CN105532657B - It is a kind of for Herbicidal combinations of monocot crops and application thereof - Google Patents
It is a kind of for Herbicidal combinations of monocot crops and application thereof Download PDFInfo
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- CN105532657B CN105532657B CN201511033695.4A CN201511033695A CN105532657B CN 105532657 B CN105532657 B CN 105532657B CN 201511033695 A CN201511033695 A CN 201511033695A CN 105532657 B CN105532657 B CN 105532657B
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- herbicidal combinations
- agent
- monocot crops
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
- A01N41/06—Sulfonic acid amides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
It is a kind of for Herbicidal combinations of monocot crops and application thereof, comprising component A and component B as active ingredient, component A：Detoxify effective quantity：2,2 dimethyl N [(4 aminomethyl phenyl) sulfonyl] 5 (methyl) 3 oxazolidine formamide；Component B：Including chlorine sulphur is grand, one kind in chlorimuronethyl, imazethapyr or fomesafen.Wherein the weight ratio comprising a effective amount of component A and B is 18: 2.Pharmaceutical dosage form is wettable powder, missible oil, suspending agent, water dispersible granular or seed coat agent; the Herbicidal combinations of the present invention are applied to monocot crops field; drug effect is not only increased compared to single agent; expand herbicide controlling spectrum; it can also delay the generation of herbicide resistance; all there is safety for working as stubble and succession crop, be not easy to bring secondary poisoning, can effectively prevent herbicide damage.The performance of the herbicidal composition of the present invention is significantly more than routine techniques level.
Description
Technical field
The present invention relates to a kind of for Herbicidal combinations of monocot crops and application thereof.
Background technology
The herbicide of substantial amounts provides strong guarantee for the modernization development of agricultural, effectively inhibits the danger of weeds
Evil, significantly improves farmland grain yield, and bringing huge economic benefit for world agriculture industry increases.But herbicide exists
Some problems are encountered in its application process, most prominent is its herbicide carryover and resistance weed problem.Some are removed
Careless agent also has stronger killing ability to crop, and dispenser is easily to crop generation poisoning during plant growth.Some herbicides
Residual in use can generate inhibition to the growth of second stubble crop, cause secondary poisoning.Part pesticide is in normal use
Can also poisoning be generated to crop, gently then influence yield under concentration, it is heavy then crop is caused disease even death occur.Herbicide it is big
Amount and Reusability also result in the generation of resistant weed, become increasingly difficult weeding process.
It prevents crop from being had water spray, top dressing of loosening the soil, place to go poisoning position etc. by the method for herbicide damage, but prevents medicine
Harmful effect is limited.Safener is generally added in industry at present to improve herbicide safety, expansion herbicide controlling spectrum, improve weeds
Control effect.The control of use chemical method and the relevant weeds of crop plants of safener selectivity, make non-selective remove
Careless agent can selectivity control farmland weed, first crop residual long residual herbicides are to the residual medicine of crop in antagonism crop rotation systems
Evil.Since being found from safener, safener has played important function in agricultural production, it goes profit from a new angle
With the use with the existing commercial herbicide of extension.Safener research is an important branch of herbicide research, is had wide
Development prospect and development and application market.But variety development and study on mechanism of the China in relation to safener are still in a step
Section.
Invention content
Be based on more than shortcoming, the object of the present invention is to provide a kind of Herbicidal combinations for monocot crops and its
Purposes can not cause to damage while controlling weeds to working as stubble and second stubble crop.
Herbicidal combinations of the present invention take following technical scheme to realize：A kind of Herbicidal combinations for monocot crops,
Comprising component A and component B as active ingredient,
Component A：Detoxify a effective amount of Formulas I：
2,2- dimethyl-N -s [(4- aminomethyl phenyls) sulfonyl] -5- (methyl) -3- oxazolidine formamides
Component B：Including chlorine sulphur is grand, one kind in chlorimuronethyl, imazethapyr or fomesafen.
Wherein the weight ratio comprising a effective amount of component A and B is 1-8: 2.
The present invention also has following technical characteristic：
1st, a kind of Herbicidal combinations for monocot crops, which is characterized in that include Herbicidal combinations as described above
And adjuvant component C, wherein the weight ratio comprising a effective amount of component A, B, C is 1-8: 2: 3-6.
2nd, auxiliary agent as described above include carrier, surfactant, dispersant, thickener, thixotropic agent, stabilizer, film forming agent,
The combination of one or more of colorant and polymer.
3rd, the dosage form of composition as described above is wettable powder, missible oil, suspending agent, water dispersible granular or seed coat agent.
It, will be as above described in any one the present invention also provides a kind of for preventing the method for noxious plant in useful plant
Herbicidal combinations be applied to the region of plant, undesired plant growth.
1st, method as described above is used to plant in unifacial leaf plant and prevents noxious plant.
2nd, method as described above is used to prevent noxious plant in maize planting.
The present invention has the advantages that compared with prior art：
The Herbicidal combinations of the present invention are applied to monocot crops field, not only increase drug effect compared to single agent, expand
Herbicide controlling spectrum can also delay the generation of herbicide resistance, all have safety for working as stubble and succession crop, be not easy to bring secondary
Poisoning can effectively prevent herbicide damage.The performance of the herbicidal composition of the present invention is significantly more than routine techniques level.
Specific embodiment
Embodiment 1
A kind of Herbicidal combinations for monocot crops, comprising component A and component B as active ingredient,
Component A：Detoxify a effective amount of Formulas I：
2,2- dimethyl-N -s [(4- aminomethyl phenyls) sulfonyl] -5- (methyl) -3- oxazolidine formamides
Component B：Including chlorine sulphur is grand, one kind in chlorimuronethyl, imazethapyr or fomesafen.
Wherein the weight ratio comprising a effective amount of component A and B is 1-8: 2.
Embodiment 2
A kind of Herbicidal combinations for monocot crops include a effective amount of Formulas I safener A, the herbicidally effective amount B of detoxifying
With auxiliary agent C, wherein the weight ratio comprising a effective amount of component A, B, C be 1-8: 2: 3-6.
A) detoxify a effective amount of Formulas I safener：2,2- dimethyl-N -s [(4- aminomethyl phenyls) sulfonyl] -5- (methyl) -3-
Oxazolidine formamide
B) herbicidally effective amount, including chlorine sulphur is grand, one kind in chlorimuronethyl, imazethapyr and fomesafen.
C) auxiliary agent, it is characterised in that include carrier, surfactant, dispersant, thickener, thixotropic agent, stabilizer, film forming
It is one or more in agent, colorant and polymer.
The weight ratio of described component A, B, C are 1-8: 2: 3-6.
The component C auxiliary agents used in the present invention include carrier, surfactant, dispersant, thickener, thixotropic agent, stabilization
It is one or more in agent and polymer, it is common various composition in pesticide, and be not particularly limited, specific ingredient and dosage
It is determined by experiment according to recipe requirements.
Be suitble to prepare the present invention Herbicidal combinations liquid-carrier include water, alcohols (ethyl alcohol), aliphatic hydrocarbon (just oneself
Alkane), aromatic hydrocarbon (benzene, toluene, ethylbenzene), esters (ethyl acetate) etc..
The solid carrier for being suitble to the herbicidal composition of the present invention is diatomite, kaolin, gypsum, bentonite, clay, white
Carbon black, calcium carbonate, shuck powder, bark powder, corn ear powder etc..
Currently preferred dosage form is wettable powder, missible oil, suspending agent, water dispersible granular or seed coat agent.
For wettable powder, corresponding auxiliary agent can be used to complete the present invention for those skilled in the art.Workable auxiliary agent
Have：Alkylnaphthalene sulfonate, polycarboxylate, vegetable oil ethylene oxide adduct or aralkyl polyoxyethylene ether yuban sulphur
One or more of hydrochlorate is used as dispersant；In alkyl sulfate, lignosulfonates, saponin or sulfite cellulose
One or more are used as wetting agent；Diatomite or kaolin are as filler.
For missible oil, corresponding auxiliary agent can be used to complete the present invention for those skilled in the art.Workable auxiliary agent has：Phenol
The ethoxylated propoxylated object of derivative ethoxylate, phenol derivatives, calcium dodecyl benzene sulfonate, polyethers sulfate, benzene second
One or more of base phenol polyethenoxy ethers, ethoxylated castor oil are used as emulsifier.
For suspending agent, corresponding auxiliary agent can be used to complete the present invention for those skilled in the art.Workable auxiliary agent has：Alkane
Base naphthalene sulfonate, polycarboxylate, vegetable oil ethylene oxide adduct or aralkyl polyoxyethylene ether yuban sulfate
One or more of be used as dispersant；Castor oil polyoxyethylene ether, polyol fatty acid ester, alkylbenzenesulfonate or agriculture
Breast one or more of 2201 is used as emulsifier；In alkyl sulfate, lignosulfonates, saponin or sulfite cellulose
One or more as wetting agent；Gelatin, guar gum, Arabic gum, xanthans, aluminium-magnesium silicate, diatomite or carboxymethyl
One or more of sodium cellulosate is used as thickener；The defoaming of one or more of organic silicon or fatty acid
Agent；Glycerine is as antifreezing agent.
For water dispersible granular, alkylnaphthalene sulfonate, polycarboxylate, vegetable oil ethylene oxide adduct or aralkyl gather
One or more of ethylene oxide ether yuban sulfate is used as dispersant；Alkyl sulfate, lignosulfonates, soap
One or more of element or sulfite cellulose are used as wetting agent；Sodium chloride is as disintegrant；Diatomite or kaolin
As filler.For seed coat agent, corresponding auxiliary agent can be used to complete the present invention for those skilled in the art.Alkylnaphthalene sulfonate gathers
Carboxylate, vegetable oil ethylene oxide adduct are either a kind of or more in aralkyl polyoxyethylene ether yuban sulfate
Kind is as dispersant；In polyvinyl acetate emulsion, polyvinyl alcohol, polyacrylamide, polyethylene glycol series, polyvinylpyrrolidone
One or more as film forming agent；One or more of xanthans, sodium alginate, sodium carboxymethylcellulose are as increasing
Thick dose；Basic rhodamine is as colorant.
The Herbicidal combinations of the present invention can use in the region for cultivating following monocot crops：
Crops：Corn, wheat, onion, garlic, green onion etc..
In addition, the present invention can be very good the appearance of delaying drug resistance weeds.
The present invention also aims to provide a kind of weed control methods using above-mentioned Herbicidal combinations, including will be above-mentioned
Herbicidal combinations are applied to raise crop, undesired plant growth region.
Specifically, weed control methods of the invention are that the real area of herbicide need to be applied according to raise crop, with
And a situation arises for weeds, determines to need the dosage of Herbicidal combinations to be used, selects arbitrary dosage form and be diluted to a certain concentration,
Finally it is sprayed on arable farming region.Method of administration refers to any effective common method during the applications of pesticide, including but not limited to sprays
Powder method, spray-on process, fumigating system, soil treatment method etc..
The method of the present invention is most preferably for prevention arable farming region or will be used for the weeds in the region of arable farming.When
During for crop growing loci, amount of application answers enough controlling weeds but will not generate apparent damage, Ke Yiti to crop simultaneously
High crop yield and quality has important use value.
The method of administration such as the Herbicidal combinations of the present invention are suitable for but are not limited to before seedling, Miao Hou, seed soaking.
+ 25% chlorimuronethyl wettable powder of 3 25% safener of embodiment
Each component is mixed in proportion, to get to Herbicidal Compositions Wettable pulvis after ultra-fine pulverizer disintegrating.
+ 30% Fluosulfonamide oxalether cream of 4 20% safener of embodiment
Each component is mixed in proportion, is stirred evenly to get to Herbicidal combinations missible oil.
+ 20% grand seed coat agent of chlorine sulphur of 5 40% safener of embodiment
Each component is mixed in proportion and is ground to get to Herbicidal combinations seed coat agent.
+ 20% imazethapyr water dispersion granule of 6 30% safener of embodiment
Each component is mixed and crushed in proportion, after being soaked with water, extruder grain and drying, it is 2-6 millimeters that grain size, which is made,
Herbicidal combinations water dispersion granule.
+ 22% chlorimuronethyl wettable powder of 7 11% safener of embodiment
Each component is mixed in proportion, to get to Herbicidal Compositions Wettable pulvis after ultra-fine pulverizer disintegrating.
+ 34% Fluosulfonamide oxalether cream of 8 17% safener of embodiment
Each component is mixed in proportion, is stirred evenly to get to Herbicidal combinations missible oil.
+ 15% grand seed coat agent of chlorine sulphur of 8 61% safener of embodiment
Each component is mixed in proportion and is ground to get to Herbicidal combinations seed coat agent.
+ 12.5% imazethapyr water dispersion granule of 9 50% safener of embodiment
Each component is mixed and crushed in proportion, after being soaked with water, extruder grain and drying, it is 2-6 millimeters that grain size, which is made,
Herbicidal combinations water dispersion granule.
Embodiment 10
Biological activity test example
Before seedling is tested：
Under greenhouse experiment, using standard soil as cultivation matrix, test plant is seeded in seedling alms bowl (diameter 8cm, depth
In 12cm), it is covered with the soil that thickness is 0.5cm.In the before seedling stage, Herbicidal combinations are administered to soil surface.Dosage depends on
In optium concentration identified under greenhouse experiment.(100% effect=plant is completely dead for evaluation test after 2-4 weeks；0%
Effect=plant-less toxicity effect).The Herbicidal combinations used in this test show good result.
It is tested after seedling：
Herbicidal Testing Trials are carried out for different types of weeds
Test method：Dress 300g standard soils, stand after adding water, are sowed after 2 days in seedling alms bowl (diameter 8cm, deep 12cm)
Weed seed is simultaneously covered with 0.5cm soil, adds water plantation a period of time.When weed growth to 3-4 leaves, by Herbicidal combinations to spray
Mist form is administered on test weeds, and dosage depends on the identified optium concentration under greenhouse experiment.Evaluation test after 5 weeks
(100% effect=plant is completely dead；0% effect=plant-less toxicity effect).The Herbicidal combinations used in this test
Show good result.
Four kinds of reagents are prepared according to constant weight percentage：1. safener+chlorine sulphur is grand；2. safener+chlorimuronethyl；3. peace
Full agent+imazethapyr；4. safener+fomesafen.Above-mentioned each reagent is diluted with water after a certain period of time, respectively observation pair
Rice barnyard grass, moleplant seed, Monochoria vaginalis, angustifolia arrowhead herb, Procumbent Falsepimpernel, difformed galingale herb herbicidal effect.
Observation is to the herbicidal effect table of rice barnyard grass after handling 5 weeks
According to result of the test as can be seen that the Herbicidal combinations of present invention herbicidal effect in the case of low usage amount is bright
It is aobvious, there is good control effect to weeds.
Embodiment 11
To the safety effect of crop
Under greenhouse experiment, by trial crops, culture is to 4 leaf phases in seedling alms bowl (diameter 8cm, deep 12cm), by Herbicidal combination
Object is administered to Sprayable on test crop, and dosage depends on the identified optium concentration under greenhouse experiment.It is evaluated after 5 weeks
(100% effect=crop is completely dead for experiment；0% effect=without crop toxic effect).Concrete condition such as following table
According to result of the test as can be seen that the Herbicidal combinations of the present invention have crop good protecting effect, do not make
Into apparent poisoning.
Claims (7)
1. a kind of Herbicidal combinations for monocot crops, comprising component A and component B as active ingredient, it is characterised in that：
Component A：Detoxify a effective amount of Formulas I：
2,2- dimethyl-N -s [(4- aminomethyl phenyls) sulfonyl] -5- (methyl) -3- oxazolidine formamides
Component B：Including chlorine sulphur is grand, one kind in chlorimuronethyl, imazethapyr or fomesafen；
Wherein the weight ratio comprising a effective amount of component A and B is 1-8: 2.
2. a kind of Herbicidal combinations for monocot crops, which is characterized in that include Herbicidal combinations described in claim 1
And adjuvant component C, wherein the weight ratio comprising a effective amount of component A, B, C is 1-8: 2: 3-6.
A kind of 3. Herbicidal combinations for monocot crops according to claim 2, which is characterized in that the auxiliary agent packet
Containing one or more of carrier, surfactant, thickener, thixotropic agent, stabilizer, film forming agent, colorant and polymer group
It closes.
4. according to a kind of Herbicidal combinations for monocot crops of claims 1 or 2, which is characterized in that the composition
Dosage form be wettable powder, missible oil, suspending agent, water dispersible granular or seed coat agent.
A kind of 5. method for the prevention noxious plant in useful crop, which is characterized in that will be any according to claim 1-3
Described in Herbicidal combinations be applied to crop, undesired plant growth region.
6. according to the method described in claim 5, it, which is used to plant, prevents noxious plant in monocotyledon.
7. according to the method described in claim 5, it is used to prevent noxious plant in maize planting.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511033695.4A CN105532657B (en) | 2015-12-28 | 2015-12-28 | It is a kind of for Herbicidal combinations of monocot crops and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201511033695.4A CN105532657B (en) | 2015-12-28 | 2015-12-28 | It is a kind of for Herbicidal combinations of monocot crops and application thereof |
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| CN105532657A CN105532657A (en) | 2016-05-04 |
| CN105532657B true CN105532657B (en) | 2018-06-19 |
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| CN201511033695.4A Expired - Fee Related CN105532657B (en) | 2015-12-28 | 2015-12-28 | It is a kind of for Herbicidal combinations of monocot crops and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108184837B (en) * | 2017-12-20 | 2020-03-17 | 东北农业大学 | Herbicidal composition and use thereof |
| CN108935460B (en) * | 2018-07-10 | 2020-03-17 | 东北农业大学 | Weeding composition for preventing and controlling harmful weeds in corn growing area and application thereof |
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| CN1794911A (en) * | 2003-05-23 | 2006-06-28 | 拜尔作物科学股份公司 | New safeners and their application |
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