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CN105542550A - Environment-friendly cleaning agent for superficial paint on metal surface - Google Patents

Environment-friendly cleaning agent for superficial paint on metal surface Download PDF

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Publication number
CN105542550A
CN105542550A CN201511023381.6A CN201511023381A CN105542550A CN 105542550 A CN105542550 A CN 105542550A CN 201511023381 A CN201511023381 A CN 201511023381A CN 105542550 A CN105542550 A CN 105542550A
Authority
CN
China
Prior art keywords
isoparaffin
environment
metal surface
limonene
paint
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201511023381.6A
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Chinese (zh)
Other versions
CN105542550B (en
Inventor
肖海燕
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHANGSHA AISEN EQUIPMENT MAINTENANCE TECHNOLOGY Co Ltd
Original Assignee
CHANGSHA AISEN EQUIPMENT MAINTENANCE TECHNOLOGY Co Ltd
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Publication date
Application filed by CHANGSHA AISEN EQUIPMENT MAINTENANCE TECHNOLOGY Co Ltd filed Critical CHANGSHA AISEN EQUIPMENT MAINTENANCE TECHNOLOGY Co Ltd
Priority to CN201511023381.6A priority Critical patent/CN105542550B/en
Publication of CN105542550A publication Critical patent/CN105542550A/en
Application granted granted Critical
Publication of CN105542550B publication Critical patent/CN105542550B/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D9/00Chemical paint or ink removers
    • C09D9/005Chemical paint or ink removers containing organic solvents

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses an environment-friendly cleaning agent for the superficial paint on the metal surface. The cleaning agent is prepared from isoparaffin of C10-C12, organic ester compounds and plant extracted limonene. The cleaning agent can be used for effectively removing residual superficial paint, does not destroy a sprayed paint coat, does not hurt human bodies or influence the environment, and is suitable for most working situations.

Description

A kind of environment-friendly type metal surface floating paint clean-out system
Technical field
The invention provides a kind of environment-friendly type metal surface floating paint clean-out system, belong to cleaning technique field, metallic surface.
Background technology
Paint is that one firmly can cover object surface, play protection, decoration, mark and the chemical mixture coating of other special purposes.
At modern science and technology and industrial circle, the application of paint is more and more extensive.Due to the misoperation in construction process, often cause the situations such as overbrushing, holiday, by mistake painting and need again to do over again and be coated with again.Both add time cost like this, cause again the waste of material.
The clean-out system of the removal paint that existing market mainly uses mainly adopts toluene, dimethylbenzene, lacquer thinner, methylene dichloride, acetone, phenol etc., these clean-out systems not only have injury to human body, easily carcinogenic, easily cause occupational illness, and these rinse product can not carry out selective clearing to floating paint, the paint coated is produced to the shortcomings such as destruction.
Summary of the invention
For the defect that existing paint-removing class rinse product exists, the object of the invention is to be to provide a kind of effectively can remove unnecessary floating paint while do not damage the enamelled coating sprayed, and to human body without harm, on the environment-friendly type metal surface floating paint clean-out system of environment without impact.
In order to realize above-mentioned technical purpose, the invention provides a kind of environment-friendly type metal surface floating paint clean-out system, this clean-out system is made up of following mass percent component: C 10~ C 12isoparaffin 60 ~ 90%; Organic esters 5 ~ 30%; Plant extract type limonene 5 ~ 30%.
Preferred scheme, C 10~ C 12isoparaffin is by C 10isoparaffin, C 11isoparaffin and C 12isoparaffin is 1:(1 ~ 4 in mass ratio): 1 composition.Preferred scheme adopts C 10, C 11and C 12mixed type isoparaffin, C 10isoparaffin has good evaporation rate, can improve the evaporation rate of clean-out system, but its flash-point is lower, and C 12isoparaffin has higher flash-point, but its evaporation rate is relatively slow, and C 11isoparaffin between, therefore adopts this mixture system, to reach the effect that volatilization is fast, flash-point is high; It is that normal paraffin can not be compared that isoparaffin has the advantages such as low smell and high flash point, so C 10~ C 12isoparaffin has not replaceability.
Preferred scheme, organic esters is at least one in tert.-butyl acetate, sec-butyl acetate, methylcarbonate, o-phthalic acid dibutyl ester and synthesis vegetable esters.
Preferred scheme, comprises at least one in 1,8-terpadiene, d-limonene and l-limonene in plant extract type limonene.
C of the present invention 10~ C 12isoparaffin, comprises C 10isoparaffin, C 11isoparaffin and C 12isoparaffins etc. can directly be bought in the company such as american exxon, Japanese bright dipping; Organic esters, comprise tert.-butyl acetate, sec-butyl acetate, methylcarbonate, o-phthalic acid dibutyl ester and synthesis vegetable esters etc. can directly buy in the happy chemical industry of Jin Jin, bright morning the company such as chemical industry; Plant extract type limonene directly can be bought and contain chemical industry in Jiangxi state, the companies such as chemical industry are converged in Guangzhou.
Metallic surface of the present invention floating paint clean-out system preparation method: add reactor by formula rate, stir under the condition of normal temperature and pressure.
The using method of paint clean-out system is floated in metallic surface of the present invention:
(1) method of soaking and washing: directly workpiece to be washed is dipped into inside this solution and takes out after 10 ~ 30 minutes, dry with clean scouring pad, dry up or naturally dry afterwards;
(2) scrub method: dip this clean-out system with cleaning means such as brushes, then to needing the floating paint part removed to scrub, to be removed clean after, dry with clean scouring pad, dry up or naturally dry;
(3) hydro-peening method: this product is sprayed on professional 161# spray gun or other spray instrument the position needing cleaning, dried with clean scouring pad, dry up or naturally dry after 10 ~ 30 minutes.
Hinge structure, the Advantageous Effects that technical scheme of the present invention is brought:
1, the raw material adopted in cleaning agent formula of the present invention is by low toxicity or nontoxic raw material is composite forms, and to producing and using the body-stimulating of operator little, also has no adverse effects to environment;
2, can effectively select to remove unnecessary floating paint, and to the lacquer painting not damaged sprayed.
3, rinse product of the present invention has low smell, volatilization is fast, flash-point is high feature, is applicable to most operating mode.
Embodiment
Following examples are intended to further illustrate content of the present invention, instead of the protection domain of restriction the claims in the present invention.
Rinse product in following examples and comparative example, adds reactor by its formula rate by various raw material, stirs under the condition of normal temperature and pressure.
Rinse product in each embodiment and comparative example adopts the conventional method of scrubbing to carry out product performance checking: dip this clean-out system with cleaning means such as brushes, again to needing the floating paint part removed to scrub, to be removed clean after dry with clean scouring pad, dry up or naturally dry.
Embodiment 1
Formula 1:
C 10isoparaffin 20%; C 11isoparaffin 20%; C 12isoparaffin 20%; Tert.-butyl acetate 7.5%; Methylcarbonate 7.5%; Synthesis vegetable esters 10%; D-limonene 15%.
Formula 2:
C 10h 22isoparaffin 15%; C 11h 24isoparaffin 60%; C 12h 26isoparaffin 15%; Tert.-butyl acetate 1.5%; Sec-butyl acetate 1.5%; Synthesis vegetable esters 2%; L-limonene 5%.
Comparative example 1
Formula 3:
C 10h 22isoparaffin 60%; C 11h 24isoparaffin 15%; C 12h 26isoparaffin 15%; Tert.-butyl acetate 1.5%; Sec-butyl acetate 1.5%; Synthesis vegetable esters 2%; L-limonene 5%.
Formula 4:
C 10h 22isoparaffin 15%; C 11h 24isoparaffin 15%; C 12h 26isoparaffin 60%; Tert.-butyl acetate 1.5%; Sec-butyl acetate 1.5%; Synthesis vegetable esters 2%; L-limonene 5%.
Formula 5:
C 10h 22isoparaffin 15%; C 11h 24isoparaffin 15%; C 12h 26isoparaffin 60%; L-limonene 10%.
Formula 6
Tert.-butyl acetate 25%; Sec-butyl acetate 25%; Synthesis vegetable esters 20%; L-limonene 30%.
Table 1: the performance comparison table of each formula and acetone, methylene dichloride in embodiment 1 and contrast enforcement 1:
Only have formula 1 and formula 2 all to meet the requirements of clean-out system for indices as can be seen from the table, meet application requiring.

Claims (4)

1. an environment-friendly type metal surface floating paint clean-out system, is characterized in that: be made up of following mass percent component:
C 10~ C 12isoparaffin 60 ~ 90%;
Organic esters 5 ~ 30%;
Plant extract type limonene 5 ~ 30%.
2. environment-friendly type metal surface according to claim 1 floating paint clean-out system, is characterized in that: described C 10~ C 12isoparaffin is by C 10isoparaffin, C 11isoparaffin and C 12isoparaffin is 1:(1 ~ 4 in mass ratio): 1 composition.
3. environment-friendly type metal surface according to claim 1 floating paint clean-out system, is characterized in that: described organic esters is at least one in tert.-butyl acetate, sec-butyl acetate, methylcarbonate, o-phthalic acid dibutyl ester and synthesis vegetable esters.
4. environment-friendly type metal surface according to claim 1 floating paint clean-out system, is characterized in that: comprise at least one in 1,8-terpadiene, d-limonene and l-limonene in described plant extract type limonene.
CN201511023381.6A 2015-12-31 2015-12-31 A kind of environment-friendly type metal surface floats paint cleaning agent Active CN105542550B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201511023381.6A CN105542550B (en) 2015-12-31 2015-12-31 A kind of environment-friendly type metal surface floats paint cleaning agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201511023381.6A CN105542550B (en) 2015-12-31 2015-12-31 A kind of environment-friendly type metal surface floats paint cleaning agent

Publications (2)

Publication Number Publication Date
CN105542550A true CN105542550A (en) 2016-05-04
CN105542550B CN105542550B (en) 2018-06-29

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109762679A (en) * 2019-03-07 2019-05-17 中山市浩科化工科技有限公司 A kind of high-purity agent for carbon hydrogen detergent of environment-friendly type and preparation method thereof
CN113875752A (en) * 2021-10-20 2022-01-04 西北农林科技大学 Application of limonene in preparation of plant resistance inducer

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1487737A (en) * 1973-11-05 1977-10-05 Nat Res Dev Paint removers
CN101225350A (en) * 2007-12-21 2008-07-23 中航材航空新材料有限公司 Solvent type environment protection cleaning agent and preparation method thereof
CN101591590A (en) * 2008-05-28 2009-12-02 天津市华阳新兴科技有限公司 A kind of environmental protection and safety type hydrocarbon cleaning agent
CN102191141A (en) * 2010-03-17 2011-09-21 东莞市新球防锈有限公司 Modified hydrocarbon cleaning agent
CN103468434A (en) * 2013-09-17 2013-12-25 华阳新兴科技(天津)集团有限公司 Environment-friendly safe solvent cleaning agent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1487737A (en) * 1973-11-05 1977-10-05 Nat Res Dev Paint removers
CN101225350A (en) * 2007-12-21 2008-07-23 中航材航空新材料有限公司 Solvent type environment protection cleaning agent and preparation method thereof
CN101591590A (en) * 2008-05-28 2009-12-02 天津市华阳新兴科技有限公司 A kind of environmental protection and safety type hydrocarbon cleaning agent
CN102191141A (en) * 2010-03-17 2011-09-21 东莞市新球防锈有限公司 Modified hydrocarbon cleaning agent
CN103468434A (en) * 2013-09-17 2013-12-25 华阳新兴科技(天津)集团有限公司 Environment-friendly safe solvent cleaning agent

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109762679A (en) * 2019-03-07 2019-05-17 中山市浩科化工科技有限公司 A kind of high-purity agent for carbon hydrogen detergent of environment-friendly type and preparation method thereof
CN113875752A (en) * 2021-10-20 2022-01-04 西北农林科技大学 Application of limonene in preparation of plant resistance inducer

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