound of organic synthesis, methyl methacrylate, tert-butyl phenol, tert-butylamine etc. can be produced, for synthetic drug, spice.Tert-butyl alcohol dehydration can produce the isobutene. of purity 99.0-99.9%.As the solvent of industrial detergent, medicine extractant, insecticide, wax solvent, cellulose esters, plastics and the solvent of paint, it is additionally operable to manufacture denatured alcohol, spice, fruit essence, isobutene. etc..In this novel alcohol ether environment-friendly fuel, mainly make antidetonator use；
Isobutanol, molecular formula is: C4H10O, inflammable, has zest, colourless transparent liquid, has special odor, boiling point 107 DEG C, self-ignition point 426.6 DEG C, be slightly soluble in water, ethanol and ether.Isobutanol is a kind of organic synthesis raw material, is mainly used in synthesizing the intermediate isopropyl cyanide of diazinon on pesticide.Organic synthesis raw material.For manufacturing petroleum additive, antioxidant, DBPC 2,6 ditertiary butyl p cresol, isobutyl acetate (paint solvent), plasticizer, synthetic rubber, synthetic musk, fruit quintessence oil and synthetic drug etc..Also can be used to purify the salt chemical reagent such as strontium, barium and lithium and be used as senior solvent.Antisepsis is acted primarily as in this novel alcohol ether environment-friendly fuel；
Isopropanol, molecular formula is: C3H8O, (CH3) 2CHOH, organic compound, calls dimethylcarbinol, 2-propanol, also makees IPA in industry.It is the isomers of normal propyl alcohol.Colourless transparent liquid, has the abnormal smells from the patient like ethanol and acetone mixture.It is dissolved in water, also is soluble in most organic solvent such as alcohol, ether, benzene, chloroform.Extensive use is had as Organic Ingredients and solvent.As industrial chemicals, acetone, hydrogen peroxide, methyl iso-butyl ketone (MIBK), diisobutyl ketone, 2-aminopropane., diisopropyl ether, isopropyl alcohol ether, isopropyl chloride compound, and isopropyl fatty acid ester and chloro fat isopropyl propionate etc. can be produced.In terms of fine chemistry industry, can be used for producing isopropyl nitrate, proxam, triisopropyl phosphite, aluminum isopropylate and medicine and pesticide etc..As solvent, can be used for producing coating, ink, extractant, aerosol agent etc..Also act as antifreezing agent, cleaning agent, the additive of blended gasoline, the dispersant of pigment production, the fixative of printing and dyeing industry, glass and the antifoggant etc. of transparent plastic.As the diluent of adhesive, it is additionally operable to antifreezing agent, dehydrant etc..Antifreeze effect is acted primarily as in this novel alcohol ether environment-friendly fuel；
Benzyl alcohol, molecular formula is: C7H8O, and benzyl alcohol is one of simplest aromatic alcohol, is considered as the substituted methanol of phenyl.In nature, majority is presented in ester in essential oil, such as all contain this composition in Flos Jasmini Sambac oil, hyacinth oil and Peruvian balsam.Benzylalcohol is very useful fixastive, indispensable spice when being the flavor deployments such as jasmine, below the moon perfume, Cananga odorata.For preparing fancy soap；Daily perfume compound for cosmetics.But benzylalcohol can autoxidation lentamente, a part generates benzaldehyde and benzyl oxide, makes commercially available prod often with almond flavor, therefore should not store for a long time.Benzylalcohol is of many uses in industrial chemical produces.Cleaning engine action is acted primarily as in this novel alcohol ether environment-friendly fuel；
Ethanol, chemical formula is: CH3CH2OH, ethanol is a kind of Organic substance, is commonly called as ethanol, and chemical formula is CH3CH2OH(C2H6O or C2H5OH) or EtOH, it being the saturated monohydroxy alcohol with a hydroxyl, be a kind of colourless transparent liquid inflammable, volatile under room temperature, normal pressure, its aqueous solution has the abnormal smells from the patient of aroma, and slightly zest.There is the pungent flavour of smells of wine and stimulation, micro-sweet.Ethanol liquid density is 0.789g/cm3 (20C °), and alcohol gas density is 1.59kg/m3, and boiling point is 78.4 DEG C, and fusing point is-114.3 DEG C, inflammable, and its steam can form explosive mixture with air, can dissolve each other with any ratio with water.Can be with water, chloroform, ether, methanol, acetone and other most immiscible organic solvents, relative density (d15.56) 0.816.Having many uses of ethanol, available ethanol manufactures acetic acid, beverage, essence, dyestuff, fuel etc..The most also commonly use the ethanol that volume fraction is 70%-75% and make disinfectant etc., all have been widely used in national defense industry, health care, organic synthesis, food industry, industrial and agricultural production.Environmental-protection function is acted primarily as in this novel alcohol ether environment-friendly fuel；
Petroleum ether, chemical formula is: C5H12 C6H14 C7H16, and petroleum ether is colourless transparent liquid, has kerosene abnormal smells from the patient.Predominantly pentane and the mixture of hexane.Water insoluble, it is dissolved in most organic solvent such as dehydrated alcohol, benzene, chloroform, oils.Inflammable and explosive, can kickback with oxidant.It is mainly used as solvent and oils and fats processes.Generally with platformate raffinate or direct steaming gasoline be fractionated into, be hydrogenated with or additive method prepare.For organic synthesis and industrial chemicals, as produced synthetic rubber, plastics, chinlon monomer, synthetic detergent, pesticide etc., also it is good organic solvent.It is mainly used as solvent, also serves as the foaming agent of foamed plastic, medicine, the extractant of essence.Density Accommodation is acted primarily as in this novel alcohol ether environment-friendly fuel；
Ether, molecular formula is: C4H10O, colourless transparent liquid.There is specific stimulation abnormal smells from the patient.Band sweet taste.Highly volatile.Its steam overweights air.Peroxide, aldehyde and acetic acid can be oxidized under the effect of air, be exposed under light and can promote that it aoxidizes.When in ether containing peroxide, the peroxide of institute's separating residual can cause violent explosion when being heated to more than 100 DEG C after evaporation；These peroxide can add 5% ferrous sulfate aqueous solution shaking and remove.With the mixture reaction of anhydrous nitric acid, concentrated sulphuric acid and concentrated nitric acid, high-explosive also can occur.Ignition action is acted primarily as in this novel alcohol ether environment-friendly fuel；
Diisopropyl ether, molecular formula is: C6H14O, colourless liquid.There is ethereal odor.Meet light and air is unstable.It is easily formed peroxide, and produces blast when shaking, the peroxide sodium sulfite solution produced is processed before therefore using.It is commonly incorporated into benzylamino phenol (p-Benzyl-AminophEnol) or hydroquinone used as stabilizers.Can be miscible with ethanol and ether, it is slightly soluble in water.Relative density (d204) 0.7258.Fusing point-60 DEG C.Boiling point 68～69 DEG C.Index of refraction (n23D) 1.3678.Flash-point (opening cup)-9 DEG C.Inflammable.Irritant.Diisopropyl ether is animal, plant and the good solvent of mineral oils and fats, can be used for extracting nicotine from Nicotiana tabacum L.；Also it is the good solvent of paraffin and resin, the industrial dewaxing technique that often diisopropyl ether and the mixing of other solvents are applied to paraffinic base oil product.Be also applied to the aspects such as pharmacy, cordite, coating and paint cleaning as solvent, diisopropyl ether has high-octane rating and anti-freezing property, can be used as gasoline blender.This product is easily formed peroxide, produces blast when shaking, is commonly incorporated into benzylamino phenol used as stabilizers.Admixture effect is acted primarily as in this novel alcohol ether environment-friendly fuel；
Isobutyltrimethylmethane., chemical formula is: (CH3) 2CHCH2C (CH3) 3, pure isooctane be commonly called as isobutyltrimethylmethane. (be referred to as " different " what 2 of main chain had a methyl, 2 have two methyl be referred to as " newly ".But out of habit, or pure isooctane is done " isobutyltrimethylmethane. "), it is a kind of isomer of octane.It is dissolved in the oils beyond benzene,toluene,xylene, chloroform, ether, Carbon bisulfide, carbon tetrachloride, dimethylformamide and fall Oleum Ricini, is slightly soluble in dehydrated alcohol, is practically insoluble in water.Relative density (relative to water, 20 DEG C) 0.6919.Fusing point-107.4 DEG C.Boiling point 99.3 DEG C.Index of refraction (n20D) 1.39157.Flash-point-12 DEG C.Inflammable.Irritant.Volatile.Fuel additive and octane enhancer effect is acted primarily as in this novel alcohol ether environment-friendly fuel；
Dimethoxymethane, molecular formula is: C3H8O2, dimethoxymethane (dimethoxymethane；Methylal) methylene dimethyl ether is had another name called；Formal；Dimethoxym ethane, is a kind of colourless liquid, has the abnormal smells from the patient of similar chloroform.It is mainly used as solvent, analytical reagent, irritant to mucosa, there is anesthetic action, suck steam and nose and larynx can be caused to stimulate；High concentration sucks there is dizziness etc..Eye is had infringement, infringement can, last from days chronic skin contact can cause xerosis cutis.Change resin mainly for the production of anion effect, also make solvent and special fuel.Its solvability is stronger than ether, acetone, and methanol and azeotropic mixture can dissolve the nitrocellulose that nitrogen content is high.But owing to its steam has stronger narcoticness, common solvent should not be made and use, generally make the solvent that special sound closes.It is additionally operable to spice manufacture, produces artificial resin, the reaction medium reacted as Grignard reaction and Lei Pa (synthesis)；Cosolvent effect is acted primarily as in this novel alcohol ether environment-friendly fuel；
3-dihydroxy butane, molecular structure: oxygen atom forms σ key with sp3 hybrid orbital, carbon atom forms σ key, colorless viscous liquid with sp3 hybrid orbital.It is dissolved in water and ethanol, is slightly soluble in ether.Mainly for the preparation of polyester resin, polyurethane resin, plasticizer etc., also serve as humidizer and the softening agent etc. of textile, paper and Nicotiana tabacum L..Additive mediation effect is acted primarily as in this novel alcohol ether environment-friendly fuel；
Octane, molecular formula is: C8H18, CH3 (CH2) 6CH3, outward appearance and character: colourless transparent liquid.Molecular weight: 114.22.Vapour pressure: 1.33kPa/19.2 DEG C.Dissolubility is water insoluble, is dissolved in most organic solvent such as ethanol, ether, benzene, acetone.Igniting combustion supporting effect is acted primarily as in this novel alcohol ether environment-friendly fuel；
Diethyl carbonate, molecular formula is: C5H10O3: colourless liquid, slightly abnormal smells from the patient;Vapour pressure 1.33kPa/23.8 DEG C；Flash-point 25 DEG C；Fusing point-43 DEG C；Boiling point 125.8 DEG C；Dissolubility: water insoluble, is miscible in most organic solvent such as alcohol, ketone, ester；Density: relative density (water=1) 1.0；Relative density (air=1) 4.07；Stability: stable；Risk markings 7(flammable liquid)；Main uses: as solvent and for organic synthesis.Blender effect is acted primarily as in this novel alcohol ether environment-friendly fuel；
2-ethylenedioxy ethyl acetate 1 part, molecular formula is: C8H16O4, Chinese: 2-ethylenedioxy ethyl acetate；Acetic acid-2-ethoxy-ethyl ester；Ethylene glycol monomethyl ether acetas；Acetic acid glycol ether；Acetic cellosolve；Ethylene glycol monoethyl ether acetate.Property description: colourless liquid.Freezing point-61.7 DEG C, boiling point 156.3 DEG C, 51 DEG C (2.8kPa), and relative density 0.973(20 DEG C), fusing point-61.7 DEG C, refractive index 1.4055(20 DEG C), flash-point 51 DEG C (closed-cup), 66 DEG C (opening cup), burning-point 379 DEG C.Can be miscible with common organic solvents, it is dissolved in water.There is pleasant esters fragrant.Purposes: as solvent, coordinates with other compounds and is used as leather adhesive；Paint stripper；Metal hot dip anti-corrosive paints etc..Additive anti-corrosive aids effect is acted primarily as in this novel alcohol ether environment-friendly fuel；
Dibutyl phosphite, chemical formula is: C8H19O3P, calls di-n-butyl phosphite molecule formula C8H19O3P；(CH3CH2CH2CH2) 2POH outward appearance and character colourless liquid.Molecular weight 194.21.Vapour pressure 0.13/20 DEG C, flash-point: 49 DEG C, boiling point 115 DEG C (1.33kPa)；Dissolubility is water insoluble, is dissolved in most organic solvent；Density 0.97 (35 DEG C) 5.58, main uses is used as solvent, antioxidant and organic synthesis intermediate.Antioxidant effect is acted primarily as in this novel alcohol ether environment-friendly fuel；
Ethyl acetate, chemical formula is: C4H8O2, is colourless transparent liquid, and when concentration is higher, irritant abnormal smells from the patient, volatile, to air-sensitive, can absorb water and divide, and moisture can make it slowly decompose and react acid.Can be miscible with chloroform, ethanol, acetone and ether, it is dissolved in water (10%ml/ml).Some metallic salt (such as lithium chloride, cobaltous chloride, zinc chloride, iron chloride etc.) can be dissolved.Relative density 0.902.Fusing point-83 DEG C.Boiling point 77 DEG C.Index of refraction 1.3719.Flash-point 7.2 DEG C (opening cup).Inflammable.Steam can form explosive mixture with air.A kind of igniting combustion supporting effect is acted primarily as in this novel alcohol ether environmental-protection additive fuel；
Second acetone, chemical formula is: C5H8O2, colourless or micro-runny transparency liquid of Huang, has the abnormal smells from the patient of ester, and congeal into during cooling glossiness crystal.During by light action, change into brown liquid, and generate resin.Fusing point-23 DEG C, boiling point 140.5 DEG C, 139 DEG C (94.5kPa), and relative density 0.9753, refractive index 1.4494, flash-point 40.56 DEG C, it is dissolved in water, ethanol, ether, chloroform, acetone, benzene, glacial acetic acid.Industrial goods have unhappy stink, are easily water dispersible as acetic acid and acetone.Act primarily as, in this novel alcohol ether environmental-protection additive fuel, the effect of dissolving each other；
501 antioxidant, molecular formula is: C15H24O, and antioxidant T501 is conventional rubber antioxidant, and heat, oxygen aging are had certain protective action, also can suppress copper evil.Be used alone and there is no ozone-resistant ability, but with antiozonant and wax with can the infringement to vulcanizate of the various factors of climate protection.The inhibitor that is gelled is can act also as in butadiene-styrene rubber.This product volatility is bigger.Rubber easily disperses, rubber can be directly mixed with or add in latex as dispersion.It is widely used in natural gum, in various rubber polymers and latex thereof.This product invariant color, does not pollutes.For manufacturing the white sidewall of tire, various rubber that normal complexion white, gorgeous is transparent and latex product thereof, and the rubber such as daily, health care, adhesive plaster, rubber overshoes.General consumption 0.5-3 part in rubber.Also will not bloom when consumption increases to 3-5 part.This product also can be used for the glue kinds such as butadiene-styrene rubber, butadiene rubber, EP rubbers, neoprene as the stabilizer when process after synthetic rubber and storage.Anticorrosion and antioxidant effect is acted primarily as in this novel alcohol ether environment-friendly fuel；
Di-t-butyl, molecular formula is: C8H18O2, di-tert-butyl peroxide (Di-t-butylperoxide), also known as di-t-butyl peroxide, initiator a, vulcanizing agent dTBP, colourless to slightly yellow transparency liquid, water insoluble, miscible with benzene, toluene, acetone and other organic solvent.There is strong oxidizing property, inflammable, more stable under room temperature, insensitive to clashing into.As the modifying agent of drying oil, add this product and the drying property of Oleum Ricini, whale oil, Oleum Verniciae fordii, Oleum Glycines and oleum lini etc. can be made to be obviously improved.Add in other plastics, its glossiness and drug resistance can be improved.As cross-linking agent, can be used for silicone rubber, synthetic rubber and natural rubber, polyethylene, EVA and EPT etc..As polymerization initiator, can be used for polystyrene and polyethylene.A kind of additive immixture is acted primarily as in this novel alcohol ether environment-friendly fuel；
Corrosion inhibitor, molecular formula is: C6H13N, corrosion inhibitor is formed by organic phospho acid, polycarboxylic acids, carbon steel corrosion inhibitor and copper inhibitor are compounding, all has the calcium carbonate in water, calcium sulfate, calcium phosphate etc. and well chelates peptizaiton and carbon steel, copper are had good corrosion mitigating effect.Corrosion inhibitor corrosion inhibitor N is mainly used in recirculating cooling water system corrosion-mitigation scale-inhibition, and such as recirculating cooling water systems such as power plant, chemical plant, petrochemical industry, iron and steel, corrosion inhibitor N-501 corrosion mitigating effect is good, scale inhibition power is strong.Corrosion inhibitor effect is acted primarily as in this novel alcohol ether environment-friendly fuel.
Detailed description of the invention
Below embodiments of the present invention are described in further detail:
Show according to relevant information, China is a rich coal, oil-poor, one of country having gas, fast development along with national economy, automobile pollution is also constantly rising, tool statistics, within 2014, automobile quantity is more than 2.55 hundred million (wherein 1.2 hundred million is strong car), expect the year two thousand twenty total vehicle and will reach 3.5 hundred million, the year two thousand thirty will reach 5.2-6 hundred million, as can be seen here, within following 20 years, China will face the energy problem of sternness, if or else changing the energy to be overly dependent upon the situation of natural oil for a long time, the ability of energy sustainable development will be seriously undermined, if the fuel for motor vehicle of China excessively dependence on import oil, the alternative of International Politics field decision-making will be influenced whether, therefore, searching to oil replacement fuel, the China of rapid economic development is seemed even more important.
Domestic petroleum imbalance between supply and demand day is aobvious prominent, the interdependency of import is increased year by year, end the first half of the year in 2014, China's domestic oil consumption demand has broken through 4.9 hundred million tons, 5.56 hundred million tons will be reached to the end of the year 2014, expect the year two thousand twenty and will break through 7.5 hundred million tons, even up to will break through 800,000,000 tons, the external dependence degree of CNPC the most constantly expands, 70% likely it is up to the year two thousand twenty, but, China's natural gas gross reserves is 39 tcms, coal gross reserves is 114,500,000,000 tons, therefore, popularization and application novel alcohol ether environment-friendly fuel is used as supplementing of petroleum resources, China is had very important strategic importance.
The one novel alcohol ether environment-friendly fuel formula that the present invention is aiming at above-mentioned oil natural resources shortage and proposes, uses finished fuels prepared by this formula, and good and cheap, function admirable, powerful, energy-conserving and environment-protective, burning is clean, not temperature influence.Below specific embodiment provided by the present invention and experimental result are carried out detailed and careful description.
Embodiment 1:
Choosing the clean aromatic hydrocarbons of high-quality 22%, molecular formula is: C10H14；Toluene 10%, molecular formula is: C7H8；Methanol 8%, chemical formula is: CH3OH；The tert-butyl alcohol 5%, molecular formula is: C4H10O；Isobutanol 4%, molecular formula is: C4H10O；Isopropanol 4%, molecular formula is: C3H8O, (CH3) 2CHOH；Benzyl alcohol 3%, molecular formula is: C7H8O；Ethanol 2%, chemical formula is: CH3CH2OH；Petroleum ether 6%, chemical formula is: C5H12 C6H14
C7H16；Ether 7%, molecular formula is: C4H10O；Diisopropyl ether 3%, molecular formula is: C6H14O；Isobutyltrimethylmethane. 5%, chemical formula is: (CH3) 2CHCH2C (CH3) 3；Dimethoxymethane 3%, molecular formula is: C3H8O2；3-dihydroxy butane 2%, molecular structure: oxygen atom forms σ key with sp3 hybrid orbital, carbon atom forms σ key with sp3 hybrid orbital；Octane 3%, molecular formula is: C8H18, CH3 (CH2) 6CH3；Diethyl carbonate 2%, molecular formula is: C5H10O3；2-ethylenedioxy ethyl acetate 2%, molecular formula is: C8H16O4；Dibutyl phosphite 2%, chemical formula is: C8H19O3P；Ethyl acetate 3%, chemical formula is: C4H8O2；Second acetone 2%, chemical formula is: C5H8O2；501 antioxidant 0.5%, molecular formula is: C15H24O；Di-t-butyl 1.1%, molecular formula is: C8H18O2；Corrosion inhibitor 0.4%, molecular formula is: C6H13N；It is contained in respective hermetic container standby respectively.First above-mentioned methanol, the tert-butyl alcohol, isobutanol, isopropanol, benzyl alcohol and the ethanol chosen is mixed after a；Again petroleum ether, ether, diisopropyl ether, isobutyltrimethylmethane., dimethoxymethane, 3-dihydroxy butane and octane are mixed to obtain b；Then diethyl carbonate, 2-ethylenedioxy ethyl acetate, dibutyl phosphite, ethyl acetate, second acetone, 501 antioxidant, di-t-butyl and corrosion inhibitor are mixed to obtain c；And then a and b is mixed homogeneously with aromatic hydrocarbons and toluene obtain d again；The most again d with c is mixed homogeneously and obtain finished product novel alcohol ether environment-friendly fuel.
Experimental result (1), novel for the finished product prepared alcohol ether environment-friendly fuel 50 liters is joined in the fuel tank of Chang'an CX30 car 1.6 discharge capacity, when travelling 592 kilometers (turn on the aircondition 50%) on a highway, average every liter travels 11.84 kilometers, every 100 kilometers of oil consumptions 8.44 liters；
Experimental result (2), the 93# merchantable gasoline 50 liters (middle petrochemical industry) on existing market is added with the car of discharge capacity with same car, same fastlink travels (turn on the aircondition 50%), its distance travelled is 560 kilometers, average every liter travels 11.2 kilometers, every 100 kilometers of oil consumptions 8.93 liters, average every liter of finished product novel alcohol ether environment-friendly fuel saves 0.49 liter than the many travelings of 93# merchantable gasoline 0.64 kilometer on existing market, 100 kilometers of oil consumptions than 93# merchantable gasoline.
Embodiment 2:
Choosing the clean aromatic hydrocarbons of high-quality 22%, molecular formula is: C10H14；Toluene 10%, molecular formula is: C7H8；Methanol 8%, chemical formula is: CH3OH；The tert-butyl alcohol 5%, molecular formula is: C4H10O；Isobutanol 4%, molecular formula is: C4H10O；Isopropanol 4%, molecular formula is: C3H8O, (CH3) 2CHOH；Benzyl alcohol 3%, molecular formula is: C7H8O；Ethanol 2%, chemical formula is: CH3CH2OH；Petroleum ether 6%, chemical formula is: C5H12 C6H14
C7H16；Ether 7%, molecular formula is: C4H10O；Diisopropyl ether 3%, molecular formula is: C6H14O；Isobutyltrimethylmethane. 5%, chemical formula is: (CH3) 2CHCH2C (CH3) 3；Dimethoxymethane 3%, molecular formula is: C3H8O2；3-dihydroxy butane 2%, molecular structure: oxygen atom forms σ key with sp3 hybrid orbital, carbon atom forms σ key with sp3 hybrid orbital；Octane 3%, molecular formula is: C8H18, CH3 (CH2) 6CH3；Diethyl carbonate 2%, molecular formula is: C5H10O3；2-ethylenedioxy ethyl acetate 2%, molecular formula is: C8H16O4；Dibutyl phosphite 2%, chemical formula is: C8H19O3P；Ethyl acetate 3%, chemical formula is: C4H8O2；Second acetone 2%, chemical formula is: C5H8O2；501 antioxidant 0.5%, molecular formula is: C15H24O；Di-t-butyl 1.1%, molecular formula is: C8H18O2；Corrosion inhibitor 0.4%, molecular formula is: C6H13N；It is contained in respective hermetic container standby respectively.First above-mentioned methanol, the tert-butyl alcohol, isobutanol, isopropanol, benzyl alcohol and the ethanol chosen is mixed after a；Again petroleum ether, ether, diisopropyl ether, isobutyltrimethylmethane., dimethoxymethane, 3-dihydroxy butane and octane are mixed to obtain b；Then diethyl carbonate, 2-ethylenedioxy ethyl acetate, dibutyl phosphite, ethyl acetate, second acetone, 501 antioxidant, di-t-butyl and corrosion inhibitor are mixed to obtain c；And then a and b is mixed homogeneously with aromatic hydrocarbons and toluene obtain d again；The most again d with c is mixed homogeneously and obtain finished product novel alcohol ether environment-friendly fuel.
Experimental result (1), novel for the finished product prepared alcohol ether environment-friendly fuel 50 liters is joined in the fuel tank of Cadillac SRX3.0 discharge capacity, when travelling 361 kilometers (turning on the aircondition) on a highway, average every liter travels 7.22 kilometers, every 100 kilometers of oil consumptions 13.85 liters；
Experimental result (2), the 97# merchantable gasoline 50 liters (middle petrochemical industry shell fuel oil) on existing market is added with the car of discharge capacity with same car, same fastlink travels (turn on the aircondition 50%), its distance travelled is 348 kilometers, average every liter travels 6.96 kilometers, every 100 kilometers of oil consumptions 14.36 liters, and this finished product novel alcohol ether environment-friendly fuel is every 100 kilometers of fuel-economizings 0.56 liter than shell fuel oil.
Embodiment 3:
Choosing the clean aromatic hydrocarbons of high-quality 22%, molecular formula is: C10H14；Toluene 10%, molecular formula is: C7H8；Methanol 8%, chemical formula is: CH3OH；The tert-butyl alcohol 5%, molecular formula is: C4H10O；Isobutanol 4%, molecular formula is: C4H10O；Isopropanol 4%, molecular formula is: C3H8O, (CH3) 2CHOH；Benzyl alcohol 3%, molecular formula is: C7H8O；Ethanol 2%, chemical formula is: CH3CH2OH；Petroleum ether 6%, chemical formula is: C5H12 C6H14
C7H16；Ether 7%, molecular formula is: C4H10O；Diisopropyl ether 3%, molecular formula is: C6H14O；Isobutyltrimethylmethane. 5%, chemical formula is: (CH3) 2CHCH2C (CH3) 3；Dimethoxymethane 3%, molecular formula is: C3H8O2；3-dihydroxy butane 2%, molecular structure: oxygen atom forms σ key with sp3 hybrid orbital, carbon atom forms σ key with sp3 hybrid orbital；Octane 3%, molecular formula is: C8H18, CH3 (CH2) 6CH3；Diethyl carbonate 2%, molecular formula is: C5H10O3；2-ethylenedioxy ethyl acetate 2%, molecular formula is: C8H16O4；Dibutyl phosphite 2%, chemical formula is: C8H19O3P；Ethyl acetate 3%, chemical formula is: C4H8O2；Second acetone 2%, chemical formula is: C5H8O2；501 antioxidant 0.5%, molecular formula is: C15H24O；Di-t-butyl 1.1%, molecular formula is: C8H18O2；Corrosion inhibitor 0.4%, molecular formula is: C6H13N；It is contained in respective hermetic container standby respectively.First above-mentioned methanol, the tert-butyl alcohol, isobutanol, isopropanol, benzyl alcohol and the ethanol chosen is mixed after a；Again petroleum ether, ether, diisopropyl ether, isobutyltrimethylmethane., dimethoxymethane, 3-dihydroxy butane and octane are mixed to obtain b；Then diethyl carbonate, 2-ethylenedioxy ethyl acetate, dibutyl phosphite, ethyl acetate, second acetone, 501 antioxidant, di-t-butyl and corrosion inhibitor are mixed to obtain c；And then a and b is mixed homogeneously with aromatic hydrocarbons and toluene obtain d again；The most again d with c is mixed homogeneously and obtain finished product novel alcohol ether environment-friendly fuel.
Experimental result (1), novel for the finished product prepared alcohol ether environment-friendly fuel 50 liters is joined in the fuel tank of Buick SCM7242ATA car 2.4 discharge capacity, when travelling 472 kilometers (turn on the aircondition 50%) on a highway, average every liter travels 9.44 kilometers, every 100 kilometers of oil consumptions 10.59 liters；
Experimental result (2), the 93# merchantable gasoline 50 liters (middle petrochemical industry) on existing market is added with the car of discharge capacity with same car, same fastlink travels (turn on the aircondition 50%), its distance travelled is 446 kilometers, average every liter travels 8.92 kilometers, every 100 kilometers of oil consumptions 11.2 liters, average every liter of finished product novel alcohol ether environment-friendly fuel saves 0.61 liter than the many travelings of 93# merchantable gasoline 0.52 kilometer on existing market, 100 kilometers of oil consumptions than 93# merchantable gasoline.
Embodiment 4:
Choosing the clean aromatic hydrocarbons of high-quality 22%, molecular formula is: C10H14；Toluene 10%, molecular formula is: C7H8；Methanol 8%, chemical formula is: CH3OH；The tert-butyl alcohol 5%, molecular formula is: C4H10O；Isobutanol 4%, molecular formula is: C4H10O；Isopropanol 4%, molecular formula is: C3H8O, (CH3) 2CHOH；Benzyl alcohol 3%, molecular formula is: C7H8O；Ethanol 2%, chemical formula is: CH3CH2OH；Petroleum ether 6%, chemical formula is: C5H12 C6H14
C7H16；Ether 7%, molecular formula is: C4H10O；Diisopropyl ether 3%, molecular formula is: C6H14O；Isobutyltrimethylmethane. 5%, chemical formula is: (CH3) 2CHCH2C (CH3) 3；Dimethoxymethane 3%, molecular formula is: C3H8O2；3-dihydroxy butane 2%, molecular structure: oxygen atom forms σ key with sp3 hybrid orbital, carbon atom forms σ key with sp3 hybrid orbital；Octane 3%, molecular formula is: C8H18, CH3 (CH2) 6CH3；Diethyl carbonate 2%, molecular formula is: C5H10O3；2-ethylenedioxy ethyl acetate 2%, molecular formula is: C8H16O4；Dibutyl phosphite 2%, chemical formula is: C8H19O3P；Ethyl acetate 3%, chemical formula is: C4H8O2；Second acetone 2%, chemical formula is: C5H8O2；501 antioxidant 0.5%, molecular formula is: C15H24O；Di-t-butyl 1.1%, molecular formula is: C8H18O2；Corrosion inhibitor 0.4%, molecular formula is: C6H13N；It is contained in respective hermetic container standby respectively.First above-mentioned methanol, the tert-butyl alcohol, isobutanol, isopropanol, benzyl alcohol and the ethanol chosen is mixed after a；Again petroleum ether, ether, diisopropyl ether, isobutyltrimethylmethane., dimethoxymethane, 3-dihydroxy butane and octane are mixed to obtain b；Then diethyl carbonate, 2-ethylenedioxy ethyl acetate, dibutyl phosphite, ethyl acetate, second acetone, 501 antioxidant, di-t-butyl and corrosion inhibitor are mixed to obtain c；And then a and b is mixed homogeneously with aromatic hydrocarbons and toluene obtain d again；The most again d with c is mixed homogeneously and obtain finished product novel alcohol ether environment-friendly fuel.
Experimental result (1), novel for the finished product prepared alcohol ether environment-friendly fuel 50 liters is joined in the fuel tank of import benz S350L car 3.5 discharge capacity, travel 305 kilometers (turning on the aircondition) on a highway, average every liter travels 6.1 kilometers, every 100 kilometers of oil consumptions 16.39 liters；
Experimental result (2), the 97# merchantable gasoline 50 liters (middle petrochemical industry) on existing market is added with the car of discharge capacity with same car, same fastlink travels (turning on the aircondition), its distance travelled is 290 kilometers, average every liter travels 5.8 kilometers, every 100 kilometers of oil consumptions 17.24 liters, average every liter of finished product novel alcohol ether environment-friendly fuel saves 0.85 liter than the many travelings of 97# merchantable gasoline 0.3 kilometer on existing market, 100 kilometers of oil consumptions than 97# merchantable gasoline.
Claims (2)
1. a novel alcohol ether environment-friendly fuel, it is characterised in that each component of described fuel and mass parts ratio thereof are as follows:
Aromatic hydrocarbons
1 part, molecular formula is: C10H14；
Toluene
1 part, molecular formula is: C7H8；
Methanol
1 part, chemical formula is: CH3OH；
The tert-butyl alcohol
1 part, molecular formula is: C4H10O；
Isobutanol
1 part, molecular formula is: C4H10O；
Isopropanol
1 part, molecular formula is: C3H8O, (CH3) 2CHOH；
Benzyl alcohol
1 part, molecular formula is: C7H8O；
Ethanol
1 part, chemical formula is: CH3CH2OH；
Petroleum ether
1 part, chemical formula is: C5H12 C6H14 C7H16；
Ether
1 part, molecular formula is: C4H10O；
Diisopropyl ether
1 part, molecular formula is: C6H14O；
Isobutyltrimethylmethane.
1 part, chemical formula is: (CH3) 2CHCH2C (CH3) 3；
Dimethoxymethane
1 part, molecular formula is: C3H8O2；
3-dihydroxy butane 1 part, molecular structure: oxygen atom forms σ key with sp3 hybrid orbital, carbon atom forms σ key with sp3 hybrid orbital；
Octane
1 part, molecular formula is: C8H18, CH3 (CH2) 6CH3；
Diethyl carbonate
1 part, molecular formula is: C5H10O3；
2-ethylenedioxy ethyl acetate 1 part, molecular formula is: C8H16O4；
Dibutyl phosphite
1 part, chemical formula is: C8H19O3P；
Ethyl acetate
1 part, chemical formula is: C4H8O2；
Second acetone
1 part, chemical formula is: C5H8O2；
501 1 part of antioxidant, molecular formula is: C15H24O；
Di-t-butyl
1 part, molecular formula is: C8H18O2；
Corrosion inhibitor
1 part, molecular formula is: C6H13N.
The preparation method of novel alcohol ether environment-friendly fuel the most according to claim 1, it is characterised in that described method comprises the steps:
A, choosing the clean aromatic hydrocarbons of high-quality 22%, molecular formula is: C10H14；Toluene 10%, molecular formula is: C7H8；Methanol 8%, chemical formula is: CH3OH；The tert-butyl alcohol 5%, molecular formula is: C4H10O；Isobutanol 4%, molecular formula is: C4H10O；Isopropanol 4%, molecular formula is: C3H8O, (CH3) 2CHOH；Benzyl alcohol 3%, molecular formula is: C7H8O；Ethanol 2%, chemical formula is: CH3CH2OH；Petroleum ether 6%, chemical formula is: C5H12 C6H14 C7H16；Ether 7%, molecular formula is: C4H10O；Diisopropyl ether 3%, molecular formula is: C6H14O；Isobutyltrimethylmethane. 5%, chemical formula is: (CH3) 2CHCH2C (CH3) 3；Dimethoxymethane 3%, molecular formula is: C3H8O2；3-dihydroxy butane 2%, molecular structure: oxygen atom forms σ key with sp3 hybrid orbital, carbon atom forms σ key with sp3 hybrid orbital；Octane 3%, molecular formula is: C8H18, CH3 (CH2) 6CH3；Diethyl carbonate 2%, molecular formula is: C5H10O3；2-ethylenedioxy ethyl acetate 2%, molecular formula is: C8H16O4；Dibutyl phosphite 2%, chemical formula is: C8H19O3P；Ethyl acetate 3%, chemical formula is: C4H8O2；Second acetone 2%, chemical formula is: C5H8O2；501 antioxidant 0.5%, molecular formula is: C15H24O；Di-t-butyl 1.1%, molecular formula is: C8H18O2；Corrosion inhibitor 0.4%, molecular formula is: C6H13N；It is contained in respective hermetic container standby respectively；
B, first above-mentioned methanol, the tert-butyl alcohol, isobutanol, isopropanol, benzyl alcohol and the ethanol chosen is mixed after a；Again petroleum ether, ether, diisopropyl ether, isobutyltrimethylmethane., dimethoxymethane, 3-dihydroxy butane and octane are mixed to obtain b；Then diethyl carbonate, 2-ethylenedioxy ethyl acetate, dibutyl phosphite, ethyl acetate, second acetone, 501 antioxidant, di-t-butyl and corrosion inhibitor are mixed to obtain c；And then a and b is mixed homogeneously with aromatic hydrocarbons and toluene obtain d again；The most again d with c is mixed homogeneously and obtain finished product novel alcohol ether environment-friendly fuel.
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| CN109135851A (en) * | 2018-10-08 | 2019-01-04 | 张文涛 | A kind of additive for automobile exhaust detergent |
| CN109913279A (en) * | 2019-04-08 | 2019-06-21 | 安徽律正科技信息服务有限公司 | A kind of low pollution new energy gasoline |
| CN111925842A (en) * | 2020-07-27 | 2020-11-13 | 普利莱（天津）燃气设备有限公司 | Formula and preparation method of methyl ethanol gasoline |
| CN113088346A (en) * | 2021-03-29 | 2021-07-09 | 叁久国际新能源科技有限公司 | Methanol fuel |
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